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CN103758329B - 具有防水胶的pvc自粘地板 - Google Patents

具有防水胶的pvc自粘地板 Download PDF

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CN103758329B
CN103758329B CN201310699234.5A CN201310699234A CN103758329B CN 103758329 B CN103758329 B CN 103758329B CN 201310699234 A CN201310699234 A CN 201310699234A CN 103758329 B CN103758329 B CN 103758329B
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marine glue
pvc
floor
self
glue
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CN103758329A (zh
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张小玲
肖志远
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Jiangsu bell Home Technology Co.,Ltd.
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JIANGSU BEIER DECORATION MATERIAL CO Ltd
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Priority to CN201310699234.5A priority Critical patent/CN103758329B/zh
Priority to EP14872742.3A priority patent/EP3085853B1/en
Priority to US15/104,984 priority patent/US9884980B2/en
Priority to CA2934376A priority patent/CA2934376C/en
Priority to PCT/CN2014/074799 priority patent/WO2015089957A1/zh
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    • C09J157/02—Copolymers of mineral oil hydrocarbons
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/0215—Flooring or floor layers composed of a number of similar elements specially adapted for being adhesively fixed to an underlayer; Fastening means therefor; Fixing by means of plastics materials hardening after application
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/06—Interconnection of layers permitting easy separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/0215—Flooring or floor layers composed of a number of similar elements specially adapted for being adhesively fixed to an underlayer; Fastening means therefor; Fixing by means of plastics materials hardening after application
    • E04F15/02155—Adhesive means specially adapted therefor, e.g. adhesive foils or strips
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
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    • E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/105—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials of organic plastics with or without reinforcements or filling materials
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
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    • E04F15/00—Flooring
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    • E04F15/107—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/584—Scratch resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00—Floor coverings

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  • Oil, Petroleum & Natural Gas (AREA)
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Abstract

一种具有防水胶的PVC自粘地板，从上至下依次包括主体层，隔离层和防水胶，防水胶的成分组成按重量百分比的各成分比例为：防水胶的成分组成按重量百分比的各成分比例为：苯乙烯-异戊二烯-苯乙烯嵌段共聚物为34-38%，C5氢化石油树脂为46.4-50.4%，环烷基橡胶填充油为13-17%，受阻酚抗氧剂为0.5-0.6%。在主体层和防水胶之间的隔离层为0PHR的PVC膜。该具有防水胶的PVC自粘地板的防水胶具有防水功能，并且可以防止塑化剂从PVC地板中游离出来而影响防水胶的粘性。

Description

具有防水胶的PVC自粘地板
技术领域
本发明涉及一种PVC地板，尤其涉及一种具有防水胶的PVC自粘地板。
背景技术
现有的PVC自粘地板的胶水是直接涂布于PVC地板的背面，胶水和地板之间没有任何的隔离层。由于PVC地板中有大量的塑化剂，在使用过程中塑化剂很容易游离出来，不仅使胶水糊化而失去粘性，而且会使胶水非常粘地粘在地上无法清除掉，这对后期地板更换中对地面的处理造成很大的麻烦。
此外，现有的PVC自粘地板的胶水没有防水的功能，胶水一旦沾到水，将会永久失去粘力。
发明内容
为了克服现有技术的不足，本发明所要解决的技术问题是提供一种具有防水胶的PVC自粘地板，该地板的防水胶具有防水功能，并且可以防止塑化剂从PVC地板中游离出来而影响防水胶的粘性。
为实现上述发明目的，本发明采用如下技术方案：
一种具有防水胶的PVC自粘地板，从上至下依次包括主体层，隔离层和防水胶，防水胶的成分组成按重量百分比的各成分比例为：苯乙烯-异戊二烯-苯乙烯嵌段共聚物为34-38%，C5氢化石油树脂为46.4-50.4%，环烷基橡胶填充油为13-17%，受阻酚抗氧剂为0.5-0.6%。
进一步的，防水胶的成分组成按重量百分比的各成分比例为：苯乙烯-异戊二烯-苯乙烯嵌段共聚物为36%，C5氢化石油树脂为48.4%，环烷基橡胶填充油为15%，受阻酚抗氧剂为0.6%。
进一步的，在主体层和防水胶之间的隔离层为0PHR的PVC膜。
进一步的，在防水胶下面还包括一层隔离纸，用于保护防水胶。
进一步的，主体层包括PU涂层，耐磨层，印刷层，PVC中料层和PVC底料层。
本发明的有益效果在于：
在本发明具有防水胶的PVC自粘地板的主体层与防水胶之间加入了一层隔离层，以使PVC地板中的塑化剂受到阻挡而不会游离至防水胶，进而与之发生化学反应。使防水胶可以持久的保持粘力并且不会造成后期置换地板导致的难以处理的胶水印记。
其次，本发明具有防水胶的PVC自粘地板摒弃了传统的热熔胶，使用的防水胶的防水功能绝佳，即便放到水里，只要风干之后也可以恢复粘力。
附图说明
图1为本发明一种具有防水胶的PVC自粘地板的结构示意图。
标号说明：
PU涂层1主体层10
耐磨层2印刷层3
PVC中料层4PVC底料层5
隔离层6防水胶7
隔离纸8。
具体实施方式
下面结合附图对本发明作进一步描述：
请参阅图1，本发明一种具有防水胶的PVC自粘地板从上至下依次包括主体层10，隔离层6，防水胶7和隔离纸8。其中，主体层10包括PU涂层1，耐磨层2，印刷层3，PVC中料层4和PVC底料层5。具有防水胶的PVC自粘地板的PU涂层1，耐磨层2，印刷层3，PVC中料层4和PVC底料层5均采用的现有的PVC自粘地板的组成成分。在现有的PVC中料层4和PVC底料层5内都含有大量的塑化剂。在主体层10和防水胶7之间的隔离层6是新增加的，在本实施例中隔离层6为0PHR的PVC膜。防水胶7的成分组成按重量百分比的各成分比例为：苯乙烯-异戊二烯-苯乙烯嵌段共聚物为34-38%，C5氢化石油树脂为46.4-50.4%，环烷基橡胶填充油为13-17%，受阻酚抗氧剂为0.5-0.6%。
优选地，防水胶7的成分组成按重量百分比的各成分比例为：苯乙烯-异戊二烯-苯乙烯嵌段共聚物为36%，C5氢化石油树脂为48.4%，环烷基橡胶填充油为15%，受阻酚抗氧剂为0.6%。防水胶7下面设置的隔离纸8可有效保护防水胶7。
在本发明具有防水胶的PVC自粘地板的主体层与防水胶之间加入的隔离层，使得主体层中的塑化剂受到阻挡而不会游离至防水胶，进而与之发生化学反应。使防水胶可以持久的保持粘力并且不会造成后期置换地板导致的难以处理的胶水印记。
其次，本发明具有防水胶的PVC自粘地板摒弃了传统的热熔胶，使用的防水胶的防水功能绝佳，即便放到水里，只要风干之后也可以恢复粘力。
本发明的技术范围不仅仅局限于上述说明中的内容，本领域技术人员可以在不脱离本发明技术思想的前提下，对上述实施例进行多种变形和修改，而这些变形和修改均应当属于本发明的范围内。

Claims (5)

1.一种具有防水胶的PVC自粘地板，其特征在于：从上至下依次包括主体层，隔离层和防水胶，防水胶的成分组成按重量百分比的各成分比例为：苯乙烯-异戊二烯-苯乙烯嵌段共聚物为34-38%，C5氢化石油树脂为46.4-50.4%，环烷基橡胶填充油为13-17%，受阻酚抗氧剂为0.5-0.6%。
2.如权利要求1所述的具有防水胶的PVC自粘地板，其特征在于：防水胶的成分组成按重量百分比的各成分比例为：苯乙烯-异戊二烯-苯乙烯嵌段共聚物为36%，C5氢化石油树脂为48.4%，环烷基橡胶填充油为15%，受阻酚抗氧剂为0.6%。
3.如权利要求1所述的具有防水胶的PVC自粘地板，其特征在于：在主体层和防水胶之间的隔离层为0PHR的PVC膜。
4.如权利要求1所述的具有防水胶的PVC自粘地板，其特征在于：在防水胶下面还包括一层隔离纸，用于保护防水胶。
5.如权利要求1所述的具有防水胶的PVC自粘地板，其特征在于：主体层包括PU涂层，耐磨层，印刷层，PVC中料层和PVC底料层。
CN201310699234.5A 2013-12-19 2013-12-19 具有防水胶的pvc自粘地板 Active CN103758329B (zh)

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Application Number Priority Date Filing Date Title
CN201310699234.5A CN103758329B (zh) 2013-12-19 2013-12-19 具有防水胶的pvc自粘地板
EP14872742.3A EP3085853B1 (en) 2013-12-19 2014-04-04 Pvc self-adhesive floorboard with water-resistant glue
US15/104,984 US9884980B2 (en) 2013-12-19 2014-04-04 PVC self-adhesive floorboard with water-resistant glue
CA2934376A CA2934376C (en) 2013-12-19 2014-04-04 Pvc self-adhesive floorboard with water-resistant glue
PCT/CN2014/074799 WO2015089957A1 (zh) 2013-12-19 2014-04-04 具有防水胶的pvc自粘地板

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CN104947914B (zh) * 2015-07-20 2017-06-06 江苏锐升新材料有限公司 一种具有防滑耐磨高透面层结构的pvc复合地板
WO2017108612A1 (de) * 2015-12-22 2017-06-29 Nora Systems Gmbh Selbstklebender bodenbelag und verfahren zu dessen herstellung
CN106281154A (zh) * 2016-08-31 2017-01-04 如皋市嘉好热熔胶有限公司 一种自粘地板用胶
WO2018089225A1 (en) * 2016-11-08 2018-05-17 Mannington Mills, Inc. Adhesive-backed flooring panel, system, and method
CN111087955A (zh) * 2019-12-31 2020-05-01 华威粘结材料（上海）股份有限公司 一种隔音减噪材料与pvc地板复合用胶及其制备方法
CN111234747A (zh) * 2020-03-25 2020-06-05 华威粘结材料（上海）股份有限公司 一种环保pvc地板背胶及其制备方法

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