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CN103117332B - Photoelectric cell - Google Patents

Photoelectric cell Download PDF

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Publication number
CN103117332B
CN103117332B CN201110362728.5A CN201110362728A CN103117332B CN 103117332 B CN103117332 B CN 103117332B CN 201110362728 A CN201110362728 A CN 201110362728A CN 103117332 B CN103117332 B CN 103117332B
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China
Prior art keywords
conductive
groove
electrode
semiconductor layer
layer
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CN201110362728.5A
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Chinese (zh)
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CN103117332A (en
Inventor
洪详竣
陈昭兴
沈建赋
王佳琨
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Epistar Corp
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Epistar Corp
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Priority to CN201710480015.6A priority patent/CN107256913B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/14Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a carrier transport control structure, e.g. highly-doped semiconductor layer or current-blocking structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/38Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The present invention discloses a kind of structure of photoelectric cell, and it is included:Semiconductor lamination, comprising:One first conductive-type semiconductor layer, an active layer and one second conductive-type semiconductor layer;One first electrode is electrically connected with the first conductive-type semiconductor layer, and first electrode also includes one first extension electrode;One second electrode is electrically connected with the second conductive-type semiconductor layer;And multiple limitation electric contact regions are located at semiconductor laminated the first extension electrode between, and multiple electric contact regions that limit are to become being spaced apart for distance.

Description

Photoelectric cell
Technical field
The present invention relates to a kind of photoelectric cell structure and its manufacture method, a kind of more particularly to utilize limits in electrical contact Region come improve electric current limitation structure and its manufacture method.
Background technology
Light emitting diode is a kind of light source being widely used in semiconductor element.Be compared to traditional incandescent lamp bulb or Fluorescent tube, light emitting diode has power saving and the longer characteristic of service life, therefore gradually replaces conventional light source and be applied to Various fields, such as traffic sign, backlight module, street lighting, Medical Devices industry.
How application with LED source increases its luminous effect with developing the demand more and more higher for brightness Rate becomes the important directions made joint efforts by industrial circle to improve its brightness.
Fig. 1 is described is used for the LED package 10 of semiconductor light-emitting elements in the prior art:Including by the envelope of encapsulating structure 11 The semi-conductor LED chips 12 of dress, wherein semi-conductor LED chips 12 have a p-n junction 13, and encapsulating structure 11 is typically thermosetting Material, such as epoxy resin (epoxy) or thermoplastic glue material.Semi-conductor LED chips 12 pass through a bonding wire (wire) 14 and two Conducting bracket 15,16 is connected.Because epoxy resin (epoxy) has deterioration (degrading) phenomenon in high temperature, therefore can only In low temperature environment running.In addition, epoxy resin (epoxy) has very high thermal resistance (thermal resistance) so that Fig. 1's Structure only provides the heat dissipation approach of the high value of semi-conductor LED chips 12, and the low-power consumption for limiting LED package 10 should With.
The content of the invention
To solve the above problems, the present invention provides the structure of a photoelectric cell, comprising:Semiconductor lamination, comprising:One One conductive-type semiconductor layer, an active layer and one second conductive-type semiconductor layer;One first electrode and the first conductive-type semiconductor Layer electrical connection, and first electrode also includes one first extension electrode;One second electrode is electrically connected with the second conductive-type semiconductor layer; And multiple limitation electric contact regions are located at semiconductor laminated between the first extension electrode, and multiple limitation electric contact regions To become being spaced apart for distance.
The present invention provides the structure of a photoelectric cell, comprising:Semiconductor lamination, comprising:One first conductive-type semiconductor Layer, an active layer and one second conductive-type semiconductor layer;One first electrode is located on semiconductor laminated, and with it is first conductive Type semiconductor layer is electrically connected, and wherein first electrode also has a width D comprising one2The first extension electrode;One groove is located at half Between conductor lamination, groove down extends to the first conductive-type semiconductor layer, and bottom portion of groove from the second conductive-type semiconductor layer Expose first conductive-type semiconductor layer;One limitation electric contact region is located on the second conductive-type semiconductor layer and along recessed Groove sidewall extends to bottom portion of groove subregion;And one second conductivity type contact layer be located at the second conductive-type semiconductor layer with limitation Separate between electric contact region and by groove, wherein the second conductivity type contact layer separated is at a distance of one apart from D1, and D1< D2
Brief description of the drawings
Fig. 1 is existing light emitting element structure figure;
Fig. 2 is the light-emitting component top view of first embodiment of the invention;
Fig. 3 A-3B are Fig. 2 region A enlarged drawings;
Fig. 4 A-4C are Fig. 2 another embodiment enlarged drawings of region A;
Fig. 4 D are Fig. 4 C sectional views.
Main element symbol description
10:LED package
11:Encapsulating structure
12:LED chip
13:P-n junction
14:Bonding wire
15,16:Conducting bracket
100:Substrate
101:First conductive-type semiconductor layer
102:First electrode
103:First extension electrode
104:Groove
105:Second conductive-type semiconductor layer
106:Second electrode
107:Limit electric contact region
108:Second conductivity type contact layer
A:Regional area
D1:The second conductivity type contact layer distance positioned at the side of groove two
D2:The width of first extension electrode
Embodiment
In order that the present invention narration it is more detailed with it is complete, refer to description below and coordinate Fig. 2 to Fig. 4 D accompanying drawing. Top view according to the photoelectric cell of first embodiment of the invention is as follows:As shown in Fig. 2 a photoelectric cell includes a substrate 100, One first conductive-type semiconductor layer 101, a first electrode 102 and first extension electrode extended out from first electrode 102 103.An active layer (not shown) and one second conductive-type semiconductor layer are formed on the first conductive-type semiconductor layer 101 (not Display), and form on the second conductive-type semiconductor layer (not shown) a second electrode 106.In the present embodiment, first prolongs Electrode 103 is stretched for comb form;In other embodiments, the first extension electrode 103 can for arc or other symmetrically or non-symmetrically Shape.It is electrically connected with addition, forming multiple limitations between one first conductive-type semiconductor layer 101 and one first extension electrode 103 Region 107 is touched, it is plurality of to limit electric contact region 107 to become being spaced apart for distance.In one embodiment, multiple limitations The spacing distance of electric contact region 107 increases with it and increased with the distance of first electrode 102 so that closer to first electrode 102 limitation electric contact region interval is smaller, therefore has less electric current injection;Further away from the limitation electricity of first electrode 102 Property contact area interval it is bigger, therefore have more electric current injection, and then improve electric current limitation (Current Crowding) Problem.
Fig. 3 A are Fig. 2 regional areas A enlarged drawing, as shown in Figure 3A:From the second etching downwards of conductive-type semiconductor layer 105 Active layer (not shown) is to exposing the first conductive-type semiconductor layer 101 to form a groove 104, and in the precalculated position of groove Multiple limitation electric contact regions 107 are formed to reach that this little region makes electrical contact with as isolation, then at limitation electric contact region 107 With exposing one first extension electrode 103 of formation on the first conductive-type semiconductor layer 101.Fig. 3 B are that Fig. 2 regional areas A is another The enlarged drawing of embodiment, as shown in Figure 3 B:From the subregion of the second conductive-type semiconductor layer 105, downward etch activity layer (does not show Show) to the first conductive-type semiconductor layer 101 is exposed, with the second conductive-type semiconductor layer of member-retaining portion 105 and amount of activated layer (not shown), then at part expose the region of the first conductive-type semiconductor layer 101 and the second conductive-type semiconductor layer of part 105 it It is upper to form multiple limitation electric contact regions 107, then at limitation electric contact region 107 with exposing the first conductive-type semiconductor One first extension electrode 103 is formed on layer 101.
Fig. 4 A- Fig. 4 D are the enlarged drawing of another embodiments of Fig. 2 regional areas A.As shown in Figure 4 A, in the conductivity type of part second One second conductivity type contact layer 108 is formed on semiconductor layer 105, and it is downward from the subregion of the second conductivity type contact layer 108 The second conductive-type semiconductor layer 105, active layer (not shown) are etched to the first conductive-type semiconductor layer 101 is exposed, to retain Part the second conductivity type contact layer 108, the second conductive-type semiconductor layer 105 and active layer (not shown).As shown in Figure 4 B, then at One is formed on second conductivity type contact layer 108 and limits electric contact region 107, but is partly led as Fig. 4 A expose the first conductivity type The region that body layer 101 is not covered by limitation electric contact region 107.As shown in Figure 4 C, then at limitation electric contact region 107 One first extension electrode 103 of upper formation, and the first conductive-type semiconductor layer that the covering of the first extension electrode 103 exposes such as Fig. 4 A 101 regions, wherein the first extension electrode 103 is electrically connected with the formation of the first conductive-type semiconductor layer 101.Fig. 4 D are Fig. 4 C section view Figure.As shown in Figure 4 D, wherein the region of the first conductive-type semiconductor layer 101 exposed such as Fig. 4 A has a groove 104, this groove 104 down extend to the first conductive-type semiconductor layer 101 from the second conductive-type semiconductor layer 105, and bottom portion of groove exposes first Conductive-type semiconductor layer 101.Electric contact region 107 is limited to be located on the second conductive-type semiconductor layer 105 and along groove 107 side walls extend to bottom portion of groove subregion;One second conductivity type contact layer 108 is located at the second conductive-type semiconductor layer 105 Between limitation electric contact region 107.The second conductivity type contact layer 108 positioned at the side of groove two has one apart from D respectively1 (i.e. a, b point to point), and the width of the first extension electrode 103 is D2.Work as D1< D2When, electric current limitation (Current can be improved Crowding) the problem of.The wherein width D of the first extension electrode 1032Can be between 5 μm~100 μm or 5 μm~80 μm or 5 μm ~60 μm or 5 μm~40 μm or 5 μm~20 μm or 5 μm~10 μm.And work as D2When bigger, the driving voltage V of photoelectric cellfHave Downward trend.
The material of above-mentioned first electrode 102, the first extension electrode 103 and second electrode 106 may be selected from:Chromium (Cr), titanium (Ti), the metal material such as nickel (Ni), platinum (Pt), copper (Cu), gold (Au), aluminium (Al), tungsten (W), tin (Sn) or silver (Ag).It is above-mentioned The material for limiting electric contact region 107 can be the dielectric materials such as silica, silicon nitride, aluminum oxide, zirconium oxide, or titanium oxide.
Specifically, photoelectric cell includes light emitting diode (LED), photodiode (photodiode), photo resistance (photo resister), laser (laser), infrared emitter (infrared emitter), Organic Light Emitting Diode At least one in (organic light-emitting diode) and solar cell (solar cell).Substrate 100 is one Growth and/or carrying basis.Candidate material can include electrically-conductive backing plate or non-conductive substrate, transparent substrates or impermeable photopolymer substrate.Its Middle electrically-conductive backing plate material can be metal, for example:Copper (Cu) or germanium (Ge);Or GaAs (GaAs), indium phosphorus (InP), carborundum (SiC), silicon (Si), lithium aluminate (LiAlO2), zinc oxide (ZnO), gallium nitride (GaN), aluminium nitride (AlN).Transparent substrates material Can be sapphire (Sapphire), lithium aluminate (LiAlO2), zinc oxide (ZnO), gallium nitride (GaN), aluminium nitride (AlN), glass, Diamond, CVD diamonds, class bore carbon (Diamond-LikeCarbon;DLC), spinelle (spinel, MgAl2O4), silica (SiOX) and lithium gallium oxide (LiGaO2)。
The above-mentioned conductive-type semiconductor layer 105 of first conductive-type semiconductor layer 101 and second at least two parts one another Electrically, polarity or dopant are different or respectively to provide the semiconductor material monolayer or multilayer (" multilayer " of electronics and hole Refer to two layers or more than two layers, it is as follows.), it electrically selects be at least any combination in p-type, N-shaped and i types. Active layer (not shown) is located between the first conductive-type semiconductor layer 101 and the second conductive-type semiconductor layer 105, is electric energy and light Can may change or be induced the region changed.Electric energy change or induce luminous energy person for example light emitting diode, liquid crystal display, Organic Light Emitting Diode;Luminous energy changes or induced electric energy person such as solar cell, photodiode.Above-mentioned first conductivity type is partly led Body layer 101, active layer (not shown) and second its material of conductive-type semiconductor layer 105 include one or more kinds of element choosings Group is constituted from gallium (Ga), aluminium (Al), indium (In), arsenic (As), phosphorus (P), nitrogen (N) and silicon (Si).
Photoelectric cell according to another embodiment of the present invention is a light emitting diode, and its luminous frequency spectrum can be by changing The physically or chemically key element of semiconductor monolayer or multilayer is adjusted.Conventional material is such as AlGaInP (AlGaInP) system Row, aluminum indium gallium nitride (AlGaInN) series, zinc oxide (ZnO) series etc..The structure of active layer (not shown) be as:It is single heterogeneous Structure (single heterostructure;SH), double-heterostructure (double heterostructure;DH), bilateral is double Heterojunction structure (double-side double heterostructure;) or multi-layer quantum well (multi-quantum DDH well;MQW).Furthermore, the logarithm of adjustment quantum well can also change emission wavelength.
In one embodiment of this invention, still it is selectively included between the first conductive-type semiconductor layer 101 and substrate 100 One cushion (buffer layer, not shown).This cushion makes the material system of substrate between two kinds of material systems " Transition " to semiconductor system material system.For the structure of light emitting diode, on the one hand, cushion is to reduce by two kinds The unmatched material layer of storeroom lattice.On the other hand, cushion can also be to combine two kinds of materials or two separation knots Individual layer, multilayer or the structure of structure, its available material is such as:Organic material, inorganic material, metal and semiconductor etc.;Its is optional Structure is such as:Reflecting layer, heat-conducting layer, conductive layer, Ohmic contact (ohmic contact) layer, anti-deformation layer, Stress Release (stress release) layer, Stress relief (stress adjustment) layer, engagement (bonding) layer, wavelength conversion layer, And it is mechanically fixed construction etc..In one embodiment, the material of this cushion can be AlN, GaN, and forming method can be sputter Or ald (Atomic Layer Deposition, ALD) (Sputter).
One second conductivity type contact layer 108 is also can be selectively formed on second conductive-type semiconductor layer 105.Contact layer is set It is placed in side of second conductive-type semiconductor layer away from active layer (not shown).Specifically, the second conductivity type contact layer can be with For optical layer, electrical layer or the combination both it.Optical layer, which can change, to be come from or into the electromagnetism of active layer (not shown) Radiation or light.At this referred to as " change " and refer at least one optical characteristics for changing electromagnetic radiation or light, afore-mentioned characteristics are included But it is not limited to frequency, wavelength, intensity, flux, efficiency, colour temperature, color rendering (rendering index), light field (light ) and angle of visibility (angle of view) field.Electrical layer can cause between any group of opposite side of the second conductivity type contact layer Voltage, resistance, electric current, at least one of numerical value in electric capacity, density, distribution change or have the trend changed.The The constituent material of two conductivity type contact layers 108 comprising oxide, conductive oxide, transparent oxide, wear with 50% or more The oxide of saturating rate, metal, relative transparent metal, the metal with 50% or more penetrance, organic matter, inanimate matter, fluorescence At least one in thing, phosphorescence thing, ceramics, semiconductor, the semiconductor of doping and undoped semiconductor.In some applications, The material of two conductivity type contact layers 108 is tin indium oxide, cadmium tin, antimony tin, indium zinc oxide, zinc oxide aluminum and oxidation At least one in zinc-tin.If with respect to transparent metal, its thickness is about 0.005 μm~0.6 μm.
Though more than each accompanying drawing and explanation only corresponding specific embodiment respectively, however, illustrated by each embodiment or exposure Element, embodiment, design criteria and know-why except showing mutually conflict, contradiction each other or in addition to being difficult to common implementing, We when can according to needed for it is any with reference to, exchange, collocation, coordinate or merge.
Although the present invention is it is stated that as above, but the scope that it is not intended to limiting the invention, implementation order or use Material and manufacture method.The various modifications and change made for the present invention, neither take off spirit and scope of the invention.

Claims (10)

1. a kind of photoelectric cell, comprising:
It is semiconductor laminated, comprising:First conductive-type semiconductor layer, active layer and the second conductive-type semiconductor layer;
First electrode is electrically connected with first conductive-type semiconductor layer, and the first electrode also includes one first extension electrode;And
Multiple limitation electric contact regions are semiconductor laminated between first extension electrode positioned at this, and the plurality of limitation is electrical Contact area is to become being spaced apart for distance, wherein the spacing distance of the plurality of limitation electric contact region is with itself and first electricity The distance of pole increases and increased.
2. photoelectric cell as claimed in claim 1, wherein also include substrate, positioned at this it is semiconductor laminated on, the wherein base Plate is located at the semiconductor laminated opposite side with the first electrode.
3. photoelectric cell as claimed in claim 1 wherein also includes second electrode, it is electrically connected with second conductive-type semiconductor layer Connect.
4. photoelectric cell as claimed in claim 1, also comprising a groove be located at this it is semiconductor laminated between, the groove is from second Conductive-type semiconductor layer down extends to first conductive-type semiconductor layer, and the bottom portion of groove exposes first conductivity type and partly led Body layer.
5. photoelectric cell as claimed in claim 4, also partly leads comprising one second conductivity type contact layer positioned at second conductivity type Between body layer and the plurality of limitation electric contact region.
6. photoelectric cell as claimed in claim 5, wherein, the groove is located under the recess sidewall comprising a recess sidewall and one Bottom portion of groove, the limitation electric contact region along the recess sidewall extend to part the bottom portion of groove, this first extension electricity Side wall of the pole along the limitation electric contact region extends to the bottom portion of groove and contacts first conductive-type semiconductor layer.
7. photoelectric cell as claimed in claim 6, wherein first extension electrode have a width D2
The second conductivity type contact layer is separated by the groove, wherein the second conductivity type contact layer separated is at a distance of one apart from D1, And D1< D2
8. photoelectric cell as claimed in claim 1, wherein also include substrate, positioned at this it is semiconductor laminated on, the wherein base Plate is located at the semiconductor laminated opposite side with the first electrode.
9. photoelectric cell as claimed in claim 7, wherein the first extension electrode width D 2 is between 5 μm~100 μm.
10. photoelectric cell as claimed in claim 4, wherein, the groove is located at the recess sidewall comprising a recess sidewall and one Under bottom portion of groove, the limitation electric contact region along the recess sidewall extend to part the bottom portion of groove, this first extension Side wall of the electrode along the limitation electric contact region extends to the bottom portion of groove and contacts first conductive-type semiconductor layer.
CN201110362728.5A 2011-11-16 2011-11-16 Photoelectric cell Active CN103117332B (en)

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CN201710480015.6A CN107256913B (en) 2011-11-16 2011-11-16 Photoelectric cell

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KR102357289B1 (en) * 2014-07-01 2022-02-03 서울바이오시스 주식회사 Light emitting device
CN105720155B (en) * 2016-02-03 2018-07-31 华灿光电(苏州)有限公司 A kind of Light-emitting diode LED and preparation method thereof

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CN103222074A (en) * 2010-11-18 2013-07-24 首尔Opto仪器股份有限公司 Light emitting diode chip having electrode pad

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KR100669733B1 (en) * 2004-10-14 2007-01-16 삼성에스디아이 주식회사 OTFT and OTFT-OLED
JP4353232B2 (en) * 2006-10-24 2009-10-28 ソニー株式会社 Light emitting element
KR101428053B1 (en) * 2007-12-13 2014-08-08 엘지이노텍 주식회사 Semiconductor light emitting device and fabrication method thereof
TWI464900B (en) * 2008-11-26 2014-12-11 Epistar Corp Optoelectronic semiconductor device
TWI527261B (en) * 2009-09-11 2016-03-21 晶元光電股份有限公司 Light-emitting device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103222074A (en) * 2010-11-18 2013-07-24 首尔Opto仪器股份有限公司 Light emitting diode chip having electrode pad

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CN107256913B (en) 2019-05-07
CN103117332A (en) 2013-05-22

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