CN1028475C - 吡咯类杀虫剂的组合物及其制备和应用 - Google Patents

Info

Publication number

CN1028475C

CN1028475C CN89108985A CN89108985A CN1028475C CN 1028475 C CN1028475 C CN 1028475C CN 89108985 A CN89108985 A CN 89108985A CN 89108985 A CN89108985 A CN 89108985A CN 1028475 C CN1028475 C CN 1028475C

Authority

CN

China

Prior art keywords

compound

cyano group

pyrroles

chloro

group

Prior art date

1988-12-09

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Lifetime

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• 239000002917 insecticide Substances 0.000 title description 13
• KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 title description 4
• 150000001875 compounds Chemical class 0.000 claims abstract description 518
• 238000000034 method Methods 0.000 claims description 271
• 239000000460 chlorine Substances 0.000 claims description 220
• -1 4Be hydrogen Chemical class 0.000 claims description 217
• 125000004093 cyano group Chemical group *C#N 0.000 claims description 126
• 150000003233 pyrroles Chemical class 0.000 claims description 126
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 113
• 239000000203 mixture Substances 0.000 claims description 109
• 238000006243 chemical reaction Methods 0.000 claims description 95
• 229910052739 hydrogen Inorganic materials 0.000 claims description 80
• 125000004414 alkyl thio group Chemical group 0.000 claims description 72
• 229910052801 chlorine Inorganic materials 0.000 claims description 72
• 239000002585 base Substances 0.000 claims description 68
• 229910052736 halogen Inorganic materials 0.000 claims description 68
• 125000003545 alkoxy group Chemical group 0.000 claims description 63
• 125000000217 alkyl group Chemical group 0.000 claims description 60
• 150000002367 halogens Chemical group 0.000 claims description 59
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 54
• 229910052794 bromium Inorganic materials 0.000 claims description 53
• 239000001257 hydrogen Substances 0.000 claims description 52
• 125000005843 halogen group Chemical group 0.000 claims description 50
• 239000003795 chemical substances by application Substances 0.000 claims description 45
• 239000002904 solvent Substances 0.000 claims description 45
• 239000004480 active ingredient Substances 0.000 claims description 44
• 125000001188 haloalkyl group Chemical group 0.000 claims description 44
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 43
• 238000002360 preparation method Methods 0.000 claims description 43
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 36
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 34
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• 125000003806 alkyl carbonyl amino group Chemical group 0.000 claims description 34
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• 238000003682 fluorination reaction Methods 0.000 claims 2
• DTMHTVJOHYTUHE-UHFFFAOYSA-N thiocyanogen Chemical compound N#CSSC#N DTMHTVJOHYTUHE-UHFFFAOYSA-N 0.000 claims 2
• BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims 1
• 125000002252 acyl group Chemical group 0.000 claims 1
• 229910003002 lithium salt Inorganic materials 0.000 claims 1
• 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 claims 1
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• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 43
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• 125000001072 heteroaryl group Chemical group 0.000 description 28
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• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 28
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