CN102677785B - Styrene-ethylene-butylene-styrene (SEBS) self-adhesion waterproof plate and production method thereof - Google Patents
Styrene-ethylene-butylene-styrene (SEBS) self-adhesion waterproof plate and production method thereof Download PDFInfo
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- CN102677785B CN102677785B CN201210131556.5A CN201210131556A CN102677785B CN 102677785 B CN102677785 B CN 102677785B CN 201210131556 A CN201210131556 A CN 201210131556A CN 102677785 B CN102677785 B CN 102677785B
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Abstract
The invention relates to a styrene-ethylene-butylene-styrene (SEBS) self-adhesion waterproof plate and a production method thereof and belongs to the field of building waterproof materials. A coiled material is composed of layers of a separation layer, an SEBS self-adhesion glue layer and a substrate, the production method includes firstly adding an SEBS elastomer and a rubber, adding a tackifier, a resin and a softening agent, stirring the mixture for 2.5-4 hours at the temperature of 140 DEG C-180 DEG C, performing swelling and blending, using a guide cylinder of a power shearing device for dispersing, and adding and stirring rest rubbers, the tackifier and functional auxiliaries to obtain an even and stable thick rubber and plastic mixing modified viscoelasticity composition-SEBS self-adhesion glue liquid; reducing the temperature to 140 DEG C to 160 DEG C for standby application; coating the cooled SEBS self-adhesion glue liquid on the substrate to form the SEBS self-adhesion glue layer; and covering the separation layer which is used for separating materials from being adhered. According to the SEBS self-adhesion waterproof plate and the production method thereof, the problems of insecure adhesion, bugling foaming, water escaping, leakage and the like are solved.
Description
Technical field
The present invention relates to a kind of non-bituminous base self-adhesion splash guard and production method thereof, belong to architectural waterproof material field.
Background technology
At present, waterproofing materials is divided into the large class of waterproof roll, water-repellent paint, leak stopping water material, rigid waterproofing and encapsulant five usually.For large-area waterproof construction, waterproof roll is current preferred material.Traditional asphaltic base waterproof roll, all with high-polymer modified pitch or the waterproof roll being referred to as polymer modified asphalt manufacture, as SBS modified asphalt waterproof coiled material, APP modified asphalt waterproof coiled material, self-adhered polymer modified bitumen waterproofing membrane, bridge surface waterproof layer polymer modified bituminous waterproof sheet material etc., they adopt hot melt or self-adhesion to construct, they serve huge effect on performance water-proof function, but the material of these traditional asphalt modification classes under normal use, be generally 25 years to 30 years its service life, be difficult to reach the situation synchronous with building application life, in addition, during construction, the blackbase of coiled material and concrete structure caking property affect greatly by constructor's skill operation, base treatment agent quality and construction environment, and difficult quality unanimously reaches job specfication requirement efficiently.So often occur bonding loosely, hollowing, foaming, the problem such as channeling water seepage.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of long service life good water-proof effect and the SEBS self-adhesion splash guard of a kind of pre-spread of easy construction/wet paving, also discloses the production method of this SEBS self-adhesion splash guard simultaneously.
The present invention is achieved through the following technical solutions:
A kind of SEBS self-adhesion splash guard, this coiled material contains following layer: separation layer, SEBS self-adhesive glue layer, base material, and on base material, at least one side is covered with SEBS self-adhesive glue layer and separation layer successively.
Described base material is macromolecular sheet material, its core thickness ≮ 0.5mm.
Described macromolecular sheet material can be the materials such as TPO, EVA, ECB, CPE, PVC, is divided into homogeneous sheet and composite sheet.
Described macromolecular sheet material is composite sheet, and its one side is SEBS self-adhesive glue layer and separation layer, and the non-woven fabrics that another side covers can have suspender belt.
Described base material is geomembrane, its core thickness ≯ 0.5mm.
Described geomembrane is cloth one film.
Described geomembrane is two cloth one films.
A non-woven fabrics of described two cloth one films is SEBS self-adhesive glue layer and separation layer, the non-woven fabrics of another side can have suspender belt.
Described separation layer be coated with silicone oil PET barrier film or be coated with the PE barrier film of silicone oil or silicone oil paper or special antiseized barrier coat;
The invention still further relates to the production method of SEBS self-adhesion splash guard:
First by SEBS elastic body, 1/2 amount rubber, 1/2 amount tackifier, resin and softening agent add reactor, stir 2.5 ~ 4 hours under 140 ~ 180 DEG C of conditions, swelling mixing, then lead tank by strong shear equipment and disperse one time, add residue rubber, tackifier and auxiliary agent again to stir, finally obtain the viscoelastic composition-SEBS self-adhesive liquid of uniform and stable thick rubber-plasitcs blend modification; Be cooled to 140 ~ 160 DEG C stand-by;
SEBS self-adhesive liquid after cooling is coated on base material, forms SEBS self-adhesive glue layer;
Isolated material is covered with the separation layer of anti-stick outside SEBS self-adhesive glue layer.
The styrene weight content 30 ~ 40% of described SEBS;
Described softening agent is rubber processing oil;
Described rubber is butyl rubber, butadiene-styrene rubber, natural rubber;
Described resin is vistanex, modified polyolefin resin;
Described auxiliary agent comprises age resistor, filler, tackifier, functional aid;
Described functional aid is the copolymer having acid anhydrides or ester functional groups;
Described filler comprises dicalcium powder, French chalk or flake asbestos, mineral powder, fine particle calcium carbonate, kieselguhr, swell soil etc.;
Described macromolecular sheet material can be the materials such as TPO, EVA, ECB, CPE, PVC, is divided into homogeneous sheet and composite sheet.
Described macromolecular sheet material is composite sheet, and its one side is SEBS self-adhesive glue layer and separation layer, and the non-woven fabrics that another side covers can have suspender belt.
Described base material is geomembrane, its core thickness ≯ 0.5mm.
Described geomembrane is cloth one film.
Described geomembrane is two cloth one films.
A non-woven fabrics of described two cloth one films is SEBS self-adhesive glue layer and separation layer, the non-woven fabrics of another side can have suspender belt.
Described separation layer be coated with silicone oil PET barrier film or be coated with the PE barrier film of silicone oil or silicone oil paper or special antiseized barrier coat;
The invention still further relates to the production method of SEBS self-adhesion splash guard:
First by SEBS elastic body, 1/2 amount rubber, 1/2 amount tackifier, resin and softening agent add reactor, stir 2.5 ~ 4 hours under 140 ~ 180 DEG C of conditions, swelling mixing, then lead tank by strong shear equipment and disperse one time, add residue rubber, tackifier and auxiliary agent again to stir, finally obtain the viscoelastic composition-SEBS self-adhesive liquid of uniform and stable thick rubber-plasitcs blend modification; Be cooled to 140 ~ 160 DEG C stand-by;
SEBS self-adhesive liquid after cooling is coated on base material, forms SEBS self-adhesive glue layer;
Isolated material is covered with the separation layer of anti-stick outside SEBS self-adhesive glue layer.
The styrene weight content 30 ~ 40% of described SEBS;
Described softening agent is rubber processing oil;
Described rubber is butyl rubber, butadiene-styrene rubber, natural rubber;
Described resin is vistanex, modified polyolefin resin;
Described auxiliary agent comprises age resistor, filler, tackifier, functional aid;
Described functional aid is the copolymer having acid anhydrides or ester functional groups;
Described filler comprises dicalcium powder, French chalk or flake asbestos, mineral powder, fine particle calcium carbonate, kieselguhr, swell soil etc.;
In described SEBS self-adhesive liquid, SEBS weight content is 2 ~ 8%; The weight content of rubber is 15 ~ 24%; The weight content of resin is 3 ~ 6%; The weight content of auxiliary agent is 45 ~ 47%; All the other are softening agent content.
The weight ratio of SEBS and softening agent is 1: 3 ~ 13.
The SEBS self-adhesion splash guard of this structure and the SEBS self-adhesion splash guard long service life adopting this production method to obtain, good water-proof effect and easy construction, bonding firmly, not hollowing, non-foaming, without problems such as channeling water seepages.
Accompanying drawing explanation
The structural representation of Fig. 1 to be base material be macromolecular sheet material one side SEBS self-adhesion splash guard of homogeneous sheet.
The structural representation of Fig. 2 to be base material be one side SEBS self-adhesion splash guard of the macromolecular sheet material of composite sheet
The structural representation of Fig. 3 to be base material be two-sided SEBS self-adhesion splash guard of the macromolecular sheet material of homogeneous sheet.
Fig. 4 is that base material is geomembrane and is the structural representation of the one side SEBS self-adhesion splash guard of cloth one film.
Fig. 5 is that base material is geomembrane and is the structural representation of the two-sided SEBS self-adhesion splash guard of two cloth one films.
Detailed description of the invention
With reference to Fig. 1, base material be homogeneous sheet macromolecular sheet material 1 on be followed successively by SEBS self-adhesive glue layer 3 and separation layer 4.
With reference to Fig. 2, base material is the one side SEBS self-adhesion splash guard of the macromolecular sheet material of composite sheet, non-woven fabrics 22 has suspender belt 25, and the another side of macromolecular sheet material 21 is followed successively by SEBS self-adhesive glue layer 23 and separation layer 24.
With reference to Fig. 3, base material is the two-sided SEBS self-adhesion splash guard of the macromolecular sheet material 31 of homogeneous sheet, and on macromolecular sheet material 31, two sides symmetry has SEBS self-adhesive glue layer 33 and separation layer 34.
With reference to Fig. 4, base material is geomembrane and is the one side SEBS self-adhesion splash guard of cloth one film 41, and the one side of geomembrane is without anti-cloth 42, and non-woven fabrics 42 can have suspender belt 45, and another side is followed successively by SEBS self-adhesive glue layer 43 and separation layer 44.
With reference to Fig. 5, base material is geomembrane and is the two-sided SEBS self-adhesion splash guard of two cloth one films, and geomembrane 51 two symmetries are with or without anti-cloth 52, SEBS self-adhesive glue layer 53 and separation layer 54.
The production method of SEBS self-adhesion splash guard:
Embodiment 1: first get that SEBS elastic body weight content is 2%, rubber adds 11.5%, tackifier add 20%, resin 5% stirs 2.5 hours with softening agent 26% under 140 ~ 180 DEG C of conditions, swelling mixing, then lead tank by strong shear equipment and disperse one time, add residue rubber 11.5%, tackifier 20%, age resistor 1.5% and functional aid 2.5% again to stir, finally obtain the viscoelastic composition-SEBS self-adhesive liquid of uniform and stable thick rubber-plasitcs blend modification; Be cooled to 145 DEG C stand-by;
SEBS self-adhesive liquid after cooling is coated on base material, forms SEBS self-adhesive glue layer;
Isolated material is covered with the separation layer of anti-stick outside SEBS self-adhesive glue layer.
Embodiment 2: first get that SEBS elastic body weight content is 5%, rubber adds 9.5%, tackifier add 19%, resin 4% stirs 2.5 hours with softening agent 26% under 140 ~ 180 DEG C of conditions, swelling mixing, then lead tank by strong shear equipment and disperse one time, add residue rubber 9.5%, tackifier 19%, age resistor 1% again, filler 4%, functional aid 3% stir, and finally obtain the viscoelastic composition-SEBS self-adhesive liquid of uniform and stable thick rubber-plasitcs blend modification; Be cooled to 150 DEG C stand-by;
SEBS self-adhesive liquid after cooling is coated on base material, forms SEBS self-adhesive glue layer;
Isolated material is covered with the separation layer of anti-stick outside SEBS self-adhesive glue layer.
Embodiment 3: first get that SEBS elastic body weight content is 8%, rubber adds 7.5%, tackifier add 15.5%, resin 4% stirs 2.5 hours with softening agent 27% under 140 ~ 180 DEG C of conditions, swelling mixing, then lead tank by strong shear equipment and disperse one time, add residue rubber 7.5%, tackifier 15.5%, age resistor 1% again, filler 10%, functional aid 4% stir, and finally obtain the viscoelastic composition-SEBS self-adhesive liquid of uniform and stable thick rubber-plasitcs blend modification; Be cooled to 160 DEG C stand-by;
SEBS self-adhesive liquid after cooling is coated on base material, forms SEBS self-adhesive glue layer;
Isolated material is covered with the separation layer of anti-stick outside SEBS self-adhesive glue layer.
Claims (6)
1. the production method of a SEBS self-adhesion splash guard, it is characterized in that: first SEBS elastic body, rubber, resin and softening agent are stirred 1.5 ~ 3 hours under 140 ~ 180 DEG C of conditions, swelling mixing, then tank dispersion 1 ~ 2 hour is led by strong shear equipment, add residue auxiliary agent again to stir, finally obtain the viscoelastic composition-SEBS self-adhesive liquid of uniform and stable thick rubber-plasitcs blend modification;
Be cooled to 140 ~ 160 DEG C stand-by;
SEBS self-adhesive liquid after cooling is coated on base material, forms SEBS self-adhesive glue layer;
Isolated material is covered with the separation layer of anti-stick outside SEBS self-adhesive glue layer.
2. the production method of a kind of SEBS self-adhesion splash guard according to claim 1, is characterized in that: the styrene weight content 30 ~ 40% of described SEBS;
Described softening agent is rubber processing oil;
Described rubber is butyl rubber, butadiene-styrene rubber, natural rubber;
Described resin is vistanex, modified polyolefin resin;
Described auxiliary agent comprises age resistor, filler, tackifier, functional aid.
3. the production method of a kind of SEBS self-adhesion splash guard according to claim 2, is characterized in that: described functional aid is the copolymer having acid anhydrides or ester functional groups.
4. the production method of a kind of SEBS self-adhesion splash guard according to claim 2, is characterized in that: described filler comprises dicalcium powder, French chalk, mineral powder, fine particle calcium carbonate, kieselguhr, swell soil.
5. the production method of a kind of SEBS self-adhesion splash guard according to claim 1 and 2, is characterized in that: in described SEBS self-adhesive liquid, SEBS weight content is 2 ~ 8%; The weight content of rubber is 15 ~ 24%; The weight content of resin is 3 ~ 6%; The weight content of auxiliary agent is 45 ~ 47%; All the other are softening agent content.
6. the production method of a kind of SEBS self-adhesion splash guard according to claim 5, is characterized in that: the weight ratio of SEBS and softening agent is 1: 3 ~ 13.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210131556.5A CN102677785B (en) | 2012-04-21 | 2012-04-21 | Styrene-ethylene-butylene-styrene (SEBS) self-adhesion waterproof plate and production method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210131556.5A CN102677785B (en) | 2012-04-21 | 2012-04-21 | Styrene-ethylene-butylene-styrene (SEBS) self-adhesion waterproof plate and production method thereof |
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| CN102677785A CN102677785A (en) | 2012-09-19 |
| CN102677785B true CN102677785B (en) | 2015-06-17 |
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| CN104086908A (en) * | 2014-06-19 | 2014-10-08 | 蚌埠市光华金属制品有限公司 | Preparation method for unvulcanized butyl rubber waterproof coil |
| CN104742454A (en) * | 2014-07-25 | 2015-07-01 | 梅东辉 | Self-adhered high polymer bactericidal waterproofing roll |
| CN104742431A (en) * | 2014-08-19 | 2015-07-01 | 吴华林 | Macromolecular elastic self-sticking waterproof coiled material |
| CN104441816A (en) * | 2014-11-17 | 2015-03-25 | 潍坊市宏源防水材料有限公司 | Macromolecular self-adhesive glue film coiled material adopting SEBS self-adhesive glue as self-adhesive layer and production method of macromolecular self-adhesive glue film coiled material |
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| CN114539944A (en) * | 2020-11-26 | 2022-05-27 | 苏州融达信新材料科技有限公司 | Novel environment-friendly self-adhesive film and synthesis method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4411954A (en) * | 1982-08-16 | 1983-10-25 | National Starch And Chemical Corporation | Hot melt pressure sensitive adhesive and diaper tape closures coated therewith |
| NZ241425A (en) * | 1991-03-01 | 1994-10-26 | Grace W R & Co | Waterproofing membrane comprising a carrier material, an adhesive layer and a protective layer; concrete structures having such a membrane retained on a surface thereof |
| CN2818134Y (en) * | 2005-08-12 | 2006-09-20 | 深圳市卓宝科技股份有限公司 | Self-binding synthetic polymer sheet materials |
| CN201214860Y (en) * | 2008-05-06 | 2009-04-01 | 秦雪辰 | High-molecular self-adhering water-proof rolled material |
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