CN104441816A - Macromolecular self-adhesive glue film coiled material adopting SEBS self-adhesive glue as self-adhesive layer and production method of macromolecular self-adhesive glue film coiled material - Google Patents
Macromolecular self-adhesive glue film coiled material adopting SEBS self-adhesive glue as self-adhesive layer and production method of macromolecular self-adhesive glue film coiled material Download PDFInfo
- Publication number
- CN104441816A CN104441816A CN201410649598.7A CN201410649598A CN104441816A CN 104441816 A CN104441816 A CN 104441816A CN 201410649598 A CN201410649598 A CN 201410649598A CN 104441816 A CN104441816 A CN 104441816A
- Authority
- CN
- China
- Prior art keywords
- self
- adhesive
- coiled material
- sebs
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 91
- 239000000463 material Substances 0.000 title claims abstract description 75
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 title claims abstract description 57
- 239000003292 glue Substances 0.000 title claims abstract description 39
- 239000012790 adhesive layer Substances 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000010410 layer Substances 0.000 claims abstract description 62
- 229920001971 elastomer Polymers 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004698 Polyethylene Substances 0.000 claims abstract description 15
- 239000006004 Quartz sand Substances 0.000 claims abstract description 15
- -1 polyethylene Polymers 0.000 claims abstract description 15
- 229920000573 polyethylene Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000806 elastomer Substances 0.000 claims abstract description 8
- 239000004611 light stabiliser Substances 0.000 claims abstract description 8
- 239000004902 Softening Agent Substances 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000002360 preparation method Methods 0.000 claims description 35
- 229920002521 macromolecule Polymers 0.000 claims description 24
- 239000012528 membrane Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 10
- 238000004078 waterproofing Methods 0.000 claims description 10
- 230000001464 adherent effect Effects 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 9
- 229920005549 butyl rubber Polymers 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 150000003505 terpenes Chemical class 0.000 claims description 7
- 235000007586 terpenes Nutrition 0.000 claims description 7
- 230000004888 barrier function Effects 0.000 claims description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 230000008961 swelling Effects 0.000 claims description 5
- 238000010008 shearing Methods 0.000 claims description 4
- 238000010276 construction Methods 0.000 abstract description 29
- 230000000694 effects Effects 0.000 abstract description 4
- 238000002955 isolation Methods 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000005266 casting Methods 0.000 description 2
- 230000005465 channeling Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 239000002998 adhesive polymer Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L45/00—Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a macromolecular self-adhesive glue film coiled material adopting SEBS self-adhesive glue as a self-adhesive layer and a production method of the macromolecular self-adhesive glue film coiled material. The coiled material comprises a macromolecular layer, an SEBS self-adhesive glue layer, a quartz sand anti-sticking layer and a polyethylene film overlap edge isolation layer, wherein the tensile strength of the macromolecular self-adhesive glue film coiled material is more than 800N/50mm, the right-angled tearing strength of the macromolecular self-adhesive glue film coiled material is more than 80N/mm, the shear strength between two coiled materials is more than 550N/50mm, the macromolecular layer is made of a polyolefins synthesized macromolecular waterproof coiled material, and the SEBS self-adhesive glue layer is prepared by adopting the following raw materials in parts by weight: 5 to 10 parts of SEBS elastomer, 25 to 30 parts of rubber, 35 parts of tackifying resin, 10 parts of a softening agent, 0.3 to 0.5 part of an antioxidant 1010 and 0.3 to 0.5 part of a light stabilizer 770. The product of the macromolecular self-adhesive glue film coiled material has the advantages of simplicity in construction, low requirement for the construction environment, less construction time and low construction cost and also has the advantages of high shear strength, high tensile strength and good waterproof effect.
Description
Technical field
The present invention relates to a kind of with SEBS self-adhesive be self-adhesive layer Macromolecular self-adhesive membrane coiled material and production method thereof, belong to architectural waterproof material field.
Background technology
At present, for large-area buildings waterproof construction, waterproof roll becomes preferred material.Traditional asphaltic base waterproof roll or modified asphalt waterproof coiled material adopt Hot-melt construction usually, but this construction method is subject to such environmental effects, can not in moist or rainy weather construction; Meanwhile, hot melt adopts naked light construction, there is potential safety hazard.Nowadays many big cities have forbidden that this has higher requirement to the manufacturing enterprise of waterproof roll with naked light construction.In addition, during construction, the adhesion strength of asphaltic base waterproof roll and xoncrete structure affects by the factor such as skill operation of base layer quality quality, construction environment and construction technical staff, can not ensure that each construction all reaches the requirement on construction technique normalizing, building site often occurs that coiled material and basic unit bond loosely, plays the problems such as drum, channeling water, seepage, and adds construction cost; The required operation of common coiled material construction is many in addition, and the engineering time is long.
Summary of the invention
The object of this invention is to provide a kind of easy construction, the Macromolecular self-adhesive membrane coiled material being self-adhesive layer with SEBS self-adhesive that is low, that reduce the engineering time, save construction cost is required to construction environment.
Another object of the present invention is to provide a kind of with the production method of the SEBS self-adhesive Macromolecular self-adhesive membrane coiled material that is self-adhesive layer, and the product that the inventive method is produced has that tensile strength is high, hot strength is high, the advantage of good water-proof effect.
For solving above technical problem, the present invention by the following technical solutions:
The Macromolecular self-adhesive membrane coiled material being self-adhesive layer with SEBS self-adhesive, described coiled material comprises following composition: macromolecule layer, SEBS self-adhesive glue layer, quartz sand adherent layer and polyethylene film overlap edge separation layer.
Below the further optimization to technique scheme:
The hot strength of described Macromolecular self-adhesive membrane coiled material is at more than 800N/50mm, and angle tear strength is at more than 80N/mm, and the shearing strength between coiled material and coiled material is at more than 550N/50mm.
Described macromolecule layer is TPO synthetic polymeric waterproofing material.
Described SEBS self-adhesive glue layer is made up of the raw material of following weight portion: the light stabilizer 770 of the SEBS elastomer of 5 ~ 10 parts, the rubber of 25 ~ 30 parts, the tackifying resin of 35 parts, the softening agent of 10 parts, the antioxidant 1010 of 0.3 ~ 0.5 part and part.
Described rubber is butyl rubber, and tackifying resin is terpene resin, and softening agent is rubber naphthenic oil.
Described with the production method of the SEBS self-adhesive Macromolecular self-adhesive membrane coiled material that is self-adhesive layer, comprise the following steps: the preparation of the preparation of the preparation of SEBS self-adhesive, the preparation of macromolecule layer, SEBS self-adhesive glue layer, the preparation of quartz sand adherent layer and polyethylene film overlap edge separation layer.
The preparation method of described SEBS self-adhesive is:
The rubber naphthenic oil of butyl (IIR) rubber of the SEBS elastomer of 5 ~ 10 weight portions, 25 ~ 30 weight portions, the terpene resin of 35 weight portions and 10 weight portions is stirred 2 hours at 190 ~ 200 DEG C, until swelling, stir after, add the mixture of the antioxidant 1010 of 0.3 ~ 0.5 weight portion and the light stabilizer 770 of 0.3 ~ 0.5 weight portion, stir, obtain uniform and stable thick SEBS self-adhesive liquid, be cooled to 165 ~ 170 DEG C stand-by.
The preparation method of described macromolecule layer is:
Homogeneous macromolecule coiled material is produced, as macromolecule layer by extruder and calender process TPO synthetic polymeric waterproofing material process TPO synthetic polymeric waterproofing material.
The preparation method of described SEBS self-adhesive glue layer is:
By automatic glue spreaders, SEBS self-adhesive is evenly coated in macromolecule coiled material surface, and self-adhesive glue layer thickness is at 0.25 ~ 0.30mm.
The preparation method of described quartz sand adherent layer is:
Quartz sand is evenly coated in self-adhesive glue layer surface, and longitudinal direction is monolateral reserves 80 ~ 100mm overlap edge, and sand is not covered in overlap edge place.
The preparation method of described polyethylene film overlap edge separation layer is:
Covered by the self-adhesive at overlap edge place with polyethylene separators, barrier film width is 80mm, obtained coiled material of the present invention.
Product of the present invention has the following advantages:
1. this product can form permanent combination with rear pouring concrete, stops moisture channelling between waterproof roll and structural concrete;
2. this product tensile strength is high, hot strength is at more than 800N/50mm, angle tear strength is at more than 80N/mm, shearing strength between coiled material and coiled material is at more than 550N/50mm, top layer adopts special release process, when adopting pre-installed and inverted adhered construction, workmen can stand on its surface walking for a long time, assembling reinforcement;
3. easy construction, basic unit, after simple process, directly emptyly can spread coiled material, assembling reinforcement, casting concrete, compared with common waterproof roll, can shorten the construction period of 1/3rd;
4. self-adhesive glue layer adopts the adhesive polymer glue of environmentally friendly type, meets environmental requirement;
5. coiled material of the present invention requires low to construction environment, and overcast and rainy or wet environment without impact on construction quality, substantially reduces construction period and curing period, saved expense;
6. coiled material of the present invention is low to basic level requirement, bonds solid and reliable, have self-repair function with xoncrete structure; Improve the self waterproofing function of xoncrete structure on the one hand; On the other hand, macromolecule layer can effectively prevent outside underground water etc. through, waterproof effect is remarkable.
Below in conjunction with the drawings and specific embodiments, the invention will be further described.
Accompanying drawing explanation
Accompanying drawing 1 is with the structural representation of the SEBS self-adhesive Macromolecular self-adhesive membrane coiled material that is self-adhesive layer in the embodiment of the present invention.
Detailed description of the invention
Embodiment 1,
1. the preparation of SEBS self-adhesive
The rubber naphthenic oil of butyl (IIR) rubber of the SEBS elastomer of 5kg, 25kg, the terpene resin of 35kg and 10kg is stirred 2 hours at 190 ~ 200 DEG C, until swelling, stir after, add the mixture of the antioxidant 1010 of 0.3kg and the light stabilizer 770 of 0.3kg, stir, obtain uniform and stable thick SEBS self-adhesive liquid, be cooled to 165 ~ 170 DEG C stand-by.
2. the preparation of macromolecule layer
Homogeneous macromolecule coiled material is produced by extruder and calender process TPO synthetic polymeric waterproofing material.
The preparation of 3.SEBS self-adhesive glue layer
By automatic glue spreaders, SEBS self-adhesive is evenly coated in macromolecule coiled material surface, and self-adhesive glue layer thickness is at 0.25mm.
4. the preparation of quartz sand adherent layer
Quartz sand is evenly coated in self-adhesive glue layer surface, and longitudinal direction is monolateral reserves 80mm overlap edge, and sand is not covered in overlap edge place.
5. the preparation of polyethylene film overlap edge separation layer
Covered by the self-adhesive at overlap edge place with polyethylene separators, barrier film width is 80mm, obtained coiled material of the present invention.
Embodiment 2,
1. the preparation of SEBS self-adhesive
The rubber naphthenic oil of butyl (IIR) rubber of the SEBS elastomer of 7kg, 27kg, the terpene resin of 35kg and 10kg is stirred 2 hours at 190 ~ 200 DEG C, until swelling, stir after, add the mixture of the antioxidant 1010 of 0.4kg and the light stabilizer 770 of 0.4kg, stir, obtain uniform and stable thick SEBS self-adhesive liquid, be cooled to 165 ~ 170 DEG C stand-by.
2. the preparation of macromolecule layer
Homogeneous macromolecule coiled material is produced by extruder and calender process TPO synthetic polymeric waterproofing material.
The preparation of 3.SEBS self-adhesive glue layer
By automatic glue spreaders, SEBS self-adhesive is evenly coated in macromolecule coiled material surface, and self-adhesive glue layer thickness is at 0.27mm.
4. the preparation of quartz sand adherent layer
Quartz sand is evenly coated in self-adhesive glue layer surface, and longitudinal direction is monolateral reserves 90mm overlap edge, and sand is not covered in overlap edge place.
5. the preparation of polyethylene film overlap edge separation layer
Covered by the self-adhesive at overlap edge place with polyethylene separators, barrier film width is 80mm, obtained coiled material of the present invention.
Embodiment 3,
1. the preparation of SEBS self-adhesive
The rubber naphthenic oil of butyl (IIR) rubber of the SEBS elastomer of 10kg, 30kg, the terpene resin of 35kg and 10kg is stirred 2 hours at 190 ~ 200 DEG C, until swelling, stir after, the weight ratio adding 0.3kg is the antioxidant 1010 of 1:1.2 and the mixture of light stabilizer 770, stir, obtain uniform and stable thick SEBS self-adhesive liquid, be cooled to 165 ~ 170 DEG C stand-by.
2. the preparation of macromolecule layer
Homogeneous macromolecule coiled material is produced by extruder and calender process TPO synthetic polymeric waterproofing material.
The preparation of 3.SEBS self-adhesive glue layer
By automatic glue spreaders, SEBS self-adhesive is evenly coated in macromolecule coiled material surface, and self-adhesive glue layer thickness is 0.30mm.
4. the preparation of quartz sand adherent layer
Quartz sand is evenly coated in self-adhesive glue layer surface, and longitudinal direction is monolateral reserves 100mm overlap edge, and sand is not covered in overlap edge place.
5. the preparation of polyethylene film overlap edge separation layer
Covered by the self-adhesive at overlap edge place with polyethylene separators, barrier film width is 80mm, obtained coiled material of the present invention.
The product got obtained by above-mentioned three embodiments is tested, and draws following data, sees the following form:
As seen from the above table, product property indices of the present invention is all higher than state quota, and especially hot strength is at more than 800N/50mm, and angle tear strength is at more than 80N/mm, and the shearing strength between coiled material and coiled material is at more than 550N/50mm.
Coiled material working procedure of the present invention mainly comprises base treatment, lays coiled material, lays reinforcing bar, casting concrete four road master operation; Compared with common waterproof coiled material construction, decrease brushing end oil, lay the operations such as protective layer, easy construction, substantially reduces the engineering time, has saved construction cost.
Coiled material of the present invention and structural concrete are completely sticky, completely eliminate channeling water passage, good water-proof effect.
The above is the citing of best mode for carrying out the invention, and the part wherein do not addressed in detail is the common practise of those of ordinary skill in the art.Protection scope of the present invention is as the criterion with the content of claim, and any equivalent transformation carried out based on technology enlightenment of the present invention, also within protection scope of the present invention.
Claims (10)
1. with the Macromolecular self-adhesive membrane coiled material that SEBS self-adhesive is self-adhesive layer, it is characterized in that: described coiled material comprises following composition: macromolecule layer, SEBS self-adhesive glue layer, quartz sand adherent layer and polyethylene film overlap edge separation layer.
2. a kind of Macromolecular self-adhesive membrane coiled material that is self-adhesive layer with SEBS self-adhesive as claimed in claim 1, it is characterized in that: the hot strength of described Macromolecular self-adhesive membrane coiled material is at more than 800N/50mm, angle tear strength is at more than 80N/mm, and the shearing strength between coiled material and coiled material is at more than 550N/50mm.
3. a kind of Macromolecular self-adhesive membrane coiled material that is self-adhesive layer with SEBS self-adhesive as claimed in claim 1, is characterized in that: described macromolecule layer is TPO synthetic polymeric waterproofing material.
4. a kind of Macromolecular self-adhesive membrane coiled material that is self-adhesive layer with SEBS self-adhesive as claimed in claim 1, is characterized in that: described SEBS self-adhesive glue layer is made up of the raw material of following weight portion: the light stabilizer 770 of the SEBS elastomer of 5 ~ 10 parts, the rubber of 25 ~ 30 parts, the tackifying resin of 35 parts, the softening agent of 10 parts, the antioxidant 1010 of 0.3 ~ 0.5 part and part.
5. a kind of Macromolecular self-adhesive membrane coiled material that is self-adhesive layer with SEBS self-adhesive as claimed in claim 4, it is characterized in that: described rubber is butyl rubber, tackifying resin is terpene resin, and softening agent is rubber naphthenic oil.
6. a kind of with the production method of the SEBS self-adhesive Macromolecular self-adhesive membrane coiled material that is self-adhesive layer as described in one of claim 1-5, is characterized in that: described production method comprises the following steps: the preparation of the preparation of the preparation of SEBS self-adhesive, the preparation of macromolecule layer, SEBS self-adhesive glue layer, the preparation of quartz sand adherent layer and polyethylene film overlap edge separation layer.
7. a kind of with the production method of the SEBS self-adhesive Macromolecular self-adhesive membrane coiled material that is self-adhesive layer as claimed in claim 6, it is characterized in that: the preparation method of described SEBS self-adhesive is:
The rubber naphthenic oil of butyl (IIR) rubber of the SEBS elastomer of 5 ~ 10 weight portions, 25 ~ 30 weight portions, the terpene resin of 35 weight portions and 10 weight portions is stirred 2 hours at 190 ~ 200 DEG C, until swelling, stir after, add the mixture of the antioxidant 1010 of 0.3 ~ 0.5 weight portion and the light stabilizer 770 of 0.3 ~ 0.5 weight portion, stir, obtain uniform and stable thick SEBS self-adhesive liquid, be cooled to 165 ~ 170 DEG C stand-by.
8. a kind of with the production method of the SEBS self-adhesive Macromolecular self-adhesive membrane coiled material that is self-adhesive layer as claimed in claim 6, it is characterized in that: the preparation method of described macromolecule layer is:
Homogeneous macromolecule coiled material is produced, as macromolecule layer by extruder and calender process TPO synthetic polymeric waterproofing material process TPO synthetic polymeric waterproofing material.
9. a kind of with the production method of the SEBS self-adhesive Macromolecular self-adhesive membrane coiled material that is self-adhesive layer as claimed in claim 6, it is characterized in that: the preparation method of described SEBS self-adhesive glue layer is:
By automatic glue spreaders, SEBS self-adhesive is evenly coated in macromolecule coiled material surface, and self-adhesive glue layer thickness is at 0.25 ~ 0.30mm.
10. a kind of with the production method of the SEBS self-adhesive Macromolecular self-adhesive membrane coiled material that is self-adhesive layer as described in one of claim 1-5, is characterized in that: the preparation method of described quartz sand adherent layer is:
Quartz sand is evenly coated in self-adhesive glue layer surface, and longitudinal direction is monolateral reserves 80 ~ 100mm overlap edge, and sand is not covered in overlap edge place;
The preparation method of described polyethylene film overlap edge separation layer is:
Covered by the self-adhesive at overlap edge place with polyethylene separators, barrier film width is 80mm, obtained coiled material of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410649598.7A CN104441816A (en) | 2014-11-17 | 2014-11-17 | Macromolecular self-adhesive glue film coiled material adopting SEBS self-adhesive glue as self-adhesive layer and production method of macromolecular self-adhesive glue film coiled material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410649598.7A CN104441816A (en) | 2014-11-17 | 2014-11-17 | Macromolecular self-adhesive glue film coiled material adopting SEBS self-adhesive glue as self-adhesive layer and production method of macromolecular self-adhesive glue film coiled material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104441816A true CN104441816A (en) | 2015-03-25 |
Family
ID=52888923
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410649598.7A Pending CN104441816A (en) | 2014-11-17 | 2014-11-17 | Macromolecular self-adhesive glue film coiled material adopting SEBS self-adhesive glue as self-adhesive layer and production method of macromolecular self-adhesive glue film coiled material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104441816A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105754280A (en) * | 2015-12-31 | 2016-07-13 | 中国建筑材料科学研究总院苏州防水研究院 | Recyclable self-cleaning reflective high polymer roof waterproof roll and preparation method thereof |
| CN107603537A (en) * | 2017-09-22 | 2018-01-19 | 广东能辉新材料科技有限公司 | Thermotropic pressure sensitive glue and preparation method thereof |
| CN108340637A (en) * | 2018-02-25 | 2018-07-31 | 厦门力嘉诚防水工程有限公司 | A kind of graphene self-adhesion glued membrane root-resistance waterproof coiled material |
| CN109054688A (en) * | 2018-06-26 | 2018-12-21 | 广东能辉新材料科技有限公司 | Not inharmonious thermotropic pressure sensitive glue of heat ageing and preparation method thereof |
| CN109291604A (en) * | 2018-09-18 | 2019-02-01 | 广东能辉新材料科技有限公司 | Exempt to apply glue-type waterproof roll preparation method |
| CN109812282A (en) * | 2018-12-21 | 2019-05-28 | 成都赛特防水材料有限责任公司 | High-polymer self-adhesion waterproof coiled material and its production method |
| CN110358476A (en) * | 2019-05-30 | 2019-10-22 | 廊坊市中油嘉昱防腐技术有限公司 | A kind of high temperature resistant butyl pressure sensitive adhesive and preparation method thereof |
| CN110938390A (en) * | 2019-11-20 | 2020-03-31 | 江苏凯伦建材股份有限公司 | Pre-paved high-molecular waterproof coiled material |
| CN111269668A (en) * | 2020-03-27 | 2020-06-12 | 山东双圆密封科技有限公司 | Exposed flexible flashing sealing repairing adhesive tape and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102677785A (en) * | 2012-04-21 | 2012-09-19 | 衡水翰林工程材料科技发展股份有限公司 | Styrene-ethylene-butylene-styrene (SEBS) self-adhesion waterproof plate and production method thereof |
| CN102774057A (en) * | 2012-08-08 | 2012-11-14 | 中国建筑材料科学研究总院苏州防水研究院 | Macromolecule pre-laid waterproof coiled material |
| KR20130033706A (en) * | 2011-09-27 | 2013-04-04 | (주)서한종합건축사사무소 | Paintable and adhesable polymer multi-layered waterproof sheet and its manufacturing method and its waterproof construction method |
| CN103334409A (en) * | 2013-07-16 | 2013-10-02 | 衡水中铁建工程橡胶有限责任公司 | Uncovering-free type macromolecule self-adhesion waterproof roll and preparing method thereof |
| CN103924692A (en) * | 2013-01-15 | 2014-07-16 | 江苏凯伦建材股份有限公司 | Thermoplastic polyolefin wet laying water-resistant coiled material |
| CN104059552A (en) * | 2014-06-11 | 2014-09-24 | 胜利油田大明新型建筑防水材料有限责任公司 | Production method of ethylene propylene diene monomer self-adhesion water-resistant coiled material |
| CN104057686A (en) * | 2014-06-11 | 2014-09-24 | 胜利油田大明新型建筑防水材料有限责任公司 | Preparation method of pre-laid waterproof coiled material for concrete mortar bonding construction |
-
2014
- 2014-11-17 CN CN201410649598.7A patent/CN104441816A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20130033706A (en) * | 2011-09-27 | 2013-04-04 | (주)서한종합건축사사무소 | Paintable and adhesable polymer multi-layered waterproof sheet and its manufacturing method and its waterproof construction method |
| CN102677785A (en) * | 2012-04-21 | 2012-09-19 | 衡水翰林工程材料科技发展股份有限公司 | Styrene-ethylene-butylene-styrene (SEBS) self-adhesion waterproof plate and production method thereof |
| CN102774057A (en) * | 2012-08-08 | 2012-11-14 | 中国建筑材料科学研究总院苏州防水研究院 | Macromolecule pre-laid waterproof coiled material |
| CN103924692A (en) * | 2013-01-15 | 2014-07-16 | 江苏凯伦建材股份有限公司 | Thermoplastic polyolefin wet laying water-resistant coiled material |
| CN103334409A (en) * | 2013-07-16 | 2013-10-02 | 衡水中铁建工程橡胶有限责任公司 | Uncovering-free type macromolecule self-adhesion waterproof roll and preparing method thereof |
| CN104059552A (en) * | 2014-06-11 | 2014-09-24 | 胜利油田大明新型建筑防水材料有限责任公司 | Production method of ethylene propylene diene monomer self-adhesion water-resistant coiled material |
| CN104057686A (en) * | 2014-06-11 | 2014-09-24 | 胜利油田大明新型建筑防水材料有限责任公司 | Preparation method of pre-laid waterproof coiled material for concrete mortar bonding construction |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105754280A (en) * | 2015-12-31 | 2016-07-13 | 中国建筑材料科学研究总院苏州防水研究院 | Recyclable self-cleaning reflective high polymer roof waterproof roll and preparation method thereof |
| CN105754280B (en) * | 2015-12-31 | 2017-11-21 | 中国建筑材料科学研究总院苏州防水研究院 | A kind of recyclable self-clean type reflection macromolecule water proof roofing sheet and preparation method thereof |
| CN107603537A (en) * | 2017-09-22 | 2018-01-19 | 广东能辉新材料科技有限公司 | Thermotropic pressure sensitive glue and preparation method thereof |
| CN107603537B (en) * | 2017-09-22 | 2020-03-24 | 广东能辉新材料科技有限公司 | Hot-melt pressure-sensitive adhesive and preparation method thereof |
| CN108340637A (en) * | 2018-02-25 | 2018-07-31 | 厦门力嘉诚防水工程有限公司 | A kind of graphene self-adhesion glued membrane root-resistance waterproof coiled material |
| CN109054688A (en) * | 2018-06-26 | 2018-12-21 | 广东能辉新材料科技有限公司 | Not inharmonious thermotropic pressure sensitive glue of heat ageing and preparation method thereof |
| CN109054688B (en) * | 2018-06-26 | 2020-11-06 | 广东能辉新材料科技有限公司 | Heat aging non-sticking hot melt pressure-sensitive adhesive and preparation method thereof |
| CN109291604A (en) * | 2018-09-18 | 2019-02-01 | 广东能辉新材料科技有限公司 | Exempt to apply glue-type waterproof roll preparation method |
| CN109812282A (en) * | 2018-12-21 | 2019-05-28 | 成都赛特防水材料有限责任公司 | High-polymer self-adhesion waterproof coiled material and its production method |
| CN110358476A (en) * | 2019-05-30 | 2019-10-22 | 廊坊市中油嘉昱防腐技术有限公司 | A kind of high temperature resistant butyl pressure sensitive adhesive and preparation method thereof |
| CN110938390A (en) * | 2019-11-20 | 2020-03-31 | 江苏凯伦建材股份有限公司 | Pre-paved high-molecular waterproof coiled material |
| CN111269668A (en) * | 2020-03-27 | 2020-06-12 | 山东双圆密封科技有限公司 | Exposed flexible flashing sealing repairing adhesive tape and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104441816A (en) | Macromolecular self-adhesive glue film coiled material adopting SEBS self-adhesive glue as self-adhesive layer and production method of macromolecular self-adhesive glue film coiled material | |
| CN104057686B (en) | The preparation method overlaying waterproof roll of a kind of concrete mortar bonding construction | |
| KR101107629B1 (en) | Multi-layer self-adhesive waterproofing sheet, and method for waterproofing using the same | |
| CN104354432A (en) | High polymer self-adhesive glue film waterproof roll adopting pre-laid stick side up construction method and production method of roll | |
| CN106183268B (en) | A kind of pre- laying water-proof coiled material of self-adhesion macromolecule and preparation method thereof | |
| KR101976185B1 (en) | Waterproofing-proof sheets, tape manufacturing and construction methods using self-adhesive butyl Compound | |
| CN102211895B (en) | Gelatinized asphalt film / felt sheet composite waterproof material for external waterproof of concrete structure | |
| CN104194628B (en) | High viscous rubber asphalt waterproof coating and preparation method thereof | |
| CN107033610B (en) | Fiber-reinforced modified asphalt roof repairing agent and preparation method thereof | |
| RU2532113C2 (en) | Road surface structure with improved adhesion properties | |
| CN106519719B (en) | Modified asphalt roof repairing agent for open water construction and preparation method thereof | |
| CN103924691A (en) | High-polymer wet laid waterproof coiled material | |
| KR100977160B1 (en) | The method for waterproofing with synthetic butyl rubber mastic waterproofing sheet | |
| KR101845316B1 (en) | High softening point reformed asphalt composition and waterproofing coating using the same | |
| KR100952689B1 (en) | Waterproof sheet and manufacturing method of waterproof sheet for using adhesive and construction method for using the waterproof sheet | |
| CN108086603A (en) | A kind of anti-water-stopping system of existing roofing and prevent water roofing | |
| KR101902836B1 (en) | Concrete repair and joint construction method using organic and inorganic hybrid water proofing material laminated self-adhesive seal reinforcing and waterproofing sheet | |
| KR100977164B1 (en) | Method for producing asphalt mastic waterproofing membrane material | |
| CN201053168Y (en) | Multiple tyre-base protective wet laying method double-face self-sticking waterproof coiled material | |
| KR101980153B1 (en) | Waterproof agent and complex waterproof construction method | |
| CN103951992A (en) | Wet-laid waterproof coiled material | |
| KR100571292B1 (en) | Waterproof asphalt adhesive composition and asphalt sheet waterproof construction method using the same | |
| CN105440707A (en) | Waterproof asphalt composition | |
| FI102256B (en) | Method for making a construction waterproof and in process using laminate | |
| CN108086490A (en) | A kind of anti-water-stopping system and ground in underground, top surface and elevation construction method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150325 |