CN102428973B - Agricultural pesticide with essential oil and application thereof - Google Patents
Agricultural pesticide with essential oil and application thereof Download PDFInfo
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- CN102428973B CN102428973B CN201110315992.3A CN201110315992A CN102428973B CN 102428973 B CN102428973 B CN 102428973B CN 201110315992 A CN201110315992 A CN 201110315992A CN 102428973 B CN102428973 B CN 102428973B
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- 239000000341 volatile oil Substances 0.000 title claims abstract description 37
- 239000000575 pesticide Substances 0.000 title claims abstract description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 24
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 13
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- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 12
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims abstract description 10
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- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
- 229940056881 imidacloprid Drugs 0.000 description 2
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- 244000025254 Cannabis sativa Species 0.000 description 1
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- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to agricultural pesticide with essential oil and an application thereof. The agricultural pesticide comprises the following components: 5-90% of the essential oil with insecticidal active components, and 5-90% of solvent, 5-90% of pesticide adjuvant. The essential oil is one or mixture made one from wintergreen oil, camphor tree oil, clove oil, peppermint oil, eucalyptus oil, citronella oil or tea tree oil. The solvent is one or a mixture made of formic acid, acetic acid, propionic acid, methyl alcohol, ethyl alcohol or propyl alcohol. The pesticide adjuvant is one or mixture made of dodecyl benzenesulfonic acid, Tween-80, Span-80 (SPAN) or OP-10. The invention has low toxin for animals, safety for environment, efficiency for pests at each life stage and good effects for killing mites and pests. The agricultural pesticide has simple use method and low manufacturing cost, and is suitable for killing the mites and the pests in agriculture and forestry.
Description
Technical field
The invention belongs to technical field of pesticide preparations, be specially agricultural chemicals and pesticidal applications thereof containing plants essential oil.
Background technology
The agricultural product loss causing due to agricultural pest reaches 15-25% every year, use on a large scale chemical pesticide to there is certain positive role for stablizing farm output, but, because the insecticidal spectrum of chemical pesticide is wide, the field longevity of residure is longer, easily bring out insect it is developed immunity to drugs, the particularly pollution of chemical pesticide to agricultural product and environment, causes that women miscarries, baby's distortion and bring out the various diseases such as human cancer.Therefore, use biopesticide pest control to be more and more subject to people's attention.Along with the enhancing of human environment protection consciousness, the biopesticide of high-efficiency low-toxicity has become the developing direction of current agricultural chemicals.Biopesticide has mode of action uniqueness, and controlling object is single-minded, and to beneficial organism safety such as natural enemies, consumption is little, and degraded is fast, dangerous low to people, animal, ambient wind, is applicable to the features such as disease, worm, crop smothering integrated control.1992, world environments once explicitly pointed out with development conference, to control in the world sale and the use of chemical pesticide by 2000, the consumption of biopesticide reaches 60%, but, biopesticide only accounts for 2% the market share in global agricultural chemicals total sales volume at present, differs greatly with re-set target.Therefore, greatly develop biopesticide and become the significant task of countries in the world facing.Relevant department of China proposes 2015, requires the use of biopesticide to account for the 30-50% of agricultural chemicals total amount, and 12% left and right that area accounts for agricultural chemicals and always applies area is applied in 10% left and right that China's biopesticide annual production only accounts for agricultural chemicals gross yield at present.Visible development biopesticide has become one of China's significant problem anxious to be resolved.
China has mite class approximately more than 500 to plant, and endangers larger more than 40 kinds that have, and is mainly spider mite kind, goitre mite class, the crops such as main harm fruit tree, cotton, wheat class, vegetables, tobacco and tea tree, and being wherein subject to harm is the most seriously mandarin tree, apple tree and cotton.To the harmful mite class of agricultural have that volume is little, breeding is fast, strong adaptability and the feature such as easily develop immunity to drugs, be one of pest communities of the most difficult control of generally acknowledging.Miticide kind accounts for 10% left and right of insecticide sum at present.Expect 2010, Lepidoptera, nematode, mite, aphid and springtail are still the insects of main control, will account for the more than 60% of the whole insecticide market share for the insecticide of preventing and treating above 5 class pests.The mite evil of China occurs the most serious with fruit tree.Wherein the most seriously will count mandarin tree, be secondly apple tree, and field crop is mainly cotton.At present external pesticide development is very fast, and because China is large agricultural country, the good China market of external agricultural chemicals company, squeezes into China market by its product one after another.From the miticide of current use, although great majority are compounds efficient, low toxicity, also more easily decompose, most products is never poison, and mammiferous toxicity be can not be ignored, and environment is also had to certain influence, mite easily develops immunity to drugs simultaneously.In the long run, acaricidal development Ying Xiangfei killing livestock property noval chemical compound and biotype compound future development, reduce the toxicity to animal, alleviate the pollution to environment, solve the pesticide resistance problem of mite, therefore developing efficient, long-acting, wide spectrum, environmental pollution few, little to natural enemy injury, to each life stage of evil mite all effectively and be difficult for producing the novel miticide of safety of resistance, is also the task of top priority.
Plants essential oil is the very important natural perfume material of a class, and what the physical methods such as general employing distillation, squeezing, extraction (lixiviate) or absorption extracted from flower, grass, leaf, branch, skin, root, stem, fruit, seed or the secretion of fragrant plant has certain fragrance and volatile oily mater.The contained chemical composition more complicated of plants essential oil, can be divided into aliphatic, aromatic series and terpene three major types compound and their containing oxygen derivative by the difference of its chemical constitution.Plants essential oil content has Cupressaceae, Magnoliaceae, Lauraceae, Carrot family, Labiatae, composite family, Rutaceae, Zingiber, Myrtaceae, Dipterocarpaceae and grass family etc. compared with the plant of horn of plenty.Plants essential oil is a class natural vegetal feed additives, has painted, anti-inflammation, the effect such as anticorrosion, anti-oxidant, antitumor, can correct the peculiar smell of food, gives fragrance.Therefore, plants essential oil is widely used in the food manufacturing industries such as meat products, fruit and vegetable product, dairy products, aquatic products, baked goods.Plants essential oil is also the important source material of medicine, spices and chemical industry, is also conventional food additives, has antibacterial, anti-oxidant, anti-inflammatory, shortly oozes, desinsection mosquito repellent and the effect such as anticorrosion.But, so far, plants essential oil is also seldom seen to the purposes such as rarely seen fresh-keeping and storage that is used for grain for stifling sterilization expelling parasite for the document announcement of pesticide research.
Summary of the invention
For the above-mentioned problems in the prior art, the object of the invention is to design a kind of low toxicity is provided, without extended residual, environmentally safe, the biopesticide preparation that kills mite good disinsection effect, its manufacture process environmental protection, using method are simple, and consumption is low, is applicable to various crop.
Described a kind of agricultural insecticide containing plants essential oil and preparation method thereof, it is characterized in that containing active insecticidal components plants essential oil 5-90%, solvent 5-90%, insecticides adjuvant 5-90%, described plants essential oil is wintergreen, camphor tree oil, caryophyllus oil, peppermint oil, eucalyptus oil, one or more mixtures of citronella oil or tea oil, described solvent is for being formic acid, acetic acid, propionic acid, methyl alcohol, one or more mixtures of ethanol or propyl alcohol, described insecticides adjuvant is DBSA, Tween-80, one or more mixtures of Span-80 (SPAN) or OP-10.
Described plants essential oil content is 20-70%, preferably 20-40%.
Described solvent is 16-65%, preferably 20-50%.
Described insecticides adjuvant content is 5-20%, preferably 10-15%.
The above-mentioned agricultural insecticide containing plants essential oil can be used as in miticide and insecticide and uses.
Described worm and mite comprise tetranychid, rice fulgorid, aphid, striped rice borer, paddy stem borer, leaf roll snout moth's larva, Bemisia tabaci, false eye leafhopper, diamond-back moth and cabbage caterpillar.
The present invention is taking plants essential oil as main active, the solvent of holding concurrently using solvent as auxiliary activity composition, and the preparation making is low to animal toxicity, Environmental compatibility is good, environmentally safe, to each life stage of insect, all effective and difficult resistance that produces, kills mite good disinsection effect; And using method is simple, low cost of manufacture, what be applicable to various crop kills mite desinsection.
Embodiment
Now, in conjunction with embodiments of the invention and the test of pesticide effectiveness, further illustrate effect of the present invention, in present specification, percentage composition is weight percentage.
Embodiment 1
Stir to dropping into wintergreen 25kg, formic acid 450kg in 1000L reactor, after all dissolving, more slowly drop into 25kg emulsifier DBSA, stir, finished product wintergreen preparation.
Embodiment 2
Stir to dropping into camphor tree oil 250kg, ethanol 200kg in 1000L reactor, after all dissolving, more slowly drop into 50kg emulsifier tween-80, stir, finished product camphor tree oil formulation.
Embodiment 3
Stir to dropping into caryophyllus oil 450kg, acetic acid 25kg in 1000L reactor, after all dissolving, more slowly drop into 25kg emulsifier neopelex, stir, finished product caryophyllus oil preparation.
Embodiment 4
Stir to dropping into peppermint oil 25kg, methyl alcohol 25kg in 1000L reactor, after all dissolving, more slowly drop into 450kg emulsifier op-10, stir, finished product menthence preparation.
Embodiment 5
In 1000L reactor, drop into eucalyptus oil 100kg, double solvents 325kg (methyl alcohol 125kg+ acetic acid 200kg) stirring, composite pesticide auxiliary agent 75kg (Span-80 25kg+ Tween-80 50kg), stir, finished product tea tree citronella oil composite plant essential oil preparation.
Embodiment 6
In 1000L reactor, drop into citronella oil 150kg, double solvents 300kg (methyl alcohol 200kg+ acetic acid 300kg) stirring, composite pesticide auxiliary agent 50kg (Span-80 20kg+ Tween-80 10kg+OP-1010kg+ DBSA 10kg), stir, the fragrant lemon composite plant of finished product tea essential oil preparation.
Embodiment 7
In 1000L reactor, drop into tea oil 350kg, double solvents 80kg (methyl alcohol 20kg+ ethanol 30kg+ formic acid 10kg+ acetic acid 15kg+ propionic acid 5kg) stirring, composite pesticide auxiliary agent 70kg (Span-80 50kg+ Tween-80 10kg+OP-105kg+ DBSA 5kg), stir, the fragrant lemon eucalyptus of finished product tea composite plant essential oil preparation.
Embodiment 8
In 1000L reactor, drop into plants essential oil 200kg (wintergreen 20kg+ camphor tree oil 30kg+ caryophyllus oil 30kg+ peppermint oil 30kg+ eucalyptus oil 30kg+ citronella oil 30kg+ tea oil 30kg), double solvents 250kg (methyl alcohol 50kg+ ethanol 100kg+ propyl alcohol 50kg+ formic acid 20kg+ acetic acid 20kg+ propionic acid 10kg) stirring, composite pesticide auxiliary agent 50kg (Span-80 20kg+ Tween-80 10kg+OP-10 10kg+ DBSA 10kg), stir, the fragrant lemon eucalyptus of finished product tea composite plant essential oil preparation.
By test, above-mentioned control efficiency of killing mite insecticide is described below.
The each chemical control tea tree of table 1. tetranychid result of the test
Table 2. is prevented and treated sweet orange spider result of the test (concentration for the treatment of is essential oil content 750mg/L)
Table 3. is prevented and treated apple result of the test (concentration for the treatment of is essential oil content 750mg/L)
Table 1-3 data show: embodiment 1-8 all has good effect to the tetranychid of control tealeaves, citrus and apple, in essential oil single dose, drug effect order is from big to small: embodiment 7 > embodiment 6 > embodiment 5 > embodiment 4 > embodiment 3 > embodiment 2 > embodiment 1, same preparation to the drug effect of 3 kinds of tetranychids order is from big to small: tealeaves > citrus > apple.
Embodiment 1-8 extension rate is advisable with activity component concentration 500-1000mg/L.
Table 4. is prevented and treated tealeaves (wild cabbage) aphid result of the test
Table 4 data show: embodiment 1-8 all has good effect to control tealeaves and cabbage aphid, the control efficiency of embodiment 1-8 does not have significant difference, also there is no significant difference with commercially available medicine 10% Imidacloprid, the effect of embodiment 1-8 and commercially available medicine 10% Imidacloprid is suitable.Same preparation to the drug effect of 2 kinds of aphids order is from big to small: tealeaves > wild cabbage.Embodiment 1-8 extension rate is advisable with activity component concentration 750mg/L.
Table 5 embodiment 1-8 control tealeaves false eye leafhopper effect (essential oil concentration 500mg/L)
The result of the test of table 5 shows, embodiment 1-8 has higher control efficiency to false eye leafhopper insect at activity component concentration 500mg/L.Wherein, the best results of embodiment 4, embodiment 1-8 extension rate is advisable with activity component concentration 500mg/L.
Table 6 embodiment 1-8 control wild cabbage diamond-back moth effect (essential oil concentration 500mg/L)
| Embodiment | 3 days schools after medicine | 7 days schools after medicine | Within after medicine 15 days, proofread and correct |
| Positive preventive effect (%) | Positive preventive effect (%) | Preventive effect (%) | |
| Embodiment 1 | 81.5 | 87.6 | 80.3 |
| Embodiment 2 | 82.7 | 89.0 | 82.6 |
| Embodiment 3 | 85.4 | 91.3 | 84.5 |
| Embodiment 4 | 87.0 | 95.0 | 88.0 |
| Embodiment 5 | 75.6 | 82.3 | 73.6 |
| Embodiment 6 | 72.7 | 85.6 | 78.9 |
| Embodiment 7 | 78.5 | 82.0 | 81.3 |
| Embodiment 8 | 78.0 | 87.6 | 82.1 |
| 5% presses down 800 times of hooligan's missible oil | 69.8 | 75.8 | 73.6 |
Table 7 embodiment 1-8 control cabbage pieris effect (essential oil concentration 500mg/L)
Table 8 embodiment 1-8 control wild cabbage Bemisia tabaci effect (essential oil concentration 500mg/L)
Table 6-8 result of the test show, embodiment 1-8 has higher control efficiency to pest such as Bemisia tabaci, diamond-back moth, cabbage caterpillars at activity component concentration 500mg/L.Wherein, embodiment 4 the bests.
Table 9 embodiment 1-8 prevents and treats rice hoppers effect (essential oil concentration 750mg/L)
Table 10 embodiment 1-8 control rice-stem borer effect (essential oil concentration 750mg/L)
Table 11 embodiment 1-8 control Yellow Rice Borer effect (essential oil concentration 750mg/L)
Table 12 embodiment 1-8 control rice leaf roll snout moth's larva effect (essential oil concentration 750mg/L)
Table 9-12 result of the test show, embodiment 1-8 has higher control efficiency to rice grubs such as rice fulgorid, striped rice borer, paddy stem borer, leaf roll snout moth's larvas at activity component concentration 750mg/L.Wherein, different embodiment in embodiment 1-8, same embodiment all show the insecticidal activity of different sizes to different insects, in the process of actual production and agricultural chemicals use, can, by adjusting the formulation (active constituent content) of agricultural chemicals and the multiple that dilution is used, reach the object of controlling above insect completely.
Claims (2)
1. the agricultural insecticide containing plants essential oil, it is characterized in that evenly being mixed by tea oil 350kg, double solvents 80kg, composite pesticide auxiliary agent 70 kg, described double solvents is methyl alcohol 20kg, ethanol 30kg, formic acid 10kg, acetic acid 15kg, propionic acid 5kg, and described composite pesticide auxiliary agent is Span-80 50kg, Tween-80 10kg, OP-10 5kg, DBSA 5kg.
2. a kind of agricultural insecticide containing plants essential oil as claimed in claim 1 is for killing tetranychid, rice fulgorid, aphid, striped rice borer, paddy stem borer, leaf roll snout moth's larva, Bemisia tabaci, false eye leafhopper, diamond-back moth and cabbage caterpillar.
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