CN102173600B - Silver blue glass and preparation technique thereof - Google Patents
Silver blue glass and preparation technique thereof Download PDFInfo
- Publication number
- CN102173600B CN102173600B CN 201110021869 CN201110021869A CN102173600B CN 102173600 B CN102173600 B CN 102173600B CN 201110021869 CN201110021869 CN 201110021869 CN 201110021869 A CN201110021869 A CN 201110021869A CN 102173600 B CN102173600 B CN 102173600B
- Authority
- CN
- China
- Prior art keywords
- film
- target
- glass
- nanometers
- rete
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000011521 glass Substances 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052709 silver Inorganic materials 0.000 title abstract 6
- 239000004332 silver Substances 0.000 title abstract 6
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 claims abstract description 28
- 238000000576 coating method Methods 0.000 claims abstract description 28
- 229910018138 Al-Y Inorganic materials 0.000 claims abstract description 19
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 19
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 19
- 210000003298 dental enamel Anatomy 0.000 claims description 15
- 238000000151 deposition Methods 0.000 claims description 11
- 230000008021 deposition Effects 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000004544 sputter deposition Methods 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 7
- 230000007797 corrosion Effects 0.000 abstract description 5
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract 4
- 230000007547 defect Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 9
- 230000005855 radiation Effects 0.000 description 8
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 3
- 230000003796 beauty Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
Landscapes
- Surface Treatment Of Glass (AREA)
- Physical Vapour Deposition (AREA)
Abstract
The invention provides a low-emissivity silver blue coated glass in a seven-layer structure and a preparation technique thereof. From bottom to top on the glass substrate, the silver blue glass is sequentially coated with a first TiO2 film 1, an SnO2 film 2, a Co-Ni-Cr-Al-Y film 3, a second TiO2 film 4, a ZnO2 film 5, an SnO2 film 6 and an SiN4 film 7, thereby constituting the low-emissivity silver blue coated glass in a seven-layer structure. The silver blue glass has the advantages of low cost, high wear resistance and high corrosion resistance, and especially has the characteristic of low emissivity. In addition, the invention also overcomes the defect in color in the LOW-E (low-emissivity) glass, and the Co-Ni-Cr-Al-Y film and the other three layers are combined, so that the silver blue glass appears bright blue in gorgeous metal silvery white, thereby simultaneously implementing favorable color and properties. The Co-Ni-Cr-Al-Y film, which is the most important film, not only has better high temperature resistance and oxidation resistance than Cr, but also has the advantages of high bonding strength, corrosion resistance, cavitation corrosion resistance, compact coating, high temperature (1038 DEG C) resistance and excellent oxidation resistance.
Description
Technical field
The present invention relates to the manufacturing process of a kind of glass and this glass, particularly the manufacturing process of a kind of Beijing enamel ware glass and this Beijing enamel ware glass.
Prior art
The film structure of common Beijing enamel ware glass generally is so in the market: it has glass substrate, on glass substrate from bottom upwards be coated with successively 1, SnO
2Or ZnO
2Rete 2, CrMnN rete 3, NiCr rete 4, ZnO
2Rete, thus consist of the Beijing enamel ware low radiation coated glass of 4 tunic architecture.
Although SnO
2Or ZnO
2Sedimentation effect is high, low price, but its provide protection is poor, and wear-corrosion resistance is bad, and does not have the functional layer of environmental protection and energy saving.And owing to do not use SiN
4Rete, thereby its film layer structure undertighten, strong not with the bonding force of glass substrate, wear-corrosion resistance is not good enough yet.In addition, what it used is low price, and material and performance be very common CrMnN target all, and not only the Beijing enamel ware colour purity is inadequate, and its color is relatively dim, not too can satisfy people's esthetic requirement.More of paramount importance is that it does not use the Co-Ni-Cr-Al-Y layer, so this glass can't reach the effect of fire-resistant oxidation resistant and low radiation.
Summary of the invention
The object of the invention is to provide
The object of the invention is to provide a kind of low radiation Beijing enamel ware coated glass with 7 layers of structure, makes it have that cost is low, wear-resisting, the advantage of corrosion resistance and good, especially has the characteristics of fire-resistant oxidation resistant and low radiance.
Purpose of the present invention can adopt following technical scheme to realize: upwards be coated with successively the 1, the one TiO from bottom on glass substrate
2Rete, the 2, the one SnO
2Rete, 3, the Co-Ni-Cr-Al-Y rete, the 4, the 2nd TiO
2Rete, 5, ZnO
2Rete, the 6, the 2nd SnO
2Rete, 7, Si
3N
4Rete, thus consist of the Beijing enamel ware low radiation coated glass of 7 tunic architecture.
When making above-mentioned glass, can take following technique.Described low radiation coated glass is to be evacuated to 1.1 * 10 at coating chamber
-4Below the pa, be filled with process gas (O
2Or N
2Or Ar), make the coating chamber pressure-stabilisation about 0.3pa, send electricity with sputtering source, target begins sputter, sends into glass, with target atom or other Compound deposition to glass surface.
First coating chamber is filled with O
2, target is the Ti target, with a TiO
2Film deposits to glass surface, thickness 8 to 20 nanometers;
Second coating chamber is filled with O
2, target is the Sn target, at a TiO
2Formation of deposits the one SnO above the film
2Film, thickness 20 to 60 nanometers;
The 3rd coating chamber is filled with Ar, and target is the Co-Ni-Cr-Al-Y target, at a SnO
2The above's deposition Co-Ni-Cr-Al-Y layer, thickness 8 to 20 nanometers;
The 4th coating chamber is filled with O
2, target is the Ti target, at Co-Ni-Cr-Al-Y layer deposition the 2nd TiO
2Film, thickness 10 to 15 nanometers;
The 5th coating chamber is filled with O
2, target is the Zn target, at the 2nd TiO
2Deposit ZnO on the rete
2Film, thickness 3 to 10 nanometers;
The 6th coating chamber is filled with O
2, target is the Sn target, at ZnO
2Formation of deposits the 2nd SnO on the film
2Film, thickness 20 to 60 nanometers;
The 7th coating chamber is filled with N
2, target is the Si target, at the 2nd SnO
2Deposit Si on the film
3N
4Film, thickness 15 to 30 nanometers.
Adopt said structure, namely can utilize SnO
2The film deposition is high, and low-cost advantage can be utilized SiN again
4Membrane structure is tight, the advantage of wear-resisting, corrosion resistance and good, and one deck Co-Ni-Cr-Al-Y rete and other the three layers use that combines that particularly wherein add make it have the performance of low radiation energy-saving environmental protection.And this glass also has distinct gorgeous color, reached harmony and the unification of inner beauty and external beauty, satisfies user's individual demand.
Description of drawings
Fig. 1 is the structural representation of Beijing enamel ware glass of the present invention.Wherein 1, glass substrate, the 2, the one TiO
2Rete, the 3, the one SnO
2Rete, 4, the Co-Ni-Cr-Al-Y rete, the 5, the 2nd TiO
2Rete, 6, ZnO
2Rete, the 7, the 2nd SnO
2Rete, 8, Si
3N
4Rete.
Embodiment
By reference to the accompanying drawings Beijing enamel ware glass of the present invention is further specified.Purpose of the present invention can adopt following technical scheme to realize: upwards be coated with successively a TiO from bottom on glass substrate 1
2Rete 2, the SnO
2Rete 3, Co-Ni-Cr-Al-Y rete 4, the two TiO
2Rete 5, ZnO
2Rete 6, the two SnO
2Rete 7 and Si
3N
4Rete 8, thus consist of the Beijing enamel ware low radiation coated glass of 7 tunic architecture.
When making above-mentioned glass, can take following technique.Described low radiation coated glass is to be evacuated to 1.1 * 10 at coating chamber
-4Below the pa, be filled with process gas (O
2Or N
2Or Ar), make the coating chamber pressure-stabilisation about 0.3pa, send electricity with sputtering source, target begins sputter, sends into glass, with target atom or other Compound deposition to glass surface.First coating chamber is filled with O
2, target is the Ti target, with a TiO
2Film deposits to glass surface, about thickness 15 nanometers; Second coating chamber is filled with O
2, target is the Sn target, at a TiO
2Formation of deposits the one SnO above the film
2Film is about thickness 40 nanometers; The 3rd coating chamber is filled with Ar, and target is the Co-Ni-Cr-Al-Y target, at a SnO
2Deposition Co-Ni-Cr-Al-Y layer above the rete is about thickness 15 nanometer; The 4th coating chamber is filled with O
2, target is the Ti target, at Co-Ni-Cr-Al-Y layer deposition the 2nd TiO
2Film is about thickness 12 nanometers; The 5th coating chamber is filled with O
2, target is the Zn target, at the 2nd TiO
2Deposit ZnO on the rete
2Film is about thickness 6 nanometers; The 6th coating chamber is filled with O
2, target is the Sn target, at ZnO
2Formation of deposits the 2nd SnO on the film
2Film is about thickness 40 nanometers; The 7th coating chamber is filled with N
2, target is the Si target, at the 2nd SnO
2Settled layer Si on the film
3N
4Film is about thickness 22 nanometers.
Claims (3)
1. a Beijing enamel ware glass is characterized in that upwards being coated with successively a TiO from bottom on glass substrate
2Rete, a SnO
2Rete, Co-Ni-Cr-Al-Y rete, the 2nd TiO
2Rete, ZnO
2Rete, the 2nd SnO
2Rete, Si
3N
4Rete.
2. the Beijing enamel ware glass described in the claim 1, a wherein said TiO
2Thicknesses of layers is 8 to 20 nanometers, a described SnO
2Thicknesses of layers is 20 to 60 nanometers, and described Co-Ni-Cr-Al-Y thicknesses of layers is 8 to 20 nanometers, described the 2nd TiO
2Thicknesses of layers is 10 to 15 nanometers, described ZnO
2Thicknesses of layers is 3 to 10 nanometers, described the 2nd SnO
2Thicknesses of layers is 20 to 60 nanometers, described Si
3N
4Thicknesses of layers is 15 to 30 nanometers.
3. method of making Beijing enamel ware glass is characterized in that:
Coating chamber is evacuated to 1.1 * 10
-4Below the pa, be filled with process gas, make the coating chamber pressure-stabilisation at 0.3pa, send electricity with sputtering source, target begins sputter, sends into glass substrate, with target atom or other Compound deposition to glass surface;
First coating chamber is filled with O
2, target is the Ti target, with a TiO
2Film deposits to glass surface, thickness 8 to 20 nanometers;
Second coating chamber is filled with O
2, target is the Sn target, at a TiO
2Formation of deposits the one SnO above the film
2Film, thickness 20 to 60 nanometers;
The 3rd coating chamber is filled with Ar, and target is the Co-Ni-Cr-Al-Y target, at a SnO
2The above's deposition Co-Ni-Cr-Al-Y layer, thickness 8 to 20 nanometers;
The 4th coating chamber is filled with O
2, target is the Ti target, at Co-Ni-Cr-Al-Y layer deposition the 2nd TiO
2Film, thickness 10 to 15 nanometers;
The 5th coating chamber is filled with O
2, target is the Zn target, at the 2nd TiO
2Deposit ZnO on the rete
2Film, thickness 3 to 10 nanometers;
The 6th coating chamber is filled with O
2, target is the Sn target, at ZnO
2Deposition the 2nd SnO on the film
2Film, thickness 20 to 60 nanometers;
The 7th coating chamber is filled with N
2, target is the Si target, at the 2nd SnO
2Deposit Si on the film
3N
4Film, thickness 15 to 30 nanometers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110021869 CN102173600B (en) | 2011-01-20 | 2011-01-20 | Silver blue glass and preparation technique thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110021869 CN102173600B (en) | 2011-01-20 | 2011-01-20 | Silver blue glass and preparation technique thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102173600A CN102173600A (en) | 2011-09-07 |
| CN102173600B true CN102173600B (en) | 2013-03-27 |
Family
ID=44516898
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110021869 Expired - Fee Related CN102173600B (en) | 2011-01-20 | 2011-01-20 | Silver blue glass and preparation technique thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102173600B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116175B (en) * | 2016-06-20 | 2018-09-21 | 东莞市银建玻璃工程有限公司 | A kind of fire prevention gold and silver indigo plant low-e glass |
| CN106082699B (en) * | 2016-06-20 | 2018-07-27 | 东莞市银建玻璃工程有限公司 | A kind of bluish grey Low emissivity low-e glass |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0275474A1 (en) * | 1986-12-29 | 1988-07-27 | Ppg Industries, Inc. | Low emissivity film for high temperature processing |
| US5376455A (en) * | 1993-10-05 | 1994-12-27 | Guardian Industries Corp. | Heat-treatment convertible coated glass and method of converting same |
| CN1931764A (en) * | 2006-10-19 | 2007-03-21 | 林嘉宏 | Low radiation coated glass capable of being toughened and its production process |
| CN201296729Y (en) * | 2008-07-23 | 2009-08-26 | 格兰特工程玻璃(中山)有限公司 | Temperable low-radiation coated glass |
-
2011
- 2011-01-20 CN CN 201110021869 patent/CN102173600B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0275474A1 (en) * | 1986-12-29 | 1988-07-27 | Ppg Industries, Inc. | Low emissivity film for high temperature processing |
| US5376455A (en) * | 1993-10-05 | 1994-12-27 | Guardian Industries Corp. | Heat-treatment convertible coated glass and method of converting same |
| CN1931764A (en) * | 2006-10-19 | 2007-03-21 | 林嘉宏 | Low radiation coated glass capable of being toughened and its production process |
| CN201296729Y (en) * | 2008-07-23 | 2009-08-26 | 格兰特工程玻璃(中山)有限公司 | Temperable low-radiation coated glass |
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| Publication number | Publication date |
|---|---|
| CN102173600A (en) | 2011-09-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: JIANGSU YUTIAN GANGBO NEW MATERIALS CO.,LTD. Free format text: FORMER OWNER: NANJING YUTIAN GLASS CO., LTD. Effective date: 20131224 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 210000 NANJING, JIANGSU PROVINCE TO: 223100 HUAIAN, JIANGSU PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20131224 Address after: 223100 east side of 328 provincial road, Hongze Economic Development Zone, Hongze County, Huaian, Jiangsu Patentee after: Jiangsu Yutian Gangbo New Materials Co., Ltd. Address before: 210000, Ma Zhen Street, Liuhe District, Jiangsu, Nanjing Patentee before: Nanjing Yutian Glass Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180306 Address after: 522000 Guangdong Province, Jieyang city Rongcheng District Xianqiao Rong Chi Lu Middle East coated glass tube workshop Patentee after: Jieyang special glass new material Co., Ltd. Address before: 223100 east side of 328 provincial road, Hongze Economic Development Zone, Hongze County, Huaian, Jiangsu Patentee before: Jiangsu Yutian Gangbo New Materials Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130327 Termination date: 20200120 |
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| CF01 | Termination of patent right due to non-payment of annual fee |