CN102153909B - Water-based ink for plastic table printing - Google Patents
Water-based ink for plastic table printing Download PDFInfo
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- CN102153909B CN102153909B CN 201110022124 CN201110022124A CN102153909B CN 102153909 B CN102153909 B CN 102153909B CN 201110022124 CN201110022124 CN 201110022124 CN 201110022124 A CN201110022124 A CN 201110022124A CN 102153909 B CN102153909 B CN 102153909B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 239000004033 plastic Substances 0.000 title claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
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- 238000009826 distribution Methods 0.000 claims description 5
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- 229920000178 Acrylic resin Polymers 0.000 claims description 4
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- 230000000996 additive effect Effects 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 239000008387 emulsifying waxe Substances 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
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- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims description 3
- 125000004069 aziridinyl group Chemical group 0.000 claims 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 1
- 239000004205 dimethyl polysiloxane Substances 0.000 claims 1
- 238000007046 ethoxylation reaction Methods 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 11
- 229920006395 saturated elastomer Polymers 0.000 abstract description 4
- 235000013305 food Nutrition 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000002274 desiccant Substances 0.000 abstract description 2
- 238000005299 abrasion Methods 0.000 abstract 2
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- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 35
- 230000000694 effects Effects 0.000 description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
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- 238000001035 drying Methods 0.000 description 4
- 239000006166 lysate Substances 0.000 description 4
- KDUFKIIMEWLUSX-UHFFFAOYSA-N C1CN1.C1CN1 Chemical group C1CN1.C1CN1 KDUFKIIMEWLUSX-UHFFFAOYSA-N 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
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- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a water-based ink for plastic table printing. The water-based ink comprises the following components in part by weight: water-based acrylic emulsion with tg value of 40 DEG C below zero to 25 DEG C, 25 to 35 parts of water-based color paste, and 3 to 6 parts of water-based auxiliary agent, wherein the water-based auxiliary agent comprises 0.2 to 0.5 part of water-based wetting agent, 0.5 to 0.8 part of water-based pH value neutralization dispersant, 0.5 to 0.8 part of water-based leveling agent, 0.5 to 2 parts of water-based quick drying agent, 0.5 to 2 parts of water-based abrasion resistant agent and 0.5 to 2 parts of water-based bridging agent. The ink has no solvent residue and no pollution to food package, and is healthy and green; and the presswork of the ink has the characteristics of high glossiness, abrasion resistance, negative adhesion resistance, high adhesive force, high temperature resistance, good leveling property, saturated and bright color, good color spread and the like.
Description
Technical field
The present invention relates to the printing-ink field, relate to particularly a kind of plastic table printing Environmental-protection water-based ink.
Background technology
All the time, the pollution of printing ink is problem the most serious in the Printing industry.World's printing ink annual production is above 3,000,000 tons.Solvent type ink on average accounts for 30%～40%, and the consumption of the annual organic solvent that brings because of printing ink in the whole world causes the huge wasting of resources up to more than 1,000,000 tons.The organic solvents such as the ethanol that wherein often uses, butylacetate, toluene, dimethylbenzene.The dry afterwards overwhelming majority all can be eliminated, but lingering section still can work the mischief to human body, and Long Term Contact can make chapped skin, coarse, if infiltrate skin or blood vessel, understands blood cell and hematopoietic function with blood crisis people, even may cause the human body chronic poisoning.In addition, the heavy metal elements such as some mineral dye is leaded, chromium, copper, mercury, the certain toxicity of tool; The part pigment dyestuff contains biphenyl glue, and carcinogenic composition is arranged, and should forbid to use.The volatilization of solvent causes topsoil, and is larger to the growth effect of each kind of plant, destroys the eubiosis, should cause the attention of the whole society.And heavy metal will cause sizable harm sometimes by plant absorbing if be absorbed by the body.
In a word, there is following shortcoming in conventional solvent type printing ink: 1) inflammable and explosive, produce the very large potential safety hazard of existence; 2) a large amount of VOC toxic organic compounds are discharged in the air polluted air; 3) solvent is a kind of thing of toxicity, has influence on the healthy of employee; 4) dissolvent residual, contaminated food products has influence on the consumer health; 5) a large amount of solvent evaporates, waste cause cost to increase.
Summary of the invention
The object of the present invention is to provide a kind of water-based ink for plastic table printing, to solve the above-mentioned problems in the prior art.Water-based ink for plastic table printing among the present invention does not contain organic solvent, is environment-friendly type.
Technical scheme provided by the invention is as follows:
A kind of water-based ink for plastic table printing by weight, comprising:
The tg value is aqueous acrylic emulsion 55-65 part of-40 ℃～25 ℃;
Aqueous color paste 25-35 part; With
Aqueous promoter 3-6 part
Wherein, this aqueous promoter comprises:
Aqueous wetting agent 0.2-0.5 part;
In the water-based pH value and dispersion agent 0.5-0.8 part;
Water-based flow agent 0.5-0.8 part;
Water-based quick dry agent 0.5-2 part;
Aqueous wear-resistant agent 0.5-2 part;
Water-based bridging agent 0.5-2 part.
Preferably, described aqueous acrylic emulsion comprises composition A and composition B: this part emulsion is that the aqueous acrylic emulsion interworking by two kinds of different pieces of information characteristics forms, the interworking ratio of these two kinds of emulsions can change according to the variation of printing condition, print speed is fast, and interworking ratio just latex A that the Tg value is high is occupied ratio more greatly.Help like this quick-drying; Print speed is slow, and interworking ratio just emulsion B that the Tg value is low is occupied ratio more greatly, helps like this print stream levelling good and be difficult for stifled version.
Aqueous acrylic emulsion A:25～35 part, the type emulsion property: the Tg value is 15 ℃～18 ℃, belongs to quick-dry type, molecular weight " 200000, molecular weight is large, and particle diameter is little, and particle distribution is tight, has outstanding bonding force.Solid content 45%～48%, acid number 50～60, water resisting property is good, viscosity 800, good printing ink ink transfer and adaptability, pH value 8.5～8.9, density 1.05.
Aqueous acrylic emulsion B:30～35 part, the type emulsion property: the Tg value is-35 ℃～-45 ℃, and film-forming temperature is low, stronger sticking power and better print stream levelling.Molecular weight " 200000, acid number 20～30, high gloss and transparency, excellent water resisting property, viscosity 300～400, good fluidity helps printing adaptability, pH value 8.5～8.9, density 1.05.
Pre-dispersed mill base fineness median size is 0.5～0.8 micron.This part is the important component part that determines the ink color, can require to adjust according to distinct colors composition and the ratio of mill base, allow it allot the ink of different colours and different look content, pre-dispersed mill base fineness median size is 0.5～0.8 micron, the ultra-fine complete coating that helps filming emulsion of particle diameter, make the molecule of look China ink perfect, therefore help to improve glossiness and the flowability of ink.
Preferably, described aqueous wetting agent is that low molecular polyether (polyether) modification oxyethyl group (E0) is changed the poly-silicon alkyl oxide of dimethyl, has splendid wetting and diffusion effect.The surface tension of water can be dropped to 20.0～21.0 dyne/cm by 72 dyne/cm, thus close with the surface tension of printing element, improve sticking power and ink transfer that ink prints.
Preferably, in the described water-based pH value and dispersion agent be water soluble amino alcohol or its mixture, preferably, it is active quantities greater than 85% water soluble amino alcohol mixture.In water color ink can in and the carboxylic acid group (～COOH), help pH value stability, improve glossiness, the advantages such as good water resisting property and corrosion stability.
Preferably, described water-based flow agent is the polyphosphazene polymer dimethylsiloxane emulsion, plays excellent printing levelling effect, excellent increases sliding effect, improves scratch resistance and good preventing adhesiving effect
Preferably, described water-based quick dry agent is high molecular zinc oxide emulsion, plays fast setting when allowing water color ink be transferred to printing element, and drying effect plays simultaneously anti and improves the wear resistance effect
Preferably, described aqueous wear-resistant agent is white emulsifying wax, has good dispersed and excellent wear resistance.
Preferably, described water-based water-based bridging agent is for containing any solvent, and solid content belongs to the environment-friendly type linking agent greater than 99% trifunctional aziridine (Aziridine) bridging agent, can improve water tolerance, ethanol-tolerant, and resistance to bond reduces transport property.
A kind of method for preparing water-based ink for plastic table printing may further comprise the steps:
The first step: solid propenoic acid resin is carried out synthetic chemistry reaction, copolymerization film forming according to different demand prescriptions in reactor.
Second step: acrylic resin liquid and the wetting dispersing auxiliary of pigment dyestuff and 10% are carried out grinding distribution, wetting through sand mill together, finally grind into about 30%～40% look content and the pre-dispersed aqueous color paste with 25 seconds/3# cup/250C flowability.
The 3rd step: film-forming aqueous ACRYLIC EMULSION, pre-dispersed aqueous color paste and corresponding additive are required to put into the dispersion a mixing bowl according to different formula rates disperse to stir.Disperseing churning time is 30～45 minutes, and stirring velocity is 600～1000 rev/mins, and churning time is unsuitable long, and stirring velocity is unsuitable too fast, otherwise demulsifying phenomenon can occur.
The 4th step: will disperse to stir complete water color ink filling, packing becomes finished product.
Beneficial effect of the present invention is as follows: the 1) discharging of zero VOC toxic organic compound, and pollution-free to air; 2) without the volatilization of poisonous organic solvent, pressman's health is had no adverse effects; 3) eliminate the inflammable and explosive hidden danger in working space, improved security.4) the printing comprehensive cost approximately economizes 35% than the traditional printing ink of solvent; 5) reduce with an organic solvent: such as toluene, Tianna solution etc., for strategic reserves provides safeguard.6) no solvent residue, pollution-free to food product pack, healthy, green; 7) printing of ink has high gloss, rub resistance, and counnter attack is sticking, high adhesive force, high temperature resistant, levelling property is good, saturated bright-coloured, the characteristics such as color development power is good of color.
Embodiment
The international PANTONE of embodiment 1 preparation 186 is red
Aqueous acrylic emulsion: 60 parts, wherein aqueous acrylic emulsion A (Argentinian diransa, model: PH702): 30 parts, aqueous acrylic emulsion B (Argentinian diransa, model: SF): 30 parts
35 parts of pre-dispersed aqueous color pastes, comprising:
A.57:1 red slurry is 20 parts, and fineness is 0.5～0.8 micron, and ultra-fine grain diameter helps to improve the glossiness of ink, look content 33%～38%, and look content is high, and is bright in luster, saturated.
10 parts in the yellow slurry in B.Y～13, fineness is 0.5～0.8 micron, ultra-fine grain diameter helps to improve the glossiness of ink, look content 33%～38%, look content is high, and is bright in luster, saturated.
5 parts of relevant aqueous promoters, comprising:
A. aqueous wetting agent is 0.2 part: weak yellow liquid, and Si Luoke Silok, model: 8000, for low molecular polyether (polyether) modification oxyethyl group (E0) is changed the poly-silicon alkyl oxide of dimethyl.
B. in the water-based pH value and 0.5 part of dispersion agent: colourless liquid, Dutch Ai De chemistry, model: Codis95.A kind of mixture of water soluble amino alcohol of active quantities 90%, in water color ink can in and the carboxylic acid group (～COOH), help pH value stability, improve glossiness, the advantages such as good water resisting property and corrosion stability.
C. the water-based flow agent is 0.5 part: white emulsion.Germany's enlightening is high, and model: Glide100 is a kind of polyphosphazene polymer dimethylsiloxane emulsion, plays excellent printing levelling effect, excellent increases sliding effect, improves scratch resistance and good preventing adhesiving effect.
D. the water-based quick dry agent is 2 parts: white emulsus, Xiamen Green spring (China), model: GS-A006 are a kind of high molecular zinc oxide emulsions, play fast setting when allowing water color ink be transferred to printing element, drying effect plays simultaneously anti and improves the wear resistance effect.
Preparation method:
The first step: the zinc oxide lysate of producing 15% content: because zinc oxide is water insoluble, therefore, use first 154g water dissolution 112g volatile salt after 3～5 minutes, volatile salt is dissolved in the water.And then add 75g zinc oxide, and become opaque lysate after 2～3 minutes, again toward the interior ammoniacal liquor that adds 28% concentration of 159g of lysate, obtain the burnett's solution of 15% content of 500g after 3～5 minutes.
Second step: this making processes must be noted whole adding procedure order, otherwise, can cause occurring caking thickening phenomenon.
Step: the 1. zinc oxide lysate (15% zinc oxide content) that takes out 15 parts of volumes
2. the ammoniacal liquor (28% concentration) that adds 2 parts of volumes in the burnett's solution
3. the deionized water that adds 15 volumes
4. the aqueous acrylic emulsion (Argentinian diransa, the model: SF), obtain water based acrylic acid type quick-drying agent that add 68 volumes.
E. the aqueous wear-resistant agent is 1 part: place of production China, and white emulsifying wax, the new promise in Shanghai, model: WE-518B5 has good dispersed and excellent wear resistance.
F. the water-based bridging agent is 0.8 part: be a kind of any solvent that do not contain, solid content is greater than 99% trifunctional aziridine (Aziridine) bridging agent, Taiwan An Feng, model: WH-5213 belongs to the environment-friendly type linking agent, can improve water tolerance, ethanol-tolerant, resistance to bond reduces transport property.
The preparation method:
The first step: solid propenoic acid resin A and B are carried out synthetic chemistry reaction, copolymerization film forming in reactor; Be reacted into and have greater than 200,000 molecular weight, 20～60 acid numbers, 8～8.9PH value and-40 ℃～25 ℃ second-order transition temperature (Tg value).Solid content is about 45%～48%, and viscosity is 300～2000 film forming modified acrylic acid emulsion, so that the water color ink that manufactures a finished product uses.
Second step: acrylic resin liquid and the wetting dispersing auxiliary of pigment dyestuff and 10% are carried out grinding distribution, wetting through sand mill together, finally grind into about 30%～40% look content and the pre-dispersed aqueous color paste with 25 seconds/3# cup/25 ℃ of flowabilities;
The 3rd step: film-forming aqueous ACRYLIC EMULSION, pre-dispersed aqueous color paste and corresponding additive are required to put into the dispersion a mixing bowl according to different formula rates disperse to stir.Disperseing churning time is 40 minutes, and stirring velocity is 800 rev/mins;
The 4th step: will disperse to stir complete water color ink filling, packing becomes finished product.
The international PANTONE Yellow of embodiment 2 preparations
Aqueous acrylic emulsion: 65 parts, wherein aqueous acrylic emulsion A (Argentinian diransa, model: PH702): 35 parts, aqueous acrylic emulsion B (Argentinian diransa, model: SF): 30 parts
30 parts of pre-dispersed aqueous color pastes, it is Y～14 mill bases, fineness is 0.5～0.8 micron.
5 parts of relevant aqueous promoters, comprising:
A. aqueous wetting agent is 0.5 part: weak yellow liquid, and Si Luoke Silok, model: 8000 is that low molecular polyether (polyether) modification oxyethyl group (EO) is changed the poly-silicon alkyl oxide of dimethyl.
B. in the water-based pH value and 0.5 part of dispersion agent: colourless liquid, Dutch Ai De chemistry, model: Codis95.A kind of mixture of water soluble amino alcohol of active quantities 90%, main component: Blend of AlKanol-amines in water.In water color ink can in and the carboxylic acid group (～COOH), help pH value stability, improve glossiness, the advantages such as good water resisting property and corrosion stability.
C. the water-based flow agent is 0.5 part: white emulsion.Germany's enlightening is high, and model: Glide100 is a kind of polyphosphazene polymer dimethylsiloxane emulsion, plays excellent printing levelling effect, excellent increases sliding effect, improves scratch resistance and good preventing adhesiving effect.
D. the water-based quick dry agent is 1 part: white emulsus, Xiamen Green spring (China), model: GS-A006 is a kind of high molecular zinc oxide emulsion, play fast setting when allowing water color ink be transferred to printing element, drying effect, play simultaneously anti and improve the wear resistance effect, its preparation method is with reference to embodiment 1.
E. the aqueous wear-resistant agent is 2 parts: white emulsifying wax, and the new promise in Shanghai, model: WE-518B5 has good dispersed and excellent wear resistance.
F. the water-based bridging agent is 0.5 part: be a kind of any solvent that do not contain, solid content is greater than 99% trifunctional aziridine (Aziridine) bridging agent, Taiwan An Feng, model: WH-5213 belongs to the environment-friendly type linking agent, can improve water tolerance, ethanol-tolerant, resistance to bond, reduce transport property, adding proportion is 0.5%～2%.
The preparation method:
The first step: solid propenoic acid resin is carried out synthetic chemistry reaction, copolymerization film forming according to different demand prescriptions in reactor; Be reacted into and have greater than 200,000 molecular weight, 20～60 acid numbers, 8～8.9PH value and-40 ℃～25 ℃ second-order transition temperature (Tg value).Solid content is about 45%～48%, and viscosity is 300～2000 film forming modified acrylic acid emulsion, so that the water color ink that manufactures a finished product uses.
Second step: acrylic resin liquid and the wetting dispersing auxiliary of pigment dyestuff and 10% are carried out grinding distribution, wetting through sand mill together, finally grind into about 30%～40% look content and the pre-dispersed aqueous color paste with 25 seconds/3# cup/25 ℃ of flowabilities;
The 3rd step: film-forming aqueous ACRYLIC EMULSION, pre-dispersed aqueous color paste and corresponding additive are required to put into the dispersion a mixing bowl according to different formula rates disperse to stir.Disperseing churning time is 40 minutes, and stirring velocity is 800 rev/mins;
The 4th step: will disperse to stir complete water color ink filling, packing becomes finished product.
Above-mentioned only is specific embodiments of the invention, but design concept of the present invention is not limited to this, allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should belong to the behavior of invading protection domain of the present invention.
Claims (8)
1. a water-based ink for plastic table printing is characterized in that, by weight, comprising:
The tg value is aqueous acrylic emulsion 55-65 part of-40 ℃～25 ℃;
Aqueous color paste 25-35 part; With
Aqueous promoter 3-6 part
Wherein, this aqueous promoter comprises:
Wherein, described water-based quick dry agent is the zinc oxide emulsion;
Described aqueous acrylic emulsion comprises:
Aqueous acrylic emulsion A:25～35 part, this emulsion Tg value is 15 ℃～18 ℃, molecular weight〉200000; Solid content 45%～48%, acid number 50～60, viscosity 800, pH value 8.5～8.9, density 1.05;
Aqueous acrylic emulsion B:30～35 part, this emulsion Tg value is-35 ℃～-45 ℃, molecular weight〉200000, acid number 20～30, viscosity 300～400, pH value 8.5～8.9, density 1.05.
2. a kind of water-based ink for plastic table printing as claimed in claim 1, it is characterized in that: pre-dispersed mill base fineness median size is 0.5～0.8 micron.
3. a kind of water-based ink for plastic table printing as claimed in claim 1 is characterized in that: described aqueous wetting agent is the poly-silicon alkyl oxide of low molecular polyether modification ethoxylation dimethyl.
4. a kind of water-based ink for plastic table printing as claimed in claim 1 is characterized in that: in the described water-based pH value and dispersion agent be water soluble amino alcohol or its mixture.
5. a kind of water-based ink for plastic table printing as claimed in claim 1, it is characterized in that: described water-based flow agent is aqueous emulsion of dimethyl polysiloxane fluid.
6. a kind of water-based ink for plastic table printing as claimed in claim 1, it is characterized in that: described aqueous wear-resistant agent is white emulsifying wax.
7. a kind of water-based ink for plastic table printing as claimed in claim 1 is characterized in that: described water-based bridging agent is solid content greater than 99% trifunctional aziridine bridging agent.
8. method for preparing each described water-based ink for plastic table printing of claim 1 to 7 may further comprise the steps:
The first step: solid propenoic acid resin is carried out synthetic chemistry reaction, copolymerization film forming according to different demand prescriptions in reactor;
Second step: acrylic resin liquid and the wetting dispersing auxiliary of pigment dyestuff and 10% are carried out grinding distribution, wetting, the pre-dispersed aqueous color paste that finally grinds to form 30%～40% look content and have 25 seconds/3# cup/25 ℃ of flowabilities through sand mill together;
The 3rd step: film-forming aqueous ACRYLIC EMULSION, pre-dispersed aqueous color paste and corresponding additive are required to put into the dispersion a mixing bowl according to different formula rates disperse to stir; Disperseing churning time is 30～45 minutes, and stirring velocity is 600～1000 rev/mins;
The 4th step: will disperse to stir complete water color ink filling, packing becomes finished product.
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| CN102358810B (en) * | 2011-09-14 | 2015-04-01 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Environment-friendly type water-based intaglio ink used for package printing and preparation method thereof |
| CN104559465B (en) * | 2013-10-24 | 2016-08-17 | 中国科学院化学研究所 | Environment-friendly type aqueous ink and preparation method thereof |
| CN103694789B (en) * | 2013-11-28 | 2015-10-28 | 福建省格林春天科技有限公司 | A kind of wallpaper use ink with repelling effect and preparation method thereof |
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| CN109337440A (en) * | 2018-09-26 | 2019-02-15 | 浙江美浓世纪集团有限公司 | A kind of environment-friendly water-based gravure printing ink and preparation method thereof |
| CN109810566A (en) * | 2019-01-16 | 2019-05-28 | 浙江理工大学 | A kind of structure of writing is added lustre to the preparation and its application of ink |
| CN110041750B (en) * | 2019-03-27 | 2022-06-03 | 山东华诺日化有限公司 | Full-aqueous ink and preparation method thereof |
| CN110760219A (en) * | 2019-11-29 | 2020-02-07 | 湖北淡雅香生物科技股份有限公司 | Full-aqueous plastic flexographic ink and preparation method thereof |
| CN111100504A (en) * | 2020-01-23 | 2020-05-05 | 上海保立佳新材料有限公司 | Water-based high-temperature-resistant ink for thermal paper printing and preparation method thereof |
| CN111647309A (en) * | 2020-06-15 | 2020-09-11 | 上海墨传新材料科技有限公司 | Water-based ink capable of being dried by microwave and microwave drying method thereof |
| CN112210245A (en) * | 2020-10-12 | 2021-01-12 | 福建格林春天新材料股份有限公司 | Water-based ink for sanitary packaging material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702126A (en) * | 2005-06-06 | 2005-11-30 | 贺文海 | Aqueous ink used for plastic |
| CN101328329A (en) * | 2007-06-22 | 2008-12-24 | 东莞市佳景印刷材料有限公司 | Aqueous flexible plate printing ink and preparation thereof |
| CN101824246A (en) * | 2010-05-06 | 2010-09-08 | 合肥元和水性化学技术有限公司 | Water-based flexographic ink system dedicated to dual-PE paper cups |
-
2011
- 2011-01-19 CN CN 201110022124 patent/CN102153909B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702126A (en) * | 2005-06-06 | 2005-11-30 | 贺文海 | Aqueous ink used for plastic |
| CN101328329A (en) * | 2007-06-22 | 2008-12-24 | 东莞市佳景印刷材料有限公司 | Aqueous flexible plate printing ink and preparation thereof |
| CN101824246A (en) * | 2010-05-06 | 2010-09-08 | 合肥元和水性化学技术有限公司 | Water-based flexographic ink system dedicated to dual-PE paper cups |
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