CN109810566A - A kind of structure of writing is added lustre to the preparation and its application of ink - Google Patents
A kind of structure of writing is added lustre to the preparation and its application of ink Download PDFInfo
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- CN109810566A CN109810566A CN201910039435.XA CN201910039435A CN109810566A CN 109810566 A CN109810566 A CN 109810566A CN 201910039435 A CN201910039435 A CN 201910039435A CN 109810566 A CN109810566 A CN 109810566A
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- ink
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- preparation
- add lustre
- write structure
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- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 239000000084 colloidal system Substances 0.000 claims abstract description 11
- 239000002562 thickening agent Substances 0.000 claims abstract description 10
- 239000011806 microball Substances 0.000 claims abstract description 7
- 239000000919 ceramic Substances 0.000 claims abstract description 6
- 239000011521 glass Substances 0.000 claims abstract description 5
- 239000000123 paper Substances 0.000 claims abstract description 5
- 239000004033 plastic Substances 0.000 claims abstract description 5
- 229920003023 plastic Polymers 0.000 claims abstract description 5
- 239000003112 inhibitor Substances 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims abstract description 3
- 239000004753 textile Substances 0.000 claims abstract description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 7
- 235000010413 sodium alginate Nutrition 0.000 claims description 7
- 239000000661 sodium alginate Substances 0.000 claims description 7
- 229940005550 sodium alginate Drugs 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 230000001629 suppression Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 22
- 239000002932 luster Substances 0.000 abstract description 5
- 239000004038 photonic crystal Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 239000011022 opal Substances 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 3
- 230000008020 evaporation Effects 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract description 3
- 238000001338 self-assembly Methods 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 8
- 239000003643 water by type Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 241000190070 Sarracenia purpurea Species 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- PXFBZOLANLWPMH-UHFFFAOYSA-N 16-Epiaffinine Natural products C1C(C2=CC=CC=C2N2)=C2C(=O)CC2C(=CC)CN(C)C1C2CO PXFBZOLANLWPMH-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- -1 siloxanes Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Structure can be write the invention discloses one kind to add lustre to the preparation and its application of ink, the ink is mainly uniformly mixed to get by following parts by weight of component substance: 5.0-10.0 parts of monodisperse black colloid micro ball (in terms of solid content), 0.2-1.0 parts of bridging agent, 0.5-1.0 parts of coffee ring inhibitor, 0.3-1.0 parts of levelling agent, 0.5-1.0 parts of thickener, 10.0-20.0 parts of decentralized medium.Gained ink mobility of the invention is good, performance is stablized, it can be applied on the substrates such as paper, textile, glass, ceramics, plastics by ways of writing, with the evaporation of solvent, microballoon meeting self assembly is piled into the photonic crystal similar to Ou Po opal microstructure, by the way that diffraction occurs with visible light, metallic luster, bright and colourful, the apparent durable construction color effect of rainbow effect can be obtained.
Description
Technical field
The invention belongs to ink areas, and in particular to a kind of structure that can write is added lustre to the preparation and its application of ink.
Background technique
Ink is the important materials for printing, it is expressed the pattern and text on stock by printing or air brushing,
The fields such as drawing, packaging, decoration, advertisement are widely used.With the promotion of aesthetic requirement, people have spy to exploitation and preparation
The ink product of different visual effect is always enjoyed it.
In nature, some organisms, such as Ou Po opal, it is big dodge butterfly, can show with metallic luster, agile
Changeable particular color effect.By adequately studying, these gorgeous particular colors are known as schemochrome by people.Substantially,
Such color is formed the effects of scattering, interference and diffraction occurs by some special physical structures and light, is usually had
Feature not available for the ordinary colors such as high brightness, high saturation, polarization characteristic and rainbow effect (with angle discolouration), it is this
Environmentally protective color effect is increasingly subject to the concern of researcher.
Based on the further investigation to schemochrome, present invention applicant, it is realized that if can develop one kind can be applied to drawing,
DIYT sympathizes, the structure of DIY Freehandhand-drawing ceramic cup and decoration etc. is added lustre to ink, will greatly enrich the diversity of existing product, and not
Losing is a kind of fresh intention.
Summary of the invention
Structure can be write the purpose of the present invention is to provide one kind to add lustre to the preparation and its application of ink, it will be with monodisperse glue
Body microballoon is that main component develops one kind and can write structure and adds lustre to ink.After preparation gained ink is applied on substrate, with molten
The evaporation of agent, microballoon meeting self assembly is piled into the photonic crystal similar to Ou Po opal microstructure, by sending out with visible light
Raw diffraction, can be obtained metallic luster, bright and colourful, the apparent durable construction color effect of rainbow effect.In order to make light
Sub- crystal structure has good stability, that is, keeps durable schemochrome effect, and friendship can be generated to microballoon by being innovatively added
The bridging agent of connection effect is reinforced affine between the associativity and layer of photonic crystals and substrate between adjacent microballoon by chemical action
Property.
In order to solve the above-mentioned technical problem, it adopts the following technical scheme that
A kind of structure of writing is added lustre to the preparation of ink, it is characterised in that: the ink is mainly by following parts by weight of component
Substance is uniformly mixed to get: partial size is 5.0-10.0 parts of the monodisperse black colloid micro ball (in terms of solid content) of 180-380nm, frame
0.2-1.0 parts of bridge agent, 0.5-1.0 parts of coffee ring inhibitor, 0.3-1.0 parts of levelling agent, 0.5-1.0 parts of thickener, decentralized medium
10.0-20.0 parts.
After it is preferred that, the monodisperse black colloid micro ball is surface or internal load has black dyes and surface is rich in carboxylic
Polystyrene (PSt) class colloid micro ball of base (- COOH).
After it is preferred that, the bridging agent is one of organosilicon 9301, aziridine.
After it is preferred that, the coffee ring inhibitor is still emulsifier FT625, ethyl acetate, n,N-Dimethylformamide, two
Any one in ethylene glycol, triethylene glycol.
After it is preferred that, the levelling agent is the butyl polyacrylate levelling agent RB505 for adsorbing titanium dioxide silicon substrate, polyether-modified poly-
Any one in siloxanes levelling agent SC-333, BYK-333 type levelling agent.
After it is preferred that, the decentralized medium is deionized water, in deionized water/ethyl alcohol mixed solution of different volumes ratio
It is a kind of.
After it is preferred that, the thickener is sodium alginate.
After it is preferred that, each component is placed in ultrasonic dispersers upon mixing to be dispersed.
After it is preferred that, the ink is any one in paper, textile, glass, ceramics and plastics using substrate.
After it is preferred that, the application mode of the ink includes writing or blade coating.
As a result of the above technical solution, the following beneficial effects are obtained:
One kind of the present invention can write structure and add lustre to the preparation and its application of ink, will be with monodisperse latex for main group
It separately sends out one kind and can write structure and add lustre to ink.After preparation gained ink is applied on substrate, with the evaporation of solvent, microballoon meeting
Self assembly is piled into the photonic crystal similar to Ou Po opal microstructure, by the way that diffraction occurs with visible light
Obtain metallic luster, bright and colourful, the apparent durable construction color effect of rainbow effect.It is good in order to have photon crystal structure
Good stability, that is, keep durable schemochrome effect, and the bridging agent that can generate crosslinked action to microballoon is innovatively added, leads to
It crosses chemical action and reinforces compatibility between associativity and layer of photonic crystals and substrate between adjacent microballoon.
Be applied on different substrate materials by writing and scratching mode so that gained printed matter show with metallic luster,
Bright and colourful, the apparent color effect of rainbow effect is greatly enriched the colors of existing similar ink product.
In addition, the present invention by way of chemical crosslinking, makes gained ink be applied to the photon being prepared on substrate crystalline substance
Body structure has good stability, ensure that the durability of its schemochrome effect.Gained ink mobility is good, performance is stablized,
It is suitable for promoting and applying.
Detailed description of the invention
Fig. 1 be in embodiment 1 using can writing ink preparation gained green photon crystal pattern digital photograph;
Fig. 2 be in embodiment 1 using can writing ink preparation gained pattern through before folded bent and friction testing SEM scheme
Picture;
Fig. 3 be in embodiment 1 using can SEM of the writing ink preparation gained pattern after folded bent and friction testing scheme
Picture.
Specific embodiment
Below with reference to specific embodiment, the invention will be further described:
Embodiment 1
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) colloid of 10 parts of 235nm
Microballoon is added into 10 parts of deionized waters, then sequentially adds 0.2 part of aziridine, 0.5 part of still emulsifier FT625, and 0.5
Part sodium alginate thickener, the butyl polyacrylate levelling agent RB505 of 0.3 part of absorption titanium dioxide silicon substrate, after each component is mixed
It is placed in ultrasonic dispersers and disperses 15min, obtain finely dispersed structure and add lustre to ink.This structure is added lustre to ink by writing brush
It is drawn on white A4 paper, after to be dried, that is, obtains gorgeous, the apparent structure colored pattern (Fig. 1) of iris of adding lustre to.It is folded through design
After bending and friction testing, gained pattern does not occur obviously to fall off on A4 paper, and schemochrome effect keeps good, and Fig. 2 illustrates survey
The SEM image of pattern before trying, Fig. 3 illustrate the SEM image of pattern after test.
Embodiment 2
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) colloid of 6 parts of 235nm
Microballoon is added into 12.5 parts of deionized waters, then sequentially adds 0.4 part of aziridine organosilicon, 9301,0.6 part of acetic acid second
Each component is mixed and is placed on by ester, 0.6 part of sodium alginate thickener, 0.45 part of Siloxane-Oxyalkylene Copolymers levelling agent SC-333
Disperse 15min in ultrasonic dispersers, obtains finely dispersed structure and add lustre to ink.By writing brush by this structure add lustre to ink draw
In on transparency glass plate, after to be dried, that is, gorgeous, the apparent structure colored pattern of iris that adds lustre to is obtained.It is transparent after rubbed test
Gained pattern does not occur obviously to fall off on glass plate, and schemochrome effect keeps good.
Embodiment 3
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) glue of 7.5 parts of 235nm
Body microballoon is added into 15 parts of deionized waters, then sequentially adds 0.6 part of organosilicon, 9301,0.75 part of N, N dimethyl formyl
Each component is mixed to be placed in ultrasonic dispersers and be divided by amine, 0.75 part of sodium alginate thickener, 0.6 part of BYK-333 type levelling agent
15min is dissipated, finely dispersed structure is obtained and adds lustre to ink.This structure ink that adds lustre to is drawn on real silk fabric by writing brush,
After to be dried, that is, obtain gorgeous, the apparent structure colored pattern of iris that adds lustre to.After design folded bent and friction testing, silk
Gained pattern does not occur obviously to fall off on fabric, and schemochrome effect keeps good.
Embodiment 4
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) colloid of 9 parts of 235nm
Microballoon is added into 17.5 parts of deionized waters, then sequentially adds 0.8 part of organosilicon, 9301,0.9 part of diethylene glycol, and 0.9 part
Sodium alginate thickener, the butyl polyacrylate levelling agent RB505 of 0.75 part of absorption titanium dioxide silicon substrate, mixes postposition for each component
Disperse 15min in ultrasonic dispersers, obtains finely dispersed structure and add lustre to ink.This structure ink that adds lustre to is drawn by writing brush
It is formed on ceramic water cup extexine, after to be dried, that is, obtains gorgeous, the apparent structure colored pattern of iris that adds lustre to.Rubbed test
Afterwards, upper gained pattern does not occur obviously to fall off on ceramic water cup extexine, and schemochrome effect keeps good.
Embodiment 5
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) colloid of 10 parts of 235nm
Microballoon is added into 20 parts of deionized waters, then sequentially adds 1 part of organosilicon, 9301,1 part of triethylene glycol, 1 part of sodium alginate
Thickener, the butyl polyacrylate levelling agent RB505 of 1 part of absorption titanium dioxide silicon substrate, each component is mixed and is placed on ultrasonic disperse
Disperse 15min in device, obtains finely dispersed structure and add lustre to ink.This structure ink that adds lustre to is drawn on PVC plastic by writing brush
On flitch, after to be dried, that is, gorgeous, the apparent structure colored pattern of iris that adds lustre to is obtained.Through design folded bent and friction testing
Afterwards, gained pattern does not occur obviously to fall off on PVC plastic flitch, and schemochrome effect keeps good.
The above is only specific embodiments of the present invention, but technical characteristic of the invention is not limited thereto.It is any with this hair
Based on bright, to solve essentially identical technical problem, essentially identical technical effect is realized, made ground simple change, etc.
With replacement or modification etc., all it is covered by among protection scope of the present invention.
Claims (10)
- Add lustre to the preparation of ink 1. one kind can write structure, it is characterised in that: the ink is mainly by following parts by weight of component object Matter is uniformly mixed to get: partial size is 5.0-10.0 parts of the monodisperse black colloid micro ball (in terms of solid content) of 180-380nm, is built bridge 0.2-1.0 parts of agent, 0.5-1.0 parts of coffee ring inhibitor, 0.3-1.0 parts of levelling agent, 0.5-1.0 parts of thickener, decentralized medium 10.0-20.0 parts.
- Add lustre to the preparation of ink 2. one kind according to claim 1 can write structure, it is characterised in that: the monodisperse Black colloid micro ball is surface or internal load has black dyes and surface is rich in polystyrene (PSt) class of carboxyl (- COOH) Colloid micro ball.
- Add lustre to the preparation of ink 3. one kind according to claim 1 can write structure, it is characterised in that: the bridging agent For one of organosilicon 9301, aziridine.
- Add lustre to the preparation of ink 4. one kind according to claim 1 can write structure, it is characterised in that: the coffee ring suppression Preparation is still emulsifier FT625, ethyl acetate, N,N-dimethylformamide, diethylene glycol, any one in triethylene glycol Kind.
- Add lustre to the preparation of ink 5. one kind according to claim 1 can write structure, it is characterised in that: the levelling agent is Adsorb butyl polyacrylate levelling agent RB505, Siloxane-Oxyalkylene Copolymers levelling agent SC-333, BYK-333 of titanium dioxide silicon substrate Any one in type levelling agent.
- Add lustre to the preparation of ink 6. one kind according to claim 1 can write structure, it is characterised in that: the decentralized medium For one of deionized water, deionized water/ethyl alcohol mixed solution of different volumes ratio.
- Add lustre to the preparation of ink 7. one kind according to claim 1 can write structure, it is characterised in that: the thickener For sodium alginate.
- Add lustre to the preparation of ink 8. one kind according to claim 1 can write structure, it is characterised in that: each component is mixing It is placed in ultrasonic dispersers and disperses.
- Add lustre to the application of ink 9. one kind as described in claim 1 can write structure, it is characterised in that: the application of the ink Substrate is any one in paper, textile, glass, ceramics and plastics.
- Add lustre to the application of ink 10. one kind according to claim 9 can write structure, it is characterised in that: the ink Application mode includes writing or blade coating.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910039435.XA CN109810566A (en) | 2019-01-16 | 2019-01-16 | A kind of structure of writing is added lustre to the preparation and its application of ink |
Applications Claiming Priority (1)
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CN201910039435.XA CN109810566A (en) | 2019-01-16 | 2019-01-16 | A kind of structure of writing is added lustre to the preparation and its application of ink |
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CN201910039435.XA Pending CN109810566A (en) | 2019-01-16 | 2019-01-16 | A kind of structure of writing is added lustre to the preparation and its application of ink |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110791981A (en) * | 2019-10-12 | 2020-02-14 | 浙江理工大学 | Preparation method of photonic crystal structure chromogenic fabric based on deep-implantation self-assembly effect |
CN111254739A (en) * | 2020-03-02 | 2020-06-09 | 浙江理工大学 | Structural color-generating window paper with double-sided printing effect and preparation method thereof |
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CN102153909A (en) * | 2011-01-19 | 2011-08-17 | 厦门格林春天环保科技材料有限公司 | Water-based ink for plastic table printing |
CN103788770A (en) * | 2014-01-27 | 2014-05-14 | 浙江理工大学 | Colloidal microsphere ink for coloring textile digital printing structure and application of colloidal microsphere ink |
CN105017863A (en) * | 2015-07-01 | 2015-11-04 | 苏州中科纳福材料科技有限公司 | Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink |
CN108442138A (en) * | 2018-02-08 | 2018-08-24 | 浙江理工大学 | A kind of textile digital spray printing self assembly adsorption dye-type nanoparticle structure is added lustre to the preparation method of ink |
-
2019
- 2019-01-16 CN CN201910039435.XA patent/CN109810566A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102153909A (en) * | 2011-01-19 | 2011-08-17 | 厦门格林春天环保科技材料有限公司 | Water-based ink for plastic table printing |
CN103788770A (en) * | 2014-01-27 | 2014-05-14 | 浙江理工大学 | Colloidal microsphere ink for coloring textile digital printing structure and application of colloidal microsphere ink |
CN105017863A (en) * | 2015-07-01 | 2015-11-04 | 苏州中科纳福材料科技有限公司 | Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink |
CN108442138A (en) * | 2018-02-08 | 2018-08-24 | 浙江理工大学 | A kind of textile digital spray printing self assembly adsorption dye-type nanoparticle structure is added lustre to the preparation method of ink |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110791981A (en) * | 2019-10-12 | 2020-02-14 | 浙江理工大学 | Preparation method of photonic crystal structure chromogenic fabric based on deep-implantation self-assembly effect |
CN111254739A (en) * | 2020-03-02 | 2020-06-09 | 浙江理工大学 | Structural color-generating window paper with double-sided printing effect and preparation method thereof |
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Application publication date: 20190528 |