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CN109810566A - A kind of structure of writing is added lustre to the preparation and its application of ink - Google Patents

A kind of structure of writing is added lustre to the preparation and its application of ink Download PDF

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Publication number
CN109810566A
CN109810566A CN201910039435.XA CN201910039435A CN109810566A CN 109810566 A CN109810566 A CN 109810566A CN 201910039435 A CN201910039435 A CN 201910039435A CN 109810566 A CN109810566 A CN 109810566A
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CN
China
Prior art keywords
ink
parts
preparation
add lustre
write structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910039435.XA
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Chinese (zh)
Inventor
周岚
吴钰
刘国金
李慧
赖伟根
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Sci Tech University ZSTU
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Zhejiang Sci Tech University ZSTU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN201910039435.XA priority Critical patent/CN109810566A/en
Publication of CN109810566A publication Critical patent/CN109810566A/en
Pending legal-status Critical Current

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Abstract

Structure can be write the invention discloses one kind to add lustre to the preparation and its application of ink, the ink is mainly uniformly mixed to get by following parts by weight of component substance: 5.0-10.0 parts of monodisperse black colloid micro ball (in terms of solid content), 0.2-1.0 parts of bridging agent, 0.5-1.0 parts of coffee ring inhibitor, 0.3-1.0 parts of levelling agent, 0.5-1.0 parts of thickener, 10.0-20.0 parts of decentralized medium.Gained ink mobility of the invention is good, performance is stablized, it can be applied on the substrates such as paper, textile, glass, ceramics, plastics by ways of writing, with the evaporation of solvent, microballoon meeting self assembly is piled into the photonic crystal similar to Ou Po opal microstructure, by the way that diffraction occurs with visible light, metallic luster, bright and colourful, the apparent durable construction color effect of rainbow effect can be obtained.

Description

A kind of structure of writing is added lustre to the preparation and its application of ink
Technical field
The invention belongs to ink areas, and in particular to a kind of structure that can write is added lustre to the preparation and its application of ink.
Background technique
Ink is the important materials for printing, it is expressed the pattern and text on stock by printing or air brushing, The fields such as drawing, packaging, decoration, advertisement are widely used.With the promotion of aesthetic requirement, people have spy to exploitation and preparation The ink product of different visual effect is always enjoyed it.
In nature, some organisms, such as Ou Po opal, it is big dodge butterfly, can show with metallic luster, agile Changeable particular color effect.By adequately studying, these gorgeous particular colors are known as schemochrome by people.Substantially, Such color is formed the effects of scattering, interference and diffraction occurs by some special physical structures and light, is usually had Feature not available for the ordinary colors such as high brightness, high saturation, polarization characteristic and rainbow effect (with angle discolouration), it is this Environmentally protective color effect is increasingly subject to the concern of researcher.
Based on the further investigation to schemochrome, present invention applicant, it is realized that if can develop one kind can be applied to drawing, DIYT sympathizes, the structure of DIY Freehandhand-drawing ceramic cup and decoration etc. is added lustre to ink, will greatly enrich the diversity of existing product, and not Losing is a kind of fresh intention.
Summary of the invention
Structure can be write the purpose of the present invention is to provide one kind to add lustre to the preparation and its application of ink, it will be with monodisperse glue Body microballoon is that main component develops one kind and can write structure and adds lustre to ink.After preparation gained ink is applied on substrate, with molten The evaporation of agent, microballoon meeting self assembly is piled into the photonic crystal similar to Ou Po opal microstructure, by sending out with visible light Raw diffraction, can be obtained metallic luster, bright and colourful, the apparent durable construction color effect of rainbow effect.In order to make light Sub- crystal structure has good stability, that is, keeps durable schemochrome effect, and friendship can be generated to microballoon by being innovatively added The bridging agent of connection effect is reinforced affine between the associativity and layer of photonic crystals and substrate between adjacent microballoon by chemical action Property.
In order to solve the above-mentioned technical problem, it adopts the following technical scheme that
A kind of structure of writing is added lustre to the preparation of ink, it is characterised in that: the ink is mainly by following parts by weight of component Substance is uniformly mixed to get: partial size is 5.0-10.0 parts of the monodisperse black colloid micro ball (in terms of solid content) of 180-380nm, frame 0.2-1.0 parts of bridge agent, 0.5-1.0 parts of coffee ring inhibitor, 0.3-1.0 parts of levelling agent, 0.5-1.0 parts of thickener, decentralized medium 10.0-20.0 parts.
After it is preferred that, the monodisperse black colloid micro ball is surface or internal load has black dyes and surface is rich in carboxylic Polystyrene (PSt) class colloid micro ball of base (- COOH).
After it is preferred that, the bridging agent is one of organosilicon 9301, aziridine.
After it is preferred that, the coffee ring inhibitor is still emulsifier FT625, ethyl acetate, n,N-Dimethylformamide, two Any one in ethylene glycol, triethylene glycol.
After it is preferred that, the levelling agent is the butyl polyacrylate levelling agent RB505 for adsorbing titanium dioxide silicon substrate, polyether-modified poly- Any one in siloxanes levelling agent SC-333, BYK-333 type levelling agent.
After it is preferred that, the decentralized medium is deionized water, in deionized water/ethyl alcohol mixed solution of different volumes ratio It is a kind of.
After it is preferred that, the thickener is sodium alginate.
After it is preferred that, each component is placed in ultrasonic dispersers upon mixing to be dispersed.
After it is preferred that, the ink is any one in paper, textile, glass, ceramics and plastics using substrate.
After it is preferred that, the application mode of the ink includes writing or blade coating.
As a result of the above technical solution, the following beneficial effects are obtained:
One kind of the present invention can write structure and add lustre to the preparation and its application of ink, will be with monodisperse latex for main group It separately sends out one kind and can write structure and add lustre to ink.After preparation gained ink is applied on substrate, with the evaporation of solvent, microballoon meeting Self assembly is piled into the photonic crystal similar to Ou Po opal microstructure, by the way that diffraction occurs with visible light Obtain metallic luster, bright and colourful, the apparent durable construction color effect of rainbow effect.It is good in order to have photon crystal structure Good stability, that is, keep durable schemochrome effect, and the bridging agent that can generate crosslinked action to microballoon is innovatively added, leads to It crosses chemical action and reinforces compatibility between associativity and layer of photonic crystals and substrate between adjacent microballoon.
Be applied on different substrate materials by writing and scratching mode so that gained printed matter show with metallic luster, Bright and colourful, the apparent color effect of rainbow effect is greatly enriched the colors of existing similar ink product.
In addition, the present invention by way of chemical crosslinking, makes gained ink be applied to the photon being prepared on substrate crystalline substance Body structure has good stability, ensure that the durability of its schemochrome effect.Gained ink mobility is good, performance is stablized, It is suitable for promoting and applying.
Detailed description of the invention
Fig. 1 be in embodiment 1 using can writing ink preparation gained green photon crystal pattern digital photograph;
Fig. 2 be in embodiment 1 using can writing ink preparation gained pattern through before folded bent and friction testing SEM scheme Picture;
Fig. 3 be in embodiment 1 using can SEM of the writing ink preparation gained pattern after folded bent and friction testing scheme Picture.
Specific embodiment
Below with reference to specific embodiment, the invention will be further described:
Embodiment 1
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) colloid of 10 parts of 235nm Microballoon is added into 10 parts of deionized waters, then sequentially adds 0.2 part of aziridine, 0.5 part of still emulsifier FT625, and 0.5 Part sodium alginate thickener, the butyl polyacrylate levelling agent RB505 of 0.3 part of absorption titanium dioxide silicon substrate, after each component is mixed It is placed in ultrasonic dispersers and disperses 15min, obtain finely dispersed structure and add lustre to ink.This structure is added lustre to ink by writing brush It is drawn on white A4 paper, after to be dried, that is, obtains gorgeous, the apparent structure colored pattern (Fig. 1) of iris of adding lustre to.It is folded through design After bending and friction testing, gained pattern does not occur obviously to fall off on A4 paper, and schemochrome effect keeps good, and Fig. 2 illustrates survey The SEM image of pattern before trying, Fig. 3 illustrate the SEM image of pattern after test.
Embodiment 2
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) colloid of 6 parts of 235nm Microballoon is added into 12.5 parts of deionized waters, then sequentially adds 0.4 part of aziridine organosilicon, 9301,0.6 part of acetic acid second Each component is mixed and is placed on by ester, 0.6 part of sodium alginate thickener, 0.45 part of Siloxane-Oxyalkylene Copolymers levelling agent SC-333 Disperse 15min in ultrasonic dispersers, obtains finely dispersed structure and add lustre to ink.By writing brush by this structure add lustre to ink draw In on transparency glass plate, after to be dried, that is, gorgeous, the apparent structure colored pattern of iris that adds lustre to is obtained.It is transparent after rubbed test Gained pattern does not occur obviously to fall off on glass plate, and schemochrome effect keeps good.
Embodiment 3
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) glue of 7.5 parts of 235nm Body microballoon is added into 15 parts of deionized waters, then sequentially adds 0.6 part of organosilicon, 9301,0.75 part of N, N dimethyl formyl Each component is mixed to be placed in ultrasonic dispersers and be divided by amine, 0.75 part of sodium alginate thickener, 0.6 part of BYK-333 type levelling agent 15min is dissipated, finely dispersed structure is obtained and adds lustre to ink.This structure ink that adds lustre to is drawn on real silk fabric by writing brush, After to be dried, that is, obtain gorgeous, the apparent structure colored pattern of iris that adds lustre to.After design folded bent and friction testing, silk Gained pattern does not occur obviously to fall off on fabric, and schemochrome effect keeps good.
Embodiment 4
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) colloid of 9 parts of 235nm Microballoon is added into 17.5 parts of deionized waters, then sequentially adds 0.8 part of organosilicon, 9301,0.9 part of diethylene glycol, and 0.9 part Sodium alginate thickener, the butyl polyacrylate levelling agent RB505 of 0.75 part of absorption titanium dioxide silicon substrate, mixes postposition for each component Disperse 15min in ultrasonic dispersers, obtains finely dispersed structure and add lustre to ink.This structure ink that adds lustre to is drawn by writing brush It is formed on ceramic water cup extexine, after to be dried, that is, obtains gorgeous, the apparent structure colored pattern of iris that adds lustre to.Rubbed test Afterwards, upper gained pattern does not occur obviously to fall off on ceramic water cup extexine, and schemochrome effect keeps good.
Embodiment 5
Accurately weigh polystyrene-n-butyl acrylate-methacrylic acid (P (St-BA-MAA)) colloid of 10 parts of 235nm Microballoon is added into 20 parts of deionized waters, then sequentially adds 1 part of organosilicon, 9301,1 part of triethylene glycol, 1 part of sodium alginate Thickener, the butyl polyacrylate levelling agent RB505 of 1 part of absorption titanium dioxide silicon substrate, each component is mixed and is placed on ultrasonic disperse Disperse 15min in device, obtains finely dispersed structure and add lustre to ink.This structure ink that adds lustre to is drawn on PVC plastic by writing brush On flitch, after to be dried, that is, gorgeous, the apparent structure colored pattern of iris that adds lustre to is obtained.Through design folded bent and friction testing Afterwards, gained pattern does not occur obviously to fall off on PVC plastic flitch, and schemochrome effect keeps good.
The above is only specific embodiments of the present invention, but technical characteristic of the invention is not limited thereto.It is any with this hair Based on bright, to solve essentially identical technical problem, essentially identical technical effect is realized, made ground simple change, etc. With replacement or modification etc., all it is covered by among protection scope of the present invention.

Claims (10)

  1. Add lustre to the preparation of ink 1. one kind can write structure, it is characterised in that: the ink is mainly by following parts by weight of component object Matter is uniformly mixed to get: partial size is 5.0-10.0 parts of the monodisperse black colloid micro ball (in terms of solid content) of 180-380nm, is built bridge 0.2-1.0 parts of agent, 0.5-1.0 parts of coffee ring inhibitor, 0.3-1.0 parts of levelling agent, 0.5-1.0 parts of thickener, decentralized medium 10.0-20.0 parts.
  2. Add lustre to the preparation of ink 2. one kind according to claim 1 can write structure, it is characterised in that: the monodisperse Black colloid micro ball is surface or internal load has black dyes and surface is rich in polystyrene (PSt) class of carboxyl (- COOH) Colloid micro ball.
  3. Add lustre to the preparation of ink 3. one kind according to claim 1 can write structure, it is characterised in that: the bridging agent For one of organosilicon 9301, aziridine.
  4. Add lustre to the preparation of ink 4. one kind according to claim 1 can write structure, it is characterised in that: the coffee ring suppression Preparation is still emulsifier FT625, ethyl acetate, N,N-dimethylformamide, diethylene glycol, any one in triethylene glycol Kind.
  5. Add lustre to the preparation of ink 5. one kind according to claim 1 can write structure, it is characterised in that: the levelling agent is Adsorb butyl polyacrylate levelling agent RB505, Siloxane-Oxyalkylene Copolymers levelling agent SC-333, BYK-333 of titanium dioxide silicon substrate Any one in type levelling agent.
  6. Add lustre to the preparation of ink 6. one kind according to claim 1 can write structure, it is characterised in that: the decentralized medium For one of deionized water, deionized water/ethyl alcohol mixed solution of different volumes ratio.
  7. Add lustre to the preparation of ink 7. one kind according to claim 1 can write structure, it is characterised in that: the thickener For sodium alginate.
  8. Add lustre to the preparation of ink 8. one kind according to claim 1 can write structure, it is characterised in that: each component is mixing It is placed in ultrasonic dispersers and disperses.
  9. Add lustre to the application of ink 9. one kind as described in claim 1 can write structure, it is characterised in that: the application of the ink Substrate is any one in paper, textile, glass, ceramics and plastics.
  10. Add lustre to the application of ink 10. one kind according to claim 9 can write structure, it is characterised in that: the ink Application mode includes writing or blade coating.
CN201910039435.XA 2019-01-16 2019-01-16 A kind of structure of writing is added lustre to the preparation and its application of ink Pending CN109810566A (en)

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Application Number Priority Date Filing Date Title
CN201910039435.XA CN109810566A (en) 2019-01-16 2019-01-16 A kind of structure of writing is added lustre to the preparation and its application of ink

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110791981A (en) * 2019-10-12 2020-02-14 浙江理工大学 Preparation method of photonic crystal structure chromogenic fabric based on deep-implantation self-assembly effect
CN111254739A (en) * 2020-03-02 2020-06-09 浙江理工大学 Structural color-generating window paper with double-sided printing effect and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153909A (en) * 2011-01-19 2011-08-17 厦门格林春天环保科技材料有限公司 Water-based ink for plastic table printing
CN103788770A (en) * 2014-01-27 2014-05-14 浙江理工大学 Colloidal microsphere ink for coloring textile digital printing structure and application of colloidal microsphere ink
CN105017863A (en) * 2015-07-01 2015-11-04 苏州中科纳福材料科技有限公司 Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink
CN108442138A (en) * 2018-02-08 2018-08-24 浙江理工大学 A kind of textile digital spray printing self assembly adsorption dye-type nanoparticle structure is added lustre to the preparation method of ink

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153909A (en) * 2011-01-19 2011-08-17 厦门格林春天环保科技材料有限公司 Water-based ink for plastic table printing
CN103788770A (en) * 2014-01-27 2014-05-14 浙江理工大学 Colloidal microsphere ink for coloring textile digital printing structure and application of colloidal microsphere ink
CN105017863A (en) * 2015-07-01 2015-11-04 苏州中科纳福材料科技有限公司 Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink
CN108442138A (en) * 2018-02-08 2018-08-24 浙江理工大学 A kind of textile digital spray printing self assembly adsorption dye-type nanoparticle structure is added lustre to the preparation method of ink

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110791981A (en) * 2019-10-12 2020-02-14 浙江理工大学 Preparation method of photonic crystal structure chromogenic fabric based on deep-implantation self-assembly effect
CN111254739A (en) * 2020-03-02 2020-06-09 浙江理工大学 Structural color-generating window paper with double-sided printing effect and preparation method thereof

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Application publication date: 20190528