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CN101992013A - Waste gas purifying system for highway tunnel - Google Patents

Waste gas purifying system for highway tunnel Download PDF

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Publication number
CN101992013A
CN101992013A CN 201010560343 CN201010560343A CN101992013A CN 101992013 A CN101992013 A CN 101992013A CN 201010560343 CN201010560343 CN 201010560343 CN 201010560343 A CN201010560343 A CN 201010560343A CN 101992013 A CN101992013 A CN 101992013A
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China
Prior art keywords
tunnel
waste gas
rose box
comprehensive purifying
clean water
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CN 201010560343
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Chinese (zh)
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CN101992013B (en
Inventor
董满生
胡晴
倪锦平
赵佳佳
余志平
刘凯
韩丁
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SCIENCE AND TEACHING DEVELOPMENT Department HEFEI POLYTECHNIC UNIV
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SCIENCE AND TEACHING DEVELOPMENT Department HEFEI POLYTECHNIC UNIV
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Priority to CN2010105603435A priority Critical patent/CN101992013B/en
Publication of CN101992013A publication Critical patent/CN101992013A/en
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Publication of CN101992013B publication Critical patent/CN101992013B/en
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Abstract

The invention discloses a waste gas purifying system for a highway tunnel, which is characterized in that the outlet end of a fan is provided with a gas inlet pipe, a suspended matter filter box, an active catalyst for ceramic carriers, a comprehensive purifying box and an exhaust pipe in sequence along the gas flow direction; the suspended matter filter box is a sealed container containing clean water; the comprehensive purifying box is a sealed container containing saturated solution with calcium and magnesium ions; and the active catalyst for ceramic carriers is formed by that the surfaces of the porous ceramic carriers are provided with active ingredient coatings. The waste gas purifying system is applied to tunnel ventilation and can directly reduce the construction cost and the ventilation operating cost.

Description

The vcehicular tunnel waste gas cleaning system
Technical field
The present invention relates to a kind of waste gas cleaning system, particularly a kind of waste gas cleaning system that is used for vcehicular tunnel.
Background technology
The tunnel typically refers to as underground passing for people, and vehicle travels, and inner headroom section is at 2m 2Above bar shaped engineering works.Pollutant component more complicated in the tunnel, it mainly is the tail gas and the dust granules of vehicle.These pernicious gases and dust granules are directly threatening human beings'health.The tail gas of vehicle not only smell is strange, and makes us dizzy, feels sick, and dust granules not only damages people's health but also may form smog, and the safety of driving in serious threat.Scientific analysis shows, contains hundreds of different compound in the vehicle exhaust, and major pollutants wherein have solid suspended particulates, carbon monoxide, carbon dioxide, hydrocarbon, oxynitrides, lead and oxygen sulfur compounds etc. such as dust, smog.According to statistics, the harmful exhaust of car discharge in a year is bigger 3 times than own wt.Now, we analyze the harm that mainly contains harmful substances in the vehicle exhaust.
1, solid suspended particle
The composition of solid suspended particle is very complicated, and has stronger adsorption capacity, can adsorb various metallic dusts, strong carcinogenic substance BaP and pathogenic microorganism etc.Solid suspended particle enters the human lung with breathing, is trapped in the different parts of respiratory tract in modes such as collision, diffusion, depositions, causes respiratory disease.When suspended particulate runs up to critical concentration, just can excite the formation malignant tumour.In addition, suspended particulate substance can also directly contact skin and eyes, blocks the hair follicle and the sweat gland of skin, causes dermatitis and eye conjunctivitis, even causes corneal injury.
2, carbon monoxide (CO)
Fast 250 times of the speed that carbon monoxide combines with hemoglobin in the blood than oxygen.Carbon monoxide enters blood circulation through respiratory tract, with generate carbonyl haemoglobin behind the hemoglobin affinity, thereby weaken blood to the function of respectively organizing delivery of oxygen, the harm central nervous system, cause people's dysfunction such as sensation, reaction, understanding, memory, weight person endangers blood circulation system, causes life danger.So,, also may cause fearful anoxic injury to the people even trace sucks carbon monoxide.
3, nitrogen oxide NO x
Nitrogen oxide mainly is meant nitric oxide, nitrogen dioxide, and they all are harmful gas, particularly respiratory system are had harm.In content of nitrogen dioxide is to expose 10 minutes in 9.4 milligrams/cubic metre the air, can cause people's respiratory system functional disturbance.
4, hydrocarbon HC
At present not clear it to the direct harm of health.But work as oxynitrides and hydrocarbon under the effect of solar ultraviolet, can produce a kind of irritating light blue smog that has, wherein include multiple complex compounds such as ozone, aldehydes, nitric acid lipid.The most outstanding harm is to stimulate eyes and upper respiratory tract mucous membrane to this photochemical fog to human body, causes eyes redness and laryngitis.In December nineteen fifty-two, photochemical fog takes place in London, the death toll long-term same period of many 4000 people in 4 days, and the death more than 45 years old is about at ordinary times 3 times at most; Be about at ordinary times 2 times below 1 year old.
5, dioxin
Dioxin is the environmental contaminants that health had very big threat, and it has strong carcinogenicity, and can cause deformity, and immunologic function and men and women's reproductive function of human body caused damage, be the strongest toxic compounds of at present known in the world toxicity it
Tail gas also can exert far reaching influence to human lives's environment when directly being detrimental to health.Sulfur dioxide in the tail gas has the strong impulse smell, causes the generation of " acid rain " when reaching finite concentration easily, causes soil and water source acidifying, influences the growth of crops and forest.Over nearly 100 years, climate warming has become a human big disaster.Glacier thawing, water level rise, EI Nino phenomenon, La Nina Phenomenon etc. have all brought stern challenge to human existence.Carbon dioxide then is the arch-criminal of global warming.
The tunnel ventilation purpose is at constructing tunnel and reduces smokescope operation stage and noxious pollutant concentration, the safety of assurance staff in tunnel and comfortable.In the construction in the tunnel of growing up, the quality of the quality of ventilation scheme, ventilation operational effect will directly have influence on cost, the operating environment of Tunnel Engineering, disaster relief function and operation benefits.For the traffic tunnel of growing up, although the frequency that fire takes place is very little, the influence that it causes and the extent of damage are huge.If the ventilation effect in the tunnel is bad, the harm for human body also is significant so, even can cause acute poisoning.So in the tunnel a good ventilating system is arranged, be significant.
At present, the mode of permanent ventilation of tunnel mainly contains the draft type of gravity-flow ventilation, force ventilation and nature and mechanically combining, and these also are present the most frequently used draft types in the tunnel ventilation design.With regard to vcehicular tunnel, one is 20%~30% of construction costs for the expense of ventilation equipment, and the tunnel even can reach 50% of growing up is so the optimization problem of ventilation aspect has economic worth.Tunnel development from now on more and more be tending towards growing up, so it is most important to solve ventilating problem technically.Technology relatively more commonly used both at home and abroad now all is the mode that combines by excavation ventilating shaft and force ventilation basically, and the foul atmosphere in the tunnel is discharged outside the hole as early as possible, guarantees the air freshness in the tunnel.This is a kind of good method, and also comparative maturity of technology.But this is the method for physics dilution only, is not purified treatment; And existing these draft types all have the weak point of oneself, be not construction costs too the higher position be that the operation maintenance expense is too high, and for automobile burning or explosion accident take place in the tunnel of growing up, existing tunnel ventilation system is difficult to all accomplish that the smog with high concentration in the tunnel is diluted to acceptable degree at short notice, in case similar accident takes place in the tunnel, its operation is paralysis fully just.
Based on the problem and shortage that above-mentioned ventilation form exists, all take up research both at home and abroad the indoor air purification principle is applied in the tunnel ventilation.Main remove airborne solid suspended particle by electrostatic precipitator technology earlier, remove wherein carbon monoxide CO and nitrogen oxide NO by catalytic oxidation and catalytic purification again x, the gas that reaction is obtained is discharged in the tunnel again at last, and it is on the books in the people's patent application publication number 200820154602.2 grades to found a capital as what is said or talked about.Compare this method advantage with foregoing draft type outstanding, directly removed carbon monoxide CO and nitrogen oxide NO xEtc. harmful substance, help environmental protection.But also exist not enough, the one, not to the gas after the catalytic reaction be mainly oxygen sulfur compound, carbon dioxide (greenhouse gases) is handled; The 2nd, electrostatic precipitation efficient is relatively low, and the deduster cleaning is frequent, and purifying functions is difficult to performance preferably, especially works as disasters such as breaking out of fire or blast in the tunnel, and when having produced a large amount of smog and dust, electrostatic dust removing method absorption haze effect is very little.
Summary of the invention
The present invention is for avoiding above-mentioned existing in prior technology weak point, at air-polluting characteristics in the vcehicular tunnel, proposes a kind ofly to be applied to tunnel ventilation, can directly reduce construction costs, reduces the tunnel waste gas cleaning system of ventilation running cost.
Technical solution problem of the present invention adopts following technical scheme:
The design feature of vcehicular tunnel waste gas cleaning system of the present invention is that the port of export at blower fan sets gradually air inlet pipe, suspension Rose Box, ceramic monolith active catalytic device, comprehensive purifying case and blast pipe along gas flow direction; Described suspension Rose Box is an airtight container that fills clean water; Described comprehensive purifying case is a closed container that fills the saturated solution of calcic and magnesium ion; Described ceramic monolith active catalytic device is to have the active component coating on the surface of the ceramic monolith of porous.
The design feature of tunnel of the present invention waste gas cleaning system also is:
Source of clean water and drainpipe are being set, are being connected with suspension Rose Box and comprehensive purifying case respectively with described source of clean water and drainpipe.
It is an open type aqua storage tank that described source of clean water is set.
Setting is led to the breather pipe in the suspension Rose Box and is led to bottom that breather pipe in the comprehensive purifying case extends suspension Rose Box and comprehensive purifying case respectively, terminal upwards curved and be bell mouth shape, and bell-mouthed end face is an orifice plate.
The present invention utilizes blower fan that the dirty gas inspiration that has in the tunnel is gone to pressurize again, makes gas pass through an airtight suspension Rose Box, filters out solid suspended particles such as airborne smog, dust; Then the residual gas that obtains is passed through ceramic monolith active catalytic device, make these gases that a series of chemical reaction take place under the effect of catalyst, remove wherein carbon monoxide, nitrogen oxide NOx, CH 2Pernicious gases such as hydro carbons; The gas that obtains at last is mainly steam, carbon dioxide, oxygen sulfur compound S yO x, nitrogen and oxygen, these gases are passed in the comprehensive purifying closed box that contains calcium, magnesium ion solution by blower fan again, remove wherein carbon dioxide, steam and oxygen sulfur compound, the clean gas that obtains the most at last is discharged in the tunnel again.
Series of chemical can take place by the active catalytic device in gas, and is mainly as follows:
2CO+O 2=2CO 2
2xCO+2NO x=N 2+2xCO 2CH 2
2xCH 2+6NO n=3N 2+2xCO 2+2xH 2O
2NO x+2xH 2=N 2+2xH 2O
Series of chemical can take place by the comprehensive purifying case in gas, and is mainly as follows:
CO 2+Ca(OH) 2=CaCO 3+H 2O
CO 2+Mg(OH) 2=MgCO 3+H 2O
SO 2+Ca(OH) 2=CaSO 3+H 2O
SO 2+Mg(OH) 2=MgSO 3+H 2O
Compared with the prior art, beneficial effect of the present invention is embodied in:
1, the present invention directly absorbs the dirty gas in the tunnel, can reduce the quantity of excavation ventilation shaft in the tunnel of growing up, and has reduced construction costs greatly.
2, the present invention does not discharge dirty gas the outside, tunnel, like this protection environment is also played a good role, and has reduced the power of fan of force ventilation simultaneously greatly yet, cuts down the consumption of energy, and it is low to guarantee that the expense of tunnel during runing tried one's best, and feasibility is good.
3, the present invention can remove dirty gas and the smog in the tunnel fast, especially in the tunnel during disaster such as breaking out of fire or blast, can remove airborne smog and pernicious gas fast, guarantee the operation ability in tunnel preferably, and can well guarantee the safety of other drivings.
Description of drawings
Fig. 1 is the horizontal layout schematic diagram of the present invention in the tunnel;
Fig. 2 arranges schematic diagram for the facade of the present invention in the tunnel;
Fig. 3 is apparatus of the present invention structural representation;
Fig. 4 is a B-B view among Fig. 1;
Number in the figure: saturated solution, 14 clean gas, 15 active coatings, 16 purifiers, 17 fresh airs, 18 vehicle exhausts of 1 blower fan, 2 breather pipes, 3 suspension Rose Boxes, 4 catalytic reactive component devices, 5 comprehensive purifying casees, 6 blast pipes, 7 source of clean water, 8 drainpipes, 9 valves, 10 waste water collection devices, 11 dirty gases, 12 clean waters, 13 calcics and magnesium ion.
The specific embodiment
Referring to Fig. 1, different tunnels, the air cleaning unit layout in the tunnel also is not quite similar, when the ventilation scheme in a tunnel of design, fully take into account the flow direction of fresh air 17, vehicle exhaust 18, and the distribution situation of the dirty gas 11 in the tunnel.
Referring to Fig. 1 and Fig. 2, the vent flow of each section and the flow direction in the analysis-by-synthesis tunnel, and in the tunnel after the distribution of the distribution of pernicious gas and smokescope, utilize these aeration flow purifier 16 to be set to the suitable place in the tunnel, can reduce the power of blower fan so greatly, also can reduce the excavation quantity of ventilation shaft simultaneously.
As shown in Figure 3 and Figure 4, the purifier in the present embodiment 16 is that the port of export at blower fan 1 sets gradually air inlet pipe 2, suspension Rose Box 3, ceramic monolith active catalytic device 4, comprehensive purifying case 5 and blast pipe 6 along gas flow direction; Suspension Rose Box 3 is an airtight container that fills clean water 12; Comprehensive purifying case 5 be one fill calcic, the magnesium ion proportioning is the closed container of 1: 1 saturated solution 13; Ceramic monolith active catalytic device 4 is to have active component coating 15 on the surface of the ceramic monolith of porous.
In concrete the enforcement, source of clean water 7 and drainpipe 8 are set, are connected with suspension Rose Box 3 and comprehensive purifying case 5 respectively with source of clean water 7 and drainpipe 8; It is an open type aqua storage tank that source of clean water 7 is set, and can be the running water water source.
Setting is led to the breather pipe in the suspension Rose Box 3 and is led to breather pipe in the comprehensive purifying case 5 and is respectively the bottom that extends suspension Rose Box 3 and comprehensive purifying case 5, terminal upwards curved and be bell mouth shape, and bell-mouthed end face is an orifice plate.
Can between catalyst converter 4 and purifying box 5, increase according to actual conditions and blower fan is set pressurizes.
By prior art, the active coating 15 of ceramic monolith catalyst converter 4 can be one or more the coating in precious metal element palladium, rhodium and the platinum; Or be one or more coating in rare-earth element cerium, lanthanum, praseodymium and the rubidium; Or be one or more coating in metallic element copper, iron, manganese and the brill.In the present embodiment, the active coating 15 on the ceramic monolith catalyst converter 4 is to be 0.1~0.15% to add γ-Al by weight percentage by precious metal catalyst materials such as palladium, rhodium or platinum 2O 3Make, its thickness is 10 μ m~15 μ m, the ceramic monolith catalyst converter is set is 400 ℃-800 ℃ hot environment, and gas is reacted.
Utilize blower fan 1 that 11 inspirations of the foul atmosphere in the tunnel are gone and pressurize, by air inlet pipe 2 dirty gas is fed in the suspension Rose Box 3, filter out solid suspended particles such as wherein smog, dust, again the residual gas that obtains is passed through high temperature cellular ceramic substrate active catalytic device 4, make these gases under the effect of active catalyst, series of chemical take place, remove pernicious gases such as wherein carbon monoxide, nitrogen oxide, hydro carbons; The gas that obtains at last is mainly and is oxygen, steam, carbon dioxide, oxygen sulfur compound and nitrogen, these gases feed in the comprehensive purifying case 5 of calcic and magnesium ion saturated solution again, remove wherein steam, carbon dioxide and oxygen sulfur compound, the clean gas 14 that finally obtains is discharged in the tunnel again by blast pipe 7, has so just finished the primary purification of dirty gas in the tunnel.
Tunnel of the present invention waste gas purification apparatus can absorb the dirty gas in the tunnel quickly and effectively, and dirty gas need not be discharged outside the tunnel, promptly help the power of fan that environmental protection also reduces force ventilation simultaneously greatly, cut down the consumption of energy, thereby save the tunnel ventilation running cost greatly; In addition, in the tunnel of growing up, can reduce the quantity of excavation ventilation shaft, reduce construction costs greatly.

Claims (4)

1. a vcehicular tunnel waste gas cleaning system is characterized in that setting gradually air inlet pipe (2), suspension Rose Box (3), ceramic monolith active catalytic device (4), comprehensive purifying case (5) and blast pipe (6) at the port of export of blower fan (1) along gas flow direction; Described suspension Rose Box (3) is an airtight container that fills clean water (12); Described comprehensive purifying case (5) is a closed container that fills the saturated solution (13) of calcic and magnesium ion; Described ceramic monolith active catalytic device (4) is to have the active component coating on the surface of the ceramic monolith of porous.
2. tunnel according to claim 1 waste gas cleaning system is characterized in that being provided with source of clean water (7) and drainpipe (8), is connected with suspension Rose Box (3) and comprehensive purifying case (5) respectively with described source of clean water (7) and drainpipe (8).
3. tunnel according to claim 2 waste gas cleaning system, it is characterized in that being provided with described source of clean water (7) is an open type aqua storage tank.
4. tunnel according to claim 1 waste gas cleaning system, it is characterized in that being provided with and lead to the breather pipe in the suspension Rose Box (3) and lead to bottom that breather pipe in the comprehensive purifying case (5) extends suspension Rose Box (3) and comprehensive purifying case (5) respectively, terminally upwards bend and be bell mouth shape, bell-mouthed end face is an orifice plate.
CN2010105603435A 2010-11-26 2010-11-26 Waste gas purifying system for highway tunnel Expired - Fee Related CN101992013B (en)

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Application Number Priority Date Filing Date Title
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CN101992013B CN101992013B (en) 2012-11-07

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102434183A (en) * 2011-11-03 2012-05-02 谢飞鸿 Air purifier for removing harmful gas and dust on long tunnel driving working face
CN102505953A (en) * 2011-11-03 2012-06-20 谢飞鸿 Air purifier for removing harmful gas and dust in long tunnel
CN102505952A (en) * 2011-11-03 2012-06-20 谢飞鸿 Method for clearing harmful gas and dust in long tunnel
CN102505954A (en) * 2011-11-03 2012-06-20 谢飞鸿 Mobile chemical-degradation ventilator for tunnels
CN111706380A (en) * 2020-05-20 2020-09-25 中国路桥工程有限责任公司 Ventilation method for long and large mountain tunnel construction

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2557702Y (en) * 2002-04-27 2003-06-25 陈大水 Tail gas purifier for motor vehicle
JP2007000733A (en) * 2005-06-22 2007-01-11 Osaka Prefecture Univ Gas processing method and processing apparatus
JP2009240973A (en) * 2008-03-31 2009-10-22 Nishimatsu Constr Co Ltd System and method for treating exhaust gas
CN101721874A (en) * 2008-10-29 2010-06-09 谈建民 Exhaust gas purification system for tunnel
CN201862355U (en) * 2010-11-26 2011-06-15 合肥工业大学科教开发部 Exhaust gas purification system for highway tunnel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2557702Y (en) * 2002-04-27 2003-06-25 陈大水 Tail gas purifier for motor vehicle
JP2007000733A (en) * 2005-06-22 2007-01-11 Osaka Prefecture Univ Gas processing method and processing apparatus
JP2009240973A (en) * 2008-03-31 2009-10-22 Nishimatsu Constr Co Ltd System and method for treating exhaust gas
CN101721874A (en) * 2008-10-29 2010-06-09 谈建民 Exhaust gas purification system for tunnel
CN201862355U (en) * 2010-11-26 2011-06-15 合肥工业大学科教开发部 Exhaust gas purification system for highway tunnel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《中国安全科学学报》 19990630 李晓红等 公路隧道空气净化的实验研究 第09卷, 第03期 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102434183A (en) * 2011-11-03 2012-05-02 谢飞鸿 Air purifier for removing harmful gas and dust on long tunnel driving working face
CN102505953A (en) * 2011-11-03 2012-06-20 谢飞鸿 Air purifier for removing harmful gas and dust in long tunnel
CN102505952A (en) * 2011-11-03 2012-06-20 谢飞鸿 Method for clearing harmful gas and dust in long tunnel
CN102505954A (en) * 2011-11-03 2012-06-20 谢飞鸿 Mobile chemical-degradation ventilator for tunnels
CN111706380A (en) * 2020-05-20 2020-09-25 中国路桥工程有限责任公司 Ventilation method for long and large mountain tunnel construction
CN111706380B (en) * 2020-05-20 2021-11-09 中国路桥工程有限责任公司 Ventilation method for long and large mountain tunnel construction

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