CN101386719A - Multifunctional coatings and preparation method thereof - Google Patents
Multifunctional coatings and preparation method thereof Download PDFInfo
- Publication number
- CN101386719A CN101386719A CNA2008101469497A CN200810146949A CN101386719A CN 101386719 A CN101386719 A CN 101386719A CN A2008101469497 A CNA2008101469497 A CN A2008101469497A CN 200810146949 A CN200810146949 A CN 200810146949A CN 101386719 A CN101386719 A CN 101386719A
- Authority
- CN
- China
- Prior art keywords
- multifunctional coating
- water
- emulsion
- filler
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 41
- 238000000576 coating method Methods 0.000 title claims description 207
- 239000000839 emulsion Substances 0.000 claims abstract description 148
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 124
- 239000003973 paint Substances 0.000 claims abstract description 104
- 239000000945 filler Substances 0.000 claims abstract description 102
- 229920000642 polymer Polymers 0.000 claims abstract description 101
- 239000003063 flame retardant Substances 0.000 claims abstract description 99
- 239000000463 material Substances 0.000 claims abstract description 95
- 239000002994 raw material Substances 0.000 claims abstract description 70
- 230000002265 prevention Effects 0.000 claims abstract description 58
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- 239000011248 coating agent Substances 0.000 claims description 168
- 239000012752 auxiliary agent Substances 0.000 claims description 114
- 230000001070 adhesive effect Effects 0.000 claims description 90
- 239000000853 adhesive Substances 0.000 claims description 89
- 239000000203 mixture Substances 0.000 claims description 66
- 238000003756 stirring Methods 0.000 claims description 66
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 54
- 239000011810 insulating material Substances 0.000 claims description 46
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 43
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 33
- 238000012856 packing Methods 0.000 claims description 33
- 230000037452 priming Effects 0.000 claims description 33
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 32
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 31
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 31
- 239000004794 expanded polystyrene Substances 0.000 claims description 31
- 235000019353 potassium silicate Nutrition 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 31
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 30
- 239000008399 tap water Substances 0.000 claims description 28
- 235000020679 tap water Nutrition 0.000 claims description 28
- 239000002253 acid Substances 0.000 claims description 25
- 239000003469 silicate cement Substances 0.000 claims description 25
- 239000013530 defoamer Substances 0.000 claims description 24
- 239000010881 fly ash Substances 0.000 claims description 23
- 150000002148 esters Chemical class 0.000 claims description 22
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 22
- 239000010445 mica Substances 0.000 claims description 21
- 229910052618 mica group Inorganic materials 0.000 claims description 21
- -1 polyol compound Chemical class 0.000 claims description 21
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 20
- 239000004113 Sepiolite Substances 0.000 claims description 19
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 19
- 239000004202 carbamide Substances 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 19
- 229910052624 sepiolite Inorganic materials 0.000 claims description 19
- 235000019355 sepiolite Nutrition 0.000 claims description 19
- 239000010455 vermiculite Substances 0.000 claims description 19
- 229910052902 vermiculite Inorganic materials 0.000 claims description 19
- 235000019354 vermiculite Nutrition 0.000 claims description 19
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 17
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 16
- 239000004408 titanium dioxide Substances 0.000 claims description 16
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 15
- 229940059574 pentaerithrityl Drugs 0.000 claims description 15
- 229920000120 polyethyl acrylate Polymers 0.000 claims description 15
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 14
- CVEPFOUZABPRMK-UHFFFAOYSA-N 2-methylprop-2-enoic acid;styrene Chemical class CC(=C)C(O)=O.C=CC1=CC=CC=C1 CVEPFOUZABPRMK-UHFFFAOYSA-N 0.000 claims description 13
- 239000003112 inhibitor Substances 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- 229940043810 zinc pyrithione Drugs 0.000 claims description 13
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims description 13
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 12
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 claims description 12
- 229920002319 Poly(methyl acrylate) Polymers 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 claims description 10
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 10
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 10
- 229920000193 polymethacrylate Polymers 0.000 claims description 10
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 10
- 238000009736 wetting Methods 0.000 claims description 10
- 239000004111 Potassium silicate Substances 0.000 claims description 9
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 9
- 229910021538 borax Inorganic materials 0.000 claims description 9
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 9
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 9
- 239000004328 sodium tetraborate Substances 0.000 claims description 9
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 9
- 239000004568 cement Substances 0.000 claims description 8
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- 150000004645 aluminates Chemical class 0.000 claims description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 7
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- DFYKHEXCUQCPEB-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)C(C)=C DFYKHEXCUQCPEB-UHFFFAOYSA-N 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- QZUJCEPTAIXZFA-UHFFFAOYSA-N methyl prop-2-enoate;styrene Chemical class COC(=O)C=C.C=CC1=CC=CC=C1 QZUJCEPTAIXZFA-UHFFFAOYSA-N 0.000 claims description 7
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 7
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 7
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 7
- 239000004299 sodium benzoate Substances 0.000 claims description 7
- 235000010234 sodium benzoate Nutrition 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 230000008719 thickening Effects 0.000 claims description 7
- 229920003169 water-soluble polymer Polymers 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 6
- 229910052712 strontium Inorganic materials 0.000 claims description 6
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 5
- VSNHCAURESNICA-UHFFFAOYSA-N Hydroxyurea Chemical compound NC(=O)NO VSNHCAURESNICA-UHFFFAOYSA-N 0.000 claims description 5
- 229920002396 Polyurea Polymers 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 5
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 5
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 5
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 5
- 150000004702 methyl esters Chemical class 0.000 claims description 5
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims description 3
- 239000010425 asbestos Substances 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 3
- 150000001720 carbohydrates Chemical class 0.000 claims description 3
- 235000014633 carbohydrates Nutrition 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 230000036571 hydration Effects 0.000 claims description 3
- 238000006703 hydration reaction Methods 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 229910052895 riebeckite Inorganic materials 0.000 claims description 3
- 229910001428 transition metal ion Inorganic materials 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 32
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 4
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- 238000004079 fireproofing Methods 0.000 description 6
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- 230000009471 action Effects 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
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- 230000003487 anti-permeability effect Effects 0.000 description 3
- 150000001875 compounds Chemical group 0.000 description 3
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- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910052917 strontium silicate Inorganic materials 0.000 description 2
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- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
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- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to multifunctional paint with the functions of water and fire prevention, lighting, noise reduction, safe escape and decoration and a preparation method thereof. The multifunctional paint comprises a polymer emulsion, a filler, a flame retardant, a long afterglow luminescent material, an addition agent and water, and the paint comprises raw materials in weight percentage: 10 to 50 percent of the polymer emulsion, 5 to 30 percent of the filler, 10 to 30 percent of the flame retardant, 10 to 60 percent of the long afterglow luminescent material, 0.1 to 5 percent of the addition agent and 1 to 50 percent of the water. The multifunctional paint is applied to a highway tunnel, an underground garage, an underground urban traffic passage, a civil defence engineering, an underground fortification, an underground warehouse, an underground production workshop and other underground buildings, can well meet the requirements of waterproof and fireproof functions and has obvious energy-saving effect; and with the characteristic of the long afterglow of the luminescent paint, the multifunctional paint exerts the function of illumination after power failure and is used to guide personnel to safely evacuate the scene of an accident. In addition, the multifunctional paint also has certain functions of noise absorption and noise reduction.
Description
Technical field
The present invention relates to multifunctional coating of uses such as a kind of tunnel and other underground structure, structures, underpass and preparation method thereof, specifically, relate to a kind of interior finishing engineering that is used for high-grade highway tunnel, underground parking, underpass etc., include but not limited to coating in the waterproof, fire prevention, noise reduction of high-grade highway, underground parking, underpass, energy-conservation, safety, decorative engineering etc. and preparation method thereof.
Background technology
The construction starting of China Higher level highway is than later, and the research and development that are exclusively used in the tunnel fire proofing material lag behind especially, and country does not also have the technical specifications of special tunnel fire proofing material at present, generally all is to use concrete floor fireproofing technique standard.In the selection of material, also can only select the material of simple function, and finish technical requirements multiple function by its simple stack.Main at present following material and the technology of adopting:
The solvent-borne type frie retardant coating
1) expanding fire-proof paint, it be a kind of be base mateiral with aminoresin, chlorinated rubber resin, acrylic resin, resol, supervinyi chloride resin etc.; With organic solvents such as hydro carbons, ester class, ketone, aromatic species, gasoline is dispersion and thinner; By being char forming catalyst with phosphoric acid salt such as ammonium polyphosphates, being char-forming agent, being that the P-C-N expandable flame retardant system that whipping agent was constituted is a fire retardant material with nitrogenous compounds such as trimeric cyanamides with rich carbon organic compound such as tetramethylolmethanes; Add the frie retardant coating that other filler, additive compound form.
2) non-expansion type frie retardant coating, it be a kind of be base mateiral with the nonflammable resin; With organic solvents such as hydro carbons, ester class, ketone, aromatic species, gasoline is dispersion and thinner; With heat-insulation and heat-preservation material or other fire retardant material is filler; Add the frie retardant coating that other filler, additive compound form.
The solvent-borne type frie retardant coating is a class frie retardant coating commonly used at present, is characterized in technology maturation, and fire resistance is good, with the cohesive force height on basis, good decorative property.But because a large amount of organic solvents that adopt, so product is inflammable, explosive, environmental pollution is bigger, to produce, the healthy of workmen have a considerable influence.And cost is than higher.
Aqueous fire-proof coating
Aqueous fire-proof coating is to be dispersion and thinner with water, is base mateiral with water soluble resin or emulsifying resins, adds composite class frie retardant coatings that form such as fire retardant material, filler, auxiliary agent.
The maximum characteristics of aqueous fire-proof coating are production and safe in utilization, environment are not polluted, to not injury of human body.Be to develop a ratio class fire-retardant material faster at present.
Inorganic fireproof coating
Inorganic fireproof coating be a class with inorganic bonding material, be jointing material as cement, water glass etc., with insulation, lagging material is main fire retardant material, adds composite class fire-retardant materials that form such as other filler, auxiliary agent.Main as thick-slurry type non-expansion type frie retardant coating.
Long afterglow luminescence material is mainly used in aspects such as sign, graticule, direction board at present as application of paints.And be to use with simple function, with the use that is grouped together of its and other function such as waterproof, fire-proof function, particularly in tunnel and other underground structure, structures, use, still be a brand-new problem.All need illumination (except the ultrashort tunnel) 24 hours every days in the tunnel, and the electric energy that accumulative total consumes is surprising.Using the purpose of luminous paint is to make the tunnel arch wall self have certain brightness, and under the situation that reduces lighting power, arch wall brightness does not subtract, and as seen the arch wall clear-cut does not influence driver's vision.Thereby reach energy saving purposes.Energy-saving effect can reach 20%.
In the freeway tunnel of having built, also seldom have and consider presence of fire, the lighting problem the when personal security when accident has a power failure is withdrawn.When burst accidents such as tunnel presence of fire, unexpected power failure, personnel's safe escape is a very important problem, owing to the application of luminous paint, can utilize the steady persistence characteristics of luminous paint, play the illuminating effect after the power failure, be used to guide personnel's safe escape scene of the accident.
More and more in the urban skyscraper, corresponding hypogee is also more and more.People often relatively pay attention to the waterproof of buildings in the construction of underground works, and this is can directly influence its functions of use because waterproof is done well.Fire-proof function is a kind of preventative function, can not show its importance very intuitively when normal the use, the power of fire-proof function, even say whether have fire-proof function can not influence its functions of use.Therefore, people often the attention degree to fire-proof function is not enough.Even the buildings that has only depends on concrete self fire prevention, and do not increase fireproofing in addition.For consideration, especially seldom to the consideration of energy-saving effect to construction cost.
Summary of the invention
The object of the present invention is to provide a kind of multifunctional coating that has waterproof, fire prevention, luminous, noise reduction, safe escape, decoration functions simultaneously and preparation method thereof.
To achieve these goals, the invention provides following expanded polystyrene veneer and have coating of waterproof, fire prevention, luminous multi-functional function and preparation method thereof concurrently.
1. expanded polystyrene veneer waterproof of the present invention, fire prevention, luminous multifunctional coating is characterized in that it comprises polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water, and the shared weight percent of described each raw material is:
Polymer emulsion 10～50%,
Filler 5～30%,
Fire retardant 5～30%,
Long after glow luminous material 10～60%,
Auxiliary agent 0.1～5%,
Water 1～50%,
2. above-mentioned 1 described multifunctional coating is characterized in that, described polymer emulsion is selected from least a in benzene emulsion or the ACRYLIC EMULSION.
3. above-mentioned 1 or 2 described multifunctional coatings is characterized in that, described benzene emulsion is the emulsion that is selected from least a resin formation of styrene-acrylate or styrene methacrylates.
4. above-mentioned 3 described multifunctional coatings is characterized in that, described styrene-acrylate is to be selected from least a in styrene acrylic methyl esters, styrene-acrylonitrile copolymer acetoacetic ester, the styrene-acrylonitrile copolymer acid butyl ester.
5. above-mentioned 3 described multifunctional coatings is characterized in that, described styrene methacrylates is to be selected from least a in styrene methyl methacrylate, vinylbenzene Jia Jibingxisuanyizhi, the vinylbenzene butyl methacrylate.
6. above-mentioned 1 or 2 described multifunctional coatings is characterized in that, described ACRYLIC EMULSION is at least a or any at least two kinds multipolymer in them that is selected from polyacrylic ester, polymethacrylate or the poly-ethyl propylene acid esters.
7. above-mentioned 6 described multifunctional coatings is characterized in that, described polyacrylic ester is to be selected from least a in polymethyl acrylate, polyethyl acrylate, the butyl polyacrylate.
8. above-mentioned 6 described multifunctional coatings is characterized in that, described polymethacrylate is to be selected from least a in polymethylmethacrylate, polyethyl methacrylate, the poly-n-butyl methacrylate.
9. above-mentioned 6 described multifunctional coatings is characterized in that, described poly-ethyl propylene acid esters is to be selected from least a in poly-ethylacrylic acid methyl esters, poly-ethyl propylene acetoacetic ester, the poly-ethyl propylene acid butyl ester.
10. the described multifunctional coating of each of above-mentioned 1～9, it is characterized in that described filler is to be selected from least a in mica powder, rhombspar, lime carbonate, talcum powder, kaolin, wollastonite, silica powder, flyash, titanium dioxide, lithopone, process white, cement, the glass fibre.
11. the described multifunctional coating of each of above-mentioned 1～10 is characterized in that described fire retardant is char-forming agent, whipping agent, catalyzer, mixes by a certain percentage.
The ratio of each component is (weight ratio):
Char-forming agent 10～20%
Whipping agent 20～40%
Catalyzer 40～60%
12. above-mentioned 11 described multifunctional coatings is characterized in that, described char-forming agent is to be selected from least a in carbohydrate, polyol compound, the hydroxy-containing resin.
13. above-mentioned 12 described multifunctional coatings is characterized in that, described char-forming agent is to be selected from least a in starch, tetramethylolmethane, Dipentaerythritol, the urea-formaldehyde resin.
14. above-mentioned 11 described multifunctional coatings is characterized in that, described whipping agent is to be selected from least a in trimeric cyanamide, Dyhard RU 100, urea, polyureas, the hexamethylenetetramine.
15. above-mentioned 11 described multifunctional coatings is characterized in that, described catalyzer is to be selected from least a in ammonium polyphosphate, melamine phosphate, Ureaphil, phosphoguanidine, the boric acid fat.
16. above-mentioned 1～15 each described multifunctional coating is characterized in that, described long after glow luminous material be selected from aluminate or silicate at least any one.
17. above-mentioned 16 described multifunctional coatings is characterized in that, described aluminate is formula M Al
2O
4: Eu
2+, RE
3+ shown in aluminate, wherein M=Ca, Sr, Ba, RE=rare earth ion.
18. above-mentioned 16 described multifunctional coatings is characterized in that, described silicate is formula M OM ' OSiO
2: Eu, the silicate shown in the Ln, wherein M=Ca, Sr, Ba, M '=Mg, Zn, Cd Ln=co-activator are rare earth ion and the part transition metal ions except that Eu.
19. above-mentioned 1～18 each described multifunctional coating is characterized in that, described auxiliary agent be selected from sanitas, wetting dispersing agent or defoamer at least any one.
20. above-mentioned 19 described multifunctional coatings is characterized in that, described sanitas is Sodium Benzoate, Zinc Pyrithione mould inhibitor or sodium pentachlorophenate.
21。Above-mentioned 1～20 each described multifunctional coating is characterized in that, described water is to be selected from least a in deionized water, tap water, the underground water.
22. the preparation method of above-mentioned 1～21 each described multifunctional coating, it is characterized in that, polymer emulsion is added in the reactor, add auxiliary agent and stir, add according to this filler, fire retardant, water mix dispersed with stirring evenly after, add the long after glow luminous material back packing that is uniformly dispersed.
23。The preparation method of above-mentioned 1～21 each described multifunctional coating, it is characterized in that, polymer emulsion is added in the reactor, adding auxiliary agent stirs, add evenly back packing of filler, fire retardant, water mixing dispersed with stirring according to this, long after glow luminous material is packed separately, used field mix to disperse the back to use.
Expanded polystyrene veneer waterproof of the present invention, fire prevention, luminous multifunctional coating are waterproof, fire prevention, the lighting functions that underground works is involved, concentrate in a kind of coating and realize.
Expanded polystyrene veneer multifunctional coating of the present invention adopts to have good waterproof action, and the snappiness benzene emulsion or the ACRYLIC EMULSION of good film-forming property, and the anti-permeability performance of coating is improved significantly, and makes coating have the excellent waterproof effect.Performance index such as its anti-permeability performance, low temperature flexibility, unit elongation, tensile strength all reach the performance index of similar waterproof paint.
Introduce embedded photoluminescent material in expanded polystyrene veneer multifunctional coating of the present invention, can absorb sunlight and light, particularly under normal conditions, absorbed and used up luminous energy by body of wall, can pass through embedded photoluminescent material, the form with light discharges again.Under the constant situation of lighting power, can improve brightness like this, perhaps will reach same brightness and can reduce lighting power, thereby reach purpose of energy saving, its energy-saving efficiency can reach more than 20%.
Because what introduce in the expanded polystyrene veneer multifunctional coating of the present invention is long afterglow luminescence material, can continue in for some time after removing light source to discharge luminous energy, play illuminating effect.Therefore when disaster accident such as presence of fire and unexpected the power failure, utilize the twilight sunset illumination of coating, the help desk personnel withdraws the scene of the accident, plays the effect of safe escape, evacuation.
In addition, the present invention also provides a kind of non-expansion type waterproof, fire prevention multifunctional coating.
24, non-expansion type waterproof of the present invention, fire prevention multifunctional coating is characterized in that it comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water, the shared weight percent of each raw material is:
Polymer adhesive 5～20%,
Inorganic adhesive 5～30%,
Filler 1～10%,
Light heat insulating material 1 0～50%,
Fire retardant 0～10%,
Auxiliary agent 0.1～5%,
Water 1～50%,
25。Above-mentioned 24 described multifunctional coatings is characterized in that described high molecular polymer comprises polymer emulsion and high molecular weight water soluble polymer.
26. above-mentioned 25 described multifunctional coatings is characterized in that, described polymer emulsion is selected from least a in benzene emulsion or the ACRYLIC EMULSION.
27。Above-mentioned 26 described multifunctional coatings is characterized in that, described benzene emulsion is the emulsion that is selected from least a resin formation of styrene-acrylate or styrene methacrylates.
28。Above-mentioned 27 described multifunctional coatings is characterized in that, described styrene-acrylate is to be selected from least a in styrene acrylic methyl esters, styrene-acrylonitrile copolymer acetoacetic ester, the styrene-acrylonitrile copolymer acid butyl ester.
29。Above-mentioned 27 described multifunctional coatings is characterized in that, described styrene methacrylates is to be selected from least a in styrene methyl methacrylate, vinylbenzene Jia Jibingxisuanyizhi, the vinylbenzene butyl methacrylate.
30。Above-mentioned 26 described multifunctional coatings is characterized in that, described ACRYLIC EMULSION is at least a or any at least two kinds multipolymer in them that is selected from polyacrylic ester, polymethacrylate or the poly-ethyl propylene acid esters.
31。Above-mentioned 30 described multifunctional coatings is characterized in that, described polyacrylic ester is to be selected from least a in polymethyl acrylate, polyethyl acrylate, the butyl polyacrylate.
32. above-mentioned 30 described multifunctional coatings is characterized in that, described polymethacrylate is to be selected from least a in polymethylmethacrylate, polyethyl methacrylate, the poly-n-butyl methacrylate.
33. above-mentioned 30 described multifunctional coatings is characterized in that, described poly-ethyl propylene acid esters is to be selected from least a in poly-ethylacrylic acid methyl esters, poly-ethyl propylene acetoacetic ester, the poly-ethyl propylene acid butyl ester.
34。Above-mentioned 25～33 each described multifunctional coatings is characterized in that, above-mentioned high molecular weight water soluble polymer be selected from ether of cellulose, polyvinyl alcohol, polyacrylamide, polyoxyethylene glycol, starch and the derivative thereof at least any one.
35. above-mentioned 24～34 each described multifunctional coatings is characterized in that, described inorganic adhesive be selected from silicate cement, aluminosilicate cement, water glass, the potassium silicate at least any one.
36. above-mentioned 24～35 each described multifunctional coatings is characterized in that described auxiliary agent is sanitas, thickening material.
37. above-mentioned 36 described multifunctional coatings is characterized in that, described sanitas is Sodium Benzoate, Zinc Pyrithione mould inhibitor or sodium pentachlorophenate; Described thickening material is methylcellulose gum, Natvosol.
38. above-mentioned 24～37 each described multifunctional coatings is characterized in that, described filler be selected from lime carbonate, mica powder, talcum powder, kaolin, silica powder, the flyash at least any one.
39. above-mentioned 24～38 each described multifunctional coatings is characterized in that, described light heat insulating material be selected from pearlstone, vermiculite, sepiolite, diatomite terra alba, the asbestos at least any one.
40. above-mentioned 24～39 each described multifunctional coatings is characterized in that, described fire retardant be selected from aluminium hydroxide, borax, hydration zinc borate, weisspiessglanz, clorafin, the ammonium polyphosphate at least any one.
41. above-mentioned 24～40 each described multifunctional coatings is characterized in that, described water is to be selected from least a in deionized water, tap water, the underground water.
42. above-mentioned 24～41 each described multifunctional coatings is characterized in that, the shared gross weight ratio of its each raw material is:
Polymer adhesive 7.0%,
Inorganic adhesive 23.0%,
Filler 2.0%,
Fire retardant 1.0%,
Light heat insulating material 45.0%
Auxiliary agent 0.1%,
Water 21.9%.
43. the preparation method of above-mentioned 24～42 each described multifunctional coatings is characterized in that, at first the aqueous high molecular material is added water, dissolving under certain condition, be added in the reactor with polymer emulsion, add auxiliary agent and stir, pack as the first component; Inorganic adhesive, filler, light heat insulating material are mixed the back packing in mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
Non-expansion type waterproof of the present invention, fire prevention multifunctional coating are waterproof, the fire-proof functions that underground works is involved, concentrate in a kind of coating and realize.Has unexpansive heat insulation, the anti-flaming dope of the thick-slurry type that heat preserving and insulating material constituted obviously fire-retardant, effect of heat insulation by a large amount of employings, it is obvious to have effect of heat insulation, the characteristics that duration of fire resistance is long, for reinforced concrete foundation, effectively duration of fire resistance was more than 4 hours.
Non-expansion type multifunctional coating of the present invention, employing has good waterproof action, and tangible snappiness phenylpropyl alcohol of bond effect or ACRYLIC EMULSION, with the compound formation organic binding material of high molecular weight water soluble polymer with the bonding system that becomes coating of the present invention than the inorganic cementitious material mutual group of high bond strength is arranged.This jointing material combination has very high bond strength and adhesion efficiency, reach bond strength similarly, its consumption is far smaller than independent use inorganic bonding material or organic adhesive material, and the relative content of lagging material is effectively improved, and has increased flame retardant effect.Because the adding of snappiness ACRYLIC EMULSION or benzene emulsion is improved significantly the anti-permeability performance of coating, makes coating have waterproof effect preferably.
In addition, the invention provides a vanish system.
43. vanish system of the present invention, it is characterized in that, this system comprises priming paint, intermediate coat and finish paint, described priming paint is the water-emulsifying type waterproof coatings that vinylformic acid or benzene emulsion are formed, described intermediate coat is above-mentioned 24～42 each described non-expansion type waterproof, fire prevention multifunctional coating, and described finish paint is above-mentioned 1～21 each described expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating.
In the vanish system of the present invention, described priming paint is the water-emulsifying type waterproof coatings that vinylformic acid or benzene emulsion are formed.Priming paint is this vanish system and the bound fraction that is coated the basis, plays the effect of interfacial agents.Be used to strengthen cohesive strength between vanish system and the basis, bear the main water-proof function of this vanish system.
Intermediate coat described in the vanish system of the present invention is above-mentioned non-expansion type waterproof, frie retardant coating.Bear the main fire-proof function and the water-proof function of native system.
Finish paint described in the vanish system of the present invention is above-mentioned expanded polystyrene veneer waterproof, fire prevention, luminous paint.Bear the main lighting function and the waterproof fireproofing function of native system.Permission is at its external coating light transmission finishing material or protecting materials.
If vanish system of the present invention is applied on the hypogee, just can solve the functional requirement of its waterproof fireproofing well, and remarkable energy saving effect is arranged, utilize the steady persistence characteristics of luminous paint, play the illuminating effect after the power failure, be used to guide personnel's safe escape scene of the accident.In addition, coating of the present invention has also that certain suction is made an uproar, decrease of noise functions.
If vanish system of the present invention is applied on other underground structure and the structures, also can plays same effect.These buildingss and structures include but not limited to City Underground Transportation passage, civil air defense constructions and installations, underground fortification, underground storehouse, underground production plant etc.
Embodiment
Below, illustrate in greater detail the present invention.
Expanded polystyrene veneer waterproof of the present invention, fire prevention, luminous multifunctional coating is characterized in that, comprise polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water, and the shared weight percent of described each raw material is:
Polymer emulsion 10～50%,
Filler 5～30%,
Fire retardant 5～30%,
Long after glow luminous material 10～60%,
Auxiliary agent 0.1～5%,
Water 1～50%,
Polymer emulsion mainly plays film forming and cohesive action, and consumption is crossed when hanging down, and cohesive strength is not enough, can cause the coating efflorescence, peel off, come off, when the polymer emulsion consumption was too high, cost increased on the one hand, to reduce other functional materialss on the other hand, the overall performance of coating is reduced.So, general value between 10～50 weight %, preferred 15～40 weight %, more preferably 17～35 weight %.
Filler is except reducing cost, can also increase the physical strength of coating, filler very little, the intensity of coating can decrease, and filler is too much, and flexible and other performances of coating can reduce, therefore, the ratio of filler generally is selected between 5～30 weight %, preferred 7～20 weight %, more preferably 8～17 weight %.
The effect of fire retardant is to play fire-retardant, anti-fire action when presence of fire, consumption is fire-retardant very little, flameproof effect is not good, consumption is excessive, the ratio of other components will reduce, other performances are reduced, proper ratio is 5～30 weight %, preferred 5～15 weight %, more preferably 6～12 weight %.
The long after glow luminous material major function is luminous and the twilight sunset illumination, it is not obvious that consumption has lacked illumination effect, twilight sunset is not enough to play illuminating effect, cost increase on the one hand that consumption is big, the ratio of other components will reduce on the other hand, and other performances are reduced, and proper ratio is 10～60 weight %, preferred 20～50 weight %, more preferably 30～45 weight %.
The effect of auxiliary agent is some specified propertys that improve and strengthen coating, as add sanitas to prolong the storage time of coating, defoamer is used for reducing and eliminating the bubble of coating, wetting agent, dispersion agent can improve the dispersion effect of filler in coating, improve the homogeneity of coating, be characterized in that consumption is few, effect is big, so general consumption is controlled at 0.Between 1～5 weight %, preferred 0.3～3 weight, more preferably 0.3～2 weight %.
The consumption of water generally is 1～50 weight %, preferred 5～30 weight %, more preferably 5～20 weight %.
Expanded polystyrene veneer waterproof of the present invention, fire prevention, luminous multifunctional coating, each raw material is better effects if in following proportional range, and described ratio is weight %:
Polymer emulsion 15～40%,
Filler 7～20%,
Fire retardant 5～15%,
Long after glow luminous material 20～50%,
Auxiliary agent 0.3～3%,
Water 5～30%,
In order to reach better over-all properties, expanded polystyrene veneer waterproof of the present invention, fire prevention, the shared weight % of each raw material of luminous multifunctional coating should be:
Polymer emulsion 17～35%,
Filler 8～17%,
Fire retardant 6～12%,
Long after glow luminous material 30～45%,
Auxiliary agent 0.3～2%,
Water 5～20%,
Expanded polystyrene veneer waterproof of the present invention, fire prevention, luminous multifunctional coating, can also mix colours according to ornamental requirement, used pigment is the aqueous color paste of being sold on the market, and concocting method is identical with the concocting method of existing emulsion paint, does not list in the ratio of raw material of the present invention.
The optimum range of expanded polystyrene veneer waterproof of the present invention, fire prevention, the shared weight % of each raw material of luminous multifunctional coating is:
Polymer emulsion 30%,
Filler 12%,
Fire retardant 8%,
Long-decay phosphor material 40%,
Auxiliary agent 1%,
Water 9%.
Described polymer emulsion be include but not limited to table 1 listed with any one or the mixing more than two kinds in the emulsifying technology synthetic high molecular polymer, during mixing more than two kinds, be proportioning (they may be used alone, can also be used in combination) arbitrarily;
Table 1 polymer emulsion
Described auxiliary agent is sanitas, wetting dispersing agent or defoamer.
Described sanitas (coating sanitas) can use Sodium Benzoate or sodium pentachlorophenate or Zinc Pyrithione mould inhibitor; Described wetting dispersing agent (aqueous wetting agent, dispersion agent) for example can use: the Teog D-750W dispersion agent of CF-10 (wetting), the GR-5M (wetting) of the SN-5040 of the big auspicious company of the U.S., ROHM AND HASS company, the BYK-181 of Bi Ke company wetting dispersing agent, Degussa company or the T-731 wetting dispersing agent of ROHM AND HASS company; Described defoamer (aqueous solution defoamer) for example can use: the BYK-33 of Bi Ke company, BYK-22 defoamer, modest 082 defoamer of moral or the SPA-202 defoamer of Shanghai coating institute or the HX-5010 defoamer of China company.
Described filler be include but not limited in the listed filler of table 2 any one or mix more than two kinds, when mixing more than two kinds, be any proportioning.
Table 2 filler
Described fire retardant is char-forming agent, whipping agent, catalyzer, mixes the fire retardant that obtains by a certain percentage.
Described char-forming agent is at least a in carbohydrate, polyol compound, the hydroxy-containing resin, includes but not limited at least a in starch, tetramethylolmethane, Dipentaerythritol, the urea-formaldehyde resin; Described whipping agent is to include but not limited at least a in trimeric cyanamide, Dyhard RU 100, urea, polyureas, the hexamethylenetetramine; Described catalyzer is to include but not limited at least a in ammonium polyphosphate, melamine phosphate, Ureaphil, phosphoguanidine, the boric acid fat.
Described long after glow luminous material is the long after glow luminous material that includes but not limited in the listed embedded photoluminescent material of table 3.
Table 3 long after glow luminous material
| Aluminate | MAl 2O 4:Eu 2+，RE 3+ wherein M=Ca, Sr, Ba, the RE=rare earth ion |
| Silicate | MO·M′O·SiO 2: Eu, Ln be M=Ca, Sr, Ba wherein, and M '=Mg, Zn, Cd Ln=co-activator are rare earth ion and the part transition metal ions except that Eu |
Described water can use at least a in deionized water, tap water, the underground water.
The preparation method of above-mentioned expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, at first polymer emulsion is added in the reactor, add auxiliary agent and stir, add successively filler, fire retardant, water mix dispersed with stirring evenly after, add the long after glow luminous material back packing that is uniformly dispersed.Also long after glow luminous material can be packed separately, used field mix to disperse the back to use.
The present invention also provides a kind of non-expansion type waterproof, fire prevention multifunctional coating.
Non-expansion type waterproof of the present invention, fire prevention multifunctional coating is characterized in that, comprise polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water, the shared weight percent of each raw material is:
Polymer adhesive 5～20%,
Inorganic adhesive 5～30%,
Filler 1～10%,
Light heat insulating material 1 0～50%,
Fire retardant 0～10%,
Auxiliary agent 0.1～5%,
Water 1～50%,
The main effect of polymer adhesive is high-adhesion energy, stopping property and a flexibility of utilizing polymer adhesive, and making between coating and coating and the coating has higher bonding strength, gives coating better waterproof energy and proper flexibility simultaneously.Proper proportion is 5～20 weight %, preferred 7～17 weight %, more preferably 7～15 weight %.
Inorganic adhesive also has the effect that increases coating ultimate compression strength and hardness except with polymer adhesive is collaborative coating being risen the adhesive effect.The cost of the cost higher molecular polymer binder of inorganic adhesive is low, is satisfying under the prerequisite of performance requriements, should improve the ratio of inorganic adhesive as far as possible, reduces the ratio of polymer adhesive.Proper proportion is 5～30 weight %, preferred 8～28 weight %, more preferably 12～25 weight %.
Filler mainly plays filling effect in the present invention, and ratio should not be too high, and 1～10 weight % is proper, and preferred 2～7 weight % more preferably pacify 2～5 weight %.
Light heat insulating material is fire prevention, heat insulation major function material, should be under the condition that allows, improve its ratio as far as possible, but the too high ratio that can influence other materials of ratio, reduce over-all properties, proper proportion between 10～50 weight %, preferred 15～45 weight %, more preferably 25～45 weight %.
Fire retardant plays auxiliary anti-fire action, can suitably add when higher fire protection requirement is arranged, and ratio is unsuitable too high, generally between 0～10 weight %, and preferred 0～8 weight %, more preferably 0～5 weight %.
The effect of auxiliary agent is some specified propertys that improve and strengthen coating, as add sanitas to prolong the storage time of coating, thickening material is used to increase the viscosity and the water-retentivity of coating, be characterized in that consumption is few, effect is big, so general consumption is controlled between 0.1～5 weight % preferred 0.1～3 weight %, more preferably 0.1～1 weight %.
Non-expansion type waterproof of the present invention, fire prevention, luminous multifunctional coating, each raw material is better effects if in following weight % scope:
Polymer adhesive 7～17%,
Inorganic adhesive 8～28%,
Filler 2～7%,
Light heat insulating material 15～45%,
Fire retardant 0～8%,
Auxiliary agent 0.1～3%,
Water 5～50%
In order to reach better over-all properties, non-expansion type waterproof of the present invention, fire prevention, luminous multifunctional coating, the shared weight % of each raw material should be:
Polymer adhesive 7～15%,
Inorganic adhesive 12～25%,
Filler 2～5%,
Light heat insulating material 25～45%,
Fire retardant 0～5%,
Auxiliary agent 0.1～1%,
Water 10～40%
As the preferred version of best non-expansion type waterproof of the present invention, fire prevention multifunctional coating, the shared weight % of its each raw material is:
Polymer adhesive 7.0%,
Inorganic adhesive 23.0%,
Filler 2.0%,
Fire retardant 1.0%,
Light heat insulating material 45.0%
Auxiliary agent 0.1%,
Water 21.9%.
Described high molecular polymer comprises polymer emulsion and high molecular weight water soluble polymer.
Described polymer emulsion is selected from least a in benzene emulsion or the ACRYLIC EMULSION.
Described benzene emulsion is the emulsion that is selected from least a resin formation of styrene-acrylate or styrene methacrylates.
Described styrene-acrylate is to be selected from least a in styrene acrylic methyl esters, styrene-acrylonitrile copolymer acetoacetic ester, the styrene-acrylonitrile copolymer acid butyl ester.
Described styrene methacrylates is to be selected from least a in styrene methacrylates, vinylbenzene Jia Jibingxisuanyizhi, the vinylbenzene butyl methacrylate.
Described ACRYLIC EMULSION is at least a or any at least two kinds multipolymer in them that is selected from polyacrylic ester, polymethacrylate or the poly-ethyl propylene acid esters.
Described polyacrylic ester is to be selected from least a in polymethyl acrylate, polyethyl acrylate, the butyl polyacrylate.
Described polymethacrylate is to be selected from least a in polymethylmethacrylate, polyethyl methacrylate, the poly-n-butyl methacrylate.
Described poly-ethyl propylene acid esters is to be selected from least a in poly-ethylacrylic acid methyl esters, poly-ethyl propylene acetoacetic ester, the poly-ethyl propylene acid butyl ester.
Above-mentioned high molecular weight water soluble polymer be selected from ether of cellulose, polyvinyl alcohol, polyacrylamide, polyoxyethylene glycol, starch and the derivative thereof at least any one.
Described inorganic adhesive be selected from silicate cement, aluminosilicate cement, water glass, the potassium silicate at least any one.
Described auxiliary agent is sanitas, thickening material.
Described sanitas is selected from Sodium Benzoate or sodium pentachlorophenate; Described thickening material is selected from methylcellulose gum, Natvosol, Vltra tears.
Described filler be selected from lime carbonate, mica powder, talcum powder, kaolin, silica powder, the flyash at least any one.
Described light heat insulating material be selected from pearlstone, vermiculite, sepiolite, diatomite, terra alba, the asbestos at least any one.
Described fire retardant be selected from aluminium hydroxide, borax, hydration zinc borate, weisspiessglanz, clorafin, the ammonium polyphosphate at least any one.
Described water is to be selected from least a in deionized water, tap water, the underground water.
In addition, the present invention also provides a kind of vanish system, it is characterized in that, this system comprises priming paint, intermediate coat and finish paint, described priming paint is the water-emulsifying type waterproof coatings that vinylformic acid or benzene emulsion are formed, described intermediate coat is above-mentioned non-expansion type waterproof, fire prevention multifunctional coating, and described finish paint is above-mentioned expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating.
In order to understand the present invention better, further illustrate content of the present invention below in conjunction with embodiment, but content of the present invention not only is confined to the following examples.
Priming paint in the vanish system of the present invention is the YG-100 silicon third JS aqueous waterproofing paint of Yangguang Building New Material Co., Ltd., Wuhan's production.All raw material is currently available products.
Embodiment 1:
A kind of non-expansion type waterproof, fire prevention multifunctional coating are applied to war preparedness material subterranean reservoir warehouse.It comprises polymer adhesive, inorganic adhesive, filler, light heat insulating material, fire retardant, auxiliary agent and water.
The shared weight % of each raw material is:
Polymer adhesive (polymethylmethacrylate emulsion) 13.0%,
Inorganic adhesive (silicate cement and water glass) 17.0%,
Filler (mica powder) 7.0%,
Fire retardant (weisspiessglanz) 1.0%,
Light heat insulating material (vermiculite and diatomite) 33.0%,
Auxiliary agent (Zinc Pyrithione mould inhibitor) 0.2%,
Water (tap water) 28.8%.
The preparation method of above-mentioned non-expansion type waterproof, fire prevention multifunctional coating at first is added to water, polymethylmethacrylate emulsion in the reactor, adds the Zinc Pyrithione mould inhibitor and stirs, and packs as the first component; Silicate cement, water glass, mica powder, weisspiessglanz, vermiculite, diatomite are mixed the back packing in mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
Embodiment 2:
A kind of expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating are applied to the urban road underpass.It comprises benzene emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water.
The shared weight % of each raw material is:
Polymer emulsion (vinylbenzene butyl methacrylate emulsion) 21.0%,
Filler (titanium dioxide and lime carbonate) 7.8%,
Fire retardant (ammonium polyphosphate, tetramethylolmethane and urea) 21.5%,
Long after glow luminous material (rare earth-calcium aluminate) 34.5%,
Auxiliary agent (BYK-33 defoamer and CF-10 dispersion agent) 0.5%,
Water (tap water) 14.7%.
The preparation method of above-mentioned expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, at first vinylbenzene butyl methacrylate emulsion is added in the reactor, adding auxiliary agent stirs, add according to this titanium dioxide, lime carbonate, ammonium polyphosphate, tetramethylolmethane, urea, water mix dispersed with stirring evenly after, add rare earth-calcium aluminate back packing that is uniformly dispersed.Also calcium aluminate can be packed separately, used field mix to disperse the back to use.
Embodiment 3:
A kind of multifunctional coating system is applied in the freeway tunnel, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (polyethyl acrylate emulsion) 15.0%,
Inorganic adhesive (silicate cement) 10.0%,
Filler (lime carbonate and silicon-dioxide) 10.0%,
Fire retardant (weisspiessglanz) 1.0%,
Light heat insulating material (perlite, sepiolite and diatomite) 45.0%,
Auxiliary agent (Zinc Pyrithione mould inhibitor) 0.1%,
Water (tap water) 18.9%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating; Comprise that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (methyl methacrylate ethyl ester copolymer emulsion) 20%,
Filler (lime carbonate) 10%,
Fire retardant (ammonium polyphosphate, Dipentaerythritol and urea) 30%,
Long after glow luminous material (rare earth-calcium aluminate) 25%,
Auxiliary agent (BYK-33 defoamer and BYK-181 dispersion agent) 0.5%,
Water (tap water) 14.5%.
The preparation method of above-mentioned intermediate coat at first is added to water, polyethyl acrylate emulsion in the reactor, adds auxiliary agent and stirs, and packs as the first component; Materials such as silicate cement, lime carbonate, silicon-dioxide, weisspiessglanz perlite, sepiolite and diatomite are mixed the back packing in mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first methyl methacrylate ethyl ester copolymer emulsion is added in the reactor, add auxiliary agent and stir, add according to this lime carbonate, ammonium polyphosphate, Dipentaerythritol, urea, water mix dispersed with stirring evenly after, add rare earth-calcium aluminate back packing that is uniformly dispersed.Also calcium aluminate can be packed separately, used field mix to disperse the back to use.
After measured, the anti-combustion time of this system, under the electricity-saving lamp irradiation, brightness improved 18% greater than 4 hours.
Embodiment 4:
A kind of multifunctional coating system is applied in the underground parking, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (vinylbenzene methacrylic acid emulsion, polyacrylamide) 18.0%,
Inorganic adhesive (silicate cement and potassium silicate) 7.2%,
Filler (lime carbonate and talcum powder) 3.5%,
Fire retardant (zinc borate) 0.5%,
Light heat insulating material (vermiculite, diatomite and perlite) 42.0%,
Auxiliary agent (sodium pentachlorophenate sanitas) 0.2%,
Water (tap water) 28.6%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (polymethyl acrylate emulsion) 11%,
Filler (lime carbonate and titanium dioxide) 5%,
Fire retardant (ammonium polyphosphate, Dipentaerythritol and urea) 10%,
Long after glow luminous material (rare earth-Calucium Silicate powder) 57%,
Auxiliary agent (BYK-33 defoamer and BYK-181 dispersion agent) 0.3%,
Water (deionized water) 16.7%.
The preparation method of above-mentioned intermediate coat at first is dissolved in water polyacrylamide, is added in the reactor with vinylbenzene methacrylic acid emulsion, adds the sodium pentachlorophenate sanitas and stirs, and packs as the first component; Vermiculite, diatomite, perlite, lime carbonate, talcum powder, zinc borate, silicate cement, potassium silicate added successively mix back packing in the solid blender, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first the polymethyl acrylate emulsion is added in the reactor, adding defoamer, dispersion agent, water stir, add successively lime carbonate, titanium dioxide, ammonium polyphosphate, Dipentaerythritol, urea mix dispersed with stirring evenly after, add rare earth-Calucium Silicate powder back packing that is uniformly dispersed.Also rare earth-Calucium Silicate powder can be packed separately, used field mix to disperse the back to use.
After measured, the anti-combustion time of this system, under the electricity-saving lamp irradiation, brightness improved 20% greater than 3.5 hours.Effectively the twilight sunset duration was greater than 2 hours.
Embodiment 5:
A kind of multifunctional coating system is applied to the city and crosses in the underpass of street, and it comprises priming paint, intermediate coat, finish paint, coating varnish.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (polystyrene ACRYLIC EMULSION) 20.0%,
Inorganic adhesive (water glass) 5.0%,
Filler (talcum powder, flyash and silica) 10.0%,
Fire retardant (zinc borate) 1.0%,
Light heat insulating material (perlite and sepiolite) 45.0%,
Auxiliary agent (Sodium Benzoate) 0.1%,
Water (tap water) 18.9%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polyacrylic acid emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (polystyrene methyl acrylate emulsion) 20.0%,
Filler (lime carbonate and titanium dioxide) 10.0%,
Fire retardant (ammonium polyphosphate, tetramethylolmethane and trimeric cyanamide) 30.0%,
Long after glow luminous material (rare earth-barium aluminate) 25.0%,
Auxiliary agent (BYK-33 defoamer and BYK-181 dispersion agent) 0.5%,
Water (deionized water) 14.5%.
Coating varnish is for being the water-latex type varnish of base mateiral preparation with listed ACRYLIC EMULSION of table 1 or benzene emulsion.
The preparation method of above-mentioned intermediate coat at first is added to polystyrene methyl acrylate emulsion in the reactor, adds entry, auxiliary agent stirs, and packs as the first component; Water glass, talcum powder, flyash, silica, zinc borate, perlite, sepiolite added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first polystyrene methyl acrylate emulsion is added in the reactor, adding auxiliary agent stirs, add successively lime carbonate, titanium dioxide, ammonium polyphosphate, tetramethylolmethane, trimeric cyanamide, water mix dispersed with stirring evenly after, add rare earth-barium aluminate back packing that is uniformly dispersed.Also rare earth-barium aluminate can be packed separately, used field mix to disperse the back to use.
Embodiment 6:
A kind of multifunctional coating system is applied in the underground storehouse, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (polystyrene Jia Jibingxisuanyizhi emulsion and polyvinyl alcohol)
5.2％，
Inorganic adhesive (silicate cement and water glass) 27.5%,
Filler (mica powder) 2.0%,
Fire retardant (weisspiessglanz) 1.0%,
Light heat insulating material (vermiculite, perlite and diatomite) 35.0%,
Auxiliary agent (sodium pentachlorophenate) 0.1%,
Water (tap water) 29.2%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (polystyrene Jia Jibingxisuanyizhi emulsion) 10.5%,
Filler (lime carbonate) 6.0%,
Fire retardant (ammonium polyphosphate, Dipentaerythritol and urea) 30.0%,
Long after glow luminous material (rare earth-calcium aluminate) 25.0%,
Auxiliary agent (modest 082 defoamer of moral, T-731 wetting dispersing agent and Walocel MT 20.000PV) 0.5%,
Water (tap water) 28.0%.
The preparation method of above-mentioned intermediate coat at first adds water with polyvinyl alcohol, and dissolving is added in the reactor with polystyrene Jia Jibingxisuanyizhi emulsion under certain condition, adds entry, auxiliary agent stirs, and packs as the first component; Vermiculite, perlite, diatomite, mica powder, weisspiessglanz, silicate cement, water glass added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first polystyrene Jia Jibingxisuanyizhi emulsion is added in the reactor, add entry, auxiliary agent stirs, successively lime carbonate, ammonium polyphosphate, Dipentaerythritol, urea are added mix dispersed with stirring evenly after, add rare earth-calcium aluminate back packing that is uniformly dispersed.Also rare earth-calcium aluminate material can be packed separately, used field mix to disperse the back to use.
Embodiment 7:
A kind of multifunctional coating system is applied in subway station and the passage, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (polyethyl acrylate emulsion and polyvinyl alcohol) 18.5%,
Inorganic adhesive (silicate cement and potassium silicate) 9.2%,
Filler (flyash, talcum powder and silicon-dioxide) 3.5%,
Fire retardant (zinc borate) 8.5%,
Light heat insulating material (vermiculite, perlite and sepiolite) 38.0%,
Auxiliary agent (Zinc Pyrithione mould inhibitor) 0.1%,
Water (tap water) 22.2%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (polyethyl acrylate emulsion) 31.5%,
Filler (titanium dioxide) 8.0%,
Fire retardant (ammonium polyphosphate, tetramethylolmethane and urea) 10.0%,
Long after glow luminous material (rare earth-Calucium Silicate powder) 38.5%,
Auxiliary agent (modest 082 defoamer of moral, T-731 wetting dispersing agent) 0.5%,
Water (deionized water) 11.5%.
The preparation method of above-mentioned intermediate coat at first adds water with polyvinyl alcohol, and dissolving is added in the reactor with the polyethyl acrylate emulsion under certain condition, adds auxiliary agent and stirs, and packs as the first component; Vermiculite, perlite, sepiolite, zinc borate, flyash, talcum powder, silicon-dioxide, silicate cement, potassium silicate added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first the polyethyl acrylate emulsion is added in the reactor, add entry, auxiliary agent stirs, add successively titanium dioxide, ammonium polyphosphate, tetramethylolmethane, urea mix dispersed with stirring evenly after, add rare earth-Calucium Silicate powder back packing that is uniformly dispersed.
Embodiment 8:
A kind of multifunctional coating system is applied in the freeway tunnel, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (polyethyl acrylate emulsion and polyvinyl alcohol) 11.5%,
Inorganic adhesive (silicate cement and water glass) 15.0%,
Filler (mica powder and flyash) 4.5%,
Fire retardant (zinc borate) 1.0%,
Light heat insulating material (perlite, sepiolite and diatomite) 25.0%,
Auxiliary agent (sodium pentachlorophenate) 0.1%,
Water (tap water) 42.9%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (polyethyl acrylate emulsion) 21.0%,
Filler (lime carbonate and titanium dioxide) 7.0%,
Fire retardant (ammonium polyphosphate, tetramethylolmethane and trimeric cyanamide) 10.0%,
Long after glow luminous material (rare earth-strontium aluminate) 45.0%,
Auxiliary agent (BYK-33 defoamer, BYK-181 dispersion moisture agent) 1.1%,
Water (tap water) 15.9%.
The preparation method of above-mentioned intermediate coat at first adds water with polyvinyl alcohol, and dissolving is added in the reactor with polyethyl acrylate emulsion, water under certain condition, adds auxiliary agent and stirs, and packs as the first component; Perlite, sepiolite, diatomite, mica powder, flyash, silicate cement, water glass, zinc borate added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first the polyethyl acrylate emulsion is added in the reactor, add auxiliary agent, water stirs, add successively lime carbonate, titanium dioxide, ammonium polyphosphate, tetramethylolmethane, trimeric cyanamide mix dispersed with stirring evenly after, add rare earth-strontium aluminate back packing that is uniformly dispersed.Also rare earth-strontium aluminate can be packed separately, used field mix to disperse the back to use.
Embodiment 9:
A kind of multifunctional coating system is applied in the underground garage, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (polystyrene methacrylic acid emulsion, polyacrylamide) 5.5%,
Inorganic adhesive (silicate cement and water glass) 28.0%,
Filler (flyash) 1.5%,
Fire retardant (zinc borate) 1.0%,
Light heat insulating material (perlite, diatomite and sepiolite) 40.0%,
Auxiliary agent (Zinc Pyrithione mould inhibitor) 0.1%,
Water (tap water) 23.9%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (polystyrene methacrylic acid emulsion) 22.5%,
Filler (lime carbonate and lithopone) 16.3%,
Fire retardant (ammonium polyphosphate, Dipentaerythritol and hexamethylenetetramine) 16.7%,
Long after glow luminous material (rare earth-calcium magnesium silicate) 33.3%,
Auxiliary agent (BYK-22 defoamer, T-731 dispersion agent) 0.7%,
Water (tap water) 10.5%.
The preparation method of above-mentioned intermediate coat at first is dissolved in water polyacrylamide, is added in the reactor with polystyrene methacrylic acid emulsion, adds auxiliary agent and stirs, and packs as the first component; Perlite, diatomite, sepiolite, zinc borate, flyash, silicate cement, water glass added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first polystyrene methacrylic acid emulsion is added in the reactor, add entry, auxiliary agent stirs, add successively ammonium polyphosphate, Dipentaerythritol, hexamethylenetetramine, lime carbonate, lithopone mix dispersed with stirring evenly after, add rare earth-calcium magnesium silicate back packing that is uniformly dispersed.
Embodiment 10:
A kind of multifunctional coating system is applied in the underpass, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (polymethyl acrylate emulsion and polyvinyl alcohol crosslinked Sumstar 190) 8.0%,
Inorganic adhesive (silicate cement and potassium silicate) 15.0%,
Filler (mica powder, flyash and kaolin) 6.0%,
Light heat insulating material (vermiculite, perlite and diatomite) 35.0%,
Auxiliary agent (Zinc Pyrithione mould inhibitor) 5.0%,
Water (tap water) 31.0%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (polymethyl acrylate emulsion) 23.0%,
Filler (titanium dioxide) 7.0%,
Fire retardant (Ureaphil, urea-formaldehyde resin and polyureas) 25.0%,
Long after glow luminous material (rare earth-barium aluminate) 30.0%,
Auxiliary agent (HX-5010 defoamer and TeogD-750W dispersion agent) 0.5%,
Water (tap water) 14.5%.
The preparation method of above-mentioned intermediate coat, at first with behind the starch oxidation with polyvinyl alcohol crosslinked, prepared polyvinyl alcohol crosslinked Sumstar 190 is added in the reactor with the polymethyl acrylate emulsion, adds auxiliary agent and stirs, and packs as the first component; Vermiculite, perlite, diatomite, mica powder, flyash, kaolin, silicate cement, potassium silicate added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first the polymethyl acrylate emulsion is added in the reactor, add entry, auxiliary agent stirs, add successively Ureaphil, urea-formaldehyde resin, polyureas, titanium dioxide mix dispersed with stirring evenly after, add rare earth-barium aluminate back packing that is uniformly dispersed.Also rare earth-barium aluminate can be packed separately, used field mix to disperse the back to use.
Embodiment 11:
A kind of multifunctional coating system is applied in the market place builet below the ground, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (Jia Jibingxisuanyizhi emulsion and polyoxyethylene glycol) 5.0%,
Inorganic adhesive (silicate cement and water glass) 30.0%,
Filler (mica powder, flyash and talcum powder) 10.0%,
Fire retardant (aluminium hydroxide and borax) 2.5%,
Light heat insulating material (vermiculite, diatomite and sepiolite) 30.0%,
Auxiliary agent (Zinc Pyrithione mould inhibitor) 0.1%,
Water (tap water) 22.4%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (methyl methacrylate-ethyl ester copolymer emulsion) 33.0%,
Filler (lime carbonate and titanium dioxide) 5.0%,
Fire retardant (ammonium polyphosphate, tetramethylolmethane and urea) 28.0%,
Long after glow luminous material (rare earth-calcium aluminate) 25.0%,
Auxiliary agent (BYK-22 defoamer, T-731 dispersion agent) 0.5%,
Water (tap water) 8.5%.
The preparation method of above-mentioned intermediate coat at first is added to polyoxyethylene glycol in the reactor with the Jia Jibingxisuanyizhi emulsion, adds auxiliary agent and stirs, and packs as the first component; Vermiculite, diatomite, sepiolite, aluminium hydroxide, borax, mica powder, flyash, talcum powder, silicate cement, water glass added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first methyl methacrylate-ethyl ester copolymer emulsion is added in the reactor, add entry, auxiliary agent stirs, add successively ammonium polyphosphate, tetramethylolmethane, urea, lime carbonate, titanium dioxide mix dispersed with stirring evenly after, add rare earth-calcium aluminate back packing that is uniformly dispersed.Also rare earth-calcium aluminate can be packed separately, used field mix to disperse the back to use.
Embodiment 12:
A kind of multifunctional coating system is applied in the river-crossing tunnel of city, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (Jia Jibingxisuanyizhi emulsion and polyvinyl alcohol) 9.5%,
Inorganic adhesive (aluminosilicate cement and water glass) 25.0%,
Filler (mica powder, flyash and talcum powder) 3.5%,
Fire retardant (borax) 1.5%,
Light heat insulating material (perlite, sepiolite and diatomite) 30.0%,
Auxiliary agent (sodium pentachlorophenate and Natvosol) 0.8%,
Water (tap water) 29.7%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (Jia Jibingxisuanyizhi emulsion) 11.0%,
Filler (lime carbonate) 17.0%,
Fire retardant (ammonium polyphosphate, Dipentaerythritol and Dyhard RU 100) 21.0%,
Long after glow luminous material (rare earth-calcium aluminate) 35.0%,
Auxiliary agent (BYK-22 defoamer, TeogD-750W dispersion agent) 0.5%,
Water (tap water) 15.5%.
The preparation method of above-mentioned intermediate coat at first adds water with polyvinyl alcohol, and dissolving is added in the reactor with the Jia Jibingxisuanyizhi emulsion under certain condition, adds entry, auxiliary agent stirs, and packs as the first component; Perlite, sepiolite, diatomite, borax, mica powder, flyash, talcum powder, aluminosilicate cement, water glass added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first the Jia Jibingxisuanyizhi emulsion is added in the reactor, add entry, auxiliary agent stirs, add successively ammonium polyphosphate, Dipentaerythritol, Dyhard RU 100, lime carbonate mix dispersed with stirring evenly after, add rare earth-calcium aluminate back packing that is uniformly dispersed.Also rare earth-calcium aluminate can be packed separately, used field mix to disperse the back to use.
Embodiment 13:
A kind of multifunctional coating system is applied in the freeway tunnel, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (ethyl propenoate emulsion and Vltra tears) 8.7%,
Inorganic adhesive (silicate cement and water glass) 11.5%,
Filler (flyash, mica powder and lime carbonate) 4.5%,
Fire retardant (borax and aluminium hydroxide) 2.0%,
Light heat insulating material (vermiculite, perlite and sepiolite) 40.0%,
Auxiliary agent (Zinc Pyrithione mould inhibitor) 0.1%,
Water (tap water) 33.2%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (Jia Jibingxisuanyizhi emulsion) 21.0%,
Filler (lime carbonate and lithopone) 9.5%,
Fire retardant (ammonium polyphosphate, tetramethylolmethane and urea) 14.5%,
Long after glow luminous material (rare earth-strontium aluminate) 35.0%,
Auxiliary agent (BYK-33 defoamer, T-731 dispersion moisture agent) 0.8%,
Water (deionized water) 19.2%.
The preparation method of above-mentioned intermediate coat at first is dissolved in water Vltra tears, is added in the reactor with the ethyl propenoate emulsion, adds auxiliary agent and stirs, and packs as the first component; Vermiculite, perlite, sepiolite, borax, aluminium hydroxide, flyash, mica powder, lime carbonate, silicate cement, water glass added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first the Jia Jibingxisuanyizhi emulsion is added in the reactor, add entry, auxiliary agent stirs, add successively ammonium polyphosphate, tetramethylolmethane, urea, lime carbonate, lithopone mix dispersed with stirring evenly after, add rare earth-strontium aluminate back packing that is uniformly dispersed.Also rare earth-strontium aluminate can be packed separately, used field mix to disperse the back to use.
Embodiment 14:
A kind of multifunctional coating system is applied in the underground parking, and it comprises priming paint, intermediate coat, finish paint.
Wherein: priming paint is the YG-100 silicon third JS aqueous waterproofing paint that Yangguang Building New Material Co., Ltd., Wuhan produces.
Intermediate coat is non-expansion type waterproof, fire prevention multifunctional coating, comprises polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer adhesive (styrene acrylic methyl esters emulsion and polyoxyethylene glycol) 11.5%,
Inorganic adhesive (silicate cement and water glass) 25.0%,
Filler (mica powder, flyash and talcum powder) 10.0%,
Fire retardant (clorafin and zinc borate) 7.5%,
Light heat insulating material (vermiculite) 15.0%,
Auxiliary agent (sodium pentachlorophenate) 0.1%,
Water (tap water) 30.9%.
Finish paint is expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating, comprises that polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water raw material mix.
The shared weight % of each raw material is:
Polymer emulsion (styrene methyl methacrylate emulsion) 21.5%,
Filler (lime carbonate) 12.3%,
Fire retardant (ammonium polyphosphate, Dipentaerythritol and urea) 12.7%,
Long after glow luminous material (rare earth-strontium silicate zinc) 25.0%,
Auxiliary agent B YK-33 defoamer, T-731 dispersion agent, Vltra tears) 1.5%,
Water (tap water) 27.0%.
The preparation method of above-mentioned intermediate coat at first is added to polyoxyethylene glycol in the reactor with styrene acrylic methyl esters emulsion, adds entry, auxiliary agent stirs, and packs as the first component; Vermiculite, clorafin, zinc borate, mica powder, flyash, talcum powder, silicate cement, water glass added successively mix back packing in the mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, uses above continuing behind the specific time again.
The preparation method of above-mentioned finish paint, at first the styrene methyl methacrylate emulsion is added in the reactor, add entry, auxiliary agent stirs, add successively ammonium polyphosphate, Dipentaerythritol, urea, lime carbonate mix dispersed with stirring evenly after, add rare earth-strontium silicate zinc back packing that is uniformly dispersed.
The bound value and the interval value of polymer emulsion of the present invention, aqueous high molecular material, inorganic adhesive, fire retardant, heat preserving and insulating material, long after glow luminous material, auxiliary agent, filler and water raw material can both be realized technique effect of the present invention, and the concrete raw material that polymer emulsion, aqueous high molecular material, inorganic adhesive, fire retardant, heat preserving and insulating material, long after glow luminous material, auxiliary agent, filler and water raw material are selected from separately can both be realized technique effect of the present invention, has not just enumerated embodiment one by one at this.
Claims (44)
1, a kind of expanded polystyrene veneer waterproof, fire prevention, luminous multifunctional coating is characterized in that it comprises polymer emulsion, filler, fire retardant, long after glow luminous material, auxiliary agent and water.
The shared weight % of described each raw material is:
Polymer emulsion 10～50%,
Filler 5～30%,
Fire retardant 10～30%,
Long after glow luminous material 10～60%,
Auxiliary agent 0.1～5%,
Water 1～50%.
2. multifunctional coating as claimed in claim 1 is characterized in that, described polymer emulsion is selected from least a in benzene emulsion or the ACRYLIC EMULSION.
3. multifunctional coating as claimed in claim 1 or 2 is characterized in that, described benzene emulsion is the emulsion that is selected from least a resin formation of styrene-acrylate or styrene methacrylates.
4. multifunctional coating as claimed in claim 3 is characterized in that, described styrene-acrylate is to be selected from least a in styrene acrylic methyl esters, styrene-acrylonitrile copolymer acetoacetic ester, the styrene-acrylonitrile copolymer acid butyl ester.
5. multifunctional coating as claimed in claim 3 is characterized in that, described styrene methacrylates is to be selected from least a in styrene methyl methacrylate, vinylbenzene Jia Jibingxisuanyizhi, the vinylbenzene butyl methacrylate.
6. multifunctional coating as claimed in claim 1 or 2 is characterized in that, described ACRYLIC EMULSION is at least a or any at least two kinds multipolymer in them that is selected from polyacrylic ester, polymethacrylate or the poly-ethyl propylene acid esters.
7. multifunctional coating as claimed in claim 6 is characterized in that, described polyacrylic ester is to be selected from least a in polymethyl acrylate, polyethyl acrylate, the butyl polyacrylate.
8. multifunctional coating as claimed in claim 6 is characterized in that, described polymethacrylate is to be selected from least a in polymethylmethacrylate, polyethyl methacrylate, the poly-n-butyl methacrylate.
9. multifunctional coating as claimed in claim 6 is characterized in that, described poly-ethyl propylene acid esters is to be selected from least a in poly-ethylacrylic acid methyl esters, poly-ethyl propylene acetoacetic ester, the poly-ethyl propylene acid butyl ester.
10. as each the described multifunctional coating in the claim 1～9, it is characterized in that described filler is to be selected from least a in mica powder, rhombspar, lime carbonate, talcum powder, kaolin, wollastonite, silica powder, flyash, titanium dioxide, lithopone, process white, cement, the glass fibre.
11. each the described multifunctional coating as in the claim 1～10 is characterized in that described fire retardant is char-forming agent, whipping agent, catalyzer, mixes by a certain percentage.
The ratio of each component is (weight ratio):
Char-forming agent 10～20%
Whipping agent 20～40%
Catalyzer 40～60%.
12. multifunctional coating as claimed in claim 11 is characterized in that, described char-forming agent is to be selected from least a in carbohydrate, polyol compound, the hydroxy-containing resin.
13. multifunctional coating as claimed in claim 12 is characterized in that, described char-forming agent is to be selected from least a in starch, tetramethylolmethane, Dipentaerythritol, the urea-formaldehyde resin.
14. multifunctional coating as claimed in claim 11 is characterized in that, described whipping agent is to be selected from least a in trimeric cyanamide, Dyhard RU 100, urea, polyureas, the hexamethylenetetramine.
15. multifunctional coating as claimed in claim 11 is characterized in that, described catalyzer is to be selected from least a in ammonium polyphosphate, melamine phosphate, Ureaphil, phosphoguanidine, the boric acid fat.
16. as each described multifunctional coating in the claim 1～15, it is characterized in that, described long after glow luminous material be selected from aluminate or silicate at least any one.
17. multifunctional coating as claimed in claim 16 is characterized in that, described aluminate is formula M al
2O
4: Eu
2+, RE
3+ shown in aluminate, wherein M=Ca, Sr, Ba, RE=rare earth ion.
18. multifunctional coating as claimed in claim 16 is characterized in that, described silicate is formula M OM ' OSiO
3: Eu, the silicate shown in the Ln, wherein M=Ca, Sr, Ba, M '=Mg, Zn, Cd Ln=co-activator are rare earth ion and the part transition metal ions except that Eu.
19. as each described multifunctional coating in the claim 1～18, it is characterized in that, described auxiliary agent be selected from sanitas, wetting dispersing agent or defoamer at least any one.
20. multifunctional coating as claimed in claim 19 is characterized in that, described sanitas is Sodium Benzoate, Zinc Pyrithione mould inhibitor or sodium pentachlorophenate.
21., it is characterized in that described water is to be selected from least a in deionized water, tap water, the underground water as each described multifunctional coating in the claim 1～20.
22. preparation method as each described multifunctional coating in the claim 1～21, it is characterized in that, polymer emulsion is added in the reactor, adding auxiliary agent stirs, add according to this filler, fire retardant, water mix dispersed with stirring evenly after, add the long-decay phosphor material back packing that is uniformly dispersed.
23. preparation method as each described multifunctional coating in the claim 1～21, it is characterized in that, polymer emulsion is added in the reactor, adding auxiliary agent stirs, add evenly back packing of filler, fire retardant, water mixing dispersed with stirring according to this, long-decay phosphor material is packed separately, used field mix to disperse the back to use.
24. a non-expansion type waterproof, fire prevention multifunctional coating is characterized in that, comprise polymer adhesive, inorganic adhesive, and filler, light heat insulating material, fire retardant, auxiliary agent and water,
The shared weight % of described each raw material is:
Polymer adhesive 5～20%,
Inorganic adhesive 5～30%,
Filler 1～10%,
Light heat insulating material 10～50%
Fire retardant 0～10%
Auxiliary agent 0.1～5%,
Water 1～50%.
25. multifunctional coating as claimed in claim 24 is characterized in that, described high molecular polymer comprises polymer emulsion and high molecular weight water soluble polymer.
26. multifunctional coating as claimed in claim 25 is characterized in that, described polymer emulsion is selected from least a in benzene emulsion or the ACRYLIC EMULSION.
27. multifunctional coating as claimed in claim 26 is characterized in that, described benzene emulsion is the emulsion that is selected from least a resin formation of styrene-acrylate or styrene methacrylates.
28. multifunctional coating as claimed in claim 27 is characterized in that, described styrene-acrylate is to be selected from least a in styrene acrylic methyl esters, styrene-acrylonitrile copolymer acetoacetic ester, the styrene-acrylonitrile copolymer acid butyl ester.
29. multifunctional coating as claimed in claim 27 is characterized in that, described styrene methacrylates is to be selected from least a in styrene methyl methacrylate, vinylbenzene Jia Jibingxisuanyizhi, the vinylbenzene butyl methacrylate.
30. multifunctional coating as claimed in claim 26 is characterized in that, described ACRYLIC EMULSION is at least a or any at least two kinds multipolymer in them that is selected from polyacrylic ester, polymethacrylate or the poly-ethyl propylene acid esters.
31. multifunctional coating as claimed in claim 30 is characterized in that, described polyacrylic ester is to be selected from least a in polymethyl acrylate, polyethyl acrylate, the butyl polyacrylate.
32. multifunctional coating as claimed in claim 30 is characterized in that, described polymethacrylate is to be selected from least a in polymethylmethacrylate, polyethyl methacrylate, the poly-n-butyl methacrylate.
33. multifunctional coating as claimed in claim 30 is characterized in that, described poly-ethyl propylene acid esters is to be selected from least a in poly-ethylacrylic acid methyl esters, poly-ethyl propylene acetoacetic ester, the poly-ethyl propylene acid butyl ester.
34. as each described multifunctional coating in the claim 25～33, it is characterized in that, above-mentioned high molecular weight water soluble polymer be selected from ether of cellulose, polyvinyl alcohol, polyacrylamide, polyoxyethylene glycol, starch and the derivative thereof at least any one.
35. as each described multifunctional coating in the claim 24～34, it is characterized in that, described inorganic adhesive be selected from silicate cement, aluminosilicate cement, water glass, the potassium silicate at least any one.
36., it is characterized in that described auxiliary agent is sanitas, thickening material as each described multifunctional coating in the claim 24～35.
37. multifunctional coating as claimed in claim 36 is characterized in that, described sanitas is Sodium Benzoate, Zinc Pyrithione mould inhibitor or sodium pentachlorophenate; Described thickening material is methylcellulose gum, Natvosol.
38. as each described multifunctional coating in the claim 24～37, it is characterized in that, described filler be selected from lime carbonate, mica powder, talcum powder, kaolin, silica powder, the flyash at least any one.
39. as each described multifunctional coating in the claim 24～38, it is characterized in that, described light heat insulating material be selected from pearlstone, vermiculite, sepiolite, diatomite, terra alba, the asbestos at least any one.
40. as each described multifunctional coating in the claim 24～39, it is characterized in that, described fire retardant be selected from aluminium hydroxide, borax, hydration zinc borate, weisspiessglanz, clorafin, the ammonium polyphosphate at least any one.
41., it is characterized in that described water is to be selected from least a in deionized water, tap water, the underground water as each described multifunctional coating in the claim 24～40.
42., it is characterized in that the shared gross weight ratio of its each raw material is as each described multifunctional coating in the claim 24～41:
Polymer adhesive 7.0%,
Inorganic adhesive 23.0%,
Filler 2.0%,
Fire retardant 1.0%,
Light heat insulating material 45.0%
Auxiliary agent 0.1%,
Water 21.9%.
43. the preparation method as each described multifunctional coating in the claim 24～42 is characterized in that, at first the aqueous high molecular material is added water, dissolving under certain condition, be added in the reactor with polymer emulsion, add auxiliary agent and stir, pack as the first component; Inorganic adhesive, filler, light heat insulating material are mixed the back packing in mixing machine, as component B; First, component B mixes before use and use the back that stirs, and mixed first, component B must use in specific time, above continuing use behind the specific time.
44. vanish system, it is characterized in that, this system comprises priming paint, intermediate coat and finish paint, described priming paint is the water-emulsifying type waterproof coatings that ACRYLIC EMULSION or benzene emulsion are formed, described intermediate coat is each described non-expansion type multifunctional coating in the claim 24～42, and described finish paint is each described expanded polystyrene veneer multifunctional coating in the claim 1～21.
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