CN101177542B - Method for preparing aspidium rhizoma natural dye - Google Patents
Method for preparing aspidium rhizoma natural dye Download PDFInfo
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- CN101177542B CN101177542B CN2007101566806A CN200710156680A CN101177542B CN 101177542 B CN101177542 B CN 101177542B CN 2007101566806 A CN2007101566806 A CN 2007101566806A CN 200710156680 A CN200710156680 A CN 200710156680A CN 101177542 B CN101177542 B CN 101177542B
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- Prior art keywords
- cyrtomium
- cyrtomium fortunei
- rhizome
- natural dye
- solution
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- 238000000034 method Methods 0.000 title claims abstract description 9
- 229930182559 Natural dye Natural products 0.000 title abstract description 8
- 239000000978 natural dye Substances 0.000 title abstract description 8
- 239000000975 dye Substances 0.000 claims abstract description 53
- 239000000243 solution Substances 0.000 claims abstract description 21
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 18
- 238000002360 preparation method Methods 0.000 claims abstract description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 15
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 9
- 238000009736 wetting Methods 0.000 claims abstract description 8
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 241001660870 Cyrtomium Species 0.000 claims description 39
- 235000017550 sodium carbonate Nutrition 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 235000011008 sodium phosphates Nutrition 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 150000001768 cations Chemical class 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 238000000605 extraction Methods 0.000 abstract description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 abstract description 3
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 3
- 150000002910 rare earth metals Chemical class 0.000 abstract description 3
- 241001226187 Cyrtomium fortunei Species 0.000 abstract 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003637 basic solution Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 description 12
- 210000002268 wool Anatomy 0.000 description 9
- 239000004753 textile Substances 0.000 description 7
- 238000009835 boiling Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 239000000284 extract Substances 0.000 description 4
- 230000000711 cancerogenic effect Effects 0.000 description 3
- 231100000315 carcinogenic Toxicity 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- 208000031320 Teratogenesis Diseases 0.000 description 2
- 208000030961 allergic reaction Diseases 0.000 description 2
- 159000000013 aluminium salts Chemical class 0.000 description 2
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 208000019838 Blood disease Diseases 0.000 description 1
- 206010014080 Ecchymosis Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010046788 Uterine haemorrhage Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- 230000002155 anti-virotic effect Effects 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 208000035861 hematochezia Diseases 0.000 description 1
- 208000014951 hematologic disease Diseases 0.000 description 1
- 208000018706 hematopoietic system disease Diseases 0.000 description 1
- 230000023597 hemostasis Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 201000009240 nasopharyngitis Diseases 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000002444 phloroglucinyl group Chemical class [H]OC1=C([H])C(O[H])=C(*)C(O[H])=C1[H] 0.000 description 1
- NFIYTPYOYDDLGO-UHFFFAOYSA-N phosphoric acid;sodium Chemical compound [Na].OP(O)(O)=O NFIYTPYOYDDLGO-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
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- 238000001228 spectrum Methods 0.000 description 1
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- 241000712461 unidentified influenza virus Species 0.000 description 1
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- Coloring (AREA)
Abstract
The invention discloses a preparation method and the product for natural dye of cyrtomium fortunei. Firstly, plant cyrtomium fortunei is ground and put into water solution, which volume is 5 to 20 times of cyrtomium fortunei for wetting; then, sodium hydroxide, sodium carbonate, sodium silicate or sodium phosphate are added to adjust the pH of the solution to 10 to 13 when the Cyrtomium fortunei is thoroughly soaked; the solution is warmed up to 95 to 100 DEG C, and insulated for heat preservation for 60 to 90 mins and filtered. Secondly, the residue continue to be leached by the basic solution with a PH from 10 to 13, the mixed solution is filtered and then the two leaching liquids of cyrtomium fortunei are merged to get cyrtomium fortunei natural dye dope. Thirdly, the natural dye dope is concentrated, solidified and ground to get dusty Cyrtomium fortunei natural dye. The cyrtomium fortunei natural dye can dye silk and woolen product under the condition of no mordant, afterchrome process with rare-earth mixed chloride, metal aluminum salt or metal ferrous salt. Cotton product can be modified by cation modifying agent before being dyed by cyrtomium fortunei natural dye. The invention has advantages of simple extraction technology, high efficiency, stable quality, broad market prospect and no environmental pollution during preparation.
Description
Technical field
The present invention relates to natural dyestuff and application thereof, particularly relate to a kind of preparation method of rhizome of cyrtomium natural dyestuff.
Background technology
Along with the continuous enhancing of human environmental consciousness and to the growing interest of self health, the partial synthesis dyestuff is more and more noticeable to the harm that human health and ecotope are produced.Existing result of study shows have 23 kinds of carcinogenic aromatic amines, more than 100 synthetic dyestuff might produce carcinogenic substance, and more than 20 synthetic dyestuff produce irritated to skin.Therefore, synthetic dyestuff and painted textiles thereof are suspected the human consumer.Moreover, along with the continuous consumption of petroleum resources on the earth, be becoming tight by day for the raw material problem of synthetic dyestuff.
Natural dyestuff is meant root, leaf, bark, trunk, shell, flower or animal secretions from plant, the mineral substance and extracts that preparation process can not cause environmental pollution; Dyeing back fabric is worn safety, carcinogenic, teratogenesis is arranged unlike some synthetic dyestuff textiles or cause allergic reaction, and natural dyestuff and ecotope consistency is good, biodegradable; Except that the dyeing function, the part natural dyestuff also has the medicinal health-care function.Advocate current people under the tide impact of green consumption product, in fields such as high grade true silk goods, health-care underclothes, home textile product, adornment, have vast potential for future development.
Rhizome of cyrtomium is the fern per nnial herb, and the nature and flavor hardship is slightly cold, and is slightly poisonous.Its main component is a complicated Phloroglucinol derivative etc., and antivirus action is arranged, and influenza virus is had the strongly inhibited effect, has effects such as clearing heat and detoxicating, expelling parasite, cool blood, hemostasis.Be used for the treatment of common cold due to wind-heat, damp and hot ecchymosis clinically, spit blood, have blood in stool and disease such as uterine bleeding.
Rhizome of cyrtomium not only can be used as a kind of natural brown dyestuff to textiles dye, stamp, also have functions such as antibacterial, antiviral.Therefore, from rhizome of cyrtomium, extract a kind of brown natural dyestuff and be applied to textile dyeing, for expansion natural dyestuff chromatogram and range of application, the development functionality textiles, the class of raising China textiles has crucial meaning.
About the preparation and the dyeing process thereof of rhizome of cyrtomium natural dyestuff, not seeing at present has report.
Summary of the invention
Purpose of the present invention provides a kind of preparation method of rhizome of cyrtomium natural dyestuff, is raw material with the rhizome of cyrtomium, adopts processing methodes such as alkaline aqueous solution extracts, concentrates, curing, pulverizing to be prepared from natural dyestuff.
The technical solution adopted for the present invention to solve the technical problems is:
One, a kind of preparation method of rhizome of cyrtomium natural dyestuff, the step of this method is as follows:
1) the plant rhizome of cyrtomium is cleaned, dried, mechanical disintegration joins then in 5～20 times of aqueous solution and soaks, after treating that rhizome of cyrtomium is fully wetting, add sodium hydroxide, yellow soda ash, water glass or sodium phosphate, the pH of regulator solution is 10～13, be warming up to 95～100 ℃, insulation 60～90min filters; It is 10～13 alkaline solution lixiviate that filter residue continues with pH, filters, and merges vat liquor twice, must natural dyestuff stoste;
2) the rhizome of cyrtomium natural dyestuff stoste of extracting is concentrated, solidifies, pulverizes, get Powdered natural dyestuff.
Two, the rhizome of cyrtomium natural dyestuff that obtains of described preparation method dye goods:
1) under the condition without mordant, the real silk, the wool product that adopt the rhizome of cyrtomium natural dyestuff can dye brownly;
2) under mordant dyeing condition behind the mixed chlorinated rare earth, can dye real silk, the wool product of yellowish brown;
3) under mordant dyeing condition after the metallic aluminium salt, can dye real silk, the wool product of reddish-brown;
4) under mordant dyeing condition behind the metal ferrous salt, can dye real silk, the wool product of brown.
5) cotton products carry out modification with cation modifier earlier, the cotton products that the back adopts the rhizome of cyrtomium natural dye dying can dye brownly.
The beneficial effect that the present invention has is:
1, with conventional natural dyestuff extract phase ratio, extraction process of the present invention is simple, the extraction efficiency height, and steady quality, market outlook are wide.Preparation process can not cause environmental pollution;
2, dyeing articles is taken safety, does not have carcinogenic, teratogenesis or causes allergic reaction; Good, biodegradable with the ecotope consistency;
3, real silk, wool and the cotton products Dry Sack is even, colour fastness good can obtain brown, brown isochromatic spectrum respectively under different mordant effects.
Embodiment
Embodiment 1:
Take by weighing rhizome of cyrtomium 500 gram, clean, dry, mechanical disintegration is soaked with 20 times of tap water then, treat that rhizome of cyrtomium is fully wetting after, add the sodium hydroxide of aequum, regulating soak solution pH is about 13, is warming up to 100 ℃, little boiling is incubated 60min left and right sides after-filtration.Filter residue continues to merge vat liquor twice with 5～10 times of water (contain sodium hydroxide, pH is about 13) solution lixiviate, neutralizes, is concentrated into 500 milliliters, is rhizome of cyrtomium natural dyestuff concentrated solution.Solidify, pulverize, get Powdered natural dyestuff.
Adopt conventional dyeing process, under the condition of metallic aluminium salt, adopt the rhizome of cyrtomium natural dyestuff of above-mentioned preparation that wool is dyeed, obtain the wool product of reddish-brown as mordant.
Embodiment 2:
Take by weighing rhizome of cyrtomium 500 gram, clean, dry, mechanical disintegration is soaked with 8 times of tap water then, treat that rhizome of cyrtomium is fully wetting after, add the yellow soda ash of aequum, regulating soak solution pH is about 12, is warming up to 98 ℃, little boiling is incubated 60min left and right sides after-filtration.Filter residue continues to merge vat liquor twice with 5～10 times of water (contain yellow soda ash, pH is about 12) solution lixiviate, neutralizes, is concentrated into 500 milliliters, is rhizome of cyrtomium natural dyestuff concentrated solution.Solidify, pulverize, get Powdered natural dyestuff.
Adopt conventional dyeing process, under the condition of metal ferrous salt, adopt the rhizome of cyrtomium natural dyestuff of above-mentioned preparation that real silk is dyeed, obtain the pure silk products of brown as mordant.
Embodiment 3:
Take by weighing rhizome of cyrtomium 500 gram, clean, dry, mechanical disintegration is soaked with 12 times of tap water then, treat that rhizome of cyrtomium is fully wetting after, add the yellow soda ash of aequum, regulating soak solution pH is about 12, is warming up to 100 ℃, little boiling is incubated 60min left and right sides after-filtration.Filter residue continues to merge vat liquor twice with 5～10 times of water (contain yellow soda ash, pH is about 12) solution lixiviate, neutralizes, is concentrated into 500 milliliters, is rhizome of cyrtomium natural dyestuff concentrated solution.Solidify, pulverize, get Powdered natural dyestuff.
Adopt conventional dyeing process, under the condition of mixed chlorinated rare earth, adopt the rhizome of cyrtomium natural dyestuff of above-mentioned preparation that real silk is dyeed, obtain the pure silk products of yellowish brown as mordant.
Embodiment 4:
Take by weighing rhizome of cyrtomium 500 gram, clean, dry, mechanical disintegration is soaked with 15 times of tap water then, treat that rhizome of cyrtomium is fully wetting after, add the yellow soda ash of aequum, regulating soak solution pH is about 10, is warming up to 100 ℃, little boiling is incubated 60min left and right sides after-filtration.Filter residue continues to merge vat liquor twice with 5～10 times of water (contain yellow soda ash, pH is about 10) solution lixiviate, neutralizes, is concentrated into 500 milliliters, is rhizome of cyrtomium natural dyestuff concentrated solution.Solidify, pulverize, get Powdered natural dyestuff.
Adopt conventional dyeing process, adopt the rhizome of cyrtomium natural dyestuff of above-mentioned preparation to dye, obtain brown cotton products the cotton after cation modifier (the city's field energy has been bought) modification.
Embodiment 5:
Take by weighing rhizome of cyrtomium 500 gram, clean, dry, mechanical disintegration is soaked with 20 times of tap water then, treat that rhizome of cyrtomium is fully wetting after, add the sodium phosphate of aequum, regulating soak solution pH is about 11, is warming up to 100 ℃, little boiling is incubated 60min left and right sides after-filtration.Filter residue continues to merge vat liquor twice with 5～10 times of water (phosphoric acid sodium, pH are about 11) solution lixiviate, neutralizes, is concentrated into 500 milliliters, is rhizome of cyrtomium natural dyestuff concentrated solution.Solidify, pulverize, get Powdered natural dyestuff.
Adopt the rhizome of cyrtomium natural dyestuff of above-mentioned preparation, directly wool is dyeed, obtain brown wool product.
Claims (1)
1. the preparation method of a rhizome of cyrtomium natural dyestuff is characterized in that the step of this method is as follows:
1) the plant rhizome of cyrtomium is cleaned, dried, mechanical disintegration joins then in 5～20 times of aqueous solution and soaks, after treating that rhizome of cyrtomium is fully wetting, add sodium hydroxide, yellow soda ash, water glass or sodium phosphate, the pH of regulator solution is 10～13, be warming up to 95～100 ℃, insulation 60～90min filters; It is 10～13 alkaline solution lixiviate that filter residue continues with pH, filters, and merges vat liquor twice, must natural dyestuff stoste;
2) the rhizome of cyrtomium natural dyestuff stoste of extracting is concentrated, solidifies, pulverizes, get Powdered natural dyestuff.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101566806A CN101177542B (en) | 2007-11-16 | 2007-11-16 | Method for preparing aspidium rhizoma natural dye |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101566806A CN101177542B (en) | 2007-11-16 | 2007-11-16 | Method for preparing aspidium rhizoma natural dye |
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| Publication Number | Publication Date |
|---|---|
| CN101177542A CN101177542A (en) | 2008-05-14 |
| CN101177542B true CN101177542B (en) | 2010-06-09 |
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| CN2007101566806A Expired - Fee Related CN101177542B (en) | 2007-11-16 | 2007-11-16 | Method for preparing aspidium rhizoma natural dye |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051063A (en) * | 2010-11-29 | 2011-05-11 | 南通职业大学 | Camphor tree dye, extracting method thereof and use thereof |
| CN102094341B (en) * | 2010-12-07 | 2016-01-13 | 江南大学 | A kind of colouring method of real silk fabrics by extracting pigment from phytolacca by ultrasonic technology |
| CN102080333A (en) * | 2010-12-07 | 2011-06-01 | 江南大学 | Process for dyeing cotton cheese by using natural dye |
| CN104233860B (en) * | 2013-06-17 | 2016-12-07 | 南安市品龙新材料科技有限公司 | A kind of Flos Impatientis pigment is to mordant dyeing technique after the iron salt of real silk fabric |
| CN103821014A (en) * | 2014-03-20 | 2014-05-28 | 海安县福兴漂染有限公司 | Cotton fiber based non-reactive type modified natural dye staining method |
| CN103865292B (en) * | 2014-03-28 | 2015-10-28 | 苏州大学 | A kind of ecological dyeing liked plum natural dyestuff, preparation method and be applied to thiozell |
| CN104452334B (en) * | 2014-11-03 | 2016-06-22 | 广东溢达纺织有限公司 | A kind of natural dye Printing and preparation method thereof |
| CN108864737B (en) * | 2018-07-19 | 2020-08-18 | 阜南县富民工艺品有限公司 | Preparation method of natural dye for wood artware |
| CN109021611B (en) * | 2018-09-05 | 2021-02-19 | 浙江稽山印染有限公司 | Extraction method and application of natural plant dye |
| CN109162119A (en) * | 2018-09-05 | 2019-01-08 | 浙江稽山印染有限公司 | A kind of natural plant dye and its application in dyeing and printing process |
| CN110029495B (en) * | 2019-04-25 | 2022-04-01 | 浙江恒生印染有限公司 | Fabric finishing liquid with anti-ultraviolet function and anti-ultraviolet functional cotton fabric prepared from same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1952020A (en) * | 2006-11-07 | 2007-04-25 | 浙江理工大学 | Chestnut shell natural dye preparation and its uses |
| CN1995151A (en) * | 2006-12-27 | 2007-07-11 | 浙江理工大学 | Spatholobus stem natural dye preparation and its uses |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1952020A (en) * | 2006-11-07 | 2007-04-25 | 浙江理工大学 | Chestnut shell natural dye preparation and its uses |
| CN1995151A (en) * | 2006-12-27 | 2007-07-11 | 浙江理工大学 | Spatholobus stem natural dye preparation and its uses |
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