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CN102080028A - Dryopteris erythrosora/soapberry natural biomass detergent and preparation method thereof - Google Patents

Dryopteris erythrosora/soapberry natural biomass detergent and preparation method thereof Download PDF

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CN102080028A
CN102080028A CN2011100007543A CN201110000754A CN102080028A CN 102080028 A CN102080028 A CN 102080028A CN 2011100007543 A CN2011100007543 A CN 2011100007543A CN 201110000754 A CN201110000754 A CN 201110000754A CN 102080028 A CN102080028 A CN 102080028A
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sapindus
extract
chinensis
liquid
purification
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CN102080028B (en
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孙先玉
孙博
李冬玲
黄海涛
张秀珍
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Institute of Chemical Industry of Forest Products of CAF
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Abstract

本发明涉及一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,即以鳞毛蕨科植物叶子、无患子植物的果实为原料,分别按蒸煮、提取、精制、复配加工工艺制备的无患子鳞毛蕨天然生物质洗涤剂,可以是液状产品,也可以是粉状产品。鳞毛蕨、无患子天然生物质洗涤剂主要用于餐具、果蔬清洗、洗发、沐浴的绿色清洗、保洁、洗涤,其清洁油渍效果颇佳,其中鳞毛蕨植物叶子提取液有天然杀菌、防腐、去污、止痒作用,无患子果肉提取液有天然去污、祛屑止痒、营养调理作用,两者均为纯天然、无毒、安全、环保。The present invention relates to the preparation and method of a kind of natural biomass detergent of Phalaenopsis and Sapindus, that is, the leaves of Sapindaceae plant and the fruit of Sapindus are used as raw materials, and the steps of cooking, extracting, refining, and compounding are respectively carried out. The natural biomass detergent of Sapindus chinensis prepared by processing technology can be a liquid product or a powder product. The natural biomass detergents of Trichofern and Sapindus are mainly used for green cleaning, cleaning and washing of tableware, fruit and vegetable washing, hair washing and bathing. , antisepsis, decontamination, antipruritic effect, Sapindus fruit pulp extract has natural decontamination, dandruff and antipruritic, nutritional conditioning effects, both of which are pure natural, non-toxic, safe and environmentally friendly.

Description

一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法 A kind of preparation and method of natural biomass detergent of hair fern and Sapindus chinensis

技术领域:Technical field:

本发明涉及一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,即以鳞毛蕨科植物叶子、无患子植物的果实为原料,分别按蒸煮、提取、精制、复配加工工艺制备的一种鳞毛蕨、无患子天然生物质洗涤剂,其可以是液状产品,也可以是粉状产品。该技术属于日用化学品。 The present invention relates to the preparation and method of a kind of natural biomass detergent of Phalaenopsis and Sapindus, that is, the leaves of Sapindaceae plant and the fruit of Sapindus are used as raw materials, and the steps of cooking, extracting, refining, and compounding are respectively carried out. The invention relates to a natural biomass detergent prepared by compounding and processing technology, which can be a liquid product or a powder product. This technology belongs to daily chemicals. the

背景技术:Background technique:

本发明的鳞毛蕨、无患子天然生物质洗涤剂主要用于餐具、果蔬清洗、洗发、沐浴的绿色清洗、保洁、洗涤,其清洁油渍效果颇佳,其中鳞毛蕨植物叶子提取液有天然杀菌、防腐、去污、止痒作用,无患子果肉提取液有天然去污、祛屑止痒、营养调理作用,两者均为纯天然、无毒、安全、环保。 The natural biomass detergent of Phytophthora edulis and Sapindus chinensis of the present invention is mainly used for green cleaning, cleaning, and washing of tableware, fruit and vegetable cleaning, shampooing, and bathing, and its cleaning effect on oil stains is quite good. It has natural bactericidal, antiseptic, decontamination, and antipruritic effects, and Sapindus fruit pulp extract has natural decontamination, antidandruff, antipruritic, and nutritional conditioning effects. Both are pure natural, non-toxic, safe, and environmentally friendly. the

目前在国内外市场上出售的餐具、果蔬清洗、洗发、沐浴洗涤剂,品种繁多,多数是以石油为原料通过化学方法获得的原料制成的。其基本成分是表面活性剂和助剂组成,大多使用化学物质如表面活性剂、助剂、防腐剂、荧光增白剂、合成香精、合成色素、止痒剂等,由于各化学物质之间的协同作用,增强作用、拮抗作用,对人体皮肤刺激性强,使其对人体都存在着或多或少的刺激性和潜在毒效应,对人体健康造成危害,并产生环境污染。 Tableware, fruit and vegetable cleaning, shampoo, and bath detergents currently sold in domestic and foreign markets are of a great variety, and most of them are made of petroleum as a raw material obtained by chemical methods. Its basic components are composed of surfactants and additives, most of which use chemical substances such as surfactants, additives, preservatives, fluorescent whitening agents, synthetic flavors, synthetic pigments, antipruritics, etc. Synergistic, enhancing, and antagonistic effects are highly irritating to human skin, making them more or less irritating and potentially toxic to the human body, causing harm to human health and causing environmental pollution. the

现有技术中,已公开的以天然物质为主要成分的洗涤剂也有一些。例如,中国专利91105963公开的一种洗涤剂组合物及其制造方法,以油茶饼粉末、十二烷基苯磺酸钠、珍珠岩粉末、污水硫酸钠等为原料制成洗涤剂;中国专利91106832公开的茶枯粉洗涤剂,以脱脂茶枯粉、脂肪酸、乙醇酰胺、防腐剂和香精组成的洗涤剂;中国专利94107096公开的无毒洗粉,是一种以天然脂肪醇、脂肪酸和其他天然物作表面活性剂,同时采用碳酸钠、硫酸镁、碳酸钙、海泡石、碳酸氢钠等作为助洗剂的洗粉;中国发明专利95108213.2“纯天然洗涤和护肤用品”以黄豆为原料,经过去脏物、去皮、烘干、粉碎和包装,制成粒度小于350目的洗涤和护肤用品。洗涤和护肤效果好,对人体和环境均无害。其洗涤效果不理想,使用为一次性;中国发明专利02803372.8“使用大豆脂肪酸的天然状态的活性可溶性洗涤组合物及其制备方法”公开了一种使用大豆脂肪酸和卵磷脂的活性水溶性天然洗涤剂组合物以及制备该组合物的方法。该方法包括搅动由天然植物脂肪酸、卵磷脂、链烷醇酰胺和有机溶剂例如高级醇或多元醇组成的混合物,皂化混合物以形成能进行布朗运动的微观洗涤剂微粒,依据湿度和pH值控制所得洗涤剂,使所得洗涤剂处于中性或碱性状态。该洗涤组合物包括14~22重量份的大豆脂肪酸,2~4重量份的卵磷脂,6~14重量份的链烷醇酰胺,15重量份的异辛基苯氧基聚氧乙氧基乙醇,42重量份蒸馏水,10重量份对-叔-羟苯氧基聚乙氧基乙醇和3重量份乙二胺四乙酸。其制成物为液体状,属于一次性使用产品,并且添加了大量合成表面活性剂。 In the prior art, there are also some disclosed detergents with natural substances as main components. For example, Chinese patent 91105963 discloses a detergent composition and a manufacturing method thereof, which use camellia cake powder, sodium dodecylbenzenesulfonate, perlite powder, sewage sodium sulfate, etc. as raw materials to make detergent; Chinese patent 91106832 The disclosed tea dry powder detergent is a detergent composed of defatted tea dry powder, fatty acid, ethanolamide, preservatives and essence; the non-toxic washing powder disclosed in Chinese patent 94107096 is a kind of natural fatty alcohol, fatty acid and other natural products as a surfactant, while using sodium carbonate, magnesium sulfate, calcium carbonate, meerschaum, sodium bicarbonate, etc. Dirty, peeled, dried, crushed and packaged to make washing and skin care products with a particle size of less than 350 mesh. It has good washing and skin care effects, and is harmless to human body and environment. Its washing effect is not ideal, and it is disposable; Chinese invention patent 02803372.8 "Active Soluble Cleansing Composition Using Soybean Fatty Acid in Natural State and Preparation Method thereof" discloses an active water-soluble natural detergent using soybean fatty acid and lecithin Compositions and methods of making the compositions. The method involves agitating a mixture of natural vegetable fatty acids, lecithin, alkanolamides, and organic solvents such as higher alcohols or polyols, saponifying the mixture to form microscopic detergent particles capable of Brownian motion, and controlling the resulting Detergent, so that the resulting detergent is in a neutral or alkaline state. The cleaning composition comprises 14-22 parts by weight of soybean fatty acid, 2-4 parts by weight of lecithin, 6-14 parts by weight of alkanolamide, and 15 parts by weight of isooctylphenoxypolyoxyethoxyethanol , 42 parts by weight of distilled water, 10 parts by weight of p-tert-hydroxyphenoxy polyethoxyethanol and 3 parts by weight of ethylenediaminetetraacetic acid. It is made as a liquid, single-use product, and contains a lot of synthetic surfactants. the

目前,餐具、果蔬清洗、洗发、沐浴洗涤剂对人体的安全性正在为人们所广泛认识,全天然的植物餐具、洗发、沐浴洗涤剂正拥有越来越广阔的市场,本发明的全天然植物餐具、洗发、沐浴洗涤剂正是顺应了这一潮流。 At present, the safety of tableware, fruit and vegetable cleaning, shampoo, and bath detergents to the human body is being widely recognized by people, and all-natural plant tableware, hair shampoo, and bath detergents just have a wider and wider market. Natural plant tableware, shampoo, and bath detergents just follow this trend. the

本发明所使用的鳞毛蕨类植物叶子天然植物原料提取液,具有多种生理活性和药理活性,如抗肿瘤、免疫促进、抗凝血、抗溃疡、降血糖、血脂、抗炎、抗疲劳等作用,用于餐具、洗发、沐浴洗涤剂中其作用于人体皮肤有抗菌、杀菌和消炎等功效。 The natural plant raw material extract of the leaves of the phyllodes fern used in the present invention has a variety of physiological activities and pharmacological activities, such as anti-tumor, immune promotion, anti-coagulation, anti-ulcer, hypoglycemic, blood lipid, anti-inflammatory, anti-fatigue It is used in tableware, shampoo, and bath detergent, and it acts on human skin to have antibacterial, bactericidal and anti-inflammatory effects. the

本发明所使用的无患子天然植物提取液,具有无患子皂甙类天然表面活性物质,其可作为天然去污剂,其作用于人体皮肤亦有抗菌、抑菌、杀菌、消炎、润肤和防皮肤老化,改善肌肤暗黄及色斑功效,用于洗涤剂中具有功效,它更含有许多对人体有益的物质,可以改善 化学洗涤剂伤害人体、污染环境的问题。此提取液中含有丰富的对人体有益的物质,如还原糖、脂肪酸、油脂、类胡萝卜素、核黄素及多种氨基酸,还含有蛋白质和多种维生素,其对头发有营养、调理作用。 The Sapindus natural plant extract used in the present invention has natural surface active substances of Sapindus saponins, which can be used as a natural detergent, and it also has antibacterial, antibacterial, bactericidal, anti-inflammatory and moisturizing properties when it acts on human skin. And anti-aging skin, improve the effect of dark yellow and pigmentation of the skin, it is effective when used in detergents, it also contains many substances beneficial to the human body, which can improve the problems of chemical detergents harming the human body and polluting the environment. The extract contains rich substances beneficial to the human body, such as reducing sugar, fatty acid, oil, carotenoid, riboflavin and various amino acids, as well as protein and multivitamins, which have nourishing and conditioning effects on hair. the

蕨类植物又称羊齿植物,属于维管束植物中较古老原始的类群,即既是高等孢子植物,又是原始的维管束植物,是植物界的重要组成部分。全世界约有蕨类植物12000种,多分布于热带、亚热带地区。中国有2600余种,其中可供药用的有48科108属396种。蕨类植物种类繁多、分布广泛、资源丰富,历来为民间所用,有食用、药用、工业、观赏等多种用途。 Ferns, also known as ferns, belong to the older and primitive group of vascular plants, that is, they are both higher spore plants and primitive vascular plants, and are an important part of the plant kingdom. There are about 12,000 species of ferns in the world, mostly distributed in tropical and subtropical regions. There are more than 2,600 species in China, of which 396 species in 48 families, 108 genera, are available for medicinal use. There are many kinds of ferns, which are widely distributed and rich in resources. They have always been used by the people, and have various uses such as food, medicine, industry, and ornamental. the

在中国,公元前6世纪《诗经》中就有“于以采苹、南涧之淀”的记载;公元2世纪《神农百草经》称石韦具有“治五癃闭不通、利小便水道”的利尿记载;11世纪中期《嘉佑本草》称木贼Equisetum hiemale无毒治目疾。明朝李时珍巨著《本草纲目》记载“苹甘寒、无毒、下水气、利小便、止消渴”,由此可以看出,蕨类植物在中国的药用历史悠久。历年来,蕨类植物被民间用来治疗各种疾病。已有研究表明,蕨类植物多糖复合物具有多种生理活性和药理活性,如抗肿瘤、免疫促进、抗凝血、抗溃疡、降血糖、血脂、抗炎抗疲劳等作用。 In China, in the "Book of Songs" in the 6th century BC, there is a record of "Yiyi picking apples and the lake of Nanjian"; in the 2nd century AD, "Shen Nong Baicao Jing" stated that Shi Wei has the ability to "cure five infirmities and blockages, and facilitate urination and water passages" "Jiayou Materia Medica" in the middle of the 11th century stated that Equisetum hiemale is non-toxic and treats eye diseases. Li Shizhen's masterpiece "Compendium of Materia Medica" in the Ming Dynasty records that "apple is sweet and cold, non-toxic, releases moisture, facilitates urination, and relieves thirst." From this, it can be seen that ferns have a long history of medicinal use in China. Ferns have been used folklore to treat various ailments over the years. Studies have shown that the fern polysaccharide complex has various physiological and pharmacological activities, such as anti-tumor, immune promotion, anti-coagulation, anti-ulcer, hypoglycemic, blood lipid, anti-inflammatory and anti-fatigue effects. the

对蕨类植物的化学成分进行研究,发现其成分复杂,其中具有生物活性的成分主要有酚类化合物,如苯丙素酚类的氯原酸、咖啡酸、阿魏酸等。二原酚有氯元酸、咖啡酸等,均有抗菌、止血、利尿的功效。三元酚类有绵马酸类和绵马素等,是有效的驱虫成分。同时还含有黄酮类、生物碱和三帖类化合物。丁酰基间苯三酚衍生物常存在于鳞毛蕨属植物中,石韦属植物含有山酮类化合物,骨碎补含有橙皮甙及柑桔甙。生物碱类广泛存在于小叶型蕨类中,如石松属中含石松碱、石松毒碱等。甾体及三萜类化合物,如蛇足石松含千层塔醇、托何宁醇,紫萁含有昆虫蜕皮激索。此外,蕨类植物中尚含有鞣质、多种氨基酸、脂肪酸,蕨菜内含有15种氨基酸,总量为136g/100g。其中人体必需氨基酸有7种,脂肪酸15种,以亚油酸为主,其次为棕榈酸、山嵛酸、亚麻酸、油酸,剩余的量微元素,其饱和脂肪酸含量略高于不饱和脂肪酸。由此可知:蕨类植物内含有的大量有机化合物具有特殊的药用功效,还有许多药用蕨类植物的化学成分还有待于进一步分析研究。 The research on the chemical composition of fern found that its composition is complex, and the main biologically active components are phenolic compounds, such as chlorogenic acid, caffeic acid and ferulic acid of phenylpropanoid phenols. Diphenols include chlorogenic acid, caffeic acid, etc., all of which have antibacterial, hemostatic, and diuretic effects. Trihydric phenols include maric acid and maricin, etc., which are effective insect repellent ingredients. At the same time, it also contains flavonoids, alkaloids and three compounds. Butyrylphloroglucinol derivatives are often found in the genus Phloroglucinol, plants of the genus Shiwei contain xanone compounds, and Rhizoma Drynaria contains hesperidin and citrus glycosides. Alkaloids widely exist in small-leaved ferns, such as lycoperus and lycopoxin in Lycopodium. Steroids and triterpenoids, such as Serpentipus pine contain melaleuca alcohol, to He Ning alcohol, Osmunda contains insect molting hormone. In addition, ferns still contain tannins, various amino acids, and fatty acids, and bracken contains 15 kinds of amino acids, with a total amount of 136g/100g. Among them, there are 7 kinds of essential amino acids and 15 kinds of fatty acids, mainly linoleic acid, followed by palmitic acid, behenic acid, linolenic acid, oleic acid, and the remaining amount of trace elements. The content of saturated fatty acids is slightly higher than that of unsaturated fatty acids . It can be seen from this that a large number of organic compounds contained in ferns have special medicinal effects, and the chemical components of many medicinal ferns have yet to be further analyzed and studied. the

蕨类植物和人类的关系非常密切,除形成了煤炭的古代蕨类植物为人类提供大量能源外,现存的蕨类植物除热带树蕨外,大多数是生于山区的多年生草本,在经济上有多种用途。 The relationship between ferns and human beings is very close. Except for the ancient ferns that formed coal to provide a large amount of energy for human beings, most of the existing ferns except tropical tree ferns are perennial herbs born in mountainous areas. There are many uses. the

蕨类植物在工业上的用途越来越广泛。如石松中含有石松碱等多种化学成分,可提供蓝色染料。其孢子含油量约40%,为不干性油,是铸造工业的优良脱模剂。将孢子撒在机器铸件模具的壁上,可以防止铸液沾附在模子的壁上,可使铸件的表面光滑,减少砂眼。作为闪光剂,能用于火箭、信号弹、照明弹等,还可作丸药的包衣。其主茎铺地蔓生可长达数米,是制作各种编织品的优质材料。木贼作为引起突然起火的燃料,含硅质很多,可代替砂皮摩擦木器和金属器械,是极好的磨光剂。凤尾蕨类的叶柄,根状茎中的纤维可制绳缆,耐水湿,用于造纸,可做纸浆板,人造棉及人造纤维板。它加工制成的淀粉,可用于浆纱或浆布,也可酿酒或提取酒精。全株含鞣质,可提取栲胶,而栲胶是具有广泛用途的原料。鳞毛蕨属的一些种含有儿茶酚类的单宁物质,可提取鞣质加工皮革。三叉蕨科中的绵马羊齿也含有丰富的单宁。此外,乌蕨可做红色染料。蕨菜的叶片可做绿色染料,它的根茎可做土黄色染料。 Ferns are increasingly used industrially. For example, lycopodium contains various chemical components such as lycopine, which can provide blue dyes. Its spore oil content is about 40%, which is a non-drying oil and is an excellent mold release agent in the foundry industry. Sprinkling the spores on the wall of the machine casting mold can prevent the casting liquid from adhering to the wall of the mold, smooth the surface of the casting and reduce sand holes. As a flash agent, it can be used in rockets, signal flares, flares, etc., and can also be used as a coating for pills. Its main stem spreads over the ground and can be as long as several meters. It is a high-quality material for making various woven products. As a fuel for sudden fire, horsetail contains a lot of silicon, which can replace sandy skins to rub wood and metal instruments, and is an excellent polishing agent. The petiole of Pteris fern and the fiber in the rhizome can be used to make ropes, which are resistant to water and humidity, and can be used for papermaking, pulp board, artificial cotton and artificial fiber board. It is processed into starch, which can be used for sizing or sizing cloth, and can also be used for brewing or extracting alcohol. The whole plant contains tannins, which can be used to extract tannins, which are widely used raw materials. Some species of Trichofern contain catechol-like tannins, which can be used to extract tannins for processing leather. The sheep's fern in the Tridentaceae family is also rich in tannins. In addition, black fern can be used as red dye. The leaves of fern can be used as green dye, and its rhizome can be used as khaki dye. the

无患子属无患子科(Sapindaceae),学名:无患子(Sapindus mukurossi Gaertn),俗称油患子、肥珠子等,也叫肥皂树或洗手果,为无患子科无患子属的一种落叶乔木,在东南亚各国、我国的台湾省及淮河以南各省均有分布. Sapindaceae belongs to Sapindaceae (Sapindaceae), scientific name: Sapindus mukurossi Gaertn, commonly known as Sapindus mukurossi Gaertn, commonly known as oil Sapindus, fat beads, etc. A deciduous tree, distributed in Southeast Asian countries, Taiwan Province of my country and the provinces south of the Huaihe River. 

无患子含有许多对人体有益的物质,如还原糖、脂肪酸、油脂、油酸、雷胡萝卜素、箊酸、核黄素、蛋白质、维生素C、维生素E、维生素B及赖氨酸、苯丙氨酸、谷氨酸、甘氨酸和组氨酸等10多种氨基酸,其中丰富的糖苷类物质,主要为三萜皂苷类和半萜糖苷类,具有很强的表面活性作用,对于人体皮肤有抗菌、杀菌和消炎功效,为天然的非离子型表面活性剂。无患子的假种皮中富含皂苷等三萜皂苷,具有良好的起泡性和去污性能,可作为天然活性物质用于洗发香波及各种洁肤护肤化妆品中;它还具有抗菌和止痒等生理功效,可用于脚 癣和轮癣的治疗;其可制造“天然无公害洗涤剂”,用于日常洗涤衣物。洗涤效果很好,能有效去除污渍,富含丰富的泡沫,可以杀菌;还能美化皮肤,还具有美白、祛斑治痘功效,能有效预防和治疗皮肤疾病;无患子皂苷还是很好的农药乳化剂,对棉蚜虫、红蜘蛛和甘薯金华虫等均有较好的杀灭效果。药理研究表明,无患子果皮所含皂苷成分具有抗皮肤真菌和念珠菌作用、抑制肿瘤细胞增殖、抗幽门螺旋杆菌活性、保肝作用等多种生物活性。由于无患子含有高含量的天然温和型非离子表面活性物质,去污、洗涤性能很好,且同时含有大量的天然营养调理物质,对人体无刺激,是理想的天然表面活性剂。因其纯天然,100%可降解,长期使用对于人体和环境均无危害。 Sapinberry contains many substances that are beneficial to the human body, such as reducing sugar, fatty acid, oil, oleic acid, ray carotene, keratin, riboflavin, protein, vitamin C, vitamin E, vitamin B and lysine, phenylpropanoid Amino acid, glutamic acid, glycine and histidine and other more than 10 kinds of amino acids, among which the rich glycosides are mainly triterpene saponins and semiterpene glycosides, which have strong surface activity and are antibacterial to human skin. , Bactericidal and anti-inflammatory effects, it is a natural non-ionic surfactant. Sapindus aril is rich in saponins and other triterpene saponins, which have good foaming and decontamination properties, and can be used as natural active substances in shampoos and various skin cleansing and skin care cosmetics; it also has antibacterial properties It can be used for the treatment of athlete's foot and ringworm; it can make "natural pollution-free detergent" for daily washing of clothes. The washing effect is very good, it can effectively remove stains, it is rich in rich foam, and can sterilize; it can also beautify the skin, and it also has the effects of whitening, removing spots and acne, and can effectively prevent and treat skin diseases; Sapindus saponin is also a good pesticide It is an emulsifier, and has a good killing effect on cotton aphids, spider mites and sweet potato worms. Pharmacological studies have shown that the saponins contained in the peel of Sapindus chinensis have various biological activities such as anti-dermatophyte and candida, inhibition of tumor cell proliferation, anti-Helicobacter pylori activity, and liver protection. Because Sapindus contains high content of natural mild non-ionic surface active substances, it has good decontamination and washing performance, and at the same time contains a large amount of natural nutritional conditioning substances, which is non-irritating to the human body, so it is an ideal natural surface active agent. Because it is pure natural and 100% degradable, long-term use is harmless to human body and environment. the

明代杰出医药学家李时珍说:山人呼为肥珠子,油珠子,因其肥如油圆如珠也。”无患子俗称。肥皂荚,较皂荚有更好的去污效果。《鸡肋篇》中记载:浙中少皂荚,澡面.浣衣皆用肥珠子。木亦高大,叶如槐而细,生角长者不过三数寸,子圆黑肥大,肉亦厚,膏润于皂荚,故一名肥皂。肥皂之名由此而来。随着科学的发展,化学清洗剂的出现,如今的肥皂基本上巳没有肥皂荚这类天然植物的成份了。当今的环境污染,促使人们提出回归大自然的要求,应充分利用大自然产物,以减少污染,保护人类环境巳具有重要意义。 Li Shizhen, an outstanding medical scientist in the Ming Dynasty, said: "Shan people call it fat beads and oil beads, because they are as fat as oil and round as beads." "Soap locust is commonly known as soap locust, which has better decontamination effect than acacia locust. It is recorded in "Chicken Ribs": there are few acacia locusts in Zhejiang, and fat beads are used for bathing noodles and clothes. The wood is also tall, and the leaves are as thin as pagoda tree , the horns are only three inches long, the seeds are round and black, and the flesh is thick. The soap basically does not have the ingredients of natural plants such as soap pods. Today's environmental pollution has prompted people to ask for a return to nature. It is of great significance to make full use of natural products to reduce pollution and protect the human environment. 

无患子树在我国13个省、自治区均有分布,资源广。经研究认为,无患子提取液中的长青藤皂甙元上有-COOR1或-COOH基团,-COOR1可以水解生成-COOH,铅等重金属和-COOH生成Pb(COO)2等而被洗脱;还有皂甙和芸香甙上有大量的羟基(-OH),铅等重金属可能与羟基(-OH)形成络合物、螯合物而被带走;另外,皂甙有类似肥皂样净化作用,类似于表面活性剂性能。 Sapindus is distributed in 13 provinces and autonomous regions in my country, and has a wide range of resources. According to research, there is a -COOR1 or -COOH group on the ivy genin in the extract of Sapindus chinensis, and -COOR1 can be hydrolyzed to form -COOH, and heavy metals such as lead and -COOH can form Pb(COO) 2 , etc. and be washed. There are also a large number of hydroxyl groups (-OH) on saponins and rutin, and heavy metals such as lead may form complexes and chelates with hydroxyl groups (-OH) and be taken away; in addition, saponins have a soap-like purification effect , similar to the properties of surfactants.

无患子又名菩提子,是新发现的植物中最具活性和洗涤效果的天然界面活性剂及天然洗涤原料。现在已引起世界各地美容化妆品生产厂商的关注,市场前景可观。无患子适合中国南方丘陵山区及庭院种植,在巨大潜在市场的鼓舞下,无患子种植基地发展很快,据不完全统计,无患子的种植面积已超过10万亩,几年以后可产无患子果实达10万吨,但目前国内外尚无无患子皂苷规模生产的成熟工艺及生产设备。 Sapindus, also known as bodhi seed, is the most active and cleansing natural surfactant and natural cleansing raw material among newly discovered plants. Now it has attracted the attention of beauty cosmetics manufacturers all over the world, and the market prospect is promising. Sapindus is suitable for planting in hilly areas and gardens in southern China. Encouraged by the huge potential market, the planting base of Sapindus has developed rapidly. According to incomplete statistics, the planting area of Sapindus has exceeded 100,000 mu. The production of Sapindus fruit reaches 100,000 tons, but there is no mature technology and production equipment for large-scale production of Sapindus saponin at home and abroad. the

本发明添加使用的EDTA是一种络合剂,同时又作为一种防腐剂,也可以起到对铅等重金属的高效抑制与洗脱作用。 The EDTA added and used in the present invention is a complexing agent, and at the same time as a preservative, it can also effectively inhibit and elute heavy metals such as lead. the

发明内容:Invention content:

1、一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,其特征在于包括以下步骤: 1, the preparation and method thereof of a kind of hair fern, Sapindus chinensis natural biomass detergent, it is characterized in that comprising the following steps:

第一步,林木植物品种的选择:鳞毛蕨叶子、无患子植物果实。 The first step is the selection of forest plant species: leaves of Phalaenopsis phylloxera, fruits of Sapindus. the

第二步,一种鳞毛蕨、无患子天然生物质洗涤剂含有鳞毛蕨生物质提取物、无患子生物质提取物。其可以是液状产品,也可以是粉状产品。 In the second step, a natural biomass detergent of Phytophthora edulis and Sapindus chinensis contains Phytophthora spp. biomass extract and Sapindia sativa biomass extract. It can be a liquid product or a powdered product. the

第三步,鳞毛蕨生物质提取液或粉的制备 The third step, the preparation of the dry fern biomass extract or powder

称取鳞毛蕨鲜叶切碎、打浆或干化叶粉碎,鳞毛蕨原料可以经过高粉碎比物料粉碎,进行备料。 Weigh the fresh leaves of Dermatophyllum and chop them up, beat or crush the dried leaves, and the raw materials of Dermastridioides can be prepared by crushing materials with a high crushing ratio. the

备好的鳞毛蕨打浆料或粉碎料放入提取灌,加入去离子水,进行三罐三步逆流提取,固液比控制在1∶5~10,浸提温度80~95℃,浸提时间控制在1.0~2.0小时。浸提完后进行浸提料液的压滤或离心卸料分离操作,得到的头部浸提液进行减压或加压或微孔过滤净化处理,滤去部分不溶物和浸提物料残渣即得到鳞毛蕨浸提净化液。 Put the prepared Dichofern beating material or crushed material into the extraction tank, add deionized water, and carry out three-pot three-step countercurrent extraction. The solid-liquid ratio is controlled at 1:5-10, and the extraction temperature is 80-95°C. Lifting time is controlled at 1.0-2.0 hours. After leaching, press filter or centrifuge unloading and separation operation of the leaching material liquid, and decompress or pressurize the obtained head leaching liquid or perform microporous filtration purification treatment to filter out part of the insoluble matter and leaching material residue. To obtain the extract and purification solution of Drichoptera. the

鳞毛蕨浸提净化液进行真空浓缩蒸出多余的水,60~65℃真空减压浓缩至原体积的1/2~1/5,,得到鳞毛蕨净化浓缩液,即使鳞毛蕨提取物。鳞毛蕨叶子提取净化浓缩液要求固体含量20~35%。 The extract and purification solution of Trichofern is vacuum-concentrated and steamed to remove excess water, and concentrated under reduced pressure at 60-65°C to 1/2-1/5 of the original volume to obtain the purified concentrated solution of Trichofern, even if the Trichofern extract thing. The concentrated liquid extracted and purified from the leaves of Trichofern requires a solid content of 20-35%. the

可以将浓缩的鳞毛蕨浓缩液用高压蒸汽灭菌罐在120℃条件下灭菌15min,备用。 The concentrated Drichoptera concentrated solution can be sterilized at 120° C. for 15 minutes in a high-pressure steam sterilizing tank, and it is ready for use. the

鳞毛蕨提取净化浓缩液也可以进行压力喷雾或离心喷雾干燥,进一步制成粉状鳞毛蕨提取物。压力喷雾或离心喷雾干燥进气温度可以控制在110~250℃,排气温度65~90℃。 The concentrated solution of Trichofern extract and purification can also be subjected to pressure spray or centrifugal spray drying to further produce powdered Trichofern extract. The inlet temperature of pressure spray or centrifugal spray drying can be controlled at 110-250°C, and the exhaust temperature is 65-90°C. the

第四步,无患子生物质提取液或粉的制备 The fourth step, preparation of Sapindus sapindus biomass extract or powder

称取新鲜的无患子果实,添2倍去离子水打浆粉碎,制取无患子打浆液。或将采集的无患子日晒或用烘干机干燥(60~65℃)至气干恒重。气干至恒重的无患子干果进行肉核分离操作,被分离出的皮肉可以经过高粉碎比物料粉碎,进行备料。 Weigh the fresh fruit of Sapindus chinensis, add 2 times of deionized water to beat and pulverize it, and prepare the Sapindia chinensis beating liquid. Or dry the collected Sapindus chinensis in the sun or with a dryer (60-65° C.) until air-dried to constant weight. The dried fruit of Sapindus chinensis, which has been air-dried to constant weight, is subjected to the flesh core separation operation, and the separated skin and flesh can be crushed by materials with a high crushing ratio for raw material preparation. the

将制备好的无患子打浆液打入提取灌,补加去离子水至固液比在1∶5~10的范围内;或将制备好的无患子粉碎料加入提取灌中,加去离子水至固液比控制在1∶5~10的范围内,进行三罐三步逆流提取,浸提温度80~102℃,浸提时间控制在1.0~2.0小时。浸提完后进行浸提料液的压滤或离心卸料分离操作,得到的头部浸提液进行减压或加压或微孔过滤净化处理,滤去部分不溶物和浸提物料残渣即得到无患子浸提净化液。 Pour the prepared Sapindus slurries into the extraction tank, add deionized water until the solid-liquid ratio is in the range of 1:5-10; The solid-liquid ratio of ionized water is controlled within the range of 1:5-10, and three tanks and three-step countercurrent extraction are carried out, the extraction temperature is 80-102°C, and the extraction time is controlled at 1.0-2.0 hours. After leaching, press filter or centrifuge unloading and separation operation of the leaching material liquid, and decompress or pressurize the obtained head leaching liquid or perform microporous filtration purification treatment to filter out part of the insoluble matter and leaching material residue. Obtain Sapindus leaching and purifying solution. the

无患子浸提净化液进行真空浓缩蒸出多余的水,60℃~65℃减压浓缩至原体积的1/2~1/5,,得到无患子净化浓缩液,即使无患子提取物。无患子提取净化浓缩液要求固体含量20~35%。 Extract and purify the solution of Sapindus chinensis by vacuum concentration and steaming to remove excess water, and concentrate under reduced pressure at 60°C to 65°C to 1/2 to 1/5 of the original volume to obtain the Sapindia chinensis purification concentrate, even if the Sapindia chinensis is extracted things. The extract and purification concentrate of Sapindus chinensis requires a solid content of 20-35%. the

无患子提取净化浓缩液为无味微黄,接近透明的粘性液体。可以将浓缩的鳞毛蕨浓缩液用高压蒸汽灭菌罐在120℃条件下灭菌10~15min,备用。 The extract and purification concentrate of Sapindus chinensis is an odorless light yellow, almost transparent viscous liquid. The concentrated Drichoptera concentrated solution can be sterilized at 120° C. for 10 to 15 minutes in a high-pressure steam sterilizing tank, and it is ready for use. the

无患子提取净化浓缩液也可以进行压力喷雾或离心喷雾干燥,进一步制成粉状无患子提取物。压力喷雾或离心喷雾干燥进气温度可以控制在115~250℃,排气温度65~90℃。 The extract and purification concentrate of Sapindus chinensis can also be subjected to pressure spraying or centrifugal spray drying, and further made into powdered Sapindus chinensis extract. The inlet temperature of pressure spray or centrifugal spray drying can be controlled at 115-250°C, and the exhaust temperature is 65-90°C. the

第五步,按一定配比制备出液状或粉状鳞毛蕨、无患子天然生物质洗涤剂,其配方组成如下: The fifth step is to prepare a liquid or powdery natural biomass detergent of Trichophyllum chinensis and Sapindus chinensis according to a certain proportion, and its formula composition is as follows:

液状产品:无患子果肉提取液,固体含量20~35%,用量30~80%;鳞毛蕨科植物叶子提取液,固体含量20~35%,用量10~40%;去离子水:余量。 Liquid products: Sapindus fruit pulp extract, solid content 20-35%, dosage 30-80%; Lepidoptera plant leaf extract, solid content 20-35%, dosage 10-40%; deionized water: remaining quantity. the

按上述配比分别称取无患子提取净化浓缩液、鳞毛蕨提取净化浓缩液,并打入搅拌容器中,补加一定量的去离子水,并加入适量的植物助剂与天然香精,搅拌均匀后,检测出料、装瓶。 According to the above proportions, weigh the extract and purification concentrate of Sapindus chinensis and the extract and purification concentrate of Trichofernium, put them into a stirring container, add a certain amount of deionized water, and add an appropriate amount of plant additives and natural flavors, After stirring evenly, the material is detected and bottled. the

去离子水质量要求符合国家标准GB6682-2000。 The quality requirements of deionized water meet the national standard GB6682-2000. the

粉状产品:无患子果肉提取物,固体含量90~95%,用量20~75%;鳞毛蕨科植物叶子提取物,固体含量90~95%,用量20~50%。 Powder products: Sapindus fruit pulp extract, with a solid content of 90-95%, and a dosage of 20-75%; the leaf extract of Phryllopaceae plants, with a solid content of 90-95%, and a dosage of 20-50%. the

按上述配比分别称取无患子提取净化浓缩物、鳞毛蕨提取净化浓缩物,加入适量的植物助剂与天然香精,混合搅拌均匀后,检测出料、包装。 According to the above proportions, weigh the extract and purification concentrate of Sapindus chinensis and the extract and purification concentrate of Trichofernium, add an appropriate amount of plant additives and natural essence, mix and stir evenly, and then test the material and pack it. the

附图说明:Description of drawings:

图1是本发明实施例的流程图。 Fig. 1 is a flowchart of an embodiment of the present invention. the

具体实施方式:Detailed ways:

实施例1: Example 1:

分别取新鲜鳞毛蕨叶子、新鲜无患子果实各5公斤,各加水20公斤煮沸、过滤、精制,滤液分别经浓缩至10公斤,再放置过夜过滤。然后分别取以上鳞毛蕨、无患子水提取液20份、40份,EDTA 4份、去离子水36份,再加入适量的香料并搅拌均匀即得到本发明的鳞毛蕨、无患子生物质液状洗涤剂产品。 Take 5 kg each of fresh Leptochondritis leaves and 5 kg of fresh Sapindus sativa fruits, add 20 kg of water to each, boil, filter, and refine, and the filtrates are concentrated to 10 kg, and then placed overnight for filtration. Then get respectively 20 parts, 40 parts of above Phytophthora edulis, 20 parts, 40 parts, 4 parts of EDTA, 36 parts of deionized waters, add appropriate spices and stir again and promptly obtain Phytophthora, Sapindus of the present invention Biomass liquid detergent products. the

实施例2: Example 2:

分别取气干鳞毛蕨叶子、新鲜气干无患子果实各5公斤,各加水30公斤煮沸、过滤、精制,滤液分别经浓缩至10公斤,再放置过夜过滤。然后分别取以上鳞毛蕨、无患子水提取液30份、30份,EDTA 4份、去离子水36份,再加入适量的香料并搅拌均匀即得到本发明的鳞毛蕨、无患子生物质液状洗涤剂产品。 Take 5 kg each of air-dried Leptochordina chinensis leaves and 5 kg of fresh air-dried Sapindus sativa fruits, add 30 kg of water to each, boil, filter, and refine. Then get respectively 30 parts, 30 parts of above Phytophthora edulis, 30 parts of water extracts of Sapindus chinensis, 4 parts of EDTA, 36 parts of deionized water, then add an appropriate amount of spices and stir to obtain Phytophthora phylloxera of the present invention, Sapindia chinensis Biomass liquid detergent products. the

实施例3。 Example 3. the

Claims (6)

1.一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,其特征在于包括以下步骤:1. preparation and method thereof of a kind of hair fern, Sapindus chinensis natural biomass detergent, it is characterized in that comprising the following steps: 第一步,林木植物品种的选择:鳞毛蕨叶子、无患子植物果实。The first step is the selection of forest plant species: leaves of Phalaenopsis phylloxera, fruits of Sapindus. 第二步,一种鳞毛蕨、无患子天然生物质洗涤剂含有鳞毛蕨生物质提取物、无患子生物质提取物。其可以是液状产品,也可以是粉状产品。In the second step, a natural biomass detergent of Phytophthora edulis and Sapindus chinensis contains Phytophthora spp. biomass extract and Sapindia sativa biomass extract. It can be a liquid product or a powdered product. 第三步,鳞毛蕨生物质提取液或粉的制备The third step, the preparation of the dry fern biomass extract or powder 称取鳞毛蕨鲜叶切碎、打浆或干化叶粉碎,鳞毛蕨原料可以经过高粉碎比物料粉碎,进行备料。Weigh the fresh leaves of Dermatophyllum and chop them up, beat or crush the dried leaves, and the raw materials of Dermastridioides can be prepared by crushing materials with a high crushing ratio. 备好的鳞毛蕨打浆料或粉碎料放入提取灌,加入去离子水,进行三罐三步逆流提取,固液比控制在1∶5~10,浸提温度80~95℃,浸提时间控制在1.0~2.0小时。浸提完后进行浸提料液的压滤或离心卸料分离操作,得到的头部浸提液进行减压或加压或微孔过滤净化处理,滤去部分不溶物和浸提物料残渣即得到鳞毛蕨浸提净化液。Put the prepared Dichofern beating material or crushed material into the extraction tank, add deionized water, and carry out three-pot three-step countercurrent extraction. The solid-liquid ratio is controlled at 1:5-10, and the extraction temperature is 80-95°C. Lifting time is controlled at 1.0-2.0 hours. After leaching, press filter or centrifuge unloading and separation operation of the leaching material liquid, and decompress or pressurize the obtained head leaching liquid or perform microporous filtration purification treatment to filter out part of the insoluble matter and leaching material residue. To obtain the extract and purification solution of Drichoptera. 鳞毛蕨浸提净化液进行真空浓缩蒸出多余的水,60℃~65℃真空减压浓缩至原体积的1/2~1/5,得到鳞毛蕨净化浓缩液,即使鳞毛蕨提取物。鳞毛蕨叶子提取净化浓缩液要求固体含量20~35%。The extract and purification solution of Trichofern is vacuum-concentrated and steamed to remove excess water, and concentrated under reduced pressure at 60°C to 65°C to 1/2 to 1/5 of the original volume to obtain the concentrated liquid of Trichofern, even if the extract of Trichofern things. The concentrated liquid extracted and purified from the leaves of Trichofern requires a solid content of 20-35%. 可以将浓缩的鳞毛蕨浓缩液用高压蒸汽灭菌罐在120℃条件下灭菌15min,备用。The concentrated Drichoptera concentrated solution can be sterilized at 120° C. for 15 minutes in a high-pressure steam sterilizing tank, and it is ready for use. 鳞毛蕨提取净化浓缩液也可以进行压力喷雾或离心喷雾干燥,进一步制成粉状鳞毛蕨提取物。压力喷雾或离心喷雾干燥进气温度可以控制在110~250℃,排气温度65~90℃。The concentrated solution of Trichofern extract and purification can also be subjected to pressure spray or centrifugal spray drying to further produce powdered Trichofern extract. The inlet temperature of pressure spray or centrifugal spray drying can be controlled at 110-250°C, and the exhaust temperature is 65-90°C. 第四步,无患子生物质提取液或粉的制备The fourth step, preparation of Sapindus sapindus biomass extract or powder 称取新鲜的无患子果实,加2倍去离子水打浆粉碎,制取无患子打浆液。或将采集的无患子日晒或用烘干机干燥(60~65℃)至气干恒重。气干至恒重的无患子干果进行肉核分离操作,被分离出的皮肉可以经过高粉碎比物料粉碎,进行备料。Weigh the fresh fruit of Sapindus chinensis, add 2 times of deionized water to beat and pulverize, and prepare the Sapindia chinensis beating liquid. Or dry the collected Sapindus chinensis in the sun or with a dryer (60-65° C.) until air-dried to constant weight. The dried fruit of Sapindus chinensis, which has been air-dried to constant weight, is subjected to the flesh core separation operation, and the separated skin and flesh can be crushed by materials with a high crushing ratio for raw material preparation. 将制备好的无患子打浆液打入提取灌,补加去离子水至固液比在1∶5~10的范围内;或将制备好的无患子粉碎料加入提取灌中,加去离子水至固液比控制在1∶5~10的范围内,进行三罐三步逆流提取,浸提温度80~102℃,浸提时间控制在1.0~2.0小时。浸提完后进行浸提料液的压滤或离心卸料分离操作,得到的头部浸提液进行减压或加压或微孔过滤净化处理,滤去部分不溶物和浸提物料残渣即得到无患子浸提净化液。Pour the prepared Sapindus slurries into the extraction tank, add deionized water until the solid-liquid ratio is in the range of 1:5-10; The solid-liquid ratio of ionized water is controlled within the range of 1:5-10, and three tanks and three-step countercurrent extraction are carried out, the extraction temperature is 80-102°C, and the extraction time is controlled at 1.0-2.0 hours. After leaching, press filter or centrifuge unloading and separation operation of the leaching material liquid, and decompress or pressurize the obtained head leaching liquid or perform microporous filtration purification treatment to filter out part of the insoluble matter and leaching material residue. Obtain Sapindus leaching and purifying solution. 无患子浸提净化液进行真空浓缩蒸出多余的水,60℃~65℃减压浓缩至原体积的1/2~1/5,得到无患子净化浓缩液,即使无患子提取物。无患子提取净化浓缩液要求固体含量20~35%。The extract and purification solution of Sapindus chinensis is vacuum-concentrated to evaporate excess water, concentrated under reduced pressure at 60°C to 65°C to 1/2 to 1/5 of the original volume, and the purified solution of Sapindia chinensis is obtained, even if the Sapindia chinensis extract . The extract and purification concentrate of Sapindus chinensis requires a solid content of 20-35%. 无患子提取净化浓缩液为无味微黄,接近透明的粘性液体。可以将浓缩的鳞毛蕨浓缩液用高压蒸汽灭菌罐在120℃条件下灭菌10~15min,备用。The extract and purification concentrate of Sapindus chinensis is an odorless light yellow, almost transparent viscous liquid. The concentrated Drichoptera concentrated solution can be sterilized at 120° C. for 10 to 15 minutes in a high-pressure steam sterilizing tank, and it is ready for use. 无患子提取净化浓缩液也可以进行压力喷雾或离心喷雾干燥,进一步制成粉状无患子提取物。压力喷雾或离心喷雾干燥进气温度可以控制在115~250℃,排气温度65~90℃。The extract and purification concentrate of Sapindus chinensis can also be subjected to pressure spraying or centrifugal spray drying, and further made into powdered Sapindus chinensis extract. The inlet temperature of pressure spray or centrifugal spray drying can be controlled at 115-250°C, and the exhaust temperature is 65-90°C. 第五步,按一定配比制备出液状或粉状鳞毛蕨、无患子天然生物质洗涤剂,其配方组成如下:The fifth step is to prepare a liquid or powdery natural biomass detergent for Trichophyllum chinensis and Sapindus chinensis according to a certain proportion, and its formula composition is as follows: 液状产品:无患子果肉提取液,固体含量20~35%,用量30~80%;鳞毛蕨科植物叶子提取液,固体含量20~35%,用量10~40%;去离子水:余量。按上述配比分别称取无患子提取净化浓缩液、鳞毛蕨提取净化浓缩液,并打入搅拌容器中,补加一定量的去离子水,并加入适量的植物助剂与天然香精,搅拌均匀后,检测出料、装瓶。去离子水质量要求符合国家标准GB6682-2000。Liquid products: Sapindus fruit pulp extract, solid content 20-35%, dosage 30-80%; Lepidoptera plant leaf extract, solid content 20-35%, dosage 10-40%; deionized water: remaining quantity. According to the above proportions, weigh the extract and purification concentrate of Sapindus chinensis and the extract and purification concentrate of Trichofernium, put them into a stirring container, add a certain amount of deionized water, and add an appropriate amount of plant additives and natural flavors, After stirring evenly, the material is detected and bottled. The quality requirements of deionized water meet the national standard GB6682-2000. 粉状产品:无患子果肉提取物,固体含量90~95%,用量20~75%;鳞毛蕨科植物叶子提取物,固体含量90~95%,用量20~50%。按上述配比分别称取无患子提取净化浓缩物、鳞毛蕨提取净化浓缩物,加入适量的植物助剂与天然香精,混合搅拌均匀后,检测出料、包装。Powder products: Sapindus fruit pulp extract, with a solid content of 90-95%, and a dosage of 20-75%; the leaf extract of Phryllopaceae plants, with a solid content of 90-95%, and a dosage of 20-50%. According to the above proportions, weigh the extract and purification concentrate of Sapindus chinensis and the extract and purification concentrate of Trichofernium, add an appropriate amount of plant additives and natural essence, mix and stir evenly, and then test the material and pack it. 2.根据权利要求1所述的一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,其特征在于其林木植物品种的选择:鳞毛蕨叶子、无患子植物果实。2. the preparation and method thereof of a kind of Phytophthora edulis according to claim 1, Sapindus natural biomass detergent, it is characterized in that the selection of its forestry plant species: Phytophthora leaf, Sapindantia fruit. 3.根据权利要求1所述的一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,其特征在于该鳞毛蕨、无患子天然生物质洗涤剂含有鳞毛蕨生物质提取物、无患子生物质提取物,其可以是液状产品,也可以是粉状产品。3. the preparation and method thereof of a kind of Phytophthora chinensis according to claim 1, Sapindus chinensis natural biomass detergent, it is characterized in that this Phytophthora sphaericus, Sapindia chinensis natural biomass detergent contain Phylophagalis biomass The extract, the Sapindus sapindus biomass extract, can be a liquid product or a powder product. 4.根据权利要求1所述的一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,其特征在于鳞毛蕨生物质提取液或粉的制备方法:4. the preparation and method thereof of a kind of Phytophthora edulis according to claim 1, natural biomass detergent of Sapindus chinensis, is characterized in that the preparation method of Phytophthora edulis biomass extract or powder: 称取鳞毛蕨鲜叶切碎、打浆或干化叶粉碎,鳞毛蕨原料可以经过高粉碎比物料粉碎,进行备料。Weigh the fresh leaves of Dermatophyllum and chop them up, beat or crush the dried leaves, and the raw materials of Dermastridioides can be prepared by crushing materials with a high crushing ratio. 备好的鳞毛蕨打浆料或粉碎料放入提取灌,加入去离子水,进行三罐三步逆流提取,固液比控制在1∶5~10,浸提温度80-95℃,浸提时间控制在1.0~2.0小时。浸提完后进行浸提料液的压滤或离心卸料分离操作,得到的头部浸提液进行减压或加压或微孔过滤净化处理,滤去部分不溶物和浸提物料残渣即得到鳞毛蕨浸提净化液。Put the prepared Trichofern beating material or crushed material into the extraction tank, add deionized water, and carry out three-pot three-step countercurrent extraction. The solid-liquid ratio is controlled at 1:5-10, and the extraction temperature is 80-95 ° C. Lifting time is controlled at 1.0-2.0 hours. After leaching, press filter or centrifuge unloading and separation operation of the leaching material liquid, and decompress or pressurize the obtained head leaching liquid or perform microporous filtration purification treatment to filter out part of the insoluble matter and leaching material residue. To obtain the extract and purification solution of Drichoptera. 鳞毛蕨浸提净化液进行真空浓缩蒸出多余的水,60℃~65℃真空减压浓缩至原体积的1/2~1/5,,得到鳞毛蕨净化浓缩液,即使鳞毛蕨提取物。鳞毛蕨叶子提取净化浓缩液要求固体含量20~35%。The extract and purification solution of Trichofern is vacuum-concentrated and steamed to remove excess water, and concentrated under reduced pressure at 60°C to 65°C to 1/2 to 1/5 of the original volume to obtain the concentrated liquid of Trichofern. Extract. The concentrated liquid extracted and purified from the leaves of Trichofern requires a solid content of 20-35%. 可以将浓缩的鳞毛蕨浓缩液用高压蒸汽灭菌罐在120℃条件下灭菌15min,备用。The concentrated Drichoptera concentrated solution can be sterilized at 120° C. for 15 minutes in a high-pressure steam sterilizing tank, and it is ready for use. 鳞毛蕨提取净化浓缩液也可以进行压力喷雾或离心喷雾干燥,进一步制成粉状鳞毛蕨提取物。压力喷雾或离心喷雾干燥进气温度可以控制在110~250℃,排气温度65~90℃。The concentrated solution of Trichofern extract and purification can also be subjected to pressure spray or centrifugal spray drying to further produce powdered Trichofern extract. The inlet temperature of pressure spray or centrifugal spray drying can be controlled at 110-250°C, and the exhaust temperature is 65-90°C. 5.根据权利要求1所述的一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,其特征在于无患子生物质提取液或粉的制备方法:5. the preparation and method thereof of a kind of hair fern according to claim 1, natural biomass detergent of Sapindus chinensis, it is characterized in that the preparation method of Sapindia chinensis biomass extract or powder: 称取新鲜的无患子果实,添2倍去离子水打浆粉碎,制取无患子打浆液。或将采集的无患子日晒或用烘干机干燥(60~65℃)至气干恒重。气干至恒重的无患子干果进行肉核分离操作,被分离出的皮肉可以经过高粉碎比物料粉碎,进行备料。Weigh the fresh fruit of Sapindus chinensis, add 2 times of deionized water to beat and pulverize it, and prepare the Sapindia chinensis beating liquid. Or dry the collected Sapindus chinensis in the sun or with a dryer (60-65° C.) until air-dried to constant weight. The dried fruit of Sapindus chinensis, which has been air-dried to constant weight, is subjected to the flesh core separation operation, and the separated skin and flesh can be crushed by materials with a high crushing ratio for raw material preparation. 将制备好的无患子打浆液打入提取灌,补加去离子水至固液比在1∶5~10的范围内;或将制备好的无患子粉碎料加入提取灌中,加去离子水至固液比控制在1∶5~10的范围内,进行三罐三步逆流提取,浸提温度80~102℃,浸提时间控制在1.0~2.0小时。浸提完后进行浸提料液的压滤或离心卸料分离操作,得到的头部浸提液进行减压或加压或微孔过滤净化处理,滤去部分不溶物和浸提物料残渣即得到无患子浸提净化液。Pour the prepared Sapindus slurries into the extraction tank, add deionized water until the solid-liquid ratio is in the range of 1:5-10; The solid-liquid ratio of ionized water is controlled within the range of 1:5-10, and three tanks and three-step countercurrent extraction are carried out, the extraction temperature is 80-102°C, and the extraction time is controlled at 1.0-2.0 hours. After leaching, press filter or centrifuge unloading and separation operation of the leaching material liquid, and decompress or pressurize the obtained head leaching liquid or perform microporous filtration purification treatment to filter out part of the insoluble matter and leaching material residue. Obtain Sapindus leaching and purifying solution. 无患子浸提净化液进行真空浓缩蒸出多余的水,60℃~65℃减压浓缩至原体积的1/2~1/5,得到无患子净化浓缩液,即使无患子提取物。无患子提取净化浓缩液要求固体含量20~35%。The extract and purification solution of Sapindus chinensis is vacuum-concentrated to evaporate excess water, concentrated under reduced pressure at 60°C to 65°C to 1/2 to 1/5 of the original volume, and the purified solution of Sapindia chinensis is obtained, even if the Sapindia chinensis extract . The extract and purification concentrate of Sapindus chinensis requires a solid content of 20-35%. 无患子提取净化浓缩液为无味微黄,接近透明的粘性液体。可以将浓缩的鳞毛蕨浓缩液用高压蒸汽灭菌罐在120℃条件下灭菌10~15min,备用。The extract and purification concentrate of Sapindus chinensis is an odorless light yellow, almost transparent viscous liquid. The concentrated Drichoptera concentrated solution can be sterilized at 120° C. for 10 to 15 minutes in a high-pressure steam sterilizing tank, and it is ready for use. 无患子提取净化浓缩液也可以进行压力喷雾或离心喷雾干燥,进一步制成粉状无患子提取物。压力喷雾或离心喷雾干燥进气温度可以控制在115~250℃,排气温度65~90℃。The extract and purification concentrate of Sapindus chinensis can also be subjected to pressure spraying or centrifugal spray drying, and further made into powdered Sapindus chinensis extract. The inlet temperature of pressure spray or centrifugal spray drying can be controlled at 115-250°C, and the exhaust temperature is 65-90°C. 6.根据权利要求1所述的一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法,其特征在于按如下组成配制。6. the preparation and method thereof of a kind of Phytophthora edulis according to claim 1, natural biomass detergent of Sapindus chinensis, is characterized in that it is prepared by the following composition. 液状产品:无患子果肉提取液,固体含量20~35%,用量30~80%;鳞毛蕨科植物叶子提取液,固体含量20~35%,用量10~40%;去离子水:余量。Liquid products: Sapindus fruit pulp extract, solid content 20-35%, dosage 30-80%; Lepidoptera plant leaf extract, solid content 20-35%, dosage 10-40%; deionized water: remaining quantity. 按上述配比分别称取无患子提取净化浓缩液、鳞毛蕨提取净化浓缩液,并打入搅拌容器中,补加一定量的去离子水,并加入适量的植物助剂与天然香精,搅拌均匀后,检测出料、装瓶。According to the above proportions, weigh the extract and purification concentrate of Sapindus chinensis and the extract and purification concentrate of Trichofernium, put them into a stirring container, add a certain amount of deionized water, and add an appropriate amount of plant additives and natural flavors, After stirring evenly, the material is detected and bottled. 粉状产品:无患子果肉提取物,固体含量90~95%,用量20~75%;鳞毛蕨科植物叶子提取物,固体含量90~95%,用量20~50%。Powder products: Sapindus fruit pulp extract, with a solid content of 90-95%, and a dosage of 20-75%; the leaf extract of Phryllopaceae plants, with a solid content of 90-95%, and a dosage of 20-50%. 按上述配比分别称取无患子提取净化浓缩物、鳞毛蕨提取净化浓缩物,加入适量的植物助剂与天然香精,混合搅拌均匀后,检测出料、包装。According to the above proportions, weigh the extract and purification concentrate of Sapindus chinensis and the extract and purification concentrate of Drichoptera, add an appropriate amount of plant additives and natural flavors, mix and stir evenly, and then inspect and pack.
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