CN109759662B - A method of ultrasonic-assisted porous ceramic brazing - Google Patents
A method of ultrasonic-assisted porous ceramic brazing Download PDFInfo
- Publication number
- CN109759662B CN109759662B CN201910041473.9A CN201910041473A CN109759662B CN 109759662 B CN109759662 B CN 109759662B CN 201910041473 A CN201910041473 A CN 201910041473A CN 109759662 B CN109759662 B CN 109759662B
- Authority
- CN
- China
- Prior art keywords
- ultrasonic
- ceramic
- ceramics
- ultrasonic wave
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 220
- 238000005219 brazing Methods 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000003466 welding Methods 0.000 claims abstract description 52
- 238000009736 wetting Methods 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims description 34
- 229910052751 metal Inorganic materials 0.000 claims description 34
- 239000000945 filler Substances 0.000 claims description 31
- 238000001816 cooling Methods 0.000 claims description 17
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims 2
- 229910002790 Si2N2O Inorganic materials 0.000 claims 1
- 229910052581 Si3N4 Inorganic materials 0.000 claims 1
- 229910004533 TaB2 Inorganic materials 0.000 claims 1
- 229910033181 TiB2 Inorganic materials 0.000 claims 1
- 229910007948 ZrB2 Inorganic materials 0.000 claims 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 238000004321 preservation Methods 0.000 abstract description 5
- 238000001465 metallisation Methods 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract 2
- 238000007781 pre-processing Methods 0.000 abstract 1
- 229910000679 solder Inorganic materials 0.000 description 71
- 239000011888 foil Substances 0.000 description 15
- 239000007788 liquid Substances 0.000 description 14
- 239000010953 base metal Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 238000003825 pressing Methods 0.000 description 9
- 238000005476 soldering Methods 0.000 description 9
- 239000002131 composite material Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 230000009286 beneficial effect Effects 0.000 description 5
- 238000010008 shearing Methods 0.000 description 4
- 238000002604 ultrasonography Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Landscapes
- Ceramic Products (AREA)
Abstract
Description
技术领域technical field
本发明涉及多孔陶瓷钎焊的方法。The present invention relates to a method for brazing porous ceramics.
背景技术Background technique
陶瓷因在高温下具有良好的力学性能和化学稳定性而被广泛应用在航空航天、核工业等领域中。多孔陶瓷因强度高、硬度高、抗腐蚀性好和密度低等优点而备受青睐。多孔陶瓷的延伸性差、加工性差，且较难实现机械加工，这使得陶瓷复合体和大尺寸部件的制造变得非常困难。然而现在制造业中的诸多零部件都会涉及到多孔陶瓷之间、以及多孔陶瓷/金属之间的连接。因此，发明一种适合于多孔陶瓷连接的方法，对促进多孔陶瓷的广泛使用有很大的促进作用。目前常用的多孔陶瓷和陶瓷的焊接方法主要有扩散焊和钎焊等。Ceramics are widely used in aerospace, nuclear industry and other fields due to their good mechanical properties and chemical stability at high temperatures. Porous ceramics are favored due to their high strength, high hardness, good corrosion resistance and low density. Porous ceramics have poor extensibility, poor machinability, and difficult machining, making the fabrication of ceramic composites and large-scale components very difficult. However, many components in manufacturing today involve connections between porous ceramics and between porous ceramics/metals. Therefore, the invention of a method suitable for the connection of porous ceramics will greatly promote the widespread use of porous ceramics. At present, the commonly used welding methods of porous ceramics and ceramics mainly include diffusion welding and brazing.
广大学者们使用了多种方法对其进行焊接，期望得到缺陷少、强度高的接头。但由于陶瓷本身的热稳定性好，属于极难润湿的材料，其焊接过程一般需要真空环境或需对陶瓷表面进行一定的金属化处理，且需要一定的保温时间，焊接效率低且接头性能不高。因此，发明一种高效、低温、可在大气环境中进行的多孔陶瓷的焊接方法势在必行。Scholars have used a variety of methods to weld it, hoping to obtain joints with fewer defects and high strength. However, due to the good thermal stability of the ceramic itself, it is a material that is extremely difficult to wet. The welding process generally requires a vacuum environment or a certain metallization treatment on the surface of the ceramic, and requires a certain holding time. The welding efficiency is low and the joint performance is low. not tall. Therefore, it is imperative to invent a welding method of porous ceramics with high efficiency, low temperature and in atmospheric environment.
发明内容SUMMARY OF THE INVENTION
本发明要解决现有陶瓷/陶瓷的焊接需要真空环境或需对陶瓷表面进行一定的金属化处理，且需要一定的保温时间，焊接效率低且接头性能不高的问题，而提供一种超声辅助多孔陶瓷钎焊的方法。In order to solve the problems that the welding of the existing ceramics/ceramics requires a vacuum environment or a certain metallization treatment on the surface of the ceramics, and a certain heat preservation time is required, the welding efficiency is low and the joint performance is not high, and the invention provides an ultrasonic auxiliary A method of brazing porous ceramics.
一种超声辅助多孔陶瓷钎焊的方法是按以下步骤进行的：A method for ultrasonic-assisted porous ceramic brazing is carried out according to the following steps:
一、待焊件预处理：1. Pretreatment of welded parts:
通过打磨、抛光和超声清洗清理2块～20块多孔陶瓷表面，得到预处理后的多孔陶瓷；The surfaces of 2 to 20 porous ceramics are cleaned by grinding, polishing and ultrasonic cleaning to obtain pretreated porous ceramics;
所述的多孔陶瓷的孔隙率为10％～90％；The porosity of the porous ceramic is 10% to 90%;
二、陶瓷的润湿：2. Wetting of ceramics:
将钎料置于钎料槽中加热至熔化，然后在超声波振动及钎料熔融温度下，将预处理后的多孔陶瓷浸入熔融钎料中进行润湿，得到超声辅助润湿的陶瓷；The brazing filler metal is placed in a brazing filler metal tank and heated to melting, and then under ultrasonic vibration and the melting temperature of the filler metal, the pretreated porous ceramics are immersed in the molten filler metal for wetting to obtain ultrasonic-assisted wetting ceramics;
当所述的超声波振动为持续施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～1800s；When the ultrasonic vibration is continuously applied, under the conditions of ultrasonic amplitude of 0.1 μm to 100 μm, ultrasonic frequency of 15 kHz to 50 kHz and ultrasonic power of 100 W to 2000 W, ultrasonic loading is performed for 1 s to 1800 s;
当所述的超声波振动为间隙施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～100s，然后暂停超声波加载10s～100s，以超声波加载及暂停为一次循环，循环2次～10次；When the ultrasonic vibration is applied in a gap, under the conditions that the ultrasonic amplitude is 0.1μm～100μm, the ultrasonic frequency is 15kHz～50kHz and the ultrasonic power is 100W～2000W, the ultrasonic wave is loaded for 1s～100s, and then the ultrasonic loading is suspended for 10s～100s , take ultrasonic loading and pause as a cycle,
三、陶瓷的焊接：3. Welding of ceramics:
在夹紧力为0.1MPa～10MPa的条件下，将2块～20块超声辅助润湿的陶瓷叠放并装夹到一起，在钎料熔融温度下，将装夹后的陶瓷件浸入熔融钎料中施加超声波振动，最后将超声后的陶瓷件取出并冷却至室温，去除夹紧力，得到多孔陶瓷焊接件，即完成超声辅助多孔陶瓷钎焊的方法；Under the condition of clamping force of 0.1MPa to 10MPa, stack 2 to 20 ultrasonic-assisted wetting ceramics and clamp them together. At the melting temperature of the solder, immerse the clamped ceramic pieces into the molten solder. Ultrasonic vibration is applied to the material, and finally the ultrasonically assisted ceramic parts are taken out and cooled to room temperature, the clamping force is removed, and the porous ceramic welded parts are obtained, that is, the method of ultrasonic-assisted porous ceramic brazing is completed;
当所述的超声波振动为持续施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～1800s；When the ultrasonic vibration is continuously applied, under the conditions of ultrasonic amplitude of 0.1 μm to 100 μm, ultrasonic frequency of 15 kHz to 50 kHz and ultrasonic power of 100 W to 2000 W, ultrasonic loading is performed for 1 s to 1800 s;
当所述的超声波振动为间隙施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～100s，然后暂停超声波加载10s～100s，以超声波加载及暂停为一次循环，循环2次～10次。When the ultrasonic vibration is applied in a gap, under the conditions that the ultrasonic amplitude is 0.1μm～100μm, the ultrasonic frequency is 15kHz～50kHz and the ultrasonic power is 100W～2000W, the ultrasonic wave is loaded for 1s～100s, and then the ultrasonic loading is suspended for 10s～100s , take ultrasonic loading and pause as a cycle,
一种超声辅助多孔陶瓷钎焊的方法是按以下步骤进行的：A method for ultrasonic-assisted porous ceramic brazing is carried out according to the following steps:
一、多孔陶瓷预处理：1. Pretreatment of porous ceramics:
通过打磨、抛光和超声清洗清理2块～20块多孔陶瓷表面，得到预处理后的多孔陶瓷；The surfaces of 2 to 20 porous ceramics are cleaned by grinding, polishing and ultrasonic cleaning to obtain pretreated porous ceramics;
所述的多孔陶瓷的孔隙率为10％～90％；The porosity of the porous ceramic is 10% to 90%;
二、陶瓷的焊接：Second, the welding of ceramics:
将2块～20块预处理后的多孔陶瓷叠放，相邻预处理后的多孔陶瓷之间设置钎料箔片，并在压紧力为0.1MPa～10MPa的条件下压紧，将压紧后的陶瓷件加热至钎料箔片熔化，在钎料熔融温度下，对压紧后的陶瓷件施加超声波振动，最后将超声后的陶瓷件取出，并保持在压紧力为0.1MPa～10MPa的条件下压紧冷却至室温，得到多孔陶瓷焊接件，即完成超声辅助多孔陶瓷钎焊的方法；Stack 2 to 20 pieces of pretreated porous ceramics, arrange brazing filler metal foils between adjacent pretreated porous ceramics, and press them under the condition of a pressing force of 0.1 MPa to 10 MPa. After the ceramic piece is heated until the solder foil is melted, at the melting temperature of the solder, ultrasonic vibration is applied to the compressed ceramic piece, and finally the ultrasonicated ceramic piece is taken out and kept at a pressing force of 0.1 MPa to 10 MPa. Under the condition of pressing and cooling to room temperature, the porous ceramic welded part is obtained, that is, the method of ultrasonic-assisted porous ceramic brazing is completed;
所述的钎料箔片厚度为0.1mm～1mm；The thickness of the brazing material foil is 0.1mm-1mm;
当所述的超声波振动为持续施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～1800s；When the ultrasonic vibration is continuously applied, under the conditions of ultrasonic amplitude of 0.1 μm to 100 μm, ultrasonic frequency of 15 kHz to 50 kHz and ultrasonic power of 100 W to 2000 W, ultrasonic loading is performed for 1 s to 1800 s;
当所述的超声波振动为间隙施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～100s，然后暂停超声波加载10s～100s，以超声波加载及暂停为一次循环，循环2次～10次。When the ultrasonic vibration is applied in a gap, under the conditions that the ultrasonic amplitude is 0.1μm～100μm, the ultrasonic frequency is 15kHz～50kHz and the ultrasonic power is 100W～2000W, the ultrasonic wave is loaded for 1s～100s, and then the ultrasonic loading is suspended for 10s～100s , take ultrasonic loading and pause as a cycle,
本发明机理：在经历超声波振动的液态水或熔融金属内部放置毛细管时，水或金属会沿导管内壁以很快的速度上升，该现象就是“声致毛细”作用。在此过程中，液体在毛细管内的上升不依赖液体对管内壁的润湿情况，在不润湿的情况下液体仍然可以渗入的毛细管内部。一般来讲，传统钎料对陶瓷的润湿性较差，即使将陶瓷热浸到钎料中很长一段时间，钎料也不会润湿并渗入陶瓷。利用声致毛细现象可以很好的解决液态钎料难以渗入多孔陶瓷的难题。除此之外，液态钎料在经历超声波振动时会产生空化，空化泡的溃灭会产生局部达到几千度的高温，也会产生速度很高的微射流，利用这两个现象可以解决陶瓷表面难润湿的问题，实现钎料对陶瓷的润湿。多孔陶瓷的空隙一般较小，而较窄间隙内可产生更强作用的声空化现象，利于液态钎料和陶瓷的连接。The mechanism of the invention: when a capillary tube is placed inside the liquid water or molten metal that has undergone ultrasonic vibration, the water or metal will rise along the inner wall of the tube at a fast speed, and this phenomenon is the "acoustic capillary" effect. In this process, the rise of the liquid in the capillary tube does not depend on the wetting of the inner wall of the tube by the liquid, and the liquid can still penetrate into the inside of the capillary tube without wetting. In general, conventional solders have poor wettability to ceramics, and even if the ceramics are hot-dipped into the solder for a long time, the solder will not wet and penetrate the ceramic. The sonocapillary phenomenon can be used to solve the problem that liquid solder is difficult to penetrate into porous ceramics. In addition, the liquid solder will generate cavitation when it undergoes ultrasonic vibration, and the collapse of the cavitation bubble will generate a high temperature of several thousand degrees locally, and will also generate a high-speed micro-jet. These two phenomena can be used to Solve the problem that the ceramic surface is difficult to wet, and realize the wetting of the ceramic by the brazing filler metal. The voids of porous ceramics are generally small, and a stronger acoustic cavitation phenomenon can be generated in the narrower gaps, which is beneficial to the connection between the liquid solder and the ceramics.
本发明的有益效果是：The beneficial effects of the present invention are:
1、陶瓷的选择灵活。本发明可以焊接任意多孔陶瓷，不受陶瓷成分的限制。1. The choice of ceramics is flexible. The present invention can weld any porous ceramic, and is not limited by the ceramic composition.
2、钎料的选择和成分配比灵活。本发明可使用任意钎料，高低温均可，且钎料成分配比灵活，可以是单一成分，也可以是复合钎料。2. The selection of solder and the proportion of components are flexible. The present invention can use any brazing filler metal, both high and low temperature, and the brazing filler metal has a flexible composition distribution ratio, which can be a single component or a composite brazing filler metal.
3、焊接过程温度范围广。本发明可根据试件的使用情况选择合适的钎料，而后根据钎料成分选择焊接温度。如Sn-9Zn钎料的焊接温度可以为200℃或以上，Zn-5Al钎料的焊接温度可以为400℃或以上，Al-12Si的焊接温度可以为600℃或以上。3. The welding process has a wide temperature range. According to the present invention, suitable brazing filler metal can be selected according to the use condition of the test piece, and then the welding temperature can be selected according to the brazing filler metal composition. For example, the soldering temperature of Sn-9Zn solder can be 200°C or above, the soldering temperature of Zn-5Al solder can be 400°C or above, and the soldering temperature of Al-12Si can be 600°C or above.
4、超声的施加位置灵活。焊接过程中，超声波可以加载在陶瓷上，也可以施加在夹具上；超声可以持续施加，也可以间隙施加。4. The application position of ultrasound is flexible. During the welding process, ultrasonic waves can be loaded on the ceramics or applied to the fixture; ultrasonic waves can be applied continuously or intermittently.
5、接头的强度高。液态钎料通过超声波毛细及空化作用，渗入到母材一定的深度，形成了致密的复合材料层，该层焊接之后强度比多孔的母材强度高，即接头受力时从母材断裂，且液态钎料渗入到母材后，使得母材强度提高，提高32％以上。5. The strength of the joint is high. The liquid brazing filler metal penetrates into the base metal to a certain depth through ultrasonic capillary action and cavitation, forming a dense composite material layer. And after the liquid brazing filler metal penetrates into the base metal, the strength of the base metal is increased by more than 32%.
6、成本低，适应性强，焊接效率高。在大气环境下即可完成焊接，几乎不受周围施工环境的影响，且焊后不需保温。6. Low cost, strong adaptability and high welding efficiency. The welding can be completed in the atmospheric environment, almost unaffected by the surrounding construction environment, and no heat preservation is required after welding.
7、本发明的使用范围广，使用于各种厚度，各种复杂件，适用于同种或异种多孔陶瓷的焊接。7. The present invention has a wide range of applications, is used in various thicknesses and various complex parts, and is suitable for welding of the same or different types of porous ceramics.
本发明用于一种超声辅助多孔陶瓷钎焊的方法。The invention is used for a method for ultrasonic-assisted porous ceramic brazing.
附图说明Description of drawings
图1为实施例一超声辅助多孔陶瓷钎焊过程示意图，1为熔融钎料，2为装夹后的陶瓷件，3为超声工具头，4为钎料槽，5为加热装置；1 is a schematic diagram of an ultrasonic-assisted porous ceramic brazing process in
图2为实施例一制备的多孔陶瓷焊接件焊缝的横截面形貌扫描电镜图，1为多孔陶瓷，2为焊缝，3为扩散层；2 is a scanning electron microscope image of the cross-sectional morphology of the weld of the porous ceramic weldment prepared in Example 1, where 1 is a porous ceramic, 2 is a weld, and 3 is a diffusion layer;
图3为实施例一制备的多孔陶瓷焊接件剪切实验后的裂纹扩展实物图，1为多孔陶瓷，2为焊缝，3为裂纹；Fig. 3 is the actual picture of crack propagation after the shearing test of the porous ceramic weldment prepared in Example 1, 1 is the porous ceramic, 2 is the weld, and 3 is the crack;
图4为实施例二超声辅助多孔陶瓷钎焊过程示意图，1为钎料箔片，2为多孔陶瓷，3为超声工具头，4为固定装置，5为加热装置。4 is a schematic diagram of the ultrasonic-assisted porous ceramic brazing process in Example 2, 1 is a solder foil, 2 is a porous ceramic, 3 is an ultrasonic tool head, 4 is a fixing device, and 5 is a heating device.
具体实施方式Detailed ways
具体实施方式一：本实施方式一种超声辅助多孔陶瓷钎焊的方法是按以下步骤进行的：Embodiment 1: A method for ultrasonic-assisted porous ceramic brazing in this embodiment is carried out according to the following steps:
一、待焊件预处理：1. Pretreatment of welded parts:
通过打磨、抛光和超声清洗清理2块～20块多孔陶瓷表面，得到预处理后的多孔陶瓷；The surfaces of 2 to 20 porous ceramics are cleaned by grinding, polishing and ultrasonic cleaning to obtain pretreated porous ceramics;
所述的多孔陶瓷的孔隙率为10％～90％；The porosity of the porous ceramic is 10% to 90%;
二、陶瓷的润湿：2. Wetting of ceramics:
将钎料置于钎料槽中加热至熔化，然后在超声波振动及钎料熔融温度下，将预处理后的多孔陶瓷浸入熔融钎料中进行润湿，得到超声辅助润湿的陶瓷；The brazing filler metal is placed in a brazing filler metal tank and heated to melting, and then under ultrasonic vibration and the melting temperature of the filler metal, the pretreated porous ceramics are immersed in the molten filler metal for wetting to obtain ultrasonic-assisted wetting ceramics;
当所述的超声波振动为持续施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～1800s；When the ultrasonic vibration is continuously applied, under the conditions of ultrasonic amplitude of 0.1 μm to 100 μm, ultrasonic frequency of 15 kHz to 50 kHz and ultrasonic power of 100 W to 2000 W, ultrasonic loading is performed for 1 s to 1800 s;
当所述的超声波振动为间隙施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～100s，然后暂停超声波加载10s～100s，以超声波加载及暂停为一次循环，循环2次～10次；When the ultrasonic vibration is applied in a gap, under the conditions that the ultrasonic amplitude is 0.1μm～100μm, the ultrasonic frequency is 15kHz～50kHz and the ultrasonic power is 100W～2000W, the ultrasonic wave is loaded for 1s～100s, and then the ultrasonic loading is suspended for 10s～100s , take ultrasonic loading and pause as a cycle,
三、陶瓷的焊接：3. Welding of ceramics:
在夹紧力为0.1MPa～10MPa的条件下，将2块～20块超声辅助润湿的陶瓷叠放并装夹到一起，在钎料熔融温度下，将装夹后的陶瓷件浸入熔融钎料中施加超声波振动，最后将超声后的陶瓷件取出并冷却至室温，去除夹紧力，得到多孔陶瓷焊接件，即完成超声辅助多孔陶瓷钎焊的方法；Under the condition of clamping force of 0.1MPa to 10MPa,
当所述的超声波振动为持续施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～1800s；When the ultrasonic vibration is continuously applied, under the conditions of ultrasonic amplitude of 0.1 μm to 100 μm, ultrasonic frequency of 15 kHz to 50 kHz and ultrasonic power of 100 W to 2000 W, ultrasonic loading is performed for 1 s to 1800 s;
当所述的超声波振动为间隙施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～100s，然后暂停超声波加载10s～100s，以超声波加载及暂停为一次循环，循环2次～10次。When the ultrasonic vibration is applied in a gap, under the conditions that the ultrasonic amplitude is 0.1μm～100μm, the ultrasonic frequency is 15kHz～50kHz and the ultrasonic power is 100W～2000W, the ultrasonic wave is loaded for 1s～100s, and then the ultrasonic loading is suspended for 10s～100s , take ultrasonic loading and pause as a cycle,
本实施方式的有益效果是：1、陶瓷的选择灵活。本实施方式可以焊接任意多孔陶瓷，不受陶瓷成分的限制。The beneficial effects of this embodiment are: 1. The selection of ceramics is flexible. This embodiment can weld any porous ceramic, and is not limited by the ceramic composition.
2、钎料的选择和成分配比灵活。本实施方式可使用任意钎料，高低温均可，且钎料成分配比灵活，可以是单一成分，也可以是复合钎料。2. The selection of solder and the proportion of components are flexible. In this embodiment, any solder can be used, both high and low temperature, and the component distribution ratio of the solder is flexible, which can be a single component or a composite solder.
3、焊接过程温度范围广。本实施方式可根据试件的使用情况选择合适的钎料，而后根据钎料成分选择焊接温度。如Sn-9Zn钎料的焊接温度可以为200℃或以上，Zn-5Al钎料的焊接温度可以为400℃或以上，Al-12Si的焊接温度可以为600℃或以上。3. The welding process has a wide temperature range. In this embodiment, a suitable brazing material can be selected according to the usage of the test piece, and then the welding temperature can be selected according to the composition of the brazing material. For example, the soldering temperature of Sn-9Zn solder can be 200°C or above, the soldering temperature of Zn-5Al solder can be 400°C or above, and the soldering temperature of Al-12Si can be 600°C or above.
4、超声的施加位置灵活。焊接过程中，超声波可以加载在陶瓷上，也可以施加在夹具上；超声可以持续施加，也可以间隙施加。4. The application position of ultrasound is flexible. During the welding process, ultrasonic waves can be loaded on the ceramics or applied to the fixture; ultrasonic waves can be applied continuously or intermittently.
5、接头的强度高。液态钎料通过超声波毛细及空化作用，渗入到母材一定的深度，形成了致密的复合材料层，该层焊接之后强度比多孔的母材强度高，即接头受力时从母材断裂，且液态钎料渗入到母材后，使得母材强度提高，提高32％以上。5. The strength of the joint is high. The liquid brazing filler metal penetrates into the base metal to a certain depth through ultrasonic capillary action and cavitation, forming a dense composite material layer. And after the liquid brazing filler metal penetrates into the base metal, the strength of the base metal is increased by more than 32%.
6、成本低，适应性强，焊接效率高。在大气环境下即可完成焊接，几乎不受周围施工环境的影响，且焊后不需保温。6. Low cost, strong adaptability and high welding efficiency. The welding can be completed in the atmospheric environment, almost unaffected by the surrounding construction environment, and no heat preservation is required after welding.
7、本实施方式的使用范围广，使用于各种厚度，各种复杂件，适用于同种或异种多孔陶瓷的焊接。7. This embodiment has a wide range of applications, is used in various thicknesses, various complex parts, and is suitable for welding of the same or different types of porous ceramics.
具体实施方式二：本实施方式与具体实施方式二不同的是：步骤一所述的多孔陶瓷为Si3N4陶瓷、Si2N2O陶瓷、SiC陶瓷、SiBCN陶瓷、ZrO2陶瓷、Al2O3陶瓷、TiB2陶瓷、B4C陶瓷、ZrB2陶瓷、TaB2陶瓷、ZrC陶瓷、二元陶瓷、三元陶瓷和四元陶瓷中的一种或其中几种。其它与具体实施方式二相同。Embodiment 2: The difference between this embodiment and
具体实施方式三：本实施方式与具体实施方式一或二不同的是：当步骤三所述的多孔陶瓷焊接件使用温度为190℃以下，则步骤二中所述的钎料为Sn基钎料；当步骤三所述的多孔陶瓷焊接件使用温度为380℃以下，则步骤二中所述的钎料为Zn基钎料；当步骤三所述的多孔陶瓷焊接件使用温度为600℃以下，则步骤二中所述的钎料为Al基钎料。其它与具体实施方式一或二相同。Embodiment 3: The difference between this embodiment and
具体实施方式四：本实施方式与具体实施方式一至三之一不同的是：所述的Sn基钎料为Sn-9Zn钎料或Sn-4Cu钎料；所述的Zn基钎料为Zn-5Al钎料；所述的Al基钎料为Al-12Si钎料。其它与具体实施方式一至三相同。Embodiment 4: This embodiment differs from one of
具体实施方式五：本实施方式与具体实施方式一至四之一不同的是：步骤三所述的冷却方式为水冷或空冷。其它与具体实施方式一至四相同。Embodiment 5: The difference between this embodiment and one of
具体实施方式六：本实施方式一种超声辅助多孔陶瓷钎焊的方法是按以下步骤进行的：Embodiment 6: A method of ultrasonic-assisted porous ceramic brazing in this embodiment is carried out according to the following steps:
一、多孔陶瓷预处理：1. Pretreatment of porous ceramics:
通过打磨、抛光和超声清洗清理2块～20块多孔陶瓷表面，得到预处理后的多孔陶瓷；The surfaces of 2 to 20 porous ceramics are cleaned by grinding, polishing and ultrasonic cleaning to obtain pretreated porous ceramics;
所述的多孔陶瓷的孔隙率为10％～90％；The porosity of the porous ceramic is 10% to 90%;
二、陶瓷的焊接：Second, the welding of ceramics:
将2块～20块预处理后的多孔陶瓷叠放，相邻预处理后的多孔陶瓷之间设置钎料箔片，并在压紧力为0.1MPa～10MPa的条件下压紧，将压紧后的陶瓷件加热至钎料箔片熔化，在钎料熔融温度下，对压紧后的陶瓷件施加超声波振动，最后将超声后的陶瓷件取出，并保持在压紧力为0.1MPa～10MPa的条件下压紧冷却至室温，得到多孔陶瓷焊接件，即完成超声辅助多孔陶瓷钎焊的方法；
所述的钎料箔片厚度为0.1mm～1mm；The thickness of the brazing material foil is 0.1mm-1mm;
当所述的超声波振动为持续施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～1800s；When the ultrasonic vibration is continuously applied, under the conditions of ultrasonic amplitude of 0.1 μm to 100 μm, ultrasonic frequency of 15 kHz to 50 kHz and ultrasonic power of 100 W to 2000 W, ultrasonic loading is performed for 1 s to 1800 s;
当所述的超声波振动为间隙施加时，在超声波振幅为0.1μm～100μm、超声波频率为15kHz～50kHz及超声波功率为100W～2000W的条件下，超声波加载1s～100s，然后暂停超声波加载10s～100s，以超声波加载及暂停为一次循环，循环2次～10次。When the ultrasonic vibration is applied in a gap, under the conditions that the ultrasonic amplitude is 0.1μm～100μm, the ultrasonic frequency is 15kHz～50kHz and the ultrasonic power is 100W～2000W, the ultrasonic wave is loaded for 1s～100s, and then the ultrasonic loading is suspended for 10s～100s , take ultrasonic loading and pause as a cycle,
本实施方式的有益效果是：1、陶瓷的选择灵活。本实施方式可以焊接任意多孔陶瓷，不受陶瓷成分的限制。The beneficial effects of this embodiment are: 1. The selection of ceramics is flexible. This embodiment can weld any porous ceramic, and is not limited by the ceramic composition.
2、钎料的选择和成分配比灵活。本实施方式可使用任意钎料，高低温均可，且钎料成分配比灵活，可以是单一成分，也可以是复合钎料。2. The selection of solder and the proportion of components are flexible. In this embodiment, any solder can be used, both high and low temperature, and the component distribution ratio of the solder is flexible, which can be a single component or a composite solder.
3、焊接过程温度范围广。本实施方式可根据试件的使用情况选择合适的钎料，而后根据钎料成分选择焊接温度。如Sn-9Zn钎料的焊接温度可以为200℃或以上，Zn-5Al钎料的焊接温度可以为400℃或以上，Al-12Si的焊接温度可以为600℃或以上。3. The welding process has a wide temperature range. In this embodiment, a suitable brazing material can be selected according to the usage of the test piece, and then the welding temperature can be selected according to the composition of the brazing material. For example, the soldering temperature of Sn-9Zn solder can be 200°C or above, the soldering temperature of Zn-5Al solder can be 400°C or above, and the soldering temperature of Al-12Si can be 600°C or above.
4、超声的施加位置灵活。焊接过程中，超声波可以加载在陶瓷上，也可以施加在夹具上；超声可以持续施加，也可以间隙施加。4. The application position of ultrasound is flexible. During the welding process, ultrasonic waves can be loaded on the ceramics or applied to the fixture; ultrasonic waves can be applied continuously or intermittently.
5、接头的强度高。液态钎料通过超声波毛细及空化作用，渗入到母材一定的深度，形成了致密的复合材料层，该层焊接之后强度比多孔的母材强度高，即接头受力时从母材断裂，且液态钎料渗入到母材后，使得母材强度提高，提高32％以上。5. The strength of the joint is high. The liquid brazing filler metal penetrates into the base metal to a certain depth through ultrasonic capillary action and cavitation, forming a dense composite material layer. And after the liquid brazing filler metal penetrates into the base metal, the strength of the base metal is increased by more than 32%.
6、成本低，适应性强，焊接效率高。在大气环境下即可完成焊接，几乎不受周围施工环境的影响，且焊后不需保温。6. Low cost, strong adaptability and high welding efficiency. The welding can be completed in the atmospheric environment, almost unaffected by the surrounding construction environment, and no heat preservation is required after welding.
7、本实施方式的使用范围广，使用于各种厚度，各种复杂件，适用于同种或异种多孔陶瓷的焊接。7. This embodiment has a wide range of applications, is used in various thicknesses, various complex parts, and is suitable for welding of the same or different types of porous ceramics.
具体实施方式七：本实施方式与具体实施方式六不同的是：步骤一中所述的多孔陶瓷为Si3N4陶瓷、Si2N2O陶瓷、SiC陶瓷、SiBCN陶瓷、ZrO2陶瓷、Al2O3陶瓷、TiB2陶瓷、B4C陶瓷、ZrB2陶瓷、TaB2陶瓷、ZrC陶瓷、二元陶瓷、三元陶瓷和四元陶瓷中的一种或其中几种。其它与具体实施方式六相同。Embodiment 7: The difference between this embodiment and Embodiment 6 is that the porous ceramics described in
具体实施方式八：本实施方式与具体实施方式六或七不同的是：当步骤二所述的多孔陶瓷焊接件使用温度为190℃以下，则所述的钎料箔片为Sn基钎料；当步骤二所述的多孔陶瓷焊接件使用温度为380℃以下，则所述的钎料箔片为Zn基钎料；当步骤二所述的多孔陶瓷焊接件使用温度为600℃以下，则所述的钎料箔片为Al基钎料。其它与具体实施方式六或七相同。Embodiment 8: The difference between this embodiment and Embodiment 6 or 7 is that: when the use temperature of the porous ceramic welding piece described in
具体实施方式九：本实施方式与具体实施方式六至八之一不同的是：所述的Sn基钎料为Sn-9Zn钎料或Sn-4Cu钎料；所述的Zn基钎料为Zn-5Al钎料；所述的Al基钎料为Al-12Si钎料。其它与具体实施方式六至八相同。Embodiment 9: This embodiment differs from one of Embodiments 6 to 8 in that: the Sn-based solder is Sn-9Zn solder or Sn-4Cu solder; the Zn-based solder is Zn -5Al solder; the Al-based solder is Al-12Si solder. Others are the same as the specific embodiments six to eight.
具体实施方式十：本实施方式与具体实施方式六至九之一不同的是：步骤二所述的冷却方式为水冷或空冷。其它与具体实施方式六至九相同。Embodiment 10: The difference between this embodiment and one of Embodiments 6 to 9 is that the cooling method described in
采用以下实施例验证本发明的有益效果：Adopt the following examples to verify the beneficial effects of the present invention:
实施例一：Example 1:
结合图1具体说明本实施例，一种超声辅助多孔陶瓷钎焊的方法是按以下步骤进行的：The present embodiment is described in detail with reference to FIG. 1 , a method for ultrasonic-assisted porous ceramic brazing is carried out according to the following steps:
一、待焊件预处理：1. Pretreatment of welded parts:
通过打磨、抛光和超声清洗清理2块多孔陶瓷表面，得到预处理后的多孔陶瓷；The surfaces of two porous ceramics were cleaned by grinding, polishing and ultrasonic cleaning to obtain pretreated porous ceramics;
所述的多孔陶瓷的孔隙率为30％；The porosity of the porous ceramic is 30%;
二、陶瓷的润湿：2. Wetting of ceramics:
将钎料置于钎料槽中，在温度为420℃的条件下加热至熔化，然后在超声波振动及温度为420℃下，将预处理后的多孔陶瓷浸入熔融钎料中进行润湿，得到超声辅助润湿的陶瓷；The solder is placed in a solder tank, heated to melt at a temperature of 420°C, and then the pretreated porous ceramics are immersed in the molten solder for wetting under ultrasonic vibration and a temperature of 420°C to obtain Ultrasound-assisted wetting of ceramics;
所述的超声波振动为持续施加，在超声波振幅为6μm、超声波频率为20kHz及超声波功率为1000W的条件下，超声波加载120s；The ultrasonic vibration is continuously applied, and the ultrasonic wave is loaded for 120s under the conditions that the ultrasonic amplitude is 6 μm, the ultrasonic frequency is 20 kHz and the ultrasonic power is 1000 W;
三、陶瓷的焊接：3. Welding of ceramics:
在夹紧力为0.2MPa～0.4MPa条件下，将2块超声辅助润湿的陶瓷叠放并装夹到一起，在温度为420℃下，将装夹后的陶瓷件浸入熔融钎料中施加超声波振动，最后将超声后的陶瓷件取出并冷却至室温，去除夹紧力，得到多孔陶瓷焊接件，即完成超声辅助多孔陶瓷钎焊的方法；Under the condition of clamping force of 0.2MPa to 0.4MPa, stack and clamp 2 pieces of ultrasonic-assisted wetting ceramics together. At a temperature of 420°C, immerse the clamped ceramic pieces in molten solder to apply Ultrasonic vibration, finally take out the ultrasonic ceramic piece and cool it to room temperature, remove the clamping force, and obtain the porous ceramic welded piece, that is, the method of ultrasonic-assisted porous ceramic brazing is completed;
所述的超声波振动为持续施加，在超声波振幅为6μm、超声波频率为20kHz及超声波功率为1000W的条件下，超声波加载120s；The ultrasonic vibration is continuously applied, and the ultrasonic wave is loaded for 120s under the conditions that the ultrasonic amplitude is 6 μm, the ultrasonic frequency is 20 kHz and the ultrasonic power is 1000 W;
步骤一所述的多孔陶瓷为ZrB2、SiC、TiB2及HfB2组成的四元陶瓷；所述的ZrB2:SiC:TiB2:HfB2的体积比为16:4:4:1；The porous ceramic described in
步骤二中所述的钎料为Zn-5Al钎料；The solder described in
步骤三所述的冷却方式为空冷；The cooling method described in
本实施例所述的超声波振动是将超声工具头施加于钎料槽上；The ultrasonic vibration described in this embodiment is that the ultrasonic tool bit is applied to the solder groove;
利用本实施例方法，可得到焊缝成形良好，内部无缺陷的多孔陶瓷焊接接头。通过改变超声时间和功率等参数，即可获得焊缝不同焊缝结构的接头；Using the method of this embodiment, a porous ceramic welded joint with good weld formation and no internal defects can be obtained. By changing parameters such as ultrasonic time and power, joints with different weld structures can be obtained;
图1中1为熔融钎料，2为装夹后的陶瓷件，3为超声工具头，4为钎料槽，5为加热装置；In Fig. 1, 1 is the molten solder, 2 is the ceramic piece after clamping, 3 is the ultrasonic tool head, 4 is the solder tank, and 5 is the heating device;
图2为实施例一制备的多孔陶瓷焊接件焊缝的横截面形貌扫描电镜图，1为多孔陶瓷，2为焊缝，3为扩散层；通过扫面电镜成分分析可得，此时液态钎料浸入到多孔陶瓷的深度为42微米；Fig. 2 is the scanning electron microscope image of the cross-sectional morphology of the welding seam of the porous ceramic weldment prepared in Example 1, 1 is the porous ceramic, 2 is the welding seam, and 3 is the diffusion layer. The depth of the solder immersion into the porous ceramic is 42 microns;
图3为实施例一制备的多孔陶瓷焊接件剪切实验后的裂纹扩展实物图，1为多孔陶瓷，2为焊缝，3为裂纹；对实施例一制备的多孔陶瓷焊接件在焊接尺寸为10mm×10mm及剪切速度为1mm/min的条件下进行剪切测试，由图可知，在剪切过程中，裂纹从陶瓷基体内部扩展，所得剪切强度为33MPa，高于本实施例四元陶瓷本身强度(约25MPa)，可知此时接头的强度高于陶瓷本身的强度，液态钎料渗入到母材后，使得母材强度进一步提高，提高约32％。Fig. 3 is the actual picture of crack propagation after the shearing test of the porous ceramic weldment prepared in Example 1, 1 is the porous ceramic, 2 is the weld, and 3 is the crack; for the porous ceramic weldment prepared in Example 1, the welding size is The shear test was carried out under the conditions of 10mm × 10mm and a shearing speed of 1mm/min. It can be seen from the figure that during the shearing process, the cracks expanded from the inside of the ceramic matrix, and the obtained shear strength was 33MPa, which was higher than that of the quaternary in this example. The strength of the ceramic itself (about 25MPa) shows that the strength of the joint is higher than that of the ceramic itself. After the liquid solder penetrates into the base metal, the strength of the base metal is further increased by about 32%.
实施例二：Embodiment 2:
结合图4具体说明本实施例，一种超声辅助多孔陶瓷钎焊的方法是按以下步骤进行的：The present embodiment is described in detail with reference to FIG. 4 , a method for ultrasonic-assisted porous ceramic brazing is carried out according to the following steps:
一、多孔陶瓷预处理：1. Pretreatment of porous ceramics:
通过打磨、抛光和超声清洗清理2块多孔陶瓷表面，得到预处理后的多孔陶瓷；The surfaces of two porous ceramics were cleaned by grinding, polishing and ultrasonic cleaning to obtain pretreated porous ceramics;
所述的多孔陶瓷的孔隙率为30％；The porosity of the porous ceramic is 30%;
二、陶瓷的焊接：Second, the welding of ceramics:
将2块预处理后的多孔陶瓷叠放，2块预处理后的多孔陶瓷之间设置钎料箔片，并在压紧力为0.2MPa～0.4MPa的条件下压紧，将压紧后的陶瓷件在温度为200℃的条件下加热至钎料熔化，在温度为200℃的条件下，对压紧后的陶瓷件施加超声波振动，最后将超声后的陶瓷件取出，并保持在压紧力为0.2MPa～0.4MPa的条件下压紧冷却至室温，得到多孔陶瓷焊接件，即完成超声辅助多孔陶瓷钎焊的方法；Two pieces of pretreated porous ceramics are stacked, and a brazing material foil is arranged between the two pieces of pretreated porous ceramics, and is pressed under the condition of a pressing force of 0.2 MPa to 0.4 MPa. The ceramic piece is heated at a temperature of 200°C until the brazing filler metal is melted. At a temperature of 200°C, ultrasonic vibration is applied to the compressed ceramic piece. Finally, the ultrasonicated ceramic piece is taken out and kept under pressure Pressing and cooling to room temperature under the condition of a force of 0.2 MPa to 0.4 MPa, to obtain a porous ceramic welding piece, that is, the method for completing the ultrasonic-assisted porous ceramic brazing;
所述的钎料箔片厚度为1mm；The thickness of the solder foil is 1mm;
所述的超声波振动为持续施加，在超声波振幅为10μm、超声波频率为30kHz及超声波功率为2000W的条件下，超声波加载10s；The ultrasonic vibration is continuously applied, and the ultrasonic wave is loaded for 10s under the conditions that the ultrasonic amplitude is 10 μm, the ultrasonic frequency is 30 kHz and the ultrasonic power is 2000 W;
步骤一所述的多孔陶瓷为ZrB2、SiC、TiB2及HfB2组成的四元陶瓷；所述的ZrB2:SiC:TiB2:HfB2的体积比为16:4:4:1；The porous ceramic described in
所述的钎料箔片为Sn-9Zn钎料；The solder foil is Sn-9Zn solder;
步骤二所述的冷却方式为空冷。The cooling method described in
本实施例将2块预处理后的多孔陶瓷之间设置钎料箔片并放置于固定装置中，固定装置的目的为防止多孔陶瓷在超声波振动过程中发生位置偏移，所述的超声波振动是将超声工具头施加于一侧陶瓷表面，且通过超声工具头施加压紧力。In this embodiment, a brazing material foil is placed between two pretreated porous ceramics and placed in a fixing device. The purpose of the fixing device is to prevent the positional deviation of the porous ceramics during the ultrasonic vibration process. The ultrasonic vibration is The ultrasonic tool tip is applied to one side of the ceramic surface, and a pressing force is applied by the ultrasonic tool tip.
图4中1为钎料箔片，2为多孔陶瓷，3为超声工具头，4为固定装置，5为加热装置。In Fig. 4, 1 is a solder foil, 2 is a porous ceramic, 3 is an ultrasonic tool head, 4 is a fixing device, and 5 is a heating device.
利用本实施例方法，可得到焊缝成形良好，内部无缺陷的接头。且使用该方法焊接时，不需提前对陶瓷进行润湿，可进一步提高焊接效率。Using the method of this embodiment, a joint with good weld formation and no internal defects can be obtained. And when using this method for welding, there is no need to wet the ceramics in advance, which can further improve the welding efficiency.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910041473.9A CN109759662B (en) | 2019-01-16 | 2019-01-16 | A method of ultrasonic-assisted porous ceramic brazing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910041473.9A CN109759662B (en) | 2019-01-16 | 2019-01-16 | A method of ultrasonic-assisted porous ceramic brazing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109759662A CN109759662A (en) | 2019-05-17 |
| CN109759662B true CN109759662B (en) | 2020-07-07 |
Family
ID=66454052
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910041473.9A Active CN109759662B (en) | 2019-01-16 | 2019-01-16 | A method of ultrasonic-assisted porous ceramic brazing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109759662B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111347114B (en) * | 2020-04-09 | 2021-10-22 | 河南科技大学 | Ultrasonic-assisted solder spreading process observation device |
| CN118385540A (en) * | 2024-04-23 | 2024-07-26 | 哈尔滨工业大学（威海） | An ultrasonic-assisted infiltration method for rapid preparation of bionic layered ceramic-metal composites |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5568174A (en) * | 1978-11-15 | 1980-05-22 | Fuji Electric Co Ltd | Ultrasonic soldering method of ceramics element |
| JPH03103786A (en) * | 1989-09-19 | 1991-04-30 | Japan Radio Co Ltd | Ultrasonic probe |
| CN104191057A (en) * | 2014-08-13 | 2014-12-10 | 中国电器科学研究院有限公司 | Preparing method for porous metal matrix compound brazing filler metal alloy soldering head |
| CN105479030A (en) * | 2016-01-07 | 2016-04-13 | 哈尔滨工业大学 | Active anti-corrosion SnZn base brazing filler metal, manufacturing method thereof and low-temperature ultrasonic brazing method of ceramic and/or composite material and aluminum and magnesium alloy |
| CN105921839A (en) * | 2016-06-06 | 2016-09-07 | 哈尔滨工业大学（威海） | Kovar alloy and ceramic material ultrasonic brazing method |
| CN106563861A (en) * | 2016-10-19 | 2017-04-19 | 哈尔滨工业大学（威海） | Ultrasonic soldering method for fast forming ceramic-metal interconnection |
| CN106673685A (en) * | 2017-01-20 | 2017-05-17 | 哈尔滨工业大学 | Method for brazing AlON ceramics and boron nitride/silicon nitride composite ceramics by adopting Ag-Cu-Ti brazing filler metal |
-
2019
- 2019-01-16 CN CN201910041473.9A patent/CN109759662B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5568174A (en) * | 1978-11-15 | 1980-05-22 | Fuji Electric Co Ltd | Ultrasonic soldering method of ceramics element |
| JPH03103786A (en) * | 1989-09-19 | 1991-04-30 | Japan Radio Co Ltd | Ultrasonic probe |
| CN104191057A (en) * | 2014-08-13 | 2014-12-10 | 中国电器科学研究院有限公司 | Preparing method for porous metal matrix compound brazing filler metal alloy soldering head |
| CN105479030A (en) * | 2016-01-07 | 2016-04-13 | 哈尔滨工业大学 | Active anti-corrosion SnZn base brazing filler metal, manufacturing method thereof and low-temperature ultrasonic brazing method of ceramic and/or composite material and aluminum and magnesium alloy |
| CN105921839A (en) * | 2016-06-06 | 2016-09-07 | 哈尔滨工业大学（威海） | Kovar alloy and ceramic material ultrasonic brazing method |
| CN106563861A (en) * | 2016-10-19 | 2017-04-19 | 哈尔滨工业大学（威海） | Ultrasonic soldering method for fast forming ceramic-metal interconnection |
| CN106673685A (en) * | 2017-01-20 | 2017-05-17 | 哈尔滨工业大学 | Method for brazing AlON ceramics and boron nitride/silicon nitride composite ceramics by adopting Ag-Cu-Ti brazing filler metal |
Non-Patent Citations (1)
| Title |
|---|
| "铝合金超声波钎焊过程中液态钎料的填缝及界面润湿行为";许志武等;《材料工程》;20101231;第1-8页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109759662A (en) | 2019-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102151930B (en) | Dissimilar metal material brazing method | |
| CN102489813B (en) | Vacuum active brazing process of molybdenum-copper alloys and stainless steel | |
| CN109759662B (en) | A method of ultrasonic-assisted porous ceramic brazing | |
| CN101259567B (en) | Method for Plug Welding of Porous Structured Aluminum Matrix Composite Materials Using Ultrasonic Vibration | |
| CN106735833A (en) | Sound based on eutectic reaction causes instant liquid-phase diffusion welding welding method | |
| CN105522244A (en) | Ultrasonic-assisted low-temperature glass brazing method | |
| CN101579768B (en) | Braze-welding method using two-stage contact reaction of aluminum alloy | |
| CN108500411B (en) | An ultrasonic brazing device and method based on a pin-type welding head | |
| CN105541366B (en) | A kind of ceramic low-temp method for welding | |
| CN105921839B (en) | A kind of kovar alloy and ceramic material ultrasonic brazing method | |
| CN111843165B (en) | A kind of diffusion connection method of diamond microfluidic channel | |
| CN113020735B (en) | Preparation method of silicon nitride ceramic/stainless steel braze welding joint with corrosion resistance and stress relief | |
| CN105965176A (en) | Ni-based rapidly-cooled brazing material and brazing process for brazing tungsten-copper alloy and stainless steel | |
| CN106378506B (en) | A kind of technique that SiC based composites are brazed using brazing material | |
| CN109836166B (en) | A kind of electromagnetic ultrasonic brazing method for SiC ceramics | |
| CN109909571B (en) | A method for preparing foamed aluminum sandwich panel by electromagnetic ultrasonic brazing | |
| CN117340379A (en) | A thermally adapted brazing connection method between carbon-based composite materials and metals based on surface groove structure | |
| CN108907492B (en) | A kind of molybdenum/steel joint and preparation method thereof | |
| CN114799475B (en) | A method for direct brazing of non-metal and metal using commercial inactive brazing filler metal at low temperature | |
| CN113770502B (en) | Method for welding ceramic and nickel-based alloy | |
| CN114769774A (en) | Preparation method of ceramic aluminum-coated substrate for power device | |
| CN103978277A (en) | A Method of Diffusion Brazing SiCp/Al Composite Material Using Al/Cu/Al Composite Foil | |
| CN110899896B (en) | A welding fixture and a method for brazing a large-size aluminum alloy curved skin and a ribbed skeleton structure | |
| CN113319418A (en) | Molybdenum-rhenium alloy interlayer-free diffusion bonding method | |
| CN117841370B (en) | A method for welding carbon fiber thermoplastic composite material and metal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |