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CN108940578A - It is a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method - Google Patents

It is a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method Download PDF

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Publication number
CN108940578A
CN108940578A CN201810459686.9A CN201810459686A CN108940578A CN 108940578 A CN108940578 A CN 108940578A CN 201810459686 A CN201810459686 A CN 201810459686A CN 108940578 A CN108940578 A CN 108940578A
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Prior art keywords
flotation
tailing
cassiterite
rougher
concentrate
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CN201810459686.9A
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CN108940578B (en
Inventor
蔺慧杰
蓝卓越
张镜翠
谢贤
童雄
刘宇彤
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/02Froth-flotation processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02Ores
    • B03D2203/04Non-sulfide ores

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  • Manufacture And Refinement Of Metals (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)

Abstract

The present invention relates to a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method, belongs to technical field of beneficiation.Cassiterite tailing is carried out ore grinding by the present invention, and water is added to size mixing, and roughing flotation medicament is added, and is uniformly mixed, and is then at the uniform velocity injected into progress flotation column roughing in flotation column and is obtained rougher concentration I and rougher tailings I;Flotation is added in rougher tailings I and scans medicament, is uniformly mixed, then is at the uniform velocity injected into progress flotation column in flotation column and scans to obtain scavenger concentrate I and scan tailing I;Scavenger concentrate I is injected into progress flotation device roughing in flotation device and obtains rougher concentration II and rougher tailings II;It scans the progress flotation device of rougher tailings II to obtain scavenger concentrate II and scans tailing II;It scans after the return of tailing II is mixed with cassiterite tailing and sizes mixing;Rougher concentration II and the merging of scavenger concentrate II carry out to flotation device is selected to obtain selected concentrate and cleaner tailings III again, progress flotation device roughing after the return of cleaner tailings III is mixed with scavenger concentrate I.

Description

It is a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method
Technical field
The present invention relates to a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method, belongs to ore dressing skill Art field.
Background technique
Tin is a kind of important meals of the national economic development, and the targeted object of tin-lead soldering is mostly cassiterite gravity treatment tail at present Mine increases essence for mostly using in this part ore production technology so the lower granularity of cassiterite grade handled by flotation is thinner The number for selecting and scanning realizes the raising of grade and the rate of recovery.Although this method simply but in actual production will directly increase The input amount for adding flotation device and the construction for selecting factory are put into.Final concentrate product are required when the raw ore for being 0.294% to tin grade is handled Position reach 6% and its more than, selected can be only achieved requirement by what flotation device experiment at least needed three times and its above;By 2 times And its above scanning just can guarantee and tailings grade be down to 0.1% or less.
Summary of the invention
For the above-mentioned problems of the prior art and deficiency, the present invention provides a kind of using flotation device-flotation column joint The beneficiation method of Fine cassiterite is recycled, the method for the present invention is combined using flotation device-flotation column is recycled cassiterite tailing, Process flow can substantially be shortened, improve recovery efficiency, and the Tin concentrate grade of this method recycling is up to 6% or more.
It is a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method, the specific steps are as follows:
(1) by cassiterite tailing carry out ore grinding to partial size be less than 0.074mm account for 80 ~ 85 %, add water size mixing to pulp density be 30 ~ 40%, sequentially add 400 ~ 500 g/t of activator, 200 ~ 300g/t of sodium carbonate, 1200 ~ 1400 g/t of collecting agent, supplementary catching agent The roughing flotation medicament of 40 ~ 50g/t, 40 ~ 50 g/t of foaming agent are uniformly mixed and obtain ore pulp I to be selected;
(2) it is at the uniform velocity injected into flotation column in step (1) gained ore pulp I to be selected, makes froth bed by adjusting liquid level and aeration quantity With a thickness of 70 ~ 80cm, the coarse-fine choosing of flotation column obtains rougher concentration I and rougher tailings I;
(3) 60 ~ 100g/t of activator, 40 ~ 50g/t of sodium carbonate, collecting are sequentially added in the rougher tailings I obtained by step (2) Medicament is scanned in the flotation of 240 ~ 280g/t of agent, 8 ~ 10g/t of supplementary catching agent, 8 ~ 10g/t of foaming agent, is uniformly mixed and is obtained to ore dressing Slurry II;
(4) ore pulp to be selected II of step (3) is at the uniform velocity injected into flotation column, makes foam thickness by adjusting liquid level and aeration quantity Degree is 30 ~ 40cm, and flotation column is scanned to obtain scavenger concentrate I and scans tailing I;
(5) step (4) scavenger concentrate I is injected into progress 4 ~ 6 min of flotation device roughing in flotation device and obtains II He of rougher concentration Rougher tailings II;The progress flotation device of rougher tailings II is scanned 4 ~ 6min to obtain scavenger concentrate II and scanning tailing II;Scan tail It sizes mixing after being mixed in II return step of mine (1) with cassiterite tailing;
(6) by step (5) rougher concentration II and scavenger concentrate II merging carry out again the selected 4 ~ 6min of flotation device obtain it is selected Concentrate and cleaner tailings III carry out flotation device roughing after being mixed in III return step of cleaner tailings (5) with scavenger concentrate I, selected Concentrate merges to obtain cassiterite concentrate with the rougher concentration I of step (1);
Further, the activator is YT-51, collecting agent JSY-19, supplementary catching agent P86, and foaming agent is No. 2 oil;
Further, step (2) flotation column is coarse-fine selects speed for 200 ~ 300mL/min;
Further, it is 200 ~ 300mL/min that step (4) flotation column, which scans speed,.
The beneficial effects of the present invention are:
(1) the method for the present invention is combined using flotation device-flotation column and is recycled to cassiterite tailing, can substantially shorten technique stream Journey improves recovery efficiency;
(2) rate of recovery of the method for the present invention tin is much higher than existing flotation device to the rate of recovery of tin, and the Tin concentrate grade recycled can Up to 6% or more.
Detailed description of the invention
Fig. 1 is process flow chart of the invention.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1: the grade of tin is 0.293% in cassiterite tailing in the present embodiment;
It is a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method, the specific steps are as follows:
(1) cassiterite tailing is subjected to ore grinding and accounts for 83.1% less than 0.074mm to partial size, wherein liberation degree of minerals in cassiterite mine tailing It is 67%, 80% or more cassiterite disseminated grain size is lower than 800 mesh;Adding water to size mixing to pulp density is 30 %, sequentially adds activator (activator YT-51) 400 g/t, sodium carbonate 200g/t, 1200 g/t of collecting agent (collecting agent JSY-19), supplementary catching agent The roughing flotation medicament of (supplementary catching agent P86) 40 g/t, foaming agent (foaming agent is No. 2 oil) 50 g/t, are uniformly mixed To ore pulp I to be selected;
(2) it is at the uniform velocity injected into flotation column in step (1) gained ore pulp I to be selected, makes froth bed by adjusting liquid level and aeration quantity With a thickness of 70cm, flotation column roughing speed is that 300mL/min obtains rougher concentration I and rougher tailings I;Tin in rougher concentration I Grade is 7.080%, rougher concentration I(Sn concentrate) it is the 2.53% of cassiterite tailing quality, the rate of recovery of tin is up to 61.13%;Roughing tail The grade of tin is 0.117% in mine I, and rougher tailings I is the 97.47% of cassiterite tailing quality;Rougher concentration I(Sn concentrate) in tin Concentration ratio reaches 24;
(3) activator (activator YT-51) 80g/t, 40 g/ of sodium carbonate are sequentially added in the rougher tailings I obtained by step (2) T, 240 g/t of collecting agent (collecting agent JSY-19), supplementary catching agent (supplementary catching agent P86) 8g/t, foaming agent (foaming agent For No. 2 oil) flotation of 10g/t scans medicament, and it is uniformly mixed and obtains ore pulp II to be selected;
(4) ore pulp to be selected II of step (3) is at the uniform velocity injected into flotation column, makes foam thickness by adjusting liquid level and aeration quantity Degree is 30cm, and it is that 250mL/min obtains scavenger concentrate I and scans tailing I that flotation column, which scans speed,;The product of tin in scavenger concentrate I Position is 1.820%, and scavenger concentrate I is the 1.50% of I mass of rougher tailings, and the rate of recovery of tin reaches in rougher tailings I in scavenger concentrate I The 23.33% of tin;The grade for scanning tin in tailing I is 0.091%, scans 98.50% that tailing I is I mass of rougher tailings;
(5) step (4) scavenger concentrate I is injected into flotation device and carries out 5 min of flotation device roughing and obtains rougher concentration II and thick Select tailing II;The progress flotation device of rougher tailings II is scanned 5 min to obtain scavenger concentrate II and scanning tailing II;Scan tailing It sizes mixing after being mixed in II return step (1) with cassiterite tailing;
(6) by step (5) rougher concentration II and the merging of scavenger concentrate II carry out selected 6 min of flotation device again and obtain selected essence Mine and cleaner tailings III carry out flotation device roughing, selected essence after being mixed in III return step of cleaner tailings (5) with scavenger concentrate I Mine merges to obtain cassiterite concentrate with the rougher concentration I of step (1);The grade of tin is 6.07% in cassiterite concentrate, and cassiterite concentrate is tin The 3.62% of stone tailing (raw ore) quality, the rate of recovery of tin is up to 72.10%.
Embodiment 2: the grade of tin is 0.335% in cassiterite tailing in the present embodiment;
It is a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method, the specific steps are as follows:
(1) cassiterite tailing is subjected to ore grinding and accounts for 86.1% less than 0.074mm to partial size, wherein liberation degree of minerals in cassiterite mine tailing It is 67.36%, 84.31% or more cassiterite disseminated grain size is lower than 800 mesh;Adding water to size mixing to pulp density is 33%, sequentially adds work Agent (activator YT-51) 450g/t, sodium carbonate 250g/t, collecting agent (collecting agent JSY-19) 1300g/t, auxiliary are caught The roughing flotation medicament for receiving agent (supplementary catching agent P86) 45g/t, foaming agent (foaming agent is No. 2 oil) 45g/t, is uniformly mixed Obtain ore pulp I to be selected;
(2) it is at the uniform velocity injected into flotation column in step (1) gained ore pulp I to be selected, makes froth bed by adjusting liquid level and aeration quantity With a thickness of 75cm, flotation column roughing speed is that 200mL/min obtains rougher concentration I and rougher tailings I;Tin in rougher concentration I Grade is 7.32%, rougher concentration I(Sn concentrate) it is the 2.12% of cassiterite tailing quality, the rate of recovery of tin is up to 45.34%;Roughing tail The grade of tin is 0.187% in mine I, and rougher tailings I is the 97.93% of cassiterite tailing quality;Rougher concentration I(Sn concentrate) in tin Concentration ratio reaches 21.85;
(3) activator (activator YT-51) 90g/t, sodium carbonate 50g/ are sequentially added in the rougher tailings I obtained by step (2) T, collecting agent (collecting agent JSY-19) 260g/t, supplementary catching agent (supplementary catching agent P86) 10g/t, foaming agent (foaming agent For No. 2 oil) flotation of 9g/t scans medicament, and it is uniformly mixed and obtains ore pulp II to be selected;
(4) ore pulp to be selected II of step (3) is at the uniform velocity injected into flotation column, makes foam thickness by adjusting liquid level and aeration quantity Degree is 35cm, and it is that 300mL/min obtains scavenger concentrate I and scans tailing I that flotation column, which scans speed,;The product of tin in scavenger concentrate I Position is 0.621%, and scavenger concentrate I is the 22.12% of I mass of rougher tailings, and the rate of recovery of tin reaches rougher tailings I in scavenger concentrate I The 60.15% of middle tin;The grade for scanning tin in tailing I is 0.287%, scans 18.11% that tailing I is I mass of rougher tailings;
(5) step (4) scavenger concentrate I is injected into flotation device and carries out 6 min of flotation device roughing and obtains rougher concentration II and thick Select tailing II;The progress flotation device of rougher tailings II is scanned 4 min to obtain scavenger concentrate II and scanning tailing II;Scan tailing It sizes mixing after being mixed in II return step (1) with cassiterite tailing;
(6) by step (5) rougher concentration II and scavenger concentrate II merging carry out again selected 4 min of flotation device obtain it is selected Concentrate and cleaner tailings III carry out flotation device roughing after being mixed in III return step of cleaner tailings (5) with scavenger concentrate I, selected Concentrate merges to obtain cassiterite concentrate with the rougher concentration I of step (1);The grade of tin is 6.31% in cassiterite concentrate, and cassiterite concentrate is The 3.92% of cassiterite tailing (raw ore) quality, the rate of recovery of tin is up to 73.90%.
Embodiment 3: the grade of tin is 0.317% in cassiterite tailing in the present embodiment;
It is a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method, the specific steps are as follows:
(1) cassiterite tailing is subjected to ore grinding and accounts for 81.7% less than 0.074mm to partial size, wherein liberation degree of minerals in cassiterite mine tailing It is 65.8%, 79.65% or more cassiterite disseminated grain size is lower than 800 mesh;Adding water to size mixing to pulp density is 35%, sequentially adds work Agent (activator YT-51) 500g/t, sodium carbonate 300g/t, collecting agent (collecting agent JSY-19) 1400g/t, auxiliary are caught The roughing flotation medicament for receiving agent (supplementary catching agent P86) 50g/t, foaming agent (foaming agent is No. 2 oil) 40g/t, is uniformly mixed Obtain ore pulp I to be selected;
(2) it is at the uniform velocity injected into flotation column in step (1) gained ore pulp I to be selected, makes froth bed by adjusting liquid level and aeration quantity With a thickness of 80cm, flotation column roughing speed is that 270mL/min obtains rougher concentration I and rougher tailings I;Tin in rougher concentration I Grade is 7.03%, rougher concentration I(Sn concentrate) it is the 2.07% of cassiterite tailing quality, the rate of recovery of tin is up to 45.94%;Roughing tail The grade of tin is 0.175% in mine I, and rougher tailings I is the 97.93% of cassiterite tailing quality;Rougher concentration I(Sn concentrate) in tin Concentration ratio reaches 22.18;
(3) activator (activator YT-51) 60g/t, sodium carbonate 45g/ are sequentially added in the rougher tailings I obtained by step (2) T, collecting agent (collecting agent JSY-19) 280g/t, supplementary catching agent (supplementary catching agent P86) 9g/t, foaming agent (foaming agent For No. 2 oil) flotation of 8g/t scans medicament, and it is uniformly mixed and obtains ore pulp II to be selected;
(4) ore pulp to be selected II of step (3) is at the uniform velocity injected into flotation column, makes foam thickness by adjusting liquid level and aeration quantity Degree is 40cm, and it is that 200mL/min obtains scavenger concentrate I and scans tailing I that flotation column, which scans speed,;The product of tin in scavenger concentrate I Position is 0.597%, and scavenger concentrate I is the 16.93% of I mass of rougher tailings, and the rate of recovery of tin reaches rougher tailings I in scavenger concentrate I The 57.75% of middle tin;The grade for scanning tin in tailing I is 0.089%, scans 83.07% that tailing I is I mass of rougher tailings;
(5) step (4) scavenger concentrate I is injected into progress flotation device roughing 4min in flotation device and obtains rougher concentration II and roughing Tailing II;The progress flotation device of rougher tailings II is scanned 6min to obtain scavenger concentrate II and scanning tailing II;Tailing II is scanned to return It returns in step (1) after being mixed with cassiterite tailing and sizes mixing;
(6) by step (5) rougher concentration II and the merging of scavenger concentrate II carry out the selected 5min of flotation device again and obtain selected essence Mine and cleaner tailings III carry out flotation device roughing, selected essence after being mixed in III return step of cleaner tailings (5) with scavenger concentrate I Mine merges to obtain cassiterite concentrate with the rougher concentration I of step (1);The grade of tin is 6.31 % in cassiterite concentrate, and cassiterite concentrate is 3.66 % of cassiterite tailing (raw ore) quality, the rate of recovery of tin is up to 72.95 %.
Above the embodiment of the present invention is explained in detail, but the present invention is not limited to above-mentioned embodiment party Formula can also be made without departing from the purpose of the present invention within the knowledge of a person skilled in the art Various change out.

Claims (4)

1. a kind of using flotation device-flotation column combined recovery Fine cassiterite beneficiation method, which is characterized in that specific steps are such as Under:
(1) by cassiterite tailing carry out ore grinding to partial size be less than 0.074mm account for 80 ~ 85%, add water size mixing to pulp density be 30 ~ 40%, sequentially add 400 ~ 500 g/t of activator, 200 ~ 300g/t of sodium carbonate, 1200 ~ 1400 g/t of collecting agent, supplementary catching agent The roughing flotation medicament of 40 ~ 50g/t, 40 ~ 50 g/t of foaming agent are uniformly mixed and obtain ore pulp I to be selected;
(2) it is at the uniform velocity injected into flotation column in step (1) gained ore pulp I to be selected, makes froth bed by adjusting liquid level and aeration quantity With a thickness of 70 ~ 80cm, the coarse-fine choosing of flotation column obtains rougher concentration I and rougher tailings I;
(3) 60 ~ 100g/t of activator, 40 ~ 50g/t of sodium carbonate, collecting are sequentially added in the rougher tailings I obtained by step (2) Medicament is scanned in the flotation of 240 ~ 280g/t of agent, 8 ~ 10g/t of supplementary catching agent, 8 ~ 10g/t of foaming agent, is uniformly mixed and is obtained to ore dressing Slurry II;
(4) ore pulp to be selected II of step (3) is at the uniform velocity injected into flotation column, makes foam thickness by adjusting liquid level and aeration quantity Degree is 30 ~ 40cm, and flotation column is scanned to obtain scavenger concentrate I and scans tailing I;
(5) step (4) scavenger concentrate I is injected into progress 4 ~ 6 min of flotation device roughing in flotation device and obtains II He of rougher concentration Rougher tailings II;The progress flotation device of rougher tailings II is scanned 4 ~ 6min to obtain scavenger concentrate II and scanning tailing II;Scan tail It sizes mixing after being mixed in II return step of mine (1) with cassiterite tailing;
(6) by step (5) rougher concentration II and scavenger concentrate II merging carry out again the selected 4 ~ 6min of flotation device obtain it is selected Concentrate and cleaner tailings III carry out flotation device roughing after being mixed in III return step of cleaner tailings (5) with scavenger concentrate I, selected Concentrate merges to obtain cassiterite concentrate with the rougher concentration I of step (1).
2. using flotation device-flotation column combined recovery Fine cassiterite beneficiation method according to claim 1, feature exists In: activator YT-51, collecting agent JSY-19, supplementary catching agent P86, foaming agent are No. 2 oil.
3. using flotation device-flotation column combined recovery Fine cassiterite beneficiation method according to claim 1, feature exists In: step (2) flotation column is coarse-fine to select speed for 200 ~ 300mL/min.
4. using flotation device-flotation column combined recovery Fine cassiterite beneficiation method according to claim 1, feature exists In: it is 200 ~ 300mL/min that step (4) flotation column, which scans speed,.
CN201810459686.9A 2018-05-15 2018-05-15 Beneficiation method for recovering fine-grained cassiterite by adopting flotation machine-flotation column Active CN108940578B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111111934A (en) * 2019-12-26 2020-05-08 黑龙江多宝山铜业股份有限公司 Flotation machine combined configuration system for copper flotation
CN112718235A (en) * 2020-11-16 2021-04-30 内蒙古维拉斯托矿业有限公司 Tungsten-tin comprehensive recovery combined reselection method

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WO2011085445A1 (en) * 2010-01-14 2011-07-21 Teebee Holdings Pty Ltd Flotation reagents
CN103736569A (en) * 2013-12-13 2014-04-23 金川集团股份有限公司 Beneficiation method of sulphide ore
CN104923408A (en) * 2015-07-08 2015-09-23 中国矿业大学 Co-platform flotation column and flotation machine combined separating technology and device
CN106492979A (en) * 2016-11-07 2017-03-15 昆明理工大学 A kind of method that ultrafine fraction cassiterite is recycled
CN107890946A (en) * 2017-09-29 2018-04-10 昆明理工大学 A kind of beneficiation method of micro fine particle

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US20100000913A1 (en) * 2008-07-02 2010-01-07 Georgia-Pacific Chemicals Llc Collectors
WO2011085445A1 (en) * 2010-01-14 2011-07-21 Teebee Holdings Pty Ltd Flotation reagents
CN103736569A (en) * 2013-12-13 2014-04-23 金川集团股份有限公司 Beneficiation method of sulphide ore
CN104923408A (en) * 2015-07-08 2015-09-23 中国矿业大学 Co-platform flotation column and flotation machine combined separating technology and device
CN106492979A (en) * 2016-11-07 2017-03-15 昆明理工大学 A kind of method that ultrafine fraction cassiterite is recycled
CN107890946A (en) * 2017-09-29 2018-04-10 昆明理工大学 A kind of beneficiation method of micro fine particle

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111111934A (en) * 2019-12-26 2020-05-08 黑龙江多宝山铜业股份有限公司 Flotation machine combined configuration system for copper flotation
CN112718235A (en) * 2020-11-16 2021-04-30 内蒙古维拉斯托矿业有限公司 Tungsten-tin comprehensive recovery combined reselection method
CN112718235B (en) * 2020-11-16 2023-03-21 内蒙古维拉斯托矿业有限公司 Tungsten-tin comprehensive recovery combined reselection method

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