CN108728269A - A kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent and preparation method thereof - Google Patents
A kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/12—Water-insoluble compounds
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- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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Abstract
The present invention provides a kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent, and the raw material for preparing of the cleaning agent includes：Component A：Surfactant, nanometer coral calcium powder, sodium citrate, chelating agent；B component：Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract；Component C：Tannin；Super Strong cleaning strengths nanometer coral calcium powder cleaning agent provided by the invention can easily tackle the dirt of the heavy oil in kitchen；Can fast decoupled greasy dirt, while the greasy dirt after decomposition is adsorbed, facilitates removing.
Description
Technical field
The present invention relates to cleaning agents, are more related to cleaning agent for kitchen use.
Background technology
In actual life, due to accumulating over a long period in life process so that the health in the kitchens such as family, hotel, restaurant
There are many dead angles in situation, and some dirts for being difficult to remove occurs in each corner, these long-term accumulative dirts, only
It is not strong by common cleaning agent clean effect, it is difficult to realize and quickly, thoroughly clean, cause cleaning process time-consuming and laborious, work
Efficiency is low, and cleaning effect is undesirable.
The cleaning agent of conventional use of kitchen heavy oil needs the cleaning ingredient of comparison stimulus, and after its oil stain decomposition
Small molecule greasy dirt is not easy to wipe, and needs to coordinate with it using steel wire lumps such as cleaning balls；Heavy oil place after simultaneously erased, subsequently
It could be again clean or same process can be undergone.
In view of the above-mentioned problems, the present invention provides a kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent.
Invention content
The present invention provides a kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent, and the raw material for preparing of the cleaning agent includes：
Component A：Surfactant, nanometer coral calcium powder, sodium citrate, chelating agent；
B component：Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract；
Component C：Tannin.
As one embodiment of the present invention, the nanometer coral calcium powder is polysaccharide-modified coral calcium powder.
As one embodiment of the present invention, the polysaccharide is pectin.
As one embodiment of the present invention, the tannin is hydrolysable tannins.
As one embodiment of the present invention, the component B is coated by release membranes.
As one embodiment of the present invention, the release membranes are modified rhamnose.
As one embodiment of the present invention, the surfactant is nonionic surfactant.
As one embodiment of the present invention, in parts by weight, the weight ratio of the component A and B component is (1-
3)：1.
As one embodiment of the present invention, the preparation method of the B component is as follows：
1.5g rhamnoses are dissolved in the acetic acid aqueous solution of 100mL 2% by S01, magnetic stirrer dissolving；The poly- second of 1g
Enol is dissolved in 30mL water, and heating makes it dissolve；Above-mentioned rhamnose, poly-vinyl alcohol solution are uniformly mixed, 50 DEG C of water-baths
48h takes the silica gel 1.6-2.8g that 200-300 mesh is added in 40mL mixed solutions to pour into glass plate, room temprature evaporation film forming.It is done
Dry film immerses the sodium hydroxide solution of 2mol/L, and 50 DEG C of water-bath 2h dissolve silica gel, rhamnose/polyvinyl alcohol is made.With 5%
In acetic acid and extra sodium hydroxide, deionized water is rinsed to neutrality, dry in drying box.
After S02 takes Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract mixing, it is mixed to obtain extract
Close object；
S03 takes rhamnose/polyvinyl alcohol that 10g steps 1 are prepared and the mixing of 80g distilled water, and is added at room temperature
6g extract mixtures, stir evenly, ultrasonic 30min, so that it is uniformly mixed, then in 175 DEG C of inlet temperature, feed rate
It is spray-dried under the conditions of 3mL/min, nozzle head diameter 0.7mm and 2 times/min of nozzle cleaning, obtains component B.
As one embodiment of the present invention, the extracting method of the Radix Stemonae extract and phellodendron extract is as follows：
(1) 1 part of tuber of stemona root and 1 part of Cortex Phellodendri bark are chosen, is cleaned, after drying is ground, it is equal that 10 parts of milk of lime stirrings are added
It after even, is put into after being impregnated 6 hours with limewash in percolator, takes percolate, it is full that 120% addition citric acid of percolate volume is added
And aqueous solution, it is stood overnight after stirring, filters to take precipitation；
(2) it will precipitate with after hot water dissolving, filter while hot, take filtrate, you can Radix Stemonae extract is prepared and Cortex Phellodendri carries
Take object crude product；
(3) crude product is added to after being dissolved in boiling water and is filtered while hot, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object.
Advantageous effect：
1. super Strong cleaning strengths nanometer coral calcium powder cleaning agent provided by the invention can easily tackle the dirt of the heavy oil in kitchen；
Can fast decoupled greasy dirt, while the greasy dirt after decomposition is adsorbed, facilitates removing；
2. the super Strong cleaning strengths nanometer coral calcium powder cleaning agent of the present invention can form one to the polluted surface after cleaning
Layer protective film, extends the pollution period of greasy dirt.
Specific implementation mode
For the purpose of following detailed description, it should be understood that the present invention can be used various replacements variation and step it is suitable
Sequence, unless specifically stated on the contrary.In addition, in the case of in addition in any operational instances or otherwise pointing out, indicate
Such as all numbers of the amount of the ingredient used in description and claims should be understood in all cases by term
" about " it modifies.Therefore, unless indicated to the contrary, the numerical parameter otherwise illustrated in the following description and appended dependent claims is root
The approximation changed according to the expected performance of the invention to be obtained.It is at least not intended to the applicable of doctrine of equivalents being limited in
In the scope of the claims, each numerical parameter at least according to the number of the effective digital of report and should pass through the common house of application
Enter technology to explain.
Although illustrating that the broad range of numberical range of the present invention and parameter are approximations, listed in specific example
Numerical value is reported as accurately as possible.However, any numerical value includes inherently the standard deviation found in being measured by its each self-test
The certain errors necessarily led to.
In addition, it should be understood that any numberical range as described herein is intended to include being included into all subranges therein.Example
Such as, the range of " 1 to 10 " is intended to include all sub- models between (and including) described minimum value 1 and the maximum value 10
It encloses, that is, there is the minimum value equal to or more than 1 and the maximum value equal to or less than 10.
The present invention provides a kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent, and the raw material for preparing of the cleaning agent includes：
Component A：Surfactant, nanometer coral calcium powder, sodium citrate, chelating agent；
B component：Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract；
Component C：Tannin.
Component A
Surfactant
In the present invention, the surfactant is nonionic surfactant and anion surfactant according to weight ratio
It is 1：2 mixture.
Nonionic surfactant：Heretofore described nonionic surfactant is lived for polyoxyethylene-type non-ionic surface
Property agent；Polyoxyethylene non-ionic surfactant is that ethylene oxide carries out addition reaction with the compound containing active hydrogen
Product；So-called reactive hydrogen atom refers to-OH ,-COOH ,-NH2With-CONH2Hydrogen atom in equal groups.
As one embodiment of the present invention, the nonionic surfactant is selected from Tween-20, Tween-60, spits
It is one or more in temperature -80.
Anion surfactant：Heretofore described anion surfactant is neopelex.
Nanometer coral calcium powder
Coral calcium is daily nutrition complementary goods, it is coral living by weathering and coral sand made of natural decomposition.It contains
There are very the calcareous of high concentration, main mine substance and trace mineral, because mineral content is abundant, be otherwise known as ocean diamond.
The nanometer coral calcium powder of the present invention is to be ground coral calcium, is ground to Nano grade, then carries out polysaccharide and changes
Property nanometer coral calcium powder；The polysaccharide is pectin.
In the present invention, the preparation method of the polysaccharide-modified nanometer coral calcium powder is as follows：
1. at ambient temperature, instilling a small amount of deionized water into nanometer coral calcium powder, supersonic oscillations is used in combination to handle
After keep its evenly dispersed；
2. in aqueous solution by polysaccharide dispersion, being prepared into a concentration of 3% polysaccharide solution；
3. under ultrasound condition, polysaccharide solution is gradually dropped in the nanometer coral calcium slurry liquid of step 1, is added dropwise
Afterwards, continue to be ultrasonically treated after ten minutes, mixed liquor is placed in after being freezed 12 hours at subzero 80 DEG C, then freeze-dried
Polysaccharide-modified nanometer coral calcium powder is prepared.
Wherein, the weight ratio of polysaccharide and nanometer coral calcium powder is 1：2.
Sodium citrate
Alias sodium citrate, is a kind of organic compound, and appearance is that white arrives clear crystal.It is odorless, there is refrigerant salty pungent.
Stablize in room temperature and air, it is micro- in humid air to have dissolubility, weathering phenomenon is generated in hot-air.150 DEG C are heated to lose
The crystallization water.It is soluble easily in water, dissolve in glycerine, be insoluble in alcohols and other organic solvents, cross thermally decompose, it is micro- in a humid environment
There is deliquescence, it is micro- in hot-air to have weathering.
Chelating agent
Metallic atom or ion are acted on the ligand containing two or more coordination atoms, and generating has cyclic annular knot
The complex compound of structure, the complex compound are called chelate.This ligand substance of chelate can be generated chelating agent, be also referred to as complexed
Agent.
Heretofore described chelating agent be selected from tetrasodium ethylenediamine tetraacetate, sodium tartrate, four sodium of 1-hydroxy ethylidene-1,1-diphosphonic acid and
One or both of four sodium of iminodisuccinic acid.
As one embodiment of the present invention, the chelating agent is tetrasodium ethylenediamine tetraacetate.
B component
In the present invention, the B component be Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract, and
The B component is coated by release membranes.
The release membranes are modified rhamnose, and the modified rhamnose is polyvinyl alcohol modification rhamnose.
In the present invention, the preparation method of the component B is as follows：
S01. 1.5g rhamnoses are dissolved in the acetic acid aqueous solution of 100mL 2%, magnetic stirrer dissolving；The poly- second of 1g
Enol is dissolved in 30mL water, and heating makes it dissolve；Above-mentioned rhamnose, poly-vinyl alcohol solution are uniformly mixed, 50 DEG C of water-baths
48h takes the silica gel 1.6-2.8g that 200-300 mesh is added in 40mL mixed solutions to pour into glass plate, room temprature evaporation film forming.It is done
Dry film immerses the sodium hydroxide solution of 2mol/L, and 50 DEG C of water-bath 2h dissolve silica gel, rhamnose/polyvinyl alcohol is made.With 5%
In acetic acid and extra sodium hydroxide, deionized water is rinsed to neutrality, dry in drying box.
S02. after taking Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract mixing, extract is obtained
Mixture；
S03. rhamnose/the polyvinyl alcohol and the mixing of 80g distilled water that 10g steps 1 are prepared are taken, and is added at room temperature
6g extract mixtures, stir evenly, ultrasonic 30min, so that it is uniformly mixed, then in 175 DEG C of inlet temperature, feed rate
It is spray-dried under the conditions of 3mL/min, nozzle head diameter 0.7mm and 2 times/min of nozzle cleaning, obtains component B.
Radix Stemonae extract, phellodendron extract
The tuber of stemona is also known as mother-in-law's woman's grass, and medicine lice medicine is the plant of Stemonaceae.The tuber of stemona is perennial herb, underground fasciation fusiform
The rising of its object is climbed up by holding on on meat root tuber, stem top.Obovate leaf, in 2-4 piece wheel tight knots.The early spring opens pale green dyeing defect, and bennet adhesion is in leaf
On master pulse, as being grown on Hua Congye.
The tuber of stemona rich in there is an a large amount of alkaloid, root containing stemonine, tuberostemonine, this is for peaceful alkali, secondary stemonine, oxidation hundred
Portion's alkali；Still contain sugar 2.32%, lipid 0.84%, protein 9.25%, ash content 12.1% and acetic acid, formic acid, malic acid, amber
Amber acid, oxalic acid etc..
Cortex Phellodendri bark is containing jamaicin, jateorrhizine, magnoflorine, phellodendrine, candicine, palmatine, bat
The alkaloids such as bat Pueraria lobota alkali；Separately containing obakunone, obakulactone, Dictamnolide, obacunonic acid, green fluorescent acid, 7- dehydrogenations stigmasterol, β-
Sitosterol, campesterol.Root skin is containing jamaicin, jateorrhizine, phellodendrine, candicine.Timber also contains jamaicin.It is fresh
Leaf is containing amurensin, amurensin, phellatin, phellavin.Dried leaf contains hyperin, is free of amurensin.
In the present invention, the extracting method of the Radix Stemonae extract and phellodendron extract is as follows：
1. choosing 1 part of tuber of stemona root and 1 part of Cortex Phellodendri bark, clean, after drying is ground, 10 parts of milk of limes is added and stir evenly
Afterwards, it is put into after being impregnated 6 hours with limewash in percolator, takes percolate, percolate volume 120% is added, citric acid saturation is added
Aqueous solution is stood overnight after stirring, filters to take precipitation；
2. by precipitating with after hot water dissolving, filter while hot, take filtrate, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object crude product；
It is filtered while hot 3. crude product is added to after being dissolved in boiling water, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object.
In the present invention, conventional Radix Stemonae extract and phellodendron extract are to separate extraction, while being added in conventional extraction
What is be added after milk of lime is alkaline matter, the present invention in excessive organic acid is added, can subtract the later stage add hydrochloric acid progress
PH is adjusted, so as to obtain the magnoflorine in addition to jamaicin and stemonine, the Huang of Radix Stemonae extract and phellodendron extract
The alkaloids such as cypress alkali avoid excessive material damage.
Radish seed extract
Radish seed, Chinese medicine name.For the dry mature seed of crucifer radish.Plant is tapped when summer fruit maturation,
It dries, rubs seed, remove impurity, then dry.
Its chemical composition, the fatty oil of seed, volatile oil.There is methyl mercaptan etc. in volatile oil.Erucic acid containing volume in fat oil,
Linoleic acid, leukotrienes and glycerol sinapate etc..Still claim raphanin containing antibacterial material.
In the present invention, the preparation method of the preparation method referenced patent CN103830305A of the radish seed extract.
Capillary extract
Containing volatile oil, in oil ingredient have carvol, cymol, limonene, perillene, α-phellandrene, Thymol,
α -, β-nopinene, terpinol -4, pinanone, naphthalene, arylmethyl acetophenone separately contain scoparone, parahydroxyacet-ophenone and chlorogenic acid
Equal Herba Artemisiae Scopariaes contain volatile oil, and ingredient has laurene, limonene, eucalyptol, australene, amphene, α-curcumene, reaches watt ketone, oriental wormwood in oil
Acetylenic ketone, eugenol, isoeugenol, naphthalene, benzaldehyde, borneol.Separately containing capillarisin, 6,7- dimethoxycoumarins.
In the present invention, the preparation method of the capillary extract is as follows：
1. choosing 10 parts of oriental wormwood, after being decocted 4 hours with water, filtering obtains Aqueous extracts；
After 2. Aqueous extracts are then concentrated into 1/4 volume, extracted with chloroform；
3. choosing chloroform extract liquor, then sodium hydroxide is chosen with 5% sodium bicarbonate and 2% sodium hydroxide extraction respectively
After extracting solution, after being acidified with hydrochloric acid, continue to use chloroform recovery；
4. choosing chloroform extracted solution, after recycling chloroform, by acidic moiety through polyamide column chromatography, with ethyl alcohol, (concentration is distinguished
For 30%, 50% and 80%) gradient elution；
5. choosing 80% concentration ethanol elutes position, then heating volatilization ethyl alcohol, after being extracted with ether, recycling ether extraction
Liquid recycles ether, obtains white solid, you can capillary extract is prepared.
Component C
In the present invention, the tannin is hydrolysable tannins, and heretofore described hydrolysable tannins is nutgall acid.
As one embodiment of the present invention, in parts by weight, the component A, the weight ratio of B component and component C
It is 8：4：1.
In component A, the surfactant, nanometer coral calcium powder, sodium citrate, chelating agent weight ratio be 1：1：0.5：
0.01。
In B component, the Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract weight ratio be 1：
1：1：1.
The super Strong cleaning strengths nanometer coral calcium powder cleaning agent provided by the invention is independently packed in packaging,
It is remixed when use.
Mechanism is explained：The cleaning agent of conventional use of kitchen heavy oil needs the cleaning ingredient of comparison stimulus, and its greasy dirt
Small molecule greasy dirt after decomposition is not easy to wipe, and needs to coordinate with it using steel wire lumps such as cleaning balls；Heavy oil after simultaneously erased
Place, subsequently could be again clean or same process can be undergone.Super Strong cleaning strengths nanometer coral calcium powder provided by the invention
Cleaning agent is solid powdery, and when use can carry out stronger decomposition and suction-operated to greasy dirt, simultaneously because coral calcium powder
The adsorption capacity of greasy dirt is enhanced by processing, while clean surface will not be treated and cause cut, is treated clearly in combination with sustained release agent
Clean surface forms protective film, alleviates the period of greasy dirt polluted again.
Super Strong cleaning strengths nanometer coral calcium powder cleaning agent provided by the invention is carried out with reference to specific embodiment detailed
Explanation.
Embodiment 1：
A kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent, the raw material for preparing of the cleaning agent include：
Component A：Surfactant, nanometer coral calcium powder, sodium citrate, chelating agent；
B component：Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract；
Component C：Tannin.
It according to weight ratio is 1 that the surfactant, which is Tween-60 and neopelex,：2 mixture.
The preparation method of the polysaccharide-modified nanometer coral calcium powder is as follows：
1. at ambient temperature, instilling a small amount of deionized water into nanometer coral calcium powder, supersonic oscillations is used in combination to handle
After keep its evenly dispersed；
2. in aqueous solution by polysaccharide dispersion, being prepared into a concentration of 3% polysaccharide solution；
3. under ultrasound condition, polysaccharide solution is gradually dropped in the nanometer coral calcium slurry liquid of step 1, is added dropwise
Afterwards, continue to be ultrasonically treated after ten minutes, mixed liquor is placed in after being freezed 12 hours at subzero 80 DEG C, then freeze-dried
Polysaccharide-modified nanometer coral calcium powder is prepared.
Wherein, the weight ratio of polysaccharide and nanometer coral calcium powder is 1：2.
The chelating agent is tetrasodium ethylenediamine tetraacetate.
The preparation method of the component B is as follows：
S01. 1.5g rhamnoses are dissolved in the acetic acid aqueous solution of 100mL 2%, magnetic stirrer dissolving；The poly- second of 1g
Enol is dissolved in 30mL water, and heating makes it dissolve；Above-mentioned rhamnose, poly-vinyl alcohol solution are uniformly mixed, 50 DEG C of water-baths
48h takes the silica gel 1.6-2.8g that 200-300 mesh is added in 40mL mixed solutions to pour into glass plate, room temprature evaporation film forming.It is done
Dry film immerses the sodium hydroxide solution of 2mol/L, and 50 DEG C of water-bath 2h dissolve silica gel, rhamnose/polyvinyl alcohol is made.With 5%
In acetic acid and extra sodium hydroxide, deionized water is rinsed to neutrality, dry in drying box.
S02. after taking Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract mixing, extract is obtained
Mixture；
S03. rhamnose/the polyvinyl alcohol and the mixing of 80g distilled water that 10g steps 1 are prepared are taken, and is added at room temperature
6g extract mixtures, stir evenly, ultrasonic 30min, so that it is uniformly mixed, then in 175 DEG C of inlet temperature, feed rate
It is spray-dried under the conditions of 3mL/min, nozzle head diameter 0.7mm and 2 times/min of nozzle cleaning, obtains component B.
The extracting method of the Radix Stemonae extract and phellodendron extract is as follows：
1. choosing 1 part of tuber of stemona root and 1 part of Cortex Phellodendri bark, clean, after drying is ground, 10 parts of milk of limes is added and stir evenly
Afterwards, it is put into after being impregnated 6 hours with limewash in percolator, takes percolate, percolate volume 120% is added, citric acid saturation is added
Aqueous solution is stood overnight after stirring, filters to take precipitation；
2. by precipitating with after hot water dissolving, filter while hot, take filtrate, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object crude product；
It is filtered while hot 3. crude product is added to after being dissolved in boiling water, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object.
The preparation method of the capillary extract is as follows：
1. choosing 10 parts of oriental wormwood, after being decocted 4 hours with water, filtering obtains Aqueous extracts；
After 2. Aqueous extracts are then concentrated into 1/4 volume, extracted with chloroform；
3. choosing chloroform extract liquor, then sodium hydroxide is chosen with 5% sodium bicarbonate and 2% sodium hydroxide extraction respectively
After extracting solution, after being acidified with hydrochloric acid, continue to use chloroform recovery；
4. choosing chloroform extracted solution, after recycling chloroform, by acidic moiety through polyamide column chromatography, with ethyl alcohol, (concentration is distinguished
For 30%, 50% and 80%) gradient elution；
5. choosing 80% concentration ethanol elutes position, then heating volatilization ethyl alcohol, after being extracted with ether, recycling ether extraction
Liquid recycles ether, obtains white solid, you can capillary extract is prepared.
The tannin is nutgall acid.
The weight ratio of the component A, B component and component C is 8：4：1.
In component A, the surfactant, nanometer coral calcium powder, sodium citrate, chelating agent weight ratio be 1：1：0.5：
0.01。
In B component, the Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract weight ratio be 1：
1：1：1.
Embodiment 2：
A kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent, the raw material for preparing of the cleaning agent include：
Component A：Surfactant, nanometer coral calcium powder, sodium citrate, chelating agent；
B component：Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract；
Component C：Tannin.
It according to weight ratio is 1 that the surfactant, which is Tween-60 and neopelex,：1 mixture.
The preparation method of the polysaccharide-modified nanometer coral calcium powder is as follows：
1. at ambient temperature, instilling a small amount of deionized water into nanometer coral calcium powder, supersonic oscillations is used in combination to handle
After keep its evenly dispersed；
2. in aqueous solution by polysaccharide dispersion, being prepared into a concentration of 3% polysaccharide solution；
3. under ultrasound condition, polysaccharide solution is gradually dropped in the nanometer coral calcium slurry liquid of step 1, is added dropwise
Afterwards, continue to be ultrasonically treated after ten minutes, mixed liquor is placed in after being freezed 12 hours at subzero 80 DEG C, then freeze-dried
Polysaccharide-modified nanometer coral calcium powder is prepared.
Wherein, the weight ratio of polysaccharide and nanometer coral calcium powder is 1：1.
The chelating agent is tetrasodium ethylenediamine tetraacetate.
The preparation method of the component B is as follows：
1. 1.5g rhamnoses are dissolved in the acetic acid aqueous solution of 100mL 2%, magnetic stirrer dissolving；1g polyethylene
Alcohol is dissolved in 30mL water, and heating makes it dissolve；Above-mentioned rhamnose, poly-vinyl alcohol solution are uniformly mixed, 50 DEG C of water-baths
48h takes the silica gel 1.6-2.8g that 200-300 mesh is added in 40mL mixed solutions to pour into glass plate, room temprature evaporation film forming.It is done
Dry film immerses the sodium hydroxide solution of 2mol/L, and 50 DEG C of water-bath 2h dissolve silica gel, rhamnose/polyvinyl alcohol is made.With 5%
In acetic acid and extra sodium hydroxide, deionized water is rinsed to neutrality, dry in drying box.
2. after taking Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract mixing, it is mixed to obtain extract
Close object；
3. rhamnose/polyvinyl alcohol and 80g the distilled water mixing for taking 10g steps 1 to be prepared, and 6g is added at room temperature
Extract mixtures stir evenly, ultrasonic 30min, so that it is uniformly mixed, then in 175 DEG C of inlet temperature, feed rate 3mL/
It is spray-dried under the conditions of min, nozzle head diameter 0.7mm and 2 times/min of nozzle cleaning, obtains component B.
The extracting method of the Radix Stemonae extract and phellodendron extract is as follows：
1. choosing 1 part of tuber of stemona root and 1 part of Cortex Phellodendri bark, clean, after drying is ground, 10 parts of milk of limes is added and stir evenly
Afterwards, it is put into after being impregnated 6 hours with limewash in percolator, takes percolate, percolate volume 120% is added, citric acid saturation is added
Aqueous solution is stood overnight after stirring, filters to take precipitation；
2. by precipitating with after hot water dissolving, filter while hot, take filtrate, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object crude product；
It is filtered while hot 3. crude product is added to after being dissolved in boiling water, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object.
The preparation method of the capillary extract is as follows：
1. choosing 10 parts of oriental wormwood, after being decocted 4 hours with water, filtering obtains Aqueous extracts；
After 2. Aqueous extracts are then concentrated into 1/4 volume, extracted with chloroform；
3. choosing chloroform extract liquor, then sodium hydroxide is chosen with 5% sodium bicarbonate and 2% sodium hydroxide extraction respectively
After extracting solution, after being acidified with hydrochloric acid, continue to use chloroform recovery；
4. choosing chloroform extracted solution, after recycling chloroform, by acidic moiety through polyamide column chromatography, with ethyl alcohol, (concentration is distinguished
For 30%, 50% and 80%) gradient elution；
5. choosing 80% concentration ethanol elutes position, then heating volatilization ethyl alcohol, after being extracted with ether, recycling ether extraction
Liquid recycles ether, obtains white solid, you can capillary extract is prepared.
The tannin is nutgall acid.
The weight ratio of the component A, B component and component C is 8：1：1.
In component A, the surfactant, nanometer coral calcium powder, sodium citrate, chelating agent weight ratio be 1：1：0.5：
0.01。
In B component, the Radix Stemonae extract, radish seed extract, capillary extract weight ratio be 1：1：1.
Embodiment 3：
A kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent, the raw material for preparing of the cleaning agent include：
Component A：Surfactant, nanometer coral calcium powder, sodium citrate, chelating agent；
B component：Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract；
Component C：Tannin.
It according to weight ratio is 1 that the surfactant, which is Tween-60 and neopelex,：2 mixture.
The preparation method of the polysaccharide-modified nanometer coral calcium powder is as follows：
1. at ambient temperature, instilling a small amount of deionized water into nanometer coral calcium powder, supersonic oscillations is used in combination to handle
After keep its evenly dispersed；
2. in aqueous solution by polysaccharide dispersion, being prepared into a concentration of 3% polysaccharide solution；
3. under ultrasound condition, polysaccharide solution is gradually dropped in the nanometer coral calcium slurry liquid of step 1, is added dropwise
Afterwards, continue to be ultrasonically treated after ten minutes, mixed liquor is placed in after being freezed 12 hours at subzero 80 DEG C, then freeze-dried
Polysaccharide-modified nanometer coral calcium powder is prepared.
Wherein, the weight ratio of polysaccharide and nanometer coral calcium powder is 1：2.
The chelating agent is tetrasodium ethylenediamine tetraacetate.
The preparation method of the component B is as follows：
1. 1.5g rhamnoses are dissolved in the acetic acid aqueous solution of 100mL 2%, magnetic stirrer dissolving；1g polyethylene
Alcohol is dissolved in 30mL water, and heating makes it dissolve；Above-mentioned rhamnose, poly-vinyl alcohol solution are uniformly mixed, 50 DEG C of water-baths
48h takes the silica gel 1.6-2.8g that 200-300 mesh is added in 40mL mixed solutions to pour into glass plate, room temprature evaporation film forming.It is done
Dry film immerses the sodium hydroxide solution of 2mol/L, and 50 DEG C of water-bath 2h dissolve silica gel, rhamnose/polyvinyl alcohol is made.With 5%
In acetic acid and extra sodium hydroxide, deionized water is rinsed to neutrality, dry in drying box.
2. after taking Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract mixing, it is mixed to obtain extract
Close object；
3. rhamnose/polyvinyl alcohol and 80g the distilled water mixing for taking 10g steps 1 to be prepared, and 6g is added at room temperature
Extract mixtures stir evenly, ultrasonic 30min, so that it is uniformly mixed, then in 175 DEG C of inlet temperature, feed rate 3mL/
It is spray-dried under the conditions of min, nozzle head diameter 0.7mm and 2 times/min of nozzle cleaning, obtains component B.
The extracting method of the Radix Stemonae extract and phellodendron extract is as follows：
1. choosing 1 part of tuber of stemona root and 1 part of Cortex Phellodendri bark, clean, after drying is ground, 10 parts of milk of limes is added and stir evenly
Afterwards, it is put into after being impregnated 6 hours with limewash in percolator, takes percolate, percolate volume 120% is added, citric acid saturation is added
Aqueous solution is stood overnight after stirring, filters to take precipitation；
2. by precipitating with after hot water dissolving, filter while hot, take filtrate, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object crude product；
It is filtered while hot 3. crude product is added to after being dissolved in boiling water, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object.
The preparation method of the capillary extract is as follows：
1. choosing 10 parts of oriental wormwood, after being decocted 4 hours with water, filtering obtains Aqueous extracts；
After 2. Aqueous extracts are then concentrated into 1/4 volume, extracted with chloroform；
3. choosing chloroform extract liquor, then sodium hydroxide is chosen with 5% sodium bicarbonate and 2% sodium hydroxide extraction respectively
After extracting solution, after being acidified with hydrochloric acid, continue to use chloroform recovery；
4. choosing chloroform extracted solution, after recycling chloroform, by acidic moiety through polyamide column chromatography, with ethyl alcohol, (concentration is distinguished
For 30%, 50% and 80%) gradient elution；
5. choosing 80% concentration ethanol elutes position, then heating volatilization ethyl alcohol, after being extracted with ether, recycling ether extraction
Liquid recycles ether, obtains white solid, you can capillary extract is prepared.
The tannin is nutgall acid.
The weight ratio of the component A, B component and component C is 8：8：1.
In component A, the surfactant, nanometer coral calcium powder, sodium citrate, chelating agent weight ratio be 1：1：0.5：
0.01。
In B component, the Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract weight ratio be 1：
1：1：1.
Embodiment 4：
A kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent, the raw material for preparing of the cleaning agent include：
Component A：Surfactant, nanometer coral calcium powder, sodium citrate, chelating agent；
B component：Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract；
Component C：Tannin.
It according to weight ratio is 1 that the surfactant, which is Tween-60 and neopelex,：2 mixture.
The preparation method of the polysaccharide-modified nanometer coral calcium powder is as follows：
1. at ambient temperature, instilling a small amount of deionized water into nanometer coral calcium powder, supersonic oscillations is used in combination to handle
After keep its evenly dispersed；
2. in aqueous solution by polysaccharide dispersion, being prepared into a concentration of 3% polysaccharide solution；
3. under ultrasound condition, polysaccharide solution is gradually dropped in the nanometer coral calcium slurry liquid of step 1, is added dropwise
Afterwards, continue to be ultrasonically treated after ten minutes, mixed liquor is placed in after being freezed 12 hours at subzero 80 DEG C, then freeze-dried
Polysaccharide-modified nanometer coral calcium powder is prepared.
Wherein, the weight ratio of polysaccharide and nanometer coral calcium powder is 1：2.
The chelating agent is tetrasodium ethylenediamine tetraacetate.
The preparation method of the component B is as follows：
1. 1.5g rhamnoses are dissolved in the acetic acid aqueous solution of 100mL 2%, magnetic stirrer dissolving；1g polyethylene
Alcohol is dissolved in 30mL water, and heating makes it dissolve；Above-mentioned rhamnose, poly-vinyl alcohol solution are uniformly mixed, 50 DEG C of water-baths
48h takes the silica gel 1.6-2.8g that 200-300 mesh is added in 40mL mixed solutions to pour into glass plate, room temprature evaporation film forming.It is done
Dry film immerses the sodium hydroxide solution of 2mol/L, and 50 DEG C of water-bath 2h dissolve silica gel, rhamnose/polyvinyl alcohol is made.With 5%
In acetic acid and extra sodium hydroxide, deionized water is rinsed to neutrality, dry in drying box.
2. after taking Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract mixing, it is mixed to obtain extract
Close object；
3. rhamnose/polyvinyl alcohol and 80g the distilled water mixing for taking 10g steps 1 to be prepared, and 6g is added at room temperature
Extract mixtures stir evenly, ultrasonic 30min, so that it is uniformly mixed, then in 175 DEG C of inlet temperature, feed rate 3mL/
It is spray-dried under the conditions of min, nozzle head diameter 0.7mm and 2 times/min of nozzle cleaning, obtains component B.
The extracting method of the Radix Stemonae extract and phellodendron extract is as follows：
1. choosing 1 part of tuber of stemona root and 1 part of Cortex Phellodendri bark, clean, after drying is ground, 10 parts of milk of limes is added and stir evenly
Afterwards, it is put into after being impregnated 6 hours with limewash in percolator, takes percolate, percolate volume 120% is added, citric acid saturation is added
Aqueous solution is stood overnight after stirring, filters to take precipitation；
2. by precipitating with after hot water dissolving, filter while hot, take filtrate, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object crude product；
It is filtered while hot 3. crude product is added to after being dissolved in boiling water, you can Radix Stemonae extract and Cortex Phellodendri extraction is prepared
Object.
The preparation method of the capillary extract is as follows：
1. choosing 10 parts of oriental wormwood, after being decocted 4 hours with water, filtering obtains Aqueous extracts；
After 2. Aqueous extracts are then concentrated into 1/4 volume, extracted with chloroform；
3. choosing chloroform extract liquor, then sodium hydroxide is chosen with 5% sodium bicarbonate and 2% sodium hydroxide extraction respectively
After extracting solution, after being acidified with hydrochloric acid, continue to use chloroform recovery；
4. choosing chloroform extracted solution, after recycling chloroform, by acidic moiety through polyamide column chromatography, with ethyl alcohol, (concentration is distinguished
For 30%, 50% and 80%) gradient elution；
5. choosing 80% concentration ethanol elutes position, then heating volatilization ethyl alcohol, after being extracted with ether, recycling ether extraction
Liquid recycles ether, obtains white solid, you can capillary extract is prepared.
The tannin is nutgall acid.
The weight ratio of the component A, B component and component C is 1：1：1.
In component A, the surfactant, nanometer coral calcium powder, sodium citrate, chelating agent weight ratio be 1：1：0.5：
0.01。
In B component, the Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract weight ratio be 1：
1：1：1.
Embodiment 5：The specific implementation mode of embodiment 5 is the same as embodiment 1, difference, the nanometer coral calcium powder warp
It crosses modified.
Embodiment 6：The specific implementation mode of embodiment 6 is with embodiment 1, and difference, the component B is without release membranes
Cladding.
Embodiment 7：The specific implementation mode of embodiment 7 is the same as embodiment 1, difference, the Radix Stemonae extract and Cortex Phellodendri
The extracting method of extract is as follows：
1. choosing 1 part of tuber of stemona root and 1 part of Cortex Phellodendri bark, clean, after drying is ground, 10 parts of milk of limes is added and stir evenly
Afterwards, it is put into after being impregnated 6 hours with limewash in percolator, takes percolate, percolate volume 7% is added, sodium chloride, stirring is added
After stand overnight, filter to take precipitation；
2. by precipitating with after hot water dissolving, filter while hot, take filtrate, it is 2 to add hydrochloric acid tune pH-value, is stood overnight, and is filtered
Precipitation is taken,
3. sediment is aqueous to neutral, it after draining, dries at room temperature, you can crude product is prepared；
It is filtered while hot 4. crude product is added to after being dissolved in boiling water, takes filtrate, it is 2 that concentrated hydrochloric acid to pH-value, which is added dropwise, and it is heavy to take
It forms sediment, is washed to neutrality, you can obtain fine work.
Embodiment 8：The specific implementation mode of embodiment 8 does not have nanometer coral with embodiment 1, difference, the component A
Calcium powder.
Embodiment 9：The specific implementation mode of embodiment 9 prepares raw material with embodiment 1, difference, the cleaning agent
Without component C.
Embodiment 10：The specific implementation mode of embodiment 10 is polyethylene with embodiment 1, difference, the release membranes
Alcohol.
Performance test
Test 1：Detergency test：
1) preparation of artificial dirt
Mix oil formula：With butter, lard, vegetable oil mass ratio for 0.5:0.5:1 prepares, and its gross mass 5% is added
Glycerin monostearate, this is artificial dirt.
Artificial dirt is set and is heated to 180 DEG C on electric furnace, stirring keeps this temperature 10min, and beaker is moved to electromagnetic agitation
Device stirs, and it is spare to naturally cool to required temperature.Temperature of defiling recommends reference：When room temperature is 20 DEG C, 80 DEG C of oil temperature is needed；Room temperature
When being 25 DEG C, 45 DEG C of oil temperature is needed；When room temperature is less than 17 DEG C or higher than 27 DEG C, experiment should not carry out, and need to carry out in air conditioning room.
The Terg-O-Tometer of attached refrigerating plant should be used when necessary.
2) preparation of dirty piece
Glass slide (110cm × 110cm) upper edge is drawn into 100cm lines, limitation is defiled below this line to show；By glass slide
Lower edge draws 50cm lines, to show the extra greasy dirt limitation of wiping below this line.
3) newly purchase glass slide needs after boiling 15min in water, and clear water, which is washed to not hanging droplet and set in acid wash liquid again, to be soaked
After steeping 1h, clear water rinsing and distilled water flushing are set spare after drying box is dried.
4) it defiles
Clean glass slide is set for one group in weighing frame with four, is precisely weighed with assay balance and is (accurately to 1mg)
m0, the glass slide after weighing is sandwiched on film airing stand one by one, clip should be clipped in glass slide ascender line or more, and film airing stand is set and wards off disk
Interior preparation is defiled.
When greasy dirt is maintained at determining temperature, glass slide is removed together with clip from film airing stand one by one, holds clip
Glass slide is immersed in greasy dirt to (1-2) s below 100cm ascender lines, is slowly taken out, after drop slows under greasy dirt, is hung back
Dirty piece is originally sequentially prepared on film airing stand.After greasy dirt solidification, by dirty piece remove with filter paper or absorbent cotton by under dirty piece along 50cm
The extra greasy dirt in bottom edge and both sides is wiped, then the absorbent cotton wiped clean of petroleum ether is speckled with tweezers folder.After hanging 4h at room temperature,
With assay balance accurate weighing it is m in weighing frame1.Every at this time group of dirt on piece dirt amount should ensure that (5 ± 0.5) g.
5) test procedure
The glass slide of the known amount of defiling is washed using same amount of embodiment 1-10 and commercial detergent, along load
One direction of slide, it is unidirectional that glass slide is wiped, after wiping 10 times, glass slide is placed in clear water, stands 5 points
It is taken out after clock, dries, weigh as m2。
6) result indicates：Remove oil cut rate ω=(m1-m2)/(m1-m0) × 100%.
In formula：m0Glass slide quality before defiling, g；m1Glass slide quality after defiling, g；m2The quality of dirty piece after washing,
g。
Table 1 removes oil cut rate test table
In the present invention, the commercial detergent is white cat lemon black tea liquid detergent of the purchase from supermarket.
Test 2：Spot reprecipitation is tested：
Dirty piece preparation manipulation again will be carried out after washing in test 1, dirt rate and oil cut rate is gone again in calculatings.
Again dirty piece preparation manipulation：
Clean glass slide is set for one group in weighing frame with four, is precisely weighed with assay balance and is (accurately to 1mg)
m0', the glass slide after weighing is sandwiched on film airing stand one by one, clip should be clipped in glass slide ascender line or more, and film airing stand is set and is warded off
Prepare to defile in disk.
When greasy dirt is maintained at determining temperature, glass slide is removed together with clip from film airing stand one by one, holds clip
Glass slide is immersed in greasy dirt to (1-2) s below 100cm ascender lines, is slowly taken out, after drop slows under greasy dirt, is hung back
Dirty piece is originally sequentially prepared on film airing stand.After greasy dirt solidification, by dirty piece remove with filter paper or absorbent cotton by under dirty piece along 50cm
The extra greasy dirt in bottom edge and both sides is wiped, then the absorbent cotton wiped clean of petroleum ether is speckled with tweezers folder.After hanging 4h at room temperature,
With assay balance accurate weighing it is m in weighing frame1'.It need not ensure that every group of dirt on piece dirt amount is (5 ± 0.5) g at this time.
Upper dirt rate=(m1’-m0’)/(m1-m0) × 100%.
The freshly prepd dirty piece of weight is carried out to the operation of test procedure in test 1 simultaneously, it is m to obtain quality2’。
Oil cut rate is gone again：ω '=(m1'-m2’)/(m1'-m0') × 100%.
Table 2 removes oil cut rate test table again
Test 3：Detergency performance test carries out the performance test of detergency referring generally to the requirement of standard GB 9985.
3 detergency performance test of table
| Embodiment | Detergency, % |
| Embodiment 1 | 91.3 |
| Embodiment 2 | 81.5 |
| Embodiment 3 | 75.2 |
| Embodiment 4 | 73.5 |
| Embodiment 5 | 52.0 |
| Embodiment 6 | 61.1 |
| Embodiment 7 | 72.1 |
| Embodiment 8 | 45.5 |
| Embodiment 9 | 62.9 |
| Embodiment 10 | 68.7 |
| Commercial detergent | 30.1 |
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of super Strong cleaning strengths nanometer coral calcium powder cleaning agent, which is characterized in that the raw material for preparing of the cleaning agent includes：
Component A：Surfactant, nanometer coral calcium powder, sodium citrate, chelating agent；
B component：Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract；
Component C：Tannin.
2. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 1, which is characterized in that the nanometer coral
Calcium powder is polysaccharide-modified coral calcium powder.
3. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 2, which is characterized in that the polysaccharide is fruit
Glue.
4. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 1, which is characterized in that the tannin is water
Solve class tannin.
5. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 1, which is characterized in that the component B is logical
Release membranes are crossed to be coated.
6. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 5, which is characterized in that the release membranes are
Modified rhamnose.
7. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 1, which is characterized in that the surface-active
Agent is nonionic surfactant.
8. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 1, which is characterized in that according to parts by weight
The weight ratio of meter, the component A and B component is (1-3)：1.
9. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 1, which is characterized in that the B component
Preparation method is as follows：
1.5g rhamnoses are dissolved in the acetic acid aqueous solution of 100mL 2% by S01, magnetic stirrer dissolving；1g polyvinyl alcohol
It is dissolved in 30mL water, heating makes it dissolve；Above-mentioned rhamnose, poly-vinyl alcohol solution are uniformly mixed, 50 DEG C of water-bath 48h,
The silica gel 1.6-2.8g that 200-300 mesh is added in 40mL mixed solutions is taken to pour into glass plate, room temprature evaporation film forming.Obtain drying
Film immerses the sodium hydroxide solution of 2mol/L, and 50 DEG C of water-bath 2h dissolve silica gel, rhamnose/polyvinyl alcohol is made.With 5% acetic acid
Neutralize extra sodium hydroxide, deionized water is rinsed to neutrality, dry in drying box.
After S02 takes Radix Stemonae extract, phellodendron extract, radish seed extract, capillary extract mixing, extract mixing is obtained
Object；
S03 takes rhamnose/polyvinyl alcohol that 10g steps 1 are prepared and the mixing of 80g distilled water, and 6g is added at room temperature and carries
Object mixture is taken, is stirred evenly, ultrasonic 30min makes it be uniformly mixed, then in 175 DEG C of inlet temperature, feed rate 3mL/
It is spray-dried under the conditions of min, nozzle head diameter 0.7mm and 2 times/min of nozzle cleaning, obtains component B.
10. a kind of superpower cleaning strength nanometer coral calcium powder cleaning agent described in claim 9, which is characterized in that the tuber of stemona carries
Take the extracting method of object and phellodendron extract as follows：
(1) 1 part of tuber of stemona root and 1 part of Cortex Phellodendri bark are chosen, is cleaned, after drying is ground, after 10 parts of milk of limes of addition stir evenly,
It is put into after being impregnated 6 hours with limewash in percolator, takes percolate, percolate volume 120% is added, citric acid saturated water is added
Solution is stood overnight after stirring, filters to take precipitation；
(2) it will precipitate with after hot water dissolving, filter while hot, take filtrate, you can Radix Stemonae extract and phellodendron extract is prepared
Crude product；
(3) crude product is added to after being dissolved in boiling water and is filtered while hot, you can Radix Stemonae extract and phellodendron extract is prepared.
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