[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CN108483749A - A kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit - Google Patents

A kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit Download PDF

Info

Publication number
CN108483749A
CN108483749A CN201810606444.8A CN201810606444A CN108483749A CN 108483749 A CN108483749 A CN 108483749A CN 201810606444 A CN201810606444 A CN 201810606444A CN 108483749 A CN108483749 A CN 108483749A
Authority
CN
China
Prior art keywords
feed liquid
high temperature
reaction
zone
dedicated unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810606444.8A
Other languages
Chinese (zh)
Inventor
李力成
李东
花泽林
赵学娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Forestry University
Original Assignee
Nanjing Forestry University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Forestry University filed Critical Nanjing Forestry University
Priority to CN201810606444.8A priority Critical patent/CN108483749A/en
Publication of CN108483749A publication Critical patent/CN108483749A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit, this method:Temperature carries out reaction precipitation higher than 35 DEG C of feed liquid by pyroreaction settler, is then separated by solid-liquid separation through filter device, obtains turbidity and is less than 1NTU treated feed liquid and solid matter;Wherein, pyroreaction settler is made of reaction zone and settling zone, reaction zone is made of concatenated 1 or more reaction tank, feed liquid enters from reaction zone, under being stirred of blender, it is reacted with the medicament of addition, the material after reaction is flowed out by settling zone, and reaction zone and settling zone are closed.The present invention can carry out high-temperature material continuous reaction precipitation filter operation, obtain the discharging that turbidity is less than 1NTU.Method is simple, and operation is easy, at low cost, efficient, dedicated unit, simple in structure, high temperature resistant, and the temperature being widely used in chemical field is higher than 35 DEG C of feed liquid, can realize that continuous precipitation is filtered.

Description

A kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit
Technical field
The invention belongs to chemical industry high-temperature materials to precipitate filtration art, be related to a kind of liquid material processing system and dress It sets, and in particular to a kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit.
Background technology
Reaction precipitation and filter process are a significant process of wastewater treatment and Chemical Manufacture.Current most of reactions It is all to carry out at normal temperatures to precipitate filter process, and the selection of equipment and material is relatively easy to.However, the temperature when material is more than 35 After DEG C, traditional organic membrane filter process can not be applied, and the material of high temperature is to reacting corrosion and the heat of settling apparatus Release is all so that room temperature equipment can not be applied.
Invention content
Goal of the invention:For the deficiencies in the prior art, the object of the present invention is to provide a kind of high temperature feed liquid is continuous Filter method is precipitated, continuous reaction precipitation filter operation can be carried out to high-temperature material, obtains the discharging that turbidity is less than 1NTU. It is a further object of the present invention to provide a kind of dedicated units of above-mentioned high temperature feed liquid continuous precipitation filter method.
Technical solution:In order to achieve the above-mentioned object of the invention, the technical solution adopted by the present invention is:
A kind of high temperature feed liquid continuous precipitation filter method, temperature higher than 35 DEG C feed liquid by pyroreaction settler into Row reaction precipitation, is then separated by solid-liquid separation through filter device, obtains turbidity less than 1NTU treated feed liquid and solids Matter;Wherein, pyroreaction settler is made of reaction zone and settling zone, and reaction zone is made of concatenated 1 or more reaction tank, Feed liquid enters from reaction zone, under being stirred of blender, is reacted with the medicament of addition, and the material after reaction is by heavy Shallow lake area is flowed out, and reaction zone and settling zone are closed.
The temperature of the high temperature feed liquid continuous precipitation filter method, feed liquid is higher than 35 DEG C, is less than 150 DEG C.
The dedicated unit of the high temperature feed liquid continuous precipitation filter method, including pyroreaction settler and filtering fill It sets;The pyroreaction settler includes pyroreaction sedimentation basin, chemicals dosing plant and mud discharging device;Chemicals dosing plant and spoil disposal Device is connected with pyroreaction sedimentation basin.
The pyroreaction sedimentation basin is made of reaction zone and settling zone, and feed liquid enters from reaction zone, by settling zone Outflow, reaction zone are made of concatenated 1 or more reaction tank.
The reaction zone and settling zone is closed.
The equal high temperature resistant of reaction zone and settling zone, material are selected from metal or high molecular material and metal and high score The composite of sub- material.
The reaction tank is equipped with blender.
The settling zone is vertical-flow, the secondary flow formula using flat flow, ramp type, one kind in inclined tube-type or it is a kind of with On combination sedimentation basin.
The filter device uses membrane filtration, and film is selected from ceramic micro filter film, ceramic super-filtering film, and one in metal micro-filtration membrane Kind or two or more.
The mud discharging device is made of sludge pump and dewaterer.
Advantageous effect:Compared with prior art, high temperature feed liquid continuous precipitation filter method and its dedicated unit of the invention, Continuous reaction precipitation filter operation can be carried out to high-temperature material, obtain the discharging that turbidity is less than 1NTU.Method is simple, operation It is easy, at low cost, efficient, the temperature being widely used in chemical field is higher than 35 DEG C of feed liquid, can realize continuous precipitation Filtering.Dedicated unit, simple in sturcture, ingenious in design, high temperature resistant improve reaction efficiency using cascade reaction pond, it is ensured that reaction is filled Point, it is conducive to the progress of reaction, there is good practicability.
Description of the drawings
Fig. 1 is high-temperature material continuous precipitation filter device schematic diagram;
Fig. 2 is the structural schematic diagram of pyroreaction sedimentation basin.
Specific implementation mode
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
As depicted in figs. 1 and 2, the dedicated unit of high temperature feed liquid continuous precipitation filter method, can be used for high-temperature material (feed temperature is higher than 35 DEG C, is less than 150 DEG C) carries out continuous reaction precipitation filter operation, obtains turbidity going out less than 1NTU Material, is mainly made of pyroreaction settler and filter device.High temperature feed liquid is reacted by pyroreaction settler Precipitation, is then separated by solid-liquid separation through filter device, obtain that treated feed liquid and solid matter.Pyroreaction settler by Pyroreaction sedimentation basin 1, chemicals dosing plant 2, mud discharging device 3 form.Wherein, pyroreaction sedimentation basin 1 is by reaction zone 11 and precipitation Area 12 forms, and feed liquid enters from reaction zone 11, is flowed out by settling zone 12.Reaction zone 11 and settling zone 12 use hermetic design (being both provided with cover board 13), material can be the composites of metal, high molecular material and metal and high molecular material.Instead Area 11 is answered to be made of concatenated reaction tank, reaction tank can be 1 or 1 or more, and reaction tank is equipped with blender 14.Settling zone It is vertical-flow using flat flow, secondary flow formula, ramp type, one or more than one kinds of combination sedimentation basins in inclined tube-type.Dosing fills It includes hydrochloric acid, sulfuric acid, caustic soda, magnesium hydroxide, magnesia, lime, sodium carbonate, flocculant, calcium chloride, sulfuric acid to set the medicament in 2 Calcium, gypsum, one or more kinds of combinations in activated carbon.Mud discharging device 3 is made of sludge pump and dewaterer.Filter device Using membrane filtration, ceramic micro filter film is selected, ceramic super-filtering film, one or more than one kinds of combinations in metal micro-filtration membrane.
High temperature feed liquid continuous precipitation filter method is carried out using above-mentioned dedicated unit:Charging of the feed temperature higher than 35 DEG C passes through It crosses pyroreaction settling system and carries out reaction precipitation, be then separated by solid-liquid separation through filtration system, obtain turbidity less than 1NTU's Feed liquid that treated and solid matter.Pyroreaction sedimentation basin 1 is made of reaction zone and settling zone, and reaction zone is by concatenated reaction Pond forms, and feed liquid enters from reaction zone, and under being stirred of blender, the medicament being added with chemicals dosing plant is reacted, instead Material after answering is flowed out by settling zone, and reaction zone and settling zone are all made of hermetic design, to avoid heat loss.
Embodiment 2
Certain 90 DEG C wastewater from chemical industry is handled using the dedicated unit and method of embodiment 1, process is as follows:
Wastewater from chemical industry water quality is as shown in table 1, which enters the reaction zone of pyroreaction sedimentation basin, and the reaction zone is by three Reaction tank is composed in series, the lime being added with chemicals dosing plant, sodium carbonate, and flocculant is sufficiently mixed simultaneously under blender stirring Reaction, the waste water after reaction enter inclined tube-type sedimentation basin, and precipitation, which is discharged from bottom and passes through dehydration, forms solid, and clear liquid is from high temperature Reaction settling basin top is flowed out, and subsequently into ceramic micro filter membrane filtration system, finally obtains the clear liquid of turbidity 0.5NTU.
1 wastewater from chemical industry water quality table of table
Project Flooding parameter Parameter after processing
Temperature 90℃ 80℃
pH 7.6 10
Suspended matter 50mg/L /
Soluble solid 23000mg/L 23500mg/L
Carbonate hardness is (with CaCO3Meter) 800mg/L 80mg/L
Cod codcr 200mg/L 180mg/L
Turbidity / 0.5NTU
Embodiment 3
So-and-so 70 DEG C of salt chemical engineering brine is handled using the dedicated unit and method of embodiment 1, process is as follows:
Certain 70 DEG C salt chemical engineering brine water quality is as shown in table 2, which enters the reaction zone of pyroreaction sedimentation basin, this is anti- Area is answered to be composed in series by two reaction tanks, the gypsum being added with chemicals dosing plant, flocculant is fully mixed under blender stirring Merge reaction, the waste water after reaction enters rectangular sedimentation tank, and precipitation, which is discharged from bottom and passes through dehydration, forms solid, clear liquid from Pyroreaction sedimentation basin top is flowed out, and subsequently into Ceramic excessive filtration membrane filtration system, finally obtains the clear liquid of turbidity 0.1NTU.
2 salt chemical engineering brine water quality table of table
Project Influent concentration Concentration after processing
Temperature 70℃ 55℃
pH 7 9
Suspended matter 20mg/L /
NaCl 296000mg/L 294800mg/L
Na2SO4 32000mg/L 35000mg/L
Ca2+ 300mg/L 20mg/L
Mg2+ 190mg/L 10mg/L
Cod codcr 60mg/L 40mg/L
Turbidity / 0.1NTU
Embodiment 4
Certain 108 DEG C wastewater from chemical industry is handled using the dedicated unit and method of embodiment 1, process is as follows:
Wastewater from chemical industry water quality is as shown in table 3, which enters the reaction zone of pyroreaction sedimentation basin, and the reaction zone is by three Reaction tank is composed in series, the calcium chloride being added with chemicals dosing plant, and flocculant is sufficiently mixed and is reacted under blender stirring, Waste water after reaction enters inclined tube-type sedimentation basin, and precipitation, which is discharged from bottom and passes through dehydration, forms solid, and clear liquid is from pyroreaction Sedimentation basin top is flowed out, and subsequently into ceramic micro filter membrane filtration system, finally obtains the clear liquid of turbidity 0.3NTU.
3 wastewater from chemical industry water quality table of table

Claims (10)

1. a kind of high temperature feed liquid continuous precipitation filter method, which is characterized in that feed liquid of the temperature higher than 35 DEG C passes through pyroreaction Settler carries out reaction precipitation, is then separated by solid-liquid separation through filter device, obtain turbidity less than 1NTU treated material Liquid and solid matter;Wherein, pyroreaction settler is made of reaction zone and settling zone, and reaction zone is by concatenated 1 or more Reaction tank forms, and feed liquid enters from reaction zone, under being stirred of blender, is reacted with the medicament of addition, after reaction Material flowed out by settling zone, reaction zone and settling zone are closed.
2. high temperature feed liquid continuous precipitation filter method according to claim 1, which is characterized in that the temperature of feed liquid is higher than 35 DEG C, it is less than 150 DEG C.
3. the dedicated unit of high temperature feed liquid continuous precipitation filter method described in claim 1, which is characterized in that anti-including high temperature Answer settler and filter device;The pyroreaction settler includes pyroreaction sedimentation basin (1), chemicals dosing plant (2) With mud discharging device (3);Chemicals dosing plant (2) and mud discharging device (3) are connected with pyroreaction sedimentation basin (1).
4. the dedicated unit of high temperature feed liquid continuous precipitation filter method according to claim 3, which is characterized in that described Pyroreaction sedimentation basin (1) is made of reaction zone (11) and settling zone (12), and feed liquid enters from reaction zone (11), by settling zone (12) it flows out, reaction zone (11) is made of concatenated 1 or more reaction tank.
5. the dedicated unit of high temperature feed liquid continuous precipitation filter method according to claim 4, which is characterized in that described Reaction zone and settling zone are closed.
6. the dedicated unit of high temperature feed liquid continuous precipitation filter method according to claim 4, which is characterized in that described The equal high temperature resistant of reaction zone and settling zone, material are selected from the composite wood of metal or high molecular material and metal and high molecular material Matter.
7. the dedicated unit of high temperature feed liquid continuous precipitation filter method according to claim 4, which is characterized in that described Reaction tank is equipped with blender.
8. the dedicated unit of high temperature feed liquid continuous precipitation filter method according to claim 4, which is characterized in that described Settling zone is vertical-flow, the secondary flow formula using flat flow, ramp type, one or more kinds of combination sedimentation basins in inclined tube-type.
9. the dedicated unit of high temperature feed liquid continuous precipitation filter method according to claim 3, which is characterized in that described Filter device uses membrane filtration, and film is selected from ceramic micro filter film, ceramic super-filtering film, one kind in metal micro-filtration membrane or two or more.
10. the dedicated unit of high temperature feed liquid continuous precipitation filter method according to claim 3, which is characterized in that described Mud discharging device (3) be made of sludge pump and dewaterer.
CN201810606444.8A 2018-06-12 2018-06-12 A kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit Pending CN108483749A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810606444.8A CN108483749A (en) 2018-06-12 2018-06-12 A kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810606444.8A CN108483749A (en) 2018-06-12 2018-06-12 A kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit

Publications (1)

Publication Number Publication Date
CN108483749A true CN108483749A (en) 2018-09-04

Family

ID=63342882

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810606444.8A Pending CN108483749A (en) 2018-06-12 2018-06-12 A kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit

Country Status (1)

Country Link
CN (1) CN108483749A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103739124A (en) * 2014-01-24 2014-04-23 太平洋水处理工程有限公司 Efficient water treatment device and water treatment method
CN204752298U (en) * 2015-07-06 2015-11-11 江苏德邦工程有限公司 High density depositing reservoir
CN205473060U (en) * 2016-01-05 2016-08-17 宜兴市永创环保科技有限公司 Multi -functional effluent treatment plant of integration
CN206467021U (en) * 2017-02-21 2017-09-05 陕西兴华环保科技有限公司 A kind of rapid sedimentation tank
CN206538270U (en) * 2017-01-10 2017-10-03 杭州贝思特节能环保科技有限公司 A kind of flocculation softening plant of waste water of heat-engine plant processing

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103739124A (en) * 2014-01-24 2014-04-23 太平洋水处理工程有限公司 Efficient water treatment device and water treatment method
CN204752298U (en) * 2015-07-06 2015-11-11 江苏德邦工程有限公司 High density depositing reservoir
CN205473060U (en) * 2016-01-05 2016-08-17 宜兴市永创环保科技有限公司 Multi -functional effluent treatment plant of integration
CN206538270U (en) * 2017-01-10 2017-10-03 杭州贝思特节能环保科技有限公司 A kind of flocculation softening plant of waste water of heat-engine plant processing
CN206467021U (en) * 2017-02-21 2017-09-05 陕西兴华环保科技有限公司 A kind of rapid sedimentation tank

Similar Documents

Publication Publication Date Title
CN102849879A (en) Treatment technology for recycling reverse osmosis concentrated water
CN204824453U (en) Desulfurization pretreatment of water device that gives up
CN208814790U (en) A kind of concentration strong brine softening of steel wastewater removes hard processing unit
CN104973717A (en) Saline wastewater deep treatment method
CN212450783U (en) Sewage treatment system for removing silicon and hardness
CN105036408A (en) Treatment method of wastewater containing high-concentration active silicon
CN109851139B (en) High-salt wastewater softening and concentrating device and method
JP2009072769A (en) Sewage treatment system
CN207713466U (en) A kind of electric flocculation high dense settling pond
CN107758941B (en) Green energy-saving desulfurization wastewater treatment system
CN112321020A (en) Efficient pretreatment system and method for circulating water sewage
CN207121501U (en) A kind of hardness removing device suitable for the hard waste water of high magnesium
CN111484149A (en) High-efficiency hardness removing device and method for high-concentration industrial waste liquid treatment
CN208561975U (en) A kind of high temperature feed liquid continuous precipitation filter device
CN109110967B (en) Bauxite beneficiation wastewater recycling system and method based on membrane chemical reactor
CN108483749A (en) A kind of high temperature feed liquid continuous precipitation filter method and its dedicated unit
CN207738544U (en) A kind of desulfurization wastewater sofening treatment device
CN212356743U (en) High-concentration industrial waste liquid treatment is with high-efficient device that removes hard
CN215559636U (en) Wastewater treatment system
CN215975369U (en) High salt waste water salt separation crystallization system that contains
CN214141973U (en) Treatment device for leachate
CN214060181U (en) Contain thallium desulfurization advanced wastewater treatment device
CN210915681U (en) High-salt and high-organic-matter wastewater treatment system
CN115259507A (en) Processing device for flowback liquid
CN206886880U (en) A kind of processing system containing high-salt wastewater

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination