CN107955763A - A kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent and preparation method thereof - Google Patents
A kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent and preparation method thereof Download PDFInfo
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- CN107955763A CN107955763A CN201711356214.2A CN201711356214A CN107955763A CN 107955763 A CN107955763 A CN 107955763A CN 201711356214 A CN201711356214 A CN 201711356214A CN 107955763 A CN107955763 A CN 107955763A
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- fish oil
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- shayu
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent and preparation method thereof, belong to detergent technical field.The present invention is using Ba Shayu as raw material, Ba Sha fish oil is made after being refined by enzymolysis, and embedded with whey protein isolate, improve its oxidizable decomposition, produce aldehyde, the problem of harmful material such as ketone, and improve fish oil water solubility, improve stability, Ba Sha fish oil fatty acid potash soaps are made as principal surfactant through saponification again, compounded with alkyl glycosides and fatty alcohol polyoxyethylene ether 9, fish oil base natural environmental-protective fruits and vegetables dish washing detergent is made in addition natural antibacterial agent and deionized water, raw materials used natural environmental-protective, the body skin of people will not be damaged, the discharge of washes will not cause environmental pollution.
Description
Technical field
The present invention relates to a kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent and preparation method thereof, belong to detergent technology
Field.
Background technology
The main component of detergent is active component and helper component, has certain dirt-removing power.Surfactant is
Main active material, and help to improve detergent scourability is to play a series of of different synergistic effects in component
Helper component.Detergent mainly includes synthetic detergent powder, liquid detergent and fertilizer（It is fragrant）3 class of soap, it is all kinds of all by different series
Product form.As the improvement of people's living standards, the continuous development of science and technology and petroleum chemical industry, the demand of detergent
Amount constantly increase, industry are rapidly developed.
The continuous improvement of living standard, also allows people more to focus on the sustainable developability of Betengent product, high concentration
Concentrated type detergent and environmentally protective environmentally friendly detergent enjoy the favor of consumer, the development of the detergent of this two class
By as one of main trend of detergent future development.
The main ingredient of fish oil is triglyceride, phosphorus glycerin ether, lipoid, liposoluble vitamin, and protein degradation thing
Deng.Do not measure mercury, arsenic, lead noxious material in the fish body of fish, and potassium, copper, aluminium, cadmium etc. are below hygienic permissible value, pesticide
Residual quantity is also no better than zero, thus the quality as grease is reliable with fish and its discarded object processing gained fish oil, with it
His grease is the same, and fish oil can also be used for carrying out saponification, in being produced applied to daily use chemicals.Have what species was enriched currently on the market
Fruits and vegetables dish washing detergent, and in existing production technology, most of Cleaning preparations are all artificial synthesized, the uses of such detergent
Certain injury can be not only caused to the body skin of people, the discharge of washes will also result in environmental pollution, therefore this area
There is still a need for more healthy environmentally friendly fruits and vegetables dish washing detergent.
The content of the invention
The technical problems to be solved by the invention：For in existing production technology, most of Cleaning preparations are all manually to close
Into, the use of such detergent can not only cause the body skin of people certain injury, and the discharge of washes can also make
Into the problem of environmental pollution, there is provided a kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent and preparation method thereof.
In order to solve the above technical problems, the technical solution adopted by the present invention is：
The detergent is made of following weight parts raw material：
20 ~ 30 parts of Ba Sha fish oil fatty acid potash soaps, 5 ~ 10 parts of alkyl glycosides, 3 ~ 5 parts of fatty alcohol polyoxyethylene ether -9,0.2 ~ 0.5
Part natural antibacterial agent, 55 ~ 75 parts of deionized waters.
The Ba Sha fish oil fatty acids potash soap is made by following methods：
（1）Fresh Ba Shayu cleaning internal organ are removed into impurity, and are drained after being washed with deionized, then are transferred to tissue mashing machine
Middle homogenate, which is smashed to pieces, to stir evenly, and obtains material liquid；
（2）Take material liquid and deionized water 1：1 mixing, and pH to 8.0 ~ 8.5 is adjusted, trypsase is added at 35 ~ 40 DEG C
3 ~ 4h is digested, centrifugation takes upper oil phase, obtains thick Ba Sha fish oil；
（3）Take lipase to add in thick Ba Sha fish oil, 3 ~ 4h of stirring reaction at 50 ~ 60 DEG C, add mass fraction for 70 ~
75% phosphoric acid solution, centrifuges after stirring 8 ~ 10min at 60 ~ 80 DEG C, takes upper strata fluid and add atlapulgite, and stirring 20 ~
Filter to get filtrate after 30min, dusty yeast is added into filtrate, centrifuge, take after 20 ~ 30min of stirring reaction at 40 ~ 50 DEG C
Liquid phase obtains Ba Sha fish oil；
（4）Take whey protein isolate to add in the phosphate buffer that pH value is 7.0 and stir 20 ~ 30min, then at 60 ~ 80 DEG C
Ba Sha fish oil is added while stirring, 3 ~ 5min is emulsified with 20000 ~ 24000r/min after addition, and followed under 60 ~ 80MPa
Ring homogenization 3 ~ 5 times, obtains Ba Shayu oil nanometer emulsions；
（5）Ba Shayu oil nanometer emulsions are taken to be uniformly mixed with mass fraction for 95% ethanol solution, it is 30% hydrogen to add mass fraction
Potassium oxide solution, stirring reaction is to sticky paste at 50 ~ 60 DEG C, then is placed in Poly Foam incubator 20 ~ 24h of inside holding, takes
Go out to be placed in ventilation to cure 2 ~ 3 weeks, obtain Ba Sha fish oil fatty acid potash soaps.
The trypsase dosage is the 2 ~ 8% of material liquid quality.
The fat enzyme dosage is the 6 ~ 24% of thick Ba Shayu oil qualities, and the phosphoric acid solution dosage is thick Ba Shayu oil
The 0.5 ~ 2.0% of amount, the atlapulgite dosage are the 10 ~ 40% of thick Ba Shayu oil qualities, and the dusty yeast dosage is thick Ba Sha
The 2.5 ~ 10.0% of fish oil quality.
The whey protein isolate dosage is the 12.5 ~ 50% of Ba Shayu oil qualities, and the phosphate buffer dosage is bar
10 times of shark oil quality.
The ethanol solution dosage is the 10 ~ 40% of Ba Shayu oil nanometer emulsion quality, and the potassium hydroxide solution dosage is bar
The 20 ~ 80% of shark oil nanometer emulsion quality.
The natural antibacterial agent is chitin, the one or more in mustard, castor oil, horseradish oil.
Compared with other methods, advantageous effects are the present invention：
（1）Ba Sha fish oil is made using Ba Shayu as raw material in the present invention after being refined by enzymolysis, and is embedded with whey protein isolate,
The problem of improving its oxidizable decomposition, producing the harmful material such as aldehyde, ketone, and improve fish oil water solubility, improve and stablize
Property, then Ba Sha fish oil fatty acids potash soap is made as principal surfactant through saponification, with alkyl glycosides and poly alkyl alcohol
Ethylene oxide ether -9 is compounded, and adds natural antibacterial agent and fish oil base natural environmental-protective fruits and vegetables dish washing detergent is made in deionized water,
Raw materials used natural environmental-protective, will not damage the body skin of people, and the discharge of washes will not cause environmental pollution；
（2）The fruits and vegetables dish washing detergent that on fruits and vegetables tableware prepared by the remaining present invention, Ba Shayu synthesis is utilized wherein containing
Butter oil, butter oil enter small intestine, and under pancreatic lipase effect, most of triglycerides is hydrolyzed into sn-2 monoglycerides and trip
From aliphatic acid, sn-2 monoglycerides are directly by intestinal absorption, and dystectic long-chain is satisfied in common fruits and vegetables dish washing detergent residue
Soap easily is combined to form with calcium and magnesium ion with aliphatic acid, causes energy and calcium to be lost, the adverse reactions such as constipation is produced, to people's
Body skin damages.
Embodiment
Fresh Ba Shayu cleaning internal organ are removed into impurity, and are drained after being washed with deionized, then are transferred to tissue mashing
Homogenate, which is smashed to pieces, in machine stirs evenly, and obtains material liquid, takes 100 ~ 200g material liquids, adds in 100 ~ 200g deionized waters, with 300 ~ 400r/
Min stirs 20 ~ 30min, and with mass fraction be 5% potassium hydroxide solution or mass fraction be 5% salt acid for adjusting pH to 8.0 ~
8.5,4 ~ 8g trypsase is added, digests 3 ~ 4h under water bath with thermostatic control at 35 ~ 40 DEG C, the mixed liquor after enzymolysis is loaded into centrifugation
10 ~ 15min is centrifuged in machine, upper oil phase is taken, obtains thick Ba Sha fish oil, takes 6 ~ 12g lipase, adds the thick Ba Sha of 50 ~ 100g
In fish oil, at 50 ~ 60 DEG C with 500 ~ 600r/min stir reaction 3 ~ 4h, be again heated to 110 ~ 120 DEG C of isothermal holdings 10 ~
15min, 0.5 ~ 1.0g mass fractions are 70 ~ 75% phosphoric acid solutions after being cooled to 60 ~ 80 DEG C, centrifuge and divide after 8 ~ 10min of insulated and stirred
From 10 ~ 15min, take upper strata fluid and add 10 ~ 20g atlapulgites, filter and must filter after stirring 20 ~ 30min at 50 ~ 60 DEG C
Liquid, 2.5 ~ 5.0g dusty yeasts are added into filtrate, and 10 ~ 15min is centrifuged after 20 ~ 30min of stirring reaction at 40 ~ 50 DEG C,
Take liquid phase to obtain Ba Sha fish oil, take 12.5 ~ 25.0g whey protein isolates, add the phosphate-buffered that 500 ~ 1000gpH values are 7.0
In liquid, 20 ~ 30min is stirred with 300 ~ 400r/min, then adds 50 ~ 100g Ba Sha fish oil while stirring at 60 ~ 80 DEG C, is added
After be transferred in high-speed shearing emulsion machine, 3 ~ 5min is emulsified with 20000 ~ 24000r/min, and circulate under 60 ~ 80MPa equal
Matter is handled 3 ~ 5 times, is obtained Ba Shayu oil nanometer emulsions, is taken 100 ~ 200g bars of shark oil nanometer emulsion, is 95% second with 20 ~ 40g mass fractions
Alcoholic solution is uniformly mixed, and it is 30% potassium hydroxide solution to add 40 ~ 80g mass fractions, is stirred and is reacted to viscous at 50 ~ 60 DEG C
Paste thing, then Poly Foam incubator 20 ~ 24h of inside holding is placed in, taking-up is placed in ventilation and cures 2 ~ 3 weeks, obtains Ba Shayu greases
Fat acid potash soap, takes 20 ~ 30g Ba Sha fish oil fatty acid potash soaps, 5 ~ 10g alkyl glycosides, and 3 ~ 5g fatty alcohol polyoxyethylene ether -9,0.2 ~
0.5g natural antibacterial agents, add 55 ~ 75g temperature as in 45 ~ 50 DEG C of deionized waters, 30 ~ 40min is stirred with 300 ~ 400r/min,
Obtain fish oil base natural environmental-protective fruits and vegetables dish washing detergent.
Example 1
Fresh Ba Shayu cleaning internal organ are removed into impurity, and are drained after being washed with deionized, then are transferred in tissue mashing machine
Homogenate, which is smashed to pieces, to stir evenly, and obtains material liquid, takes 100g material liquids, adds in 100g deionized waters, and 20min is stirred with 300r/min, and
With mass fraction be 5% potassium hydroxide solution or mass fraction be 5% salt acid for adjusting pH to 8.0,4g trypsase is added, 35
3h is digested under water bath with thermostatic control at DEG C, the mixed liquor after enzymolysis is fitted into centrifuge and centrifuges 10min, takes upper oil phase, is obtained
Thick Ba Sha fish oil, takes 6g lipase, adds in the thick Ba Sha fish oil of 50g, stirs reaction 3h with 500r/min at 50 DEG C, reheats
To 110 DEG C of isothermal holding 10min, 0.5g mass fractions are 70% phosphoric acid solution after being cooled to 60 DEG C, are centrifuged after insulated and stirred 8min
10min is separated, upper strata fluid is taken and adds 10g atlapulgites, is filtered to get filtrate after stirring 20min at 50 DEG C, into filtrate
2.5g dusty yeasts are added, 10min is centrifuged after stirring reaction 20min at 40 DEG C, takes liquid phase to obtain Ba Sha fish oil, take 12.5g
Whey protein isolate, adds in the phosphate buffer that 500gpH values are 7.0, and 20min is stirred with 300r/min, then at 60 DEG C
50g Ba Sha fish oil is added while stirring, is transferred to after addition in high-speed shearing emulsion machine, and 3min is emulsified with 20000r/min,
And homogenization 3 times is circulated under 60MPa, Ba Shayu oil nanometer emulsions are obtained, take 100g bars of shark oil nanometer emulsion, with 20g mass point
Number is uniformly mixed for 95% ethanol solution, and it is 30% potassium hydroxide solution to add 40g mass fractions, and reaction is stirred extremely at 50 DEG C
Sticky paste, then Poly Foam incubator inside holding 20h is placed in, taking-up is placed in ventilation and cures 2 weeks, obtains Ba Sha fish oil fatty acids
Potash soap, takes 20g Ba Sha fish oil fatty acid potash soaps, 5g alkyl glycosides, 3g fatty alcohol polyoxyethylene ether -9,0.2g natural antibacterial agents,
55g temperature is added in 45 DEG C of deionized waters, to stir 30min with 300r/min, obtaining fish oil base natural environmental-protective fruits and vegetables dishwashing detergent
Agent.
Example 2
Fresh Ba Shayu cleaning internal organ are removed into impurity, and are drained after being washed with deionized, then are transferred in tissue mashing machine
Homogenate, which is smashed to pieces, to stir evenly, and obtains material liquid, takes 150g material liquids, adds in 150g deionized waters, and 25min is stirred with 350r/min, and
With mass fraction be 5% potassium hydroxide solution or mass fraction be 5% salt acid for adjusting pH to 8.2,6g trypsase is added, 38
3h is digested under water bath with thermostatic control at DEG C, the mixed liquor after enzymolysis is fitted into centrifuge and centrifuges 12min, takes upper oil phase, is obtained
Thick Ba Sha fish oil, takes 8g lipase, adds in the thick Ba Sha fish oil of 75g, stirs reaction 3h with 550r/min at 55 DEG C, reheats
To 115 DEG C of isothermal holding 12min, 0.8g mass fractions are 72% phosphoric acid solution after being cooled to 70 DEG C, are centrifuged after insulated and stirred 9min
12min is separated, upper strata fluid is taken and adds 15g atlapulgites, is filtered to get filtrate after stirring 25min at 55 DEG C, into filtrate
3.0g dusty yeasts are added, 12min is centrifuged after stirring reaction 25min at 45 DEG C, takes liquid phase to obtain Ba Sha fish oil, take 18.0g
Whey protein isolate, adds in the phosphate buffer that 750gpH values are 7.0, and 25min is stirred with 350r/min, then at 70 DEG C
75g Ba Sha fish oil is added while stirring, is transferred to after addition in high-speed shearing emulsion machine, and 4min is emulsified with 22000r/min,
And homogenization 4 times is circulated under 70MPa, Ba Shayu oil nanometer emulsions are obtained, take 150g bars of shark oil nanometer emulsion, with 30g mass point
Number is uniformly mixed for 95% ethanol solution, and it is 30% potassium hydroxide solution to add 60g mass fractions, and reaction is stirred extremely at 55 DEG C
Sticky paste, then Poly Foam incubator inside holding 22h is placed in, taking-up is placed in ventilation and cures 2 weeks, obtains Ba Sha fish oil fatty acids
Potash soap, takes 25g Ba Sha fish oil fatty acid potash soaps, 8g alkyl glycosides, 4g fatty alcohol polyoxyethylene ether -9,0.3g natural antibacterial agents,
65g temperature is added in 48 DEG C of deionized waters, to stir 35min with 350r/min, obtaining fish oil base natural environmental-protective fruits and vegetables dishwashing detergent
Agent.
Example 3
Fresh Ba Shayu cleaning internal organ are removed into impurity, and are drained after being washed with deionized, then are transferred in tissue mashing machine
Homogenate, which is smashed to pieces, to stir evenly, and obtains material liquid, takes 200g material liquids, adds in 200g deionized waters, and 30min is stirred with 400r/min, and
With mass fraction be 5% potassium hydroxide solution or mass fraction be 5% salt acid for adjusting pH to 8.5,8g trypsase is added, 40
4h is digested under water bath with thermostatic control at DEG C, the mixed liquor after enzymolysis is fitted into centrifuge and centrifuges 15min, takes upper oil phase, is obtained
Thick Ba Sha fish oil, takes 12g lipase, adds in the thick Ba Sha fish oil of 100g, stirs reaction 4h at 60 DEG C with 600r/min, then add
Heat is to 120 DEG C of isothermal holding 15min, and 1.0g mass fractions are 75% phosphoric acid solution after being cooled to 80 DEG C, after insulated and stirred 10min
15min is centrifuged, upper strata fluid is taken and adds 20g atlapulgites, is filtered to get filtrate after stirring 30min at 60 DEG C, to filter
5.0g dusty yeasts are added in liquid, 15min is centrifuged after stirring reaction 30min at 50 DEG C, takes liquid phase to obtain Ba Sha fish oil, take
25.0g whey protein isolates, add in the phosphate buffer that 1000gpH values are 7.0, with 400r/min stirring 30min, then
100g Ba Sha fish oil is added at 80 DEG C while stirring, is transferred to after addition in high-speed shearing emulsion machine, with 24000r/min breasts
Change 5min, and homogenization 5 times is circulated under 80MPa, obtain Ba Shayu oil nanometer emulsions, 200g bars of shark oil nanometer emulsion is taken, with 40g
Mass fraction is uniformly mixed for 95% ethanol solution, and it is 30% potassium hydroxide solution to add 80g mass fractions, is stirred at 60 DEG C
Reaction is to sticky paste, then is placed in Poly Foam incubator inside holding 24h, and taking-up is placed in ventilation and cures 3 weeks, obtains Ba Sha fish oil
Fatty acid potassium soap, takes 30g Ba Sha fish oil fatty acid potash soaps, 10g alkyl glycosides, and 5g fatty alcohol polyoxyethylene ether -9,0.5g is natural
Antiseptic, adds 75g temperature as in 50 DEG C of deionized waters, 40min is stirred with 400r/min, obtains fish oil base natural environmental-protective fruits and vegetables meal
Has detergent.
Fish oil base natural environmental-protective fruits and vegetables dish washing detergent prepared by the present invention and the fruits and vegetables tableware of Guangzhou company production
Detergent is detected, specific testing result such as following table table 1：
The multiple dimensioned fiber composite high temperature air filtration material property characterization of table 1
| Performance characterization | Example 1 | Example 2 | Example 3 | Comparative example |
| Stand 360 days | Appearance transparent, it is not stratified | Appearance transparent, it is not stratified | Appearance transparent, it is not stratified | There is a small amount of precipitation |
| Rate % is cleaned in hand washing | 45.78 | 46.01 | 46.53 | 44.12 |
| Machine washing cleans rate % | 38.95 | 39.14 | 39.42 | 38.67 |
The fish oil base natural environmental-protective fruits and vegetables dish washing detergent stability that as shown in Table 1 prepared by the present invention is good, and scourability is excellent.
Claims (7)
1. a kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent, it is characterised in that the detergent is by following weight parts raw material
Composition：
20 ~ 30 parts of Ba Sha fish oil fatty acid potash soaps, 5 ~ 10 parts of alkyl glycosides, 3 ~ 5 parts of fatty alcohol polyoxyethylene ether -9,0.2 ~ 0.5
Part natural antibacterial agent, 55 ~ 75 parts of deionized waters.
A kind of 2. fish oil base natural environmental-protective fruits and vegetables dish washing detergent as claimed in claim 1, it is characterised in that the Ba Shayu
Fatty acid oil potash soap is made by following methods：
（1）Fresh Ba Shayu cleaning internal organ are removed into impurity, and are drained after being washed with deionized, then are transferred to tissue mashing machine
Middle homogenate, which is smashed to pieces, to stir evenly, and obtains material liquid；
（2）Take material liquid and deionized water 1：1 mixing, and pH to 8.0 ~ 8.5 is adjusted, trypsase is added at 35 ~ 40 DEG C
3 ~ 4h is digested, centrifugation takes upper oil phase, obtains thick Ba Sha fish oil；
（3）Take lipase to add in thick Ba Sha fish oil, 3 ~ 4h of stirring reaction at 50 ~ 60 DEG C, add mass fraction for 70 ~
75% phosphoric acid solution, centrifuges after stirring 8 ~ 10min at 60 ~ 80 DEG C, takes upper strata fluid and add atlapulgite, and stirring 20 ~
Filter to get filtrate after 30min, dusty yeast is added into filtrate, centrifuge, take after 20 ~ 30min of stirring reaction at 40 ~ 50 DEG C
Liquid phase obtains Ba Sha fish oil；
（4）Take whey protein isolate to add in the phosphate buffer that pH value is 7.0 and stir 20 ~ 30min, then at 60 ~ 80 DEG C
Ba Sha fish oil is added while stirring, 3 ~ 5min is emulsified with 20000 ~ 24000r/min after addition, and followed under 60 ~ 80MPa
Ring homogenization 3 ~ 5 times, obtains Ba Shayu oil nanometer emulsions；
（5）Ba Shayu oil nanometer emulsions are taken to be uniformly mixed with mass fraction for 95% ethanol solution, it is 30% hydrogen to add mass fraction
Potassium oxide solution, stirring reaction is to sticky paste at 50 ~ 60 DEG C, then is placed in Poly Foam incubator 20 ~ 24h of inside holding, takes
Go out to be placed in ventilation to cure 2 ~ 3 weeks, obtain Ba Sha fish oil fatty acid potash soaps.
A kind of 3. fish oil base natural environmental-protective fruits and vegetables dish washing detergent as claimed in claim 2, it is characterised in that the tryptose
Enzyme dosage is the 2 ~ 8% of material liquid quality.
A kind of 4. fish oil base natural environmental-protective fruits and vegetables dish washing detergent as claimed in claim 2, it is characterised in that the lipase
Dosage is the 6 ~ 24% of thick Ba Shayu oil qualities, and the phosphoric acid solution dosage is the 0.5 ~ 2.0% of thick Ba Shayu oil qualities, the work
Property carclazyte dosage be the 10 ~ 40% of thick Ba Shayu oil qualities, the dusty yeast dosage is the 2.5 ~ 10.0% of thick Ba Shayu oil qualities.
A kind of 5. fish oil base natural environmental-protective fruits and vegetables dish washing detergent as claimed in claim 2, it is characterised in that the whey point
From 12.5 ~ 50% that albumen dosage is Ba Shayu oil qualities, the phosphate buffer dosage is 10 times of Ba Shayu oil qualities.
6. a kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent as claimed in claim 2, it is characterised in that the ethanol is molten
Liquid dosage is the 10 ~ 40% of Ba Shayu oil nanometer emulsion quality, and the potassium hydroxide solution dosage is Ba Shayu oil nanometer emulsion quality
20~80%。
7. a kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent as claimed in claim 1, it is characterised in that described natural anti-
Microbial inoculum is chitin, the one or more in mustard, castor oil, horseradish oil.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711356214.2A CN107955763A (en) | 2017-12-16 | 2017-12-16 | A kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711356214.2A CN107955763A (en) | 2017-12-16 | 2017-12-16 | A kind of fish oil base natural environmental-protective fruits and vegetables dish washing detergent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107955763A true CN107955763A (en) | 2018-04-24 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111150012A (en) * | 2019-07-02 | 2020-05-15 | 山东省科学院生物研究所 | Method for quickly removing smooth skin on surface of kelp |
| CN114591788A (en) * | 2022-03-29 | 2022-06-07 | 陈志刚 | Heavy oil dirt cleaning agent capable of directly contacting skin and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862131A (en) * | 2015-06-05 | 2015-08-26 | 浙江海洋学院 | Fruit and vegetable tableware detergent based on marine fish oil and preparation method thereof |
| CN104962408A (en) * | 2015-07-01 | 2015-10-07 | 浙江海洋学院 | Marine fish oil washing product and preparation method thereof |
-
2017
- 2017-12-16 CN CN201711356214.2A patent/CN107955763A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862131A (en) * | 2015-06-05 | 2015-08-26 | 浙江海洋学院 | Fruit and vegetable tableware detergent based on marine fish oil and preparation method thereof |
| CN104962408A (en) * | 2015-07-01 | 2015-10-07 | 浙江海洋学院 | Marine fish oil washing product and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111150012A (en) * | 2019-07-02 | 2020-05-15 | 山东省科学院生物研究所 | Method for quickly removing smooth skin on surface of kelp |
| CN111150012B (en) * | 2019-07-02 | 2023-02-28 | 山东省科学院生物研究所 | Method for quickly removing smooth skin on surface of kelp |
| CN114591788A (en) * | 2022-03-29 | 2022-06-07 | 陈志刚 | Heavy oil dirt cleaning agent capable of directly contacting skin and preparation method and application thereof |
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Application publication date: 20180424 |