CN107847020A - Phosphor ceramic material - Google Patents
Phosphor ceramic material Download PDFInfo
- Publication number
- CN107847020A CN107847020A CN201680009335.7A CN201680009335A CN107847020A CN 107847020 A CN107847020 A CN 107847020A CN 201680009335 A CN201680009335 A CN 201680009335A CN 107847020 A CN107847020 A CN 107847020A
- Authority
- CN
- China
- Prior art keywords
- ceramic material
- phosphor
- phosphor ceramic
- metal parts
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
- C09K11/025—Use of particular materials as binders, particle coatings or suspension media therefor non-luminescent particle coatings or suspension media
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C15/00—Other forms of jewellery
- A44C15/0015—Illuminated or sound-producing jewellery
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
- C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
- C04B37/023—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
- C04B37/026—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of metals or metal salts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3213—Strontium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Adornments (AREA)
- Luminescent Compositions (AREA)
Abstract
The present invention relates to a kind of component, the component includes at least one phosphor ceramic material (2) and at least one metal parts (3), the phosphor ceramic material (2) is fixed on the metal parts (3), and the phosphor ceramic material (2) includes the mixture of phosphor material and the compound containing ceramics.
Description
Technical field
The field of the invention is article and component containing ceramics, especially jewellry or ceramic tile.
Background technology
The use of ceramics is known in jewelry manufacturing field with metallic combination.But ceramics have color is lacklustre to lack
Point, this makes the visual appearance of jewellry degrade (devaluation) sometimes, particularly in dim environment and in the sudden strain of a muscle with metal
When bright outward appearance is contrasted.
The content of the invention
Present invention aim to address the shortcoming, therefore, the present invention relates to a kind of phosphor ceramic material, the phosphor ceramic
Material includes the mixture of following material：
Compound containing ceramics, and
Phosphor material.
Therefore, the mixture of compound and phosphor material containing ceramics assigns jewellry with glittering outer in the dark
See, while remain noble quality of the ceramics in more bright light environments.
The each embodiment that can be used together or be used alone according to the present invention：
The 55%~75% of the quality of the phosphor ceramic material is made up of the compound；
The 25%~45% of the quality of the phosphor ceramic material is made up of the phosphor material；
The 2/3 of the quality of the phosphor ceramic material is made up of the compound；
The 1/3 of the quality of the phosphor ceramic material is made up of the phosphor material；
The compound includes the mass % of 60 mass %~90 ceramics.
The invention further relates to a kind of component, particularly jewellry, fashion accessories or ceramic tile, the component includes at least one
Kind phosphor ceramic material as defined above, and at least one metal parts that the phosphor ceramic material is fixed with thereon.
The invention further relates to a kind of technique for being used to manufacture phosphor ceramic material as defined above, wherein, the technique
The step of including mixing compound and the ceramic material containing ceramics, the compound is in the pasty state and the phosphor material is phosphorus
Light powder.
The each embodiment that can be used together or be used alone according to the present invention：
The phosphorescence powder is the mixture containing alkaline earth aluminates and strontium.
Blend step is carried out under vacuo.
Further, the present invention relates to the method for a kind of manufacture component, particularly jewellry, fashion accessories or ceramic tile,
The step of methods described includes manufacturing phosphor ceramic material as defined above, and the phosphor ceramic material is fixed to metal
The step of part.
Each embodiment that can be used together or be used alone according to the present invention：
Methods described includes, and before fixing step, at least one above is fixed in the phosphor ceramic material
On individual region, to the metal parts carry out sandblasting the step of；
Methods described includes, and after fixing step, heats the metal parts and the phosphor ceramic material so that institute
The step of stating phosphor ceramic material solidification.
Brief description of the drawings
With reference to appended accompanying drawing, and it following are only the description for referring to and being used and be not intended to and limiting the invention in any way
To more fully understand the present invention.In the accompanying drawings：
Fig. 1 is the schematic diagram according to the jewellry with metal parts and phosphor ceramic material of the present invention；With
Fig. 2 is the view similar with Fig. 1, shows the instrument for being placed on phosphor ceramic material on metalwork.
Embodiment
The present invention relates to component 1, especially jewelry external member, jewellry particularly as shown in Figure 1, including phosphorescence pottery
Ceramic material 2 and metal parts 3.Such jewellry can be necklace, jewelry, ear pendant, or for forming Vogue or making
Any other complete jewelry external member of Vogue or article.
Such phosphor ceramic material 2 includes the mixture of phosphor material and the compound containing ceramics, and the phosphor material is outstanding
It is phosphorescence powder.
In a preferred embodiment：
The phosphorescence powder is the mixture containing alkaline earth aluminates and strontium；With
The compound containing ceramics includes the mass % of 65 mass %~85 ceramics, and polymer, colored pigment, use
In the silane finish of bonding, and nano particle.
The invention further relates to a kind of manufacturing process for being used to manufacture phosphor ceramic material 2, it is multiple that the manufacturing process includes mixing
The step of compound (containing ceramics) and the ceramic material.Before mixing, in the pasty state, and the phosphor material is the compound
Powder type.The phosphor material that pasty state compound and powder type is applied in combination is easy to mix material, and can obtain
Obtain the uniform ceramic material of phosphorescence.
After just mixing phosphor ceramic material 2 also in the pasty state, so as to which easily the phosphor ceramic material 2 is applied
To metal parts 3 to form jewellry.
The mixture includes the mass %, preferably 67 mass % of 55 mass %~75 compound, and 25 mass %
~45 mass %, especially 33 mass % phosphor material.These ratios allow to obtain the phosphorus for including enough ceramic complexes
Light ceramic material, so as to which it keeps paste forms, while the phosphor material comprising abundance is with the quality with it and uniform phosphorus
Light.The compound includes the mass % of 60 mass %~90 ceramics.It also includes polymer, to be paste state.
Blend step is carried out under vacuo.In this way, it specifically avoid and form gas in phosphor ceramic material 2
Bubble.
Present invention also offers place and be fixed on metal parts 3 the phosphor ceramic material 2 to form jewelry decorations
The step of thing.In this step, especially for making phosphor ceramic material 2 that there is desired shape, such as using including phosphorescence
The pen 4 (Fig. 2) of the feed pipe 5 of ceramic material 2, pasty state phosphor ceramic material 2 is arranged on metal parts 3.It is viscous in order to improve
Attached property, cored solder is added, so that phosphor ceramic material 2 can be soldered to metal parts 3.
Before fixing step, methods described, which is included in phosphor ceramic material 2, to be fixed in area above, to gold
Belong to the step of part 3 carries out sandblasting.By carrying out sandblasting to metal parts 3, produced on the region of phosphor ceramic material 2 to be accommodated
Roughness is given birth to, which improve fixation of the phosphor ceramic material 2 on metal parts.
Furthermore, it is possible to receiving slit is produced on metal parts 3, to form the container for defining the region.The container can be just
Place and be fixed on metal parts 3 in by phosphor ceramic material 2.
After sandblasting, the step of methods described includes for example cleaning metal parts 3 using distilled water and ethanol.Then,
Dry metal parts 3.
After fixing step, methods described includes heating the metal parts 3 and the phosphor ceramic material 2 so that institute
State the step of phosphor ceramic material 2 solidifies.Therefore, jewellry is placed in an oven, wherein, jewellry is under 120 °
Heating 60 minutes.After such baking, jewellry is taken out from baking oven, and be cooled to room temperature.By jewellry
Before placing in an oven, it is advantageously that place it in glycerine to improve its baking.Jewellry is taken out from baking oven
Afterwards, it is rinsed immediately to remove excessive glycerine.
Finally, phosphor ceramic material 2 can be polished, to remove all unnecessary materials.
Although not shown, but the present invention component 1 can also be for example for decorated table or floor, wall and/or
The ceramic tile of ceiling.In this case, scale is marked to phosphor ceramic material 2 and is moulded, then arranges and is glued to
Metal parts is to form the component of the present invention, and in this case, component of the invention is ceramic tile.The porcelain formed by this way
Brick can be configured, in the form of obtaining such as mosaic class.
Claims (9)
1. a kind of component, the component includes at least one phosphor ceramic material (2) and at least one metal parts (3), described
Phosphor ceramic material (2) is fixed on the metal parts (3), and the phosphor ceramic material (2) includes the mixing of following material
Thing：
Compound containing ceramics, and
Phosphor material.
2. component according to claim 1, wherein, the quality of the phosphor ceramic material 55%~75% by described multiple
Compound is formed, and the 25%~45% of the quality of the phosphor ceramic material is made up of the phosphor material.
3. component according to claim 2, wherein, the quality of the phosphor ceramic material 2/3 by the compound structure
Into, and the 1/3 of the quality of the phosphor ceramic material is made up of the phosphor material.
4. component according to any one of the preceding claims, wherein, the compound includes the matter of 60 mass %~90
Measure % ceramics.
5. a kind of method for manufacturing component, methods described includes being used for manufacturing the technique of phosphor ceramic material (2), and by the phosphorus
Light ceramic material (2) is fixed on the step on metal parts (3), and the manufacturing process of the phosphor ceramic material (2) includes mixing
The step of containing ceramic compound and phosphor material, the compound is in the pasty state and the phosphor material is phosphorescence powder.
6. the method for manufacture component according to claim 5, wherein, the phosphorescence powder is to contain alkaline earth aluminates and strontium
Mixture.
7. the method for the manufacture component according to claim 5 or 6, wherein, the blend step is carried out under vacuo.
8. the method for the manufacture component according to any one of claim 5 to 7, methods described includes, fixing step it
Before, to be fixed at least one region above in the phosphor ceramic material (2), the metal parts (3) is carried out
The step of sandblasting.
9. the method for the manufacture component according to any one of claim 5 to 8, methods described includes, fixing step it
Afterwards, the metal parts (3) and the phosphor ceramic material (2) are heated so that the step of phosphor ceramic material (2) solidifies.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1551163 | 2015-02-12 | ||
| FR1551163A FR3032703B1 (en) | 2015-02-12 | 2015-02-12 | PHOSPHORESCENT CERAMIC MATERIAL |
| PCT/FR2016/050284 WO2016128667A1 (en) | 2015-02-12 | 2016-02-09 | Phosphorescent ceramic material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107847020A true CN107847020A (en) | 2018-03-27 |
Family
ID=53040563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680009335.7A Pending CN107847020A (en) | 2015-02-12 | 2016-02-09 | Phosphor ceramic material |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP3256017A1 (en) |
| CN (1) | CN107847020A (en) |
| FR (1) | FR3032703B1 (en) |
| WO (1) | WO2016128667A1 (en) |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3897359A (en) * | 1969-06-11 | 1975-07-29 | Matsushita Electronics Corp | Europium activated alkaline earth metal alumino silicate phosphor and method for preparing the same |
| CN1414061A (en) * | 2000-08-08 | 2003-04-30 | 株式会社多佩尔 | Luminous and luminescent artificial stone and its structure |
| CN2590897Y (en) * | 2002-12-05 | 2003-12-10 | 蒋荣昌 | Container with metal base ceramic surface |
| CN1637663A (en) * | 2003-12-23 | 2005-07-13 | 劳力士有限公司 | Ceramic element for a watch case and process for manufacturing this element |
| US6953536B2 (en) * | 2003-02-25 | 2005-10-11 | University Of Georgia Research Foundation, Inc. | Long persistent phosphors and persistent energy transfer technique |
| US20060038161A1 (en) * | 2004-08-23 | 2006-02-23 | Vistas Group International, Inc. | Long lasting thermoformable phosphorescent acrylic resin for casting, molding, coatings, and adhesives |
| CN1806711A (en) * | 2005-12-27 | 2006-07-26 | 雷蜀荔 | Ceramic precious metal finger ring and method for making the same |
| CN101116910A (en) * | 2006-07-31 | 2008-02-06 | 劳力士有限公司 | Pigmented ceramic element |
| WO2014065683A1 (en) * | 2012-10-22 | 2014-05-01 | Secil S.A.-Companhia Geral De Cal E Cimiento Outão | White or colored cementitious mixture for manufacture of concrete, mortar and interactive pastes with photoluminescent properties |
| WO2014072388A1 (en) * | 2012-11-07 | 2014-05-15 | Rolex S.A. | Watch components |
| CN104626334A (en) * | 2013-11-13 | 2015-05-20 | 深圳市金宝盈珠宝首饰有限公司 | Metal and porcelain seamless combining technology |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002040421A1 (en) * | 2000-11-20 | 2002-05-23 | S.L.E. (Australia) Pty Ltd | Photoluminescent plastic aggregates |
| US8722835B2 (en) * | 2007-09-17 | 2014-05-13 | Ppg Industries Ohio, Inc. | One component polysiloxane coating compositions and related coated substrates |
| SK6395Y1 (en) * | 2012-04-30 | 2013-03-01 | Ladislav Kozmer | A luminiscent materials |
-
2015
- 2015-02-12 FR FR1551163A patent/FR3032703B1/en active Active
-
2016
- 2016-02-09 CN CN201680009335.7A patent/CN107847020A/en active Pending
- 2016-02-09 EP EP16707887.2A patent/EP3256017A1/en not_active Withdrawn
- 2016-02-09 WO PCT/FR2016/050284 patent/WO2016128667A1/en active Application Filing
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3897359A (en) * | 1969-06-11 | 1975-07-29 | Matsushita Electronics Corp | Europium activated alkaline earth metal alumino silicate phosphor and method for preparing the same |
| CN1414061A (en) * | 2000-08-08 | 2003-04-30 | 株式会社多佩尔 | Luminous and luminescent artificial stone and its structure |
| CN2590897Y (en) * | 2002-12-05 | 2003-12-10 | 蒋荣昌 | Container with metal base ceramic surface |
| US6953536B2 (en) * | 2003-02-25 | 2005-10-11 | University Of Georgia Research Foundation, Inc. | Long persistent phosphors and persistent energy transfer technique |
| CN1637663A (en) * | 2003-12-23 | 2005-07-13 | 劳力士有限公司 | Ceramic element for a watch case and process for manufacturing this element |
| US20060038161A1 (en) * | 2004-08-23 | 2006-02-23 | Vistas Group International, Inc. | Long lasting thermoformable phosphorescent acrylic resin for casting, molding, coatings, and adhesives |
| CN1806711A (en) * | 2005-12-27 | 2006-07-26 | 雷蜀荔 | Ceramic precious metal finger ring and method for making the same |
| CN101116910A (en) * | 2006-07-31 | 2008-02-06 | 劳力士有限公司 | Pigmented ceramic element |
| WO2014065683A1 (en) * | 2012-10-22 | 2014-05-01 | Secil S.A.-Companhia Geral De Cal E Cimiento Outão | White or colored cementitious mixture for manufacture of concrete, mortar and interactive pastes with photoluminescent properties |
| WO2014072388A1 (en) * | 2012-11-07 | 2014-05-15 | Rolex S.A. | Watch components |
| CN107338053A (en) * | 2012-11-07 | 2017-11-10 | 劳力士有限公司 | There is the phosphorescence composite of twilight sunset |
| CN104626334A (en) * | 2013-11-13 | 2015-05-20 | 深圳市金宝盈珠宝首饰有限公司 | Metal and porcelain seamless combining technology |
Also Published As
| Publication number | Publication date |
|---|---|
| FR3032703B1 (en) | 2019-06-21 |
| EP3256017A1 (en) | 2017-12-20 |
| WO2016128667A1 (en) | 2016-08-18 |
| FR3032703A1 (en) | 2016-08-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180327 |