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CN107732001A - A kind of pressure sensor and its manufacture method based on resistance bridge structure - Google Patents

A kind of pressure sensor and its manufacture method based on resistance bridge structure Download PDF

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Publication number
CN107732001A
CN107732001A CN201710826236.4A CN201710826236A CN107732001A CN 107732001 A CN107732001 A CN 107732001A CN 201710826236 A CN201710826236 A CN 201710826236A CN 107732001 A CN107732001 A CN 107732001A
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Prior art keywords
pressure sensor
wafer
bridge structure
back side
metal
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CN201710826236.4A
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CN107732001B (en
Inventor
谭鑫
冯志红
吕元杰
王元刚
宋旭波
周幸叶
房玉龙
顾国栋
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CETC 13 Research Institute
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/80Constructional details
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/01Manufacture or treatment
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/30Piezoelectric or electrostrictive devices with mechanical input and electrical output, e.g. functioning as generators or sensors
    • H10N30/302Sensors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/80Constructional details
    • H10N30/85Piezoelectric or electrostrictive active materials

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Pressure Sensors (AREA)
  • Measuring Fluid Pressure (AREA)

Abstract

The invention discloses a kind of pressure sensor and its manufacture method based on resistance bridge structure, it is related to semiconductor pressure sensor technical field;It is gallium nitride including bonding wafer, bonding medium, substrate, cushion, barrier layer, plain conductor, barrier layer, cavity and Ohmic electrode, the material of cushion 5, the material of barrier layer 6 is InxAlyGa1‑x‑yN;Ensure the stability of resistance, preparation method is simple, production precision is improved, available for hot environment.

Description

A kind of pressure sensor and its manufacture method based on resistance bridge structure
Technical field
The present invention relates to semiconductor pressure sensor technical field.
Background technology
Pressure sensor is a kind of transducer for the electric signal that pressure signal can be converted into intuitively obtaining, wide The general every aspect for being applied to life.Semiconductor pressure sensor is mainly based upon Si materials at present, using silicon cup formula film knot Structure.And Si material temperature characteristics are poor, using diffusion technique formed resistance characteristic can change at relatively high temperatures, for every Decline also occurs from the isolation of resistance and the PN junction of substrate.Usual Si base pressure sensors are only operable on less than 120 DEG C In the environment of.It is also very high for technological requirement that four resistance identical Si diffusion resistances are obtained in addition, craft precision, uniformity It is difficult to ensure that.
The content of the invention
The technical problem to be solved in the present invention is to be directed to above-mentioned the deficiencies in the prior art, there is provided one kind is based on resistance bridge The pressure sensor and its manufacture method of structure, application environment temperature is high, ensures the stability of resistance, preparation method is simple, carries High product makes precision.
In order to solve the above technical problems, the technical solution used in the present invention is:Including bonding wafer, bonding medium, lining Bottom, cushion, plain conductor, barrier layer, cavity and Ohmic electrode, it is characterised in that:The cushioning layer material is gallium nitride, gesture Barrier material layer is InxAlyGa1-x-yN multi-element compounds.
A kind of manufacture method of the pressure sensor based on resistance bridge structure, it is characterised in that including:Chip is provided Material structure-table top photoetching, development-mesa etch-device Ohmic electrode photoetching-electrode metal evaporation-high annealing-metal are led Lithography, evaporation of metal-back side cavity photoetching-back side cavity etching-bonding medium deposit-bonding chip obtain pressure sensing Device;There is provided wafer material structure includes the barrier layer on the cushion and cushion on substrate, substrate.
Preferably, the method for mesa etch is:Active area and remainder by physical chemistry etching to barrier layer Passive region carry out mesa-isolated, gas is chosen for Cl2/BCl3Mixed gas.
Preferably, the method for device Ohmic electrode photoetching is:The uniform resist coating of wafer surface after mesa etch, Device Ohmic electrode region is exposed, unexposed photoresist is obtained after development, unglazed photoresist region is Ohmic electrode area.
Preferably, the method for electrode metal evaporation is:Method in Ohmic electrode area using electron beam evaporation, in chip Surface evaporated metal successively, obtain metal laminated, as Ohmic electrode.
Preferably, plain conductor photoetching, the method for evaporation of metal are:In the uniform resist coating of wafer surface, using exposure Ray machine is exposed to device metal conductor area;Photoresist is developed;Magnetron sputtering or electricity are used after the completion of development The method of beamlet evaporation, evaporated metal are peeled off as device metal wire, obtain plain conductor.
Preferably, the method for back side cavity photoetching is:Photoresist is uniformly smeared in chip back surface, to device back side cavity Etch areas be exposed, development obtains unexposed photoresist, and the intermediate region without photoresist is the cavity that need to etch.
Preferably, the method for back side cavity etching is:With the unexposed photoresist part obtained in the cavity photoetching of the back side For etch mask, back side cavity is performed etching using physical chemistry lithographic method.
Preferably, the method for bonding medium deposit is:Make in the back side housing surface deposition layer of metal that etching is completed For wafer bonding medium, while same metal level is deposited on the wafer substrate surface of a piece of surfacing.
Preferably, the method that wafer bonding obtains pressure sensor is:By the chip of deposited bonding medium and crystalline substance Circle substrate by wafer bond techniques bonding together so that between back side cavity and substrate formed a pressure it is constant Cavity.
It is using beneficial effect caused by above-mentioned technical proposal:The present invention is prohibited using gallium nitride as cushion, GaN Bandwidth is 3.4eV, is 3 times of Si materials, and wide forbidden band determines the good hot properties of material, and report has proven to GaN materials Glassware part is operable with 600 DEG C and not failed.Other GaN material also has electron concentration height, and electron mobility is high, Radiation hardness Many advantages, such as strong, therefore, the pressure sensor based on GaN material, may operate in extremely complicated environment.GaN material system Spontaneous polarization and piezoelectric polarization effect the two-dimensional electron gas (2DEG) of high concentration, its resistance value can be formed at material interface It is extremely sensitive to pressure-responsive.The GaN base diaphragm pressure sensor structure of traditional resistance bridge structure is used based on this, due to The good characteristic of material, this kind of sensor are operable with exceedingly odious environment, realize that pressure signal senses, ensure the steady of resistance Qualitative, preparation method is simple, improves production precision.
Sensor front technique and general GaN HEMT preparation technologies, back process and existing conventional MEMS technology Mutually compatible, compared with traditional Si base film pressure sensors, the present invention need not carry out impurity diffusion, by controlling active area Size is that can obtain the resistance of respective resistance values, and back process is compatible with existing MEMS technology, and obtained sensor can be with work Make in fail under extreme environment.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the cross-sectional view in Fig. 1 A-A directions;
Fig. 3 is the schematic diagram of wafer material structure of the present invention;
Fig. 4 is table top photoetching of the present invention, the schematic diagram of development step;
Fig. 5 is the schematic diagram of mesa etch step of the present invention;
Fig. 6 is the schematic diagram of device Ohmic electrode lithography step of the present invention;
Fig. 7 is the schematic diagram of electrode metal evaporation step of the present invention;
Fig. 8 is plain conductor photoetching of the present invention, the schematic diagram of evaporation of metal step;
Fig. 9 is the schematic diagram of cavity lithography step in the back side of the present invention;
Figure 10 is the schematic diagram of cavity etch step in the back side of the present invention;
Figure 11 is the schematic diagram of bonding medium depositing step of the present invention;
Figure 12 is the schematic diagram of wafer bonding step of the present invention.
In figure:1st, GaN device;2nd, cavity film;3rd, cavity 4, substrate;5th, cushion;6th, barrier layer;7th, unexposed light Photoresist;8th, Ohmic electrode;9th, plain conductor;10th, bonding medium;11st, it is bonded wafer.
Embodiment
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
As shown in Fig. 2 one for the present invention a kind of pressure sensor and its manufacture method based on resistance bridge structure Individual embodiment, including bonding wafer, bonding medium, substrate, cushion, plain conductor, barrier layer, cavity and Ohmic electrode, institute It is gallium nitride to state cushioning layer material, abarrier layer material InxAlyGa1-x-yN multi-element compounds, make obtain bridge resistor according to this.
Fig. 1 includes plain conductor 9, cavity film 2 and GAN devices 1.
Using gallium nitride as cushion, GaN energy gaps are 3.4eV, are 3 times of Si materials, wide forbidden band determines The good hot properties of material, report have proven to GaN material device and are operable with 600 DEG C not fail.Other GaN material also has Many advantages, such as electron concentration is high, and electron mobility is high, and Radiation hardness is strong, therefore, the pressure sensor based on GaN material can To work in extremely complicated environment.The spontaneous polarization of GaN material system and piezoelectric polarization effect can at material interface shape It is extremely sensitive to pressure-responsive into the two-dimensional electron gas (2DEG) of high concentration, its resistance value.Based on this using traditional Hui Sidun electricity The GaN base diaphragm pressure sensor structure of bridge structure, due to the good characteristic of material, this kind of sensor is operable with exceedingly odious Environment, realize pressure signal sense, ensure the stability of resistance, preparation method is simple, improve production precision.
Abarrier layer material is InxAlyGa1-x-yN multi-element compounds;Including being not limited in different component concentration InAlGaN quaternary compounds, InAlN, AlGaN, InGaN ternary compound of different component concentration, and AlN, InN etc., delay It is GaN to rush layer.Backing material includes being not limited in sapphire, SiC, Si etc..
A kind of manufacture method of the pressure sensor based on resistance bridge structure, including:Wafer material structure-platform is provided Face photoetching, development-mesa etch-device Ohmic electrode photoetching-electrode metal evaporation-high annealing-plain conductor photoetching, metal Evaporation-back side cavity photoetching-back side cavity etching-bonding medium deposit-bonding chip obtains pressure sensor;Chip material is provided Expect that structure includes the barrier layer on the cushion and cushion on substrate, substrate, cushioning layer material is gallium nitride.
Sensor front technique and general GaN HEMT preparation technologies, back process and existing conventional MEMS technology Mutually compatible, compared with traditional Si base film pressure sensors, the present invention need not carry out impurity diffusion, by controlling active area Size is that can obtain the resistance of respective resistance values, and back process is compatible with existing MEMS technology, and obtained sensor can be with work Make in fail under extreme environment.
As shown in Figure 3, there is provided wafer material structure:In is providedxAlyGa1-x-yN/GaN material wafers, the material of substrate 4 can be with Selection is not limited in sapphire, SiC, Si, GaN etc.;GaN cushions 5, barrier layer 6 are certain thickness and concentration of component InxAlyGa1-x-yN, including it is not limited in the InAlGaN quaternary compounds of different component concentration, different component concentration InAlN, AlGaN, InGaN ternary compound, and AlN, InN etc..
As shown in figure 4, table top photoetching, development:Organic and inorganic cleaning is carried out to chip, after completing label creating, carries out platform Face photoetching, in the uniform resist coating of wafer surface, single or multiple lift can be chosen according to demand;Using contact exposure machine, or Person's electron beam exposure apparatus is exposed to device source leakage;Developer solution is chosen according to photoresist to be developed;In 5 in figure on barrier layer For the unexposed photoresist 7 left after development, institute overlay area is table top to unexposed photoresist 7 below.
As shown in figure 5, the method for mesa etch is:Active area and remainder by physical chemistry etching to barrier layer Passive region carry out mesa-isolated, gas is chosen for Cl2/BCl3Mixed gas, and remove unexposed photoresist 7.
As shown in fig. 6, the method for device Ohmic electrode photoetching is:Wafer surface after mesa etch uniformly applies photoetching Glue, single or multiple lift can be chosen according to demand;Using contact exposure machine, or electron beam exposure apparatus is to device Ohmic electrode Region is exposed, and unexposed photoresist 7 is obtained after development, and unglazed photoresist region is Ohmic electrode area.
As shown in fig. 7, the method for electrode metal evaporation is:Method in Ohmic electrode area using electron beam evaporation, in crystalline substance Certain thickness metal is evaporated on piece surface successively, obtain it is metal laminated, after the completion of stripping, as Ohmic electrode 8;It is metal laminated can Include being not limited in Ti/Al/Ni/Au, Si/Ti/Al/Ni/Au, Ti/Al/Pt/Au etc. to choose.
High annealing:Using short annealing equipment, quick high-temp annealing is carried out to chip in N2 atmosphere, folded according to metal Layer different structure, chooses different annealing temperatures and annealing time, realizes the Ohmic contact of electrode.
As shown in figure 8, plain conductor photoetching, the method for evaporation of metal are:In the uniform resist coating of wafer surface, according to need Single or multiple lift can be chosen by asking;Device metal conductor area is carried out using contact exposure machine, or electron beam exposure apparatus Exposure;Developer solution is chosen according to photoresist to develop to photoresist;Steamed after the completion of development using magnetron sputtering or electron beam The method of hair, certain thickness metal is evaporated as device metal wire 9, such as Ti/Au, Pt/Au, Ni/Au etc.;And stripper light Photoresist, further peel off and obtain plain conductor 9.
As shown in figure 9, the method for back side cavity photoetching is:Photoresist is uniformly smeared in chip back surface, using double contact Formula exposure machine is exposed to the etch areas of device back side cavity, is chosen corresponding developer solution and is developed, and development obtains not Exposure photo-etching glue 7, the intermediate region without photoresist are the cavity that need to be etched.
As shown in Figure 10, the method for back side cavity etching is:With the unexposed photoresist portion obtained in the cavity photoetching of the back side It is divided into etch mask, back side cavity is performed etching using physical chemistry lithographic method, different according to backing material chooses phase Corresponding etching gas and etching power;Different etching depths is determined according to different sensitivity requirements, etching completion is gone Except photoresist.
As shown in figure 11, the method for bonding medium deposit is:In the back side housing surface deposition layer of metal that etching is completed As wafer bonding medium 10, metal can choose single layer of gold or multilayer composite metal lamination, and acquisition pattern can select electricity Beamlet evaporation, sputtering or plating etc.;Same metal level is deposited on the wafer substrate surface of a piece of surfacing simultaneously.
As shown in figure 12, the method that wafer bonding obtains pressure sensor is:By the chip of deposited bonding medium with Substrate by wafer bond techniques bonding together so that the constant sky of a pressure is formed between back side cavity and substrate Chamber.
By above step, that is, complete the making of the GaN film pressure sensor of the present invention.Carrying out pressure signal survey During examination, end is perceived using GaN film as pressure, using diagonal two electrode as input/output terminal, measures different pressures condition The magnitude of voltage of lower output end is the sensing that pressure signal can be achieved.The technique that the structure can reduce pressure sensor to a certain degree Difficulty of processing, realize the sensing of pressure signal under extreme condition.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.

Claims (10)

1. a kind of pressure sensor based on resistance bridge structure, including bonding wafer 11, bonding medium 10, substrate 4, buffering Layer 5, plain conductor 9, barrier layer 6, cavity 3 and Ohmic electrode 8, it is characterised in that:The material of cushion 5 is gallium nitride;Gesture Barrier material layer is InxAlyGa1-x-yN multi-element compounds.
2. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 1, its feature It is to include:There is provided wafer material structure-table top photoetching, development-mesa etch-device Ohmic electrode photoetching-electrode metal steams Hair-high annealing-plain conductor photoetching, evaporation of metal-back side cavity photoetching-back side cavity etching-bonding medium deposit-chip Bonding obtains pressure sensor;There is provided wafer material structure includes the potential barrier on the cushion 5 and cushion 5 on substrate 4, substrate Layer 6.
3. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 2, its feature The method for being the mesa etch is:Etched by physical chemistry to the active area of barrier layer 6 and the passive region of remainder Mesa-isolated is carried out, gas is chosen for Cl2/BCl3Mixed gas.
4. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 2, its feature The method for being the device Ohmic electrode photoetching is:The uniform resist coating of wafer surface after mesa etch, to device Europe Nurse electrode zone is exposed, and unexposed photoresist 7 is obtained after development, and unglazed photoresist region is Ohmic electrode area.
5. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 2, its feature It is that the method that the electrode metal evaporates is:Method in Ohmic electrode area using electron beam evaporation, in wafer surface successively Evaporated metal, obtain metal laminated, as Ohmic electrode 8.
6. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 2, its feature It is that the plain conductor photoetching, the method for evaporation of metal are:In the uniform resist coating of wafer surface, using exposure machine to device Plain conductor region is exposed;Photoresist is developed;Using magnetron sputtering or electron beam evaporation after the completion of development Method, evaporated metal are peeled off as device metal wire 9, obtain plain conductor 9.
7. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 2, its feature The method for being the back side cavity photoetching is:Photoresist is uniformly smeared in chip back surface, to the etched area of device back side cavity Domain is exposed, and development obtains unexposed photoresist, and the intermediate region without photoresist is the cavity that need to be etched.
8. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 2, its feature It is that the method that the back side cavity etches is:Covered using the unexposed photoresist part obtained in the cavity photoetching of the back side as etching Film, back side cavity is performed etching using physical chemistry lithographic method.
9. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 2, its feature It is that the method that the bonding medium deposits is:Layer of metal is deposited as wafer bonding in the back side housing surface that etching is completed Medium, while same metal level is deposited on the wafer substrate surface of a piece of surfacing.
10. a kind of manufacture method of pressure sensor based on resistance bridge structure according to claim 2, its feature It is that the method that the wafer bonding obtains pressure sensor is:The chip of deposited bonding medium 10 is led to wafer substrate Cross wafer bond techniques bonding together so that the constant cavity 3 of a pressure is formed between back side cavity and substrate.
CN201710826236.4A 2017-09-14 2017-09-14 Pressure sensor based on Wheatstone bridge structure and manufacturing method thereof Active CN107732001B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108376735A (en) * 2018-02-28 2018-08-07 中国电子科技集团公司第十三研究所 A kind of bridge type GaN pressure sensors preparation method and device
CN108389959A (en) * 2018-02-28 2018-08-10 中国电子科技集团公司第十三研究所 A kind of bridge type GaN pressure sensors preparation method and device
CN108400235A (en) * 2018-02-28 2018-08-14 中国电子科技集团公司第十三研究所 The preparation method of Si base GaN pressure sensors
CN108414120A (en) * 2018-02-28 2018-08-17 中国电子科技集团公司第十三研究所 The preparation method of Si base GaN pressure sensors
CN108414121A (en) * 2018-02-28 2018-08-17 中国电子科技集团公司第十三研究所 A kind of GaN pressure sensors preparation method and device
CN108519174A (en) * 2018-03-27 2018-09-11 中国电子科技集团公司第十三研究所 GaN bridge type absolute pressure pressure sensors and production method
CN108598253A (en) * 2018-02-28 2018-09-28 中国电子科技集团公司第十三研究所 The preparation method of Si base GaN pressure sensors
CN109682510A (en) * 2018-12-07 2019-04-26 中国电子科技集团公司第十三研究所 GaN high-temp pressure sensor and preparation method
CN117147023A (en) * 2023-11-01 2023-12-01 合肥美镓传感科技有限公司 Gallium nitride pressure sensor and manufacturing method thereof

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US20090317931A1 (en) * 2008-06-23 2009-12-24 Commissariat A L'energie Atomique Method of fabricating an electromechanical device including at least one active element
CN103582951A (en) * 2011-05-17 2014-02-12 Hrl实验室有限责任公司 GaN HEMT with a back gate connected to the source
CN106206930A (en) * 2016-07-15 2016-12-07 中国电子科技集团公司第十三研究所 Pressure transducer and preparation method thereof

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US20090317931A1 (en) * 2008-06-23 2009-12-24 Commissariat A L'energie Atomique Method of fabricating an electromechanical device including at least one active element
CN101520350A (en) * 2009-03-24 2009-09-02 无锡市纳微电子有限公司 Process for manufacturing improved high-sensitivity low pressure sensor chip
CN103582951A (en) * 2011-05-17 2014-02-12 Hrl实验室有限责任公司 GaN HEMT with a back gate connected to the source
CN106206930A (en) * 2016-07-15 2016-12-07 中国电子科技集团公司第十三研究所 Pressure transducer and preparation method thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108598253A (en) * 2018-02-28 2018-09-28 中国电子科技集团公司第十三研究所 The preparation method of Si base GaN pressure sensors
CN108389959A (en) * 2018-02-28 2018-08-10 中国电子科技集团公司第十三研究所 A kind of bridge type GaN pressure sensors preparation method and device
CN108400235A (en) * 2018-02-28 2018-08-14 中国电子科技集团公司第十三研究所 The preparation method of Si base GaN pressure sensors
CN108414120A (en) * 2018-02-28 2018-08-17 中国电子科技集团公司第十三研究所 The preparation method of Si base GaN pressure sensors
CN108414121A (en) * 2018-02-28 2018-08-17 中国电子科技集团公司第十三研究所 A kind of GaN pressure sensors preparation method and device
CN108376735A (en) * 2018-02-28 2018-08-07 中国电子科技集团公司第十三研究所 A kind of bridge type GaN pressure sensors preparation method and device
CN108400235B (en) * 2018-02-28 2021-06-15 中国电子科技集团公司第十三研究所 Preparation method of Si-based GaN pressure sensor
CN108598253B (en) * 2018-02-28 2021-12-24 中国电子科技集团公司第十三研究所 Preparation method of Si-based GaN pressure sensor
CN108519174A (en) * 2018-03-27 2018-09-11 中国电子科技集团公司第十三研究所 GaN bridge type absolute pressure pressure sensors and production method
CN108519174B (en) * 2018-03-27 2020-09-08 中国电子科技集团公司第十三研究所 GaN bridge type absolute pressure sensor and manufacturing method thereof
CN109682510A (en) * 2018-12-07 2019-04-26 中国电子科技集团公司第十三研究所 GaN high-temp pressure sensor and preparation method
CN117147023A (en) * 2023-11-01 2023-12-01 合肥美镓传感科技有限公司 Gallium nitride pressure sensor and manufacturing method thereof
CN117147023B (en) * 2023-11-01 2024-02-13 合肥美镓传感科技有限公司 Gallium nitride pressure sensor and manufacturing method thereof

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Inventor after: Tan Xin

Inventor after: Intelligence

Inventor after: Feng Zhihong

Inventor after: Lv Yuanjie

Inventor after: Wang Yuangang

Inventor after: Song Xubo

Inventor after: Zhou Xingye

Inventor after: Fang Yulong

Inventor after: Gu Guodong

Inventor before: Tan Xin

Inventor before: Feng Zhihong

Inventor before: Lv Yuanjie

Inventor before: Wang Yuangang

Inventor before: Song Xubo

Inventor before: Zhou Xingye

Inventor before: Fang Yulong

Inventor before: Gu Guodong

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