CN106995631A - A kind of waterborne antibacterial electrically-conducting paint - Google Patents
A kind of waterborne antibacterial electrically-conducting paint Download PDFInfo
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- CN106995631A CN106995631A CN201710332036.3A CN201710332036A CN106995631A CN 106995631 A CN106995631 A CN 106995631A CN 201710332036 A CN201710332036 A CN 201710332036A CN 106995631 A CN106995631 A CN 106995631A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of waterborne antibacterial electrically-conducting paint, it is made up of the raw material of following parts by weight：Water-based acrylic resin：24 63 parts, color stuffing：10 33 parts, carbon fiber：6 10 parts, graphene：6 10 parts, ZnO/ CNT antiseptics：0.01 1 parts, organic silicon defoamer：0.01 1 parts, water：14 36 parts.The waterborne antibacterial electrically-conducting paint of the present invention has the good feature of environmental protection, and the present invention uses Multiple components science compounding use, and obtained coating has excellent tack, mechanical property, filming performance, antibiotic property, electric conductivity, is a kind of coating of excellent quality.
Description
Technical field
The present invention relates to paint field, a kind of waterborne antibacterial electrically-conducting paint is specifically related to.
Background technology
Electrically-conducting paint is a kind of functional coating that there is conductive and exclusion to accumulate electrostatic charge ability, and it is developed so far existing
The history of over half a century.With deepening continuously that electrically-conducting paint is researched and developed, its application is also increasingly extensive, electronics, building,
The fields such as aviation have important application value, especially have very big practical value at conductive, antistatic aspect.
Conventional conductive filler has metal dust and carbon system powder, and the coating that wherein metal dust is prepared as filler has
Preferable electric conductivity, but density metal is big, the free settling in coating, and easily oxidation causes coated conductive during service
It can decline and even lose electric conductivity.For metal packing, carbon conductive filler has density small, corrosion-resistant and electric conductivity
Can be stable the advantages of.
With the development of society, many fields such as daily life and building, ship, recirculated cooling water are all present
Antibacterial demand.Therefore, coating of the exploitation with antibacterial functions is one of direction of coatings industry development.One is added in coating
Determine anti-biotic material that is suitable, being stabilized, that is, can be made into antibiotic paint.Antibiotic paint can directly be painted on various materials
On, received much concern because its is easy to use.
The A of Chinese patent application CN 101210124 disclose a kind of electrically-conducting paint and preparation method thereof, and the coating is by weight
Amount is than meter, including following component：Film forming matter 30~55%, electrically-conducting paint auxiliary agent 1~10%, mixed diluent 40~69%；
Wherein, described film forming matter includes metal dust, its content be conductive paint vehicle weight than 15~30%.The patent is using gold
Belong to powder as the conductive compositions of coating, although with excellent electric conductivity, but cost is also of a relatively high, and corrosion resistance is not
Good, metallic pollution is serious.
Research in the prior art on being provided simultaneously with antibacterial and conductive two kinds of functional character coating is also few, and with warp
Help the development of society, increasing to the demand that is provided simultaneously with above two performance coating, therefore, development one kind is provided simultaneously with leading
The coating tool of electrical property and anti-microbial property is of great significance.
The content of the invention
The present invention is very excellent aqueous there is provided a kind of anti-microbial property and conductive capability according to the deficiencies in the prior art
Antibiotic conductive coating.
To achieve the above object, the present invention is adopted the following technical scheme that：
The present invention provides a kind of waterborne antibacterial electrically-conducting paint, is made up of the raw material of following parts by weight：
Water-based acrylic resin：24-63 parts；
Color stuffing：10-33 parts；
Carbon fiber：6-10 parts；
Graphene：6-10 parts；
ZnO/ CNT antiseptics：0.01-1 parts；
Organic silicon defoamer：0.01-1 parts；
Water：14-36 parts.
Further, the waterborne antibacterial electrically-conducting paint is made up of the raw material of following parts by weight：
Water-based acrylic resin：30-50 parts；
Color stuffing：15-30 parts；
Carbon fiber：7-9 parts；
Graphene：7-9 parts；
ZnO/ CNT antiseptics：0.3-0.8 parts；
Organic silicon defoamer：0.3-0.8 parts；
Water：20-30 parts.
Further, the waterborne antibacterial electrically-conducting paint is made up of the raw material of following parts by weight：
Water-based acrylic resin：40 parts；
Color stuffing：22 parts；
Carbon fiber：8 parts；
Graphene：8 parts；
ZnO/ CNT antiseptics：0.5 part；
Organic silicon defoamer：0.5 part；
Water：25 parts.
Further, the color stuffing is at least one of calcium carbonate, barium sulfate, mica powder, talcum powder.
Further, the ZnO/ CNTs antiseptic, its preparation method comprises the following steps：
(1) 10-20g zinc acetates are dissolved in 200-300ml diglycols, add 10-20ml distilled water, stirring
And it is warming up to 175~185 DEG C, 5-10min is persistently stirred, occurs taking out beaker after white opacity, 2-3h is stood at room temperature, nothing is obtained
Color transparent ZnO colloidal sol；
(2) CNT 0.1-0.5g, ultrasonic disperse 0.5-1h are added, 170-180 DEG C is slowly heated to, 1-2h is stirred,
Cooling is stood, is centrifuged, drying is washed, obtains ZnO/ CNT antiseptics.
Compared with prior art, beneficial effects of the present invention are：With the good feature of environmental protection, and present invention use is a variety of
Composition science compounding use, obtained coating has excellent tack, mechanical property, filming performance, antibiotic property, electric conductivity,
It is a kind of coating of excellent quality.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of waterborne antibacterial electrically-conducting paint, is made up of the raw material of following parts by weight：
Water-based acrylic resin：24 parts；
Barium sulfate：10 parts；
Carbon fiber：6 parts；
Graphene：6 parts；
ZnO/ CNT antiseptics：0.01 part；
Organic silicon defoamer：0.01 part；
Water：14 parts；
The ZnO/ CNTs antiseptic, its preparation method comprises the following steps：
(1) 10g zinc acetates are dissolved in 200ml diglycols, add 10ml distilled water, stir and be warming up to
175 DEG C, 5min is persistently stirred, occurs taking out beaker after white opacity, 2h is stood at room temperature, water white transparency ZnO colloidal sols are obtained；
(2) CNT 0.1g, ultrasonic disperse 0.5h are added, 170 DEG C are slowly heated to, 1h is stirred, cooling, centrifugation is stood
Separation, washs drying, obtains ZnO/ CNT antiseptics.
Embodiment 2
A kind of waterborne antibacterial electrically-conducting paint, is made up of the raw material of following parts by weight：
Water-based acrylic resin：63 parts；
Calcium carbonate：20 parts；
Talcum powder：13 parts
Carbon fiber：10 parts；
Graphene：10 parts；
ZnO/ CNT antiseptics：1 part；
Organic silicon defoamer：1 part；
Water：36 parts.
The ZnO/ CNTs antiseptic, its preparation method comprises the following steps：
(1) 20g zinc acetates are dissolved in 300ml diglycols, add 20ml distilled water, stir and be warming up to
185 DEG C, 10min is persistently stirred, occurs taking out beaker after white opacity, 3h is stood at room temperature, water white transparency ZnO colloidal sols are obtained；
(2) CNT 0.5g, ultrasonic disperse 1h are added, 180 DEG C are slowly heated to, 2h is stirred, cooling, centrifugation point is stood
From washing drying obtains ZnO/ CNT antiseptics.
Embodiment 3
A kind of waterborne antibacterial electrically-conducting paint, is made up of the raw material of following parts by weight：
Water-based acrylic resin：30 parts；
Calcium carbonate：5 parts；
Mica powder：10 parts；
Carbon fiber：7 parts；
Graphene：7 parts；
ZnO/ CNT antiseptics：0.3 part；
Organic silicon defoamer：0.3 part；
Water：20 parts；
The ZnO/ CNTs antiseptic, its preparation method comprises the following steps：
(1) 15g zinc acetates are dissolved in 250ml diglycols, add 15ml distilled water, stir and be warming up to
180 DEG C, 5min is persistently stirred, occurs taking out beaker after white opacity, 2.5h is stood at room temperature, water white transparency ZnO colloidal sols are obtained；
(2) CNT 0.2g, ultrasonic disperse 0.6h are added, 175 DEG C are slowly heated to, 1.5h is stirred, cooling is stood, from
The heart is separated, and is washed drying, is obtained ZnO/ CNT antiseptics.
Embodiment 4
A kind of waterborne antibacterial electrically-conducting paint, is made up of the raw material of following parts by weight：
Water-based acrylic resin：50 parts；
Barium sulfate：30 parts；
Carbon fiber：9 parts；
Graphene：9 parts；
ZnO/ CNT antiseptics：0.8 part；
Organic silicon defoamer：0.8 part；
Water：30 parts；
The ZnO/ CNTs antiseptic, its preparation method comprises the following steps：
(1) 12g zinc acetates are dissolved in 220ml diglycols, add 12ml distilled water, stir and be warming up to
178 DEG C, 7min is persistently stirred, occurs taking out beaker after white opacity, 2.3h is stood at room temperature, water white transparency ZnO colloidal sols are obtained；
(2) CNT 0.3g, ultrasonic disperse 0.9h are added, 172 DEG C are slowly heated to, 1.2h is stirred, cooling is stood, from
The heart is separated, and is washed drying, is obtained ZnO/ CNT antiseptics.
Embodiment 5
A kind of waterborne antibacterial electrically-conducting paint, is made up of the raw material of following parts by weight：
Water-based acrylic resin：40 parts；
Calcium carbonate：12 parts；
Mica powder：10 parts
Carbon fiber：8 parts；
Graphene：8 parts；
ZnO/ CNT antiseptics：0.5 part；
Organic silicon defoamer：0.5 part；
Water：25 parts；
The ZnO/ CNTs antiseptic, its preparation method comprises the following steps：
(1) 18g zinc acetates are dissolved in 280ml diglycols, add 18ml distilled water, stir and be warming up to
182 DEG C, 9min is persistently stirred, occurs taking out beaker after white opacity, 2.8h is stood at room temperature, water white transparency ZnO colloidal sols are obtained；
(2) CNT 0.4g, ultrasonic disperse 0.7h are added, 178 DEG C are slowly heated to, 1.8h is stirred, cooling is stood, from
The heart is separated, and is washed drying, is obtained ZnO/ CNT antiseptics.
Comparative example 1
In addition to ZnO/ CNT antiseptics are not added with component, other components and preparation method are same as Example 5.
Comparative example 2
In addition to carbon fiber and graphene are not added with component, other components and preparation method are same as Example 5.
Antibacterial film coating performance test
Preferably to prove that a kind of waterborne antibacterial electrically-conducting paint provided by the present invention has excellent effect, choose and implement
Example 1,2,3,4,5 distinguishes roller coat in applying body surface with comparative example 1,2, and gained film carries out performance test described in following table.
Table 3, table 4 are test index and result.
Table 3
Table 4
As a result show：
From table 3, embodiment 1-5 prepares the equal flat smooth of film, no demoulding cracking phenomena, with excellent attachment
Property, mechanical property, filming performance, antibiotic property, electric conductivity.Table 4 understands that wherein the volume of embodiment 1-5 coating is electric with the contrast of table 3
Resistance coefficient reaches 107Rank, more much smaller than the specific volume resistance of comparative example 2, electric conductivity is very excellent, show carbon fiber and
The addition of graphene makes coating have excellent electric conductivity；The antibiotic rate for adding the embodiment 1-5 coating of antiseptic is higher,
And far above comparative example 1, show that its anti-microbial property is very excellent, showing the addition of ZnO/ CNT antiseptics has coating
There is excellent anti-microbial property.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can be readily occurred in,
It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims
Scope is defined.
Claims (5)
1. a kind of waterborne antibacterial electrically-conducting paint, it is characterised in that be made up of the raw material of following parts by weight：Water soluble acrylic acid tree
Fat：24-63 parts, color stuffing：10-33 parts, carbon fiber：6-10 parts, graphene：6-10 parts, ZnO/ CNT antiseptics：
0.01-1 parts, organic silicon defoamer：0.01-1 parts, water：14-36 parts.
2. waterborne antibacterial electrically-conducting paint according to claim 1, it is characterised in that by the raw material system of following parts by weight
Into：Water-based acrylic resin：30-50 parts, color stuffing：15-30 parts, carbon fiber：7-9 parts, graphene：7-9 parts, ZnO/ carbon nanometer
Pipe antiseptic：0.3-0.8 parts, organic silicon defoamer：0.3-0.8 parts, water：20-30 parts.
3. waterborne antibacterial electrically-conducting paint according to claim 2, it is characterised in that by the raw material system of following parts by weight
Into：Water-based acrylic resin：40 parts, color stuffing：22 parts, carbon fiber：8 parts, graphene：8 parts, ZnO/ CNT antiseptics：
0.5 part, organic silicon defoamer：0.5 part, water：25 parts.
4. the waterborne antibacterial electrically-conducting paint according to claim any one of 1-3, it is characterised in that the color stuffing is carbonic acid
At least one of calcium, barium sulfate, mica powder, talcum powder.
5. the waterborne antibacterial electrically-conducting paint according to claim any one of 1-3, it is characterised in that the ZnO/ CNTs
Antiseptic, its preparation method comprises the following steps：
(1) 10-20g zinc acetates are dissolved in 200-300ml diglycols, add 10-20ml distilled water, stir and rise
Temperature persistently stirs 5-10min, occurs taking out beaker after white opacity, 2-3h is stood at room temperature, obtain colourless to 175~185 DEG C
Bright ZnO colloidal sols；
(2) CNT 0.1-0.5g, ultrasonic disperse 0.5-1h are added, 170-180 DEG C is slowly heated to, 1-2h is stirred, stood
Cooling, is centrifuged, and is washed drying, is obtained ZnO/ CNT antiseptics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710332036.3A CN106995631A (en) | 2017-05-11 | 2017-05-11 | A kind of waterborne antibacterial electrically-conducting paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710332036.3A CN106995631A (en) | 2017-05-11 | 2017-05-11 | A kind of waterborne antibacterial electrically-conducting paint |
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| CN106995631A true CN106995631A (en) | 2017-08-01 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102483A (en) * | 2018-01-02 | 2018-06-01 | 佛山实瑞先导材料研究院（普通合伙） | A kind of waterborne antibacterial electrically-conducting paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073953A (en) * | 2013-02-07 | 2013-05-01 | 苏州牛剑新材料有限公司 | Waterborne conductive ink and preparation method thereof |
| CN103108923A (en) * | 2010-07-12 | 2013-05-15 | 韩华石油化学株式会社 | Conductive coating composition and method for manufacturing a conductive layer using same |
| CN105969009A (en) * | 2016-05-31 | 2016-09-28 | 无锡伊佩克科技有限公司 | Water-based conductive paint and preparation method thereof |
-
2017
- 2017-05-11 CN CN201710332036.3A patent/CN106995631A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103108923A (en) * | 2010-07-12 | 2013-05-15 | 韩华石油化学株式会社 | Conductive coating composition and method for manufacturing a conductive layer using same |
| CN103073953A (en) * | 2013-02-07 | 2013-05-01 | 苏州牛剑新材料有限公司 | Waterborne conductive ink and preparation method thereof |
| CN105969009A (en) * | 2016-05-31 | 2016-09-28 | 无锡伊佩克科技有限公司 | Water-based conductive paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 朱路平等: "ZnO-CNTs纳米复合材料的制备及性能表征", 《物理化学学报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102483A (en) * | 2018-01-02 | 2018-06-01 | 佛山实瑞先导材料研究院（普通合伙） | A kind of waterborne antibacterial electrically-conducting paint and preparation method thereof |
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