CN106758215A - A kind of bafta hydrophobic finishing method based on the modified silicon ball electron beam technology of esters of acrylic acid - Google Patents
A kind of bafta hydrophobic finishing method based on the modified silicon ball electron beam technology of esters of acrylic acid Download PDFInfo
- Publication number
- CN106758215A CN106758215A CN201611225915.8A CN201611225915A CN106758215A CN 106758215 A CN106758215 A CN 106758215A CN 201611225915 A CN201611225915 A CN 201611225915A CN 106758215 A CN106758215 A CN 106758215A
- Authority
- CN
- China
- Prior art keywords
- silicon ball
- bafta
- electron beam
- fabric
- acrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
- D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
Landscapes
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of bafta hydrophobic finishing method based on the modified silicon ball electron beam technology of esters of acrylic acid, belong to function textile field.The inventive method uses electron beam irradiation technology, and this method can be low in room temperature reaction, energy consumption, and without adding initiator, the reaction time is short, can significantly save production cost；Monomer selects long chain acrylate, can significantly reduce the free energy of fabric face, while avoiding the environmental issue that fluorinated reagent is also easy to produce；Adding improved silica can improve the roughness of fabric face, while avoiding silica silicon ball because of the low problem of attachment fastness caused by simple physical absorption.Method with reference to low-surface-energy with Roughness is improved, by the step radiation grafting copolymerization technology of electron beam one, obtains the textile with excellent hydrophobic performance.
Description
Technical field
The present invention relates to it is a kind of based on esters of acrylic acid-the bafta hydrophobic finishing method of modified silicon ball-electron beam technology,
Belong to function textile field.
Background technology
In recent years, with the raising of people's level, textile is from simple warmth retention property gradually to comfortableness, feature side
To conversion, the application value of textile is expanded.Hydrophobic fabric has wide application market, such as outdoor sports coat, protective garment
Deng developing a kind of easy hydrophobic preparation method of fabric has immeasurable economic implications.
There is bafta the function such as comfortable and easy to wear, ventilative to be favored by people.But due in cotton fiber molecular structure
With numerous hydroxyls, hydrophily is very strong, it is easy to by water stain pollution.The hydrophobic finishing of bafta can be prevented effectively from problem above
Produce.Reducing fabric face can assign fabric certain hydrophobic performance, and increase Roughness on this basis
The hydrophobic performance of fabric can further be lifted.The conventional chemical reagent of hydrophobic finishing is generally long chain alkane class, perfluor class.Entirely
Fluorine class chemical reagent due to environmental problem can be caused, using being restricted.Traditional silicon dioxide microsphere is applied on fabric
Fabric apparent roughness can be increased, but it cannot react with cotton fiber, only be attached to fiber surface, fastness pole
It is low.The traditional handicraft of textile function finishing is hot-working method, and the technique has severe reaction conditions, equipment operation complexity etc. and asks
Topic, belongs to time-consuming, effort, feed consumption, power consumption technique.Electron radiation technology has obtained more and more should in terms of polymer modification
With, the techniques save energy, the pollution of waste water and gas can be reduced, compensate for the deficiency of traditional method of modifying.
Wang Li et al. utilize vinyltrimethoxy silane improved silica microballoon, then by the low of fluorochemical
Surface energy reagent is grafted in modified silicon ball, has good hydrophobic performance (Journal of Colloid after prepared product film forming
and Interface Science 435(2014)75–82).But because without can with bafta react chemical group, it is whole
After managing fabric, fastness can be poor；Fluorine-containing reagent can cause environmental pollution simultaneously, using also have received limitation.Also have been reported that by
Acrylic ester compound is chemically grafted on bafta, to prepare hydrophobic bafta.Although having using the fabric that this method is obtained
There is certain hydrophobic performance, but the static contact angle of fabric need to be improved.
The content of the invention
In order to solve the above problems, the invention provides it is a kind of based on esters of acrylic acid-modified silicon ball-electron beam technology
Bafta hydrophobic finishing method.Long chain acrylic ester monomer is due to containing carbochain more long, can significantly drop the low surface freedom of fabric
Energy.To build modified silicon ball be to assign silicon ball carbon-carbon double bond by the hydrolytie polycondensation of siloxanes on silicon dioxide microsphere containing double.Propylene
Acid esters and modified silicon ball all contain unsaturated double-bond, under certain condition, Covalent bonding together can occur with cotton fiber, arrange jail
Spend.Be grafted to for the acrylic ester compound containing unsaturated double-bond and modified silicon ball using electron radiation technology by the present invention
On bafta.Under the collective effect of low fabric face energy and roughness high, the textile with excellent hydrophobic performance is obtained.
The method for sorting is to impregnated in bafta containing acrylic ester compound and build improved silica containing double
In the organic solvent of silicon ball, then padding machine roll compacting redundant solution, recycles electron beam irradiation grafting, is obtained with hydrophobic after drying
The bafta of performance.
In one embodiment of the invention, the mass fraction of acrylic ester compound is in the organic solvent
5%-50%.
In one embodiment of the invention, the acrylic ester compound is acrylate or methacrylic acid
Ester or its mixing.
In one embodiment of the invention, the acrylic ester compound includes following any one or two kinds
Mixing above：Dodecylacrylate, tridecyl acrylate, acrylic acid tetradecane base ester, acrylic acid pentadecyl
Ester, aliphatic acrylate, acrylic acid heptadecane base ester, octadecyl acrylate, lauryl methacrylate, first
Base tridecyl acrylate, methacrylic acid tetradecane base ester, methacrylic acid pentadecane base ester, methacrylic acid hexadecane
Base ester, methacrylic acid heptadecane base ester, octadecyl methacrylate.
In one embodiment of the invention, the organic solvent is the mixed liquor or olefines of alkane and alcohols solvent
With the mixed liquor of alcohols solvent.The mass ratio of alkane and alcohols is 1 in mixed liquor：1-6：1；Olefines is with the mass ratio of alcohols
1：1-6：1.Wherein alkane solvents include：Hexane, heptane, octane.Olefines solvent includes：Hexene, heptene, octene.Alcohols
Solvent includes methyl alcohol, ethanol, isopropanol.Alkane or olefines organic solvent can dissolve acrylic ester compound, and alcohols is molten
Agent can improve the dispersive property of improved silica.
In one embodiment of the invention, the silicon ball of improved silica containing double bond is by vinylsiloxane
The silicon ball of modifier modification, modifying agent is 2 with the mass ratio of silica silicon ball：1-10：1.
In one embodiment of the invention, the preparation method of the silicon ball of improved silica containing double bond is specifically：
The ethanol solution of tetraethyl orthosilicate is instilled the mixed liquor of ammoniacal liquor and absolute ethyl alcohol, lasting stirring is 25 DEG C in temperature
Under the conditions of react 3h, be subsequently adding vinyltrimethoxy silane, continue to react 12 hours.
In one embodiment of the invention, the vinylsiloxane modifying agent includes vinyltrimethoxy silane
And VTES.
In one embodiment of the invention, the mass fraction of the improved silica silicon ball is 1-10%, particle diameter
It is 100nm-700nm.
In one embodiment of the invention, the time of the dipping is 5-30 minutes.
In one embodiment of the invention, the roll compacting rate of the padding machine roll compacting is 60-200%.
In one embodiment of the invention, the dosage of the electron beam irradiation is 16-65KGy.
In one embodiment of the invention, methods described is specifically：(1) bafta impregnated in and contains mass fraction
For 5%-50% acrylic ester compounds and mass fraction for the organic solvent of 1%-10% improved silicas in, during dipping
Between be 5-30 minute, control liquid carrying rate for 60%-200%；(2) it is the electron beam irradiation of 16-65KGy to use dosage, after drying
Obtain the bafta with hydrophobic performance.
Beneficial effects of the present invention：
(1) it is that hydrophobic finishing is carried out by the way of electron beam irradiation grafting by the inventive method, it is hydrophobic relative to other
Method for sorting, the method has time-consuming shorter, and capacity usage ratio is high, without adding initiator, can with room temperature reacted it is excellent
Point, reduces that the power consumption of general chemistry method is big and with serious pollution defect.
(2) monomer that the inventive method is selected is acrylic ester monomer, it is to avoid what perfluor class chemical reagent can cause
Environmental problem.Double bond is contained on modified silica particles surface can be occurred altogether by electron radiation and esters of acrylic acid and cotton fiber
Valence link is combined, and finish fabric fastness is high.
(3) the product hydrophobic effect that obtains by the inventive method is stable, reproducible, low cost, with great society and
Economic implications.
Brief description of the drawings
Fig. 1 is bafta scanning electron microscopic picture after before modified；Wherein (a) before modified, (b) is modified；
Fig. 2 is water droplet equivalent to through the existence on the modified cotton fabric before and after 30 home washings；Wherein (a) water
Before washing, after (b) washing.
Specific embodiment
Static contact angle is tested：Cloth specimen is placed on slide, 10 μ L distilled water is added dropwise, using contact angle measurement (moral
Kruss companies of state, DSA25) measurement water drop static contact angle.Every piece of cloth specimen tests 5 different locis, and takes its average value.
Water drenching is tested：With reference to GBT 4745-2012《The detection and evaluation of textile water proof performance get wet method》Testing standard,
Using instrument YB813 (Wenzhou Darong Textile Instrument Co., Ltd.) the detection resistance to water drenching performances of fabric that get wet.
Hydrostatic pressure experiment：With reference to GBT 4744-2013《The detection of textile water proof performance and evaluation hydrostatic platen press》Test
Standard, fabric resistance to hydrostatic pressure is determined using fabric seepage of water analyzer YG (B) 812 (Wenzhou Darong Textile Instrument Co., Ltd.)
Performance.Embodiment 1
Fabric：Pure cotton woven fabric (40S×40S/133*72)
Prescription：
Octadecyl methacrylate (mass fraction)：5%
Modified silicon ball：Vinyltrimethoxy silane improved silica silicon ball
Amount of modifier：Modifying agent is 6 with the mass ratio of silica silicon ball：1
Modified silicon spherolite footpath：100nm
Improved silica (mass fraction)：1%,
Solvent：Hexane is 6 with the mass ratio of ethanol：1
Dip time：5min
Pick-up：60%
Radiation：16kGy
Fabric property is shown in Table 1 after treatment.
Embodiment 2
Fabric：Pure cotton woven fabric (40S×40S/133*72)
Prescription：
Dodecyl acrylate (mass fraction)：50%
Modified silicon ball：VTES improved silica silicon ball
Amount of modifier：Modifying agent is 2 with the mass ratio of silica silicon ball：1
Modified silicon spherolite footpath：700nm
Improved silica (mass fraction)：5%,
Solvent：Hexene is 1 with the mass ratio of ethanol：1
Dip time：30min
Pick-up：200%
Radiation：65kGy
Fabric property is shown in Table 1 after treatment.
Embodiment 3
Fabric：Pure cotton woven fabric (40S×40S/133*72)
Prescription：
Octadecyl acrylate (mass fraction)：30%
Modified silicon ball：Vinyltrimethoxy silane improved silica silicon ball
Amount of modifier：Modifying agent is 4 with the mass ratio of silica silicon ball：1
Modified silicon spherolite footpath：200nm
Improved silica (mass fraction)：10%,
Solvent：Hexane is 6 with the mass ratio of ethanol：1
Dip time：5min
Pick-up：100%
Radiation：43kGy
Fabric property is shown in Table 1 after treatment.
Control 1
Fabric：Pure cotton woven fabric (40S×40S/133*72)
Prescription：
Octadecyl acrylate (mass fraction)：30%
Solvent：Hexane is 6 with the mass ratio of ethanol：1
Dip time：5min
Pick-up：100%
Radiation：43kGy
Fabric property is shown in Table 1 after treatment.
Control 2
Fabric：Pure cotton woven fabric (40S×40S/133*72)
Prescription：
Octadecyl acrylate (mass fraction)：30%
Silica silicon ball particle diameter：200nm
Silica (mass fraction)：10%
Solvent：Hexane is 6 with the mass ratio of ethanol：1
Dip time：5min
Pick-up：100%
Radiation：43kGy
Fabric property is shown in Table 1 after treatment.
Bafta rationality energy after the before processing of table 1
From table 1 and Fig. 1-2, the method for the invention can lead to acrylic ester monomer and improved silica
Cross electron radiation technology to be grafted on bafta, the fabric (embodiment 1-3) that the method for the invention is arranged has preferably quiet
State water contact angle, resistance to water drenching performance and resistance to hydrostatic pressure performance, and after equivalent to average family washing of drum type washing machine 30 times, prepare
Fabric still have extraordinary hydrophobic performance.Bafta (the embodiment 3 for not adding silicon ball is can also be seen that by the table
With control 1), hydrophobic effect is significantly lower than the finishing effect for adding modified silicon ball, and the titanium dioxide that addition is modified without double bond
The finish fabric of silicon silicon ball, although hydrophobic effect is good before washing, but there is no any hydrophobic effect (embodiment 3 and control after washing
2), showing silica cannot be chemically grafted to bafta, only physical attachment, be come off after washing, while taking away low-surface-energy
Acrylate analog assistant, cause fabric recover hydrophily.
The uniformity test of bafta hydrophobic effect：5 diverse locations of sample test after reason are rounded according to embodiment 3
Static water contact angles, its fluctuation range is 152 ± 4 °, and water droplet penetration phenomenon does not occur in sample, and hydrophobic effect is preferable.This
Outward, other schemes of embodiment 1~2 are repeated, as a result basically identical with table 1, fluctuation range very little.
The reperformance test of bafta hydrophobic effect：According to hydrophobic bafta prepared by embodiment 3,10 are arranged in batches
Secondary, every batch of Static water contact angular region of sample of test is at 152 ± 5 °.Additionally, other schemes of embodiment 1~2 are repeated,
Result is basically identical with table 1, fluctuation range very little.
Embodiment 5：Influence of the technique to hydrophobic effect
(1) esters of acrylic acid concentration
Fixed modified silicon spherolite footpath is 200nm, and when octadecyl acrylate concentration is 5%, contact angle reaches 145 °, has
Preferable hydrophobic effect；With the increase of octadecyl acrylate concentration, contact angle gradually increases, when concentration is 30%, contact
Angle reaches 152 °；Continue to increase octadecyl acrylate concentration, fabric hydrophobic effect is basically unchanged after arrangement.But because monomer is dense
Spend big, in radiative process, monomer autohemagglutination increases, be that cleaning cloth specimen below causes difficulty, meanwhile, the utilization rate drop of monomer
Low, production cost is improved.
(2) silicon ball concentration
Securing unit is octadecyl acrylate, when the silicon ball mass concentration that is modified in treatment fluid is 1%, cotton after radiation arrangement
Fabric contact angle is less than 140 °, and main cause is that silicon ball content is less, it is impossible to be effectively covered in fabric face, it is impossible to significantly improve
The roughness of fabric face, the surface free energy for relying solely on this low-surface energy substance reduction fabric of acrylic ester monomer comes
Improve hydrophobic effect.With the increase of modified silicon ball concentration, contact angle increase reaches 152 °.Main cause is probably modified silicon
Ball causes Roughness to increase in the increasing number of fabric face.When modified silicon ball concentration is more than 10%, contact
Angle is not changed in substantially.
(3) irradiation dose
Irradiation dose is crossed during less than 16kGy, and the hydrophobic effect of fabric is poor, and main cause is that emittance is too low, not enough
To trigger acrylic ester compound and containing the modified silicon ball of double bond and the graft polymerization reaction of bafta, have impact on hydrophobic monomer and exist
The covering of fabric face, grafting rate is relatively low.When dose of radiation is more than 65kGy, monomer homopolymerization increases, and system viscosity increases, together
Sample can have a negative impact to hydrophobic effect.And, radiation not only can excitation fiber, monomer and modified silicon ball occur it is anti-
Should, it is also possible to act on cellulose, when emittance is excessive, cellulose molecular chain is broken, under causing fabric mechanicses
Drop.
Although present invention preferred embodiment is disclosed as above, it is not limited to the present invention, any to be familiar with this technology
People, without departing from the spirit and scope of the present invention, can all do various changes with modification, therefore protection scope of the present invention
What should be defined by claims is defined.
Claims (10)
1. it is a kind of based on esters of acrylic acid-the bafta hydrophobic finishing method of modified silicon ball-electron beam technology, it is characterised in that
Methods described is to impregnated in bafta containing acrylic ester compound and build the organic molten of improved silica silicon ball containing double
In agent, then padding machine roll compacting redundant solution, recycles electron beam irradiation grafting, the cotton with hydrophobic performance is obtained after drying and is knitted
Thing.
2. method according to claim 1, it is characterised in that the quality of acrylic ester compound in the organic solvent
Fraction is 5%-50%.
3. method according to claim 1, it is characterised in that the mass fraction of the improved silica silicon ball is 1-
10%, particle diameter is 100nm-700nm.
4. method according to claim 1, it is characterised in that the acrylic ester compound for it is following any one or
The two or more mixing of person：Dodecylacrylate, tridecyl acrylate, acrylic acid tetradecane base ester, acrylic acid ten
Five Arrcostabs, aliphatic acrylate, acrylic acid heptadecane base ester, octadecyl acrylate, lauryl
Base ester, Tridecyl methacrylate base ester, methacrylic acid tetradecane base ester, methacrylic acid pentadecane base ester, metering system
Sour cetyl ester, methacrylic acid heptadecane base ester, octadecyl methacrylate.
5. method according to claim 1, it is characterised in that the silicon ball of improved silica containing double bond is by ethene
The silicon ball of radical siloxane modifier modification, modifying agent is 2 with the mass ratio of silica silicon ball：1-10：1.
6. method according to claim 5, it is characterised in that the vinylsiloxane modifying agent includes vinyl front three
TMOS and VTES.
7. method according to claim 1, it is characterised in that the organic solvent is the mixed liquor of alkane and alcohols solvent
Or the mixed liquor of olefines and alcohols solvent.
8. method according to claim 1, it is characterised in that the fabric dip time is 5-30 minutes, pick-up is
60-200%.
9. method according to claim 1, it is characterised in that the dose of radiation of the electron beam irradiation is 16-65kGy.
10. method according to claim 1, it is characterised in that methods described is specifically：(1) bafta impregnated in and contains
It is that 1%-10% contains the organic of the modified silicon ball of double bond for 5%-50% acrylic ester compounds and mass fraction to have mass fraction
Solvent, dip time is 5-30 minutes, and roll compacting pick-up is controlled in 60-200%；(2) it is the electronics of 16-65KGy to use dosage
Beam is irradiated, and the bafta with hydrophobic performance is obtained after drying fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611225915.8A CN106758215B (en) | 2016-12-27 | 2016-12-27 | It is a kind of based on esters of acrylic acid-modification silicon ball-electron beam technology cotton fabric hydrophobic finishing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611225915.8A CN106758215B (en) | 2016-12-27 | 2016-12-27 | It is a kind of based on esters of acrylic acid-modification silicon ball-electron beam technology cotton fabric hydrophobic finishing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106758215A true CN106758215A (en) | 2017-05-31 |
| CN106758215B CN106758215B (en) | 2019-03-01 |
Family
ID=58921492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611225915.8A Active CN106758215B (en) | 2016-12-27 | 2016-12-27 | It is a kind of based on esters of acrylic acid-modification silicon ball-electron beam technology cotton fabric hydrophobic finishing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106758215B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110462128A (en) * | 2017-03-31 | 2019-11-15 | 信越化学工业株式会社 | Electron ray cementation fibre finish |
| CN111225961A (en) * | 2017-10-18 | 2020-06-02 | 大金工业株式会社 | Coating film |
| CN111893766A (en) * | 2020-07-28 | 2020-11-06 | 西安科技大学 | Preparation method of multifunctional pH-responsive super-wetting material and application of multifunctional pH-responsive super-wetting material in oil-water separation |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103290674A (en) * | 2012-02-28 | 2013-09-11 | 明仁精细化工（嘉兴）有限公司 | Treatment method and treatment liquid for preparing fluoride-free super-hydrophobic cotton fabric |
| CN104264468A (en) * | 2014-10-22 | 2015-01-07 | 湖北久瑞核技术股份有限公司 | Preparation method for water-repellent textile |
| CN105220475A (en) * | 2015-10-10 | 2016-01-06 | 江南大学 | A kind of COTTON FABRIC hydrophobic finishing method based on acetic anhydride-esters of acrylic acid-electron beam technology |
| CN105220474A (en) * | 2015-10-10 | 2016-01-06 | 江南大学 | A kind of COTTON FABRIC hydrophobic finishing method based on esters of acrylic acid and electron beam technology |
-
2016
- 2016-12-27 CN CN201611225915.8A patent/CN106758215B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103290674A (en) * | 2012-02-28 | 2013-09-11 | 明仁精细化工（嘉兴）有限公司 | Treatment method and treatment liquid for preparing fluoride-free super-hydrophobic cotton fabric |
| CN104264468A (en) * | 2014-10-22 | 2015-01-07 | 湖北久瑞核技术股份有限公司 | Preparation method for water-repellent textile |
| CN105220475A (en) * | 2015-10-10 | 2016-01-06 | 江南大学 | A kind of COTTON FABRIC hydrophobic finishing method based on acetic anhydride-esters of acrylic acid-electron beam technology |
| CN105220474A (en) * | 2015-10-10 | 2016-01-06 | 江南大学 | A kind of COTTON FABRIC hydrophobic finishing method based on esters of acrylic acid and electron beam technology |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110462128A (en) * | 2017-03-31 | 2019-11-15 | 信越化学工业株式会社 | Electron ray cementation fibre finish |
| CN111225961A (en) * | 2017-10-18 | 2020-06-02 | 大金工业株式会社 | Coating film |
| CN111893766A (en) * | 2020-07-28 | 2020-11-06 | 西安科技大学 | Preparation method of multifunctional pH-responsive super-wetting material and application of multifunctional pH-responsive super-wetting material in oil-water separation |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106758215B (en) | 2019-03-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105131174B (en) | It is common to lasting uvioresistant finishing agent of cotton and terylene and preparation method thereof | |
| CN102127186B (en) | Method for preparing fluorine-containing silicon acrylate emulsion | |
| CN101928367B (en) | Environmentally-friendly acrylic ester coating printing adhesive emulsion and preparation method | |
| CN104672403B (en) | A kind of environmentally friendly silicone acrylic emulsion and preparation method thereof | |
| EP2071072B1 (en) | Treatment composition for textile products | |
| CN106758215B (en) | It is a kind of based on esters of acrylic acid-modification silicon ball-electron beam technology cotton fabric hydrophobic finishing method | |
| CN105601799B (en) | Core/shell type organosilicon-modified acrylate emulsion and its preparation method and application | |
| CN106381709B (en) | For super-hydrophobic and anti UV finishing agent, the preparation method and applications of textile | |
| CN109281172B (en) | Core-shell type fluorine-free waterproof finishing agent and preparation method and application thereof | |
| CN109667154A (en) | A kind of organic silicon rigidity-increasing depth finishing agent and its preparation process | |
| CN110184822A (en) | A kind of fabric fluffy softening agent and preparation method thereof | |
| CN104404763B (en) | A kind of preparation method of the wool fabric of antistatic, felt proofing and good dyeability | |
| CN110230216A (en) | A kind of Lyocell fibers fabric of natural dye dying and preparation method thereof | |
| CN109930386A (en) | A kind of preparation method of the washable superhydrophobic fabric of pressure resistance | |
| CN104119483A (en) | Preparing method of modified acrylate emulsion | |
| CN105859950B (en) | A kind of hud typed fluorine-containing siliceous Long carbon chain acrylate water-repellent oil-repellent agent | |
| CN107700216A (en) | A kind of preparation method of nano modification fluorine-containing textile finishing agent | |
| CN104109975A (en) | Modified acrylate printing emulsion and preparation method thereof | |
| CN108864774A (en) | A kind of preparation method of the reactive self-dispersing nano carbon black of cotton fabric dyeing process | |
| CN106012543A (en) | Fluoride-free water-repellent antifouling finishing agent and preparation method and application thereof | |
| CN109680522B (en) | Organic silicon modified coating printing paste for textiles and preparation method thereof | |
| CN105220474A (en) | A kind of COTTON FABRIC hydrophobic finishing method based on esters of acrylic acid and electron beam technology | |
| CN110079992A (en) | A kind of preparation method of superhydrophobic fabric | |
| CN106087421B (en) | Soil-releasing finishing agent and its preparation method and application | |
| CN106283664B (en) | Hydrophobic performance can selfreparing water-fastness fabric preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201009 Address after: No.2657, Qingyuan Road, Gaobo County, Shandong Province Patentee after: Gaoqing Ruyi Textile Co., Ltd Address before: 1800 No. 214122 Jiangsu city of Wuxi Province Li Lake Avenue Patentee before: Jiangnan University |