CN106699267A - Method for producing organic fertilizers by utilizing waste bacteria sticks and excrements - Google Patents
Method for producing organic fertilizers by utilizing waste bacteria sticks and excrements Download PDFInfo
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- CN106699267A CN106699267A CN201710156343.0A CN201710156343A CN106699267A CN 106699267 A CN106699267 A CN 106699267A CN 201710156343 A CN201710156343 A CN 201710156343A CN 106699267 A CN106699267 A CN 106699267A
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- zymocyte liquid
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- 241000894006 Bacteria Species 0.000 title claims abstract description 25
- 239000003337 fertilizer Substances 0.000 title abstract description 29
- 239000002699 waste material Substances 0.000 title abstract description 6
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 238000000855 fermentation Methods 0.000 claims abstract description 27
- 230000004151 fermentation Effects 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 11
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 241000228212 Aspergillus Species 0.000 claims abstract description 6
- 241000235342 Saccharomycetes Species 0.000 claims abstract description 5
- 239000004310 lactic acid Substances 0.000 claims abstract description 5
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 5
- 241000193830 Bacillus <bacterium> Species 0.000 claims abstract description 4
- 241000233866 Fungi Species 0.000 claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 239000003895 organic fertilizer Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 7
- 241000213006 Angelica dahurica Species 0.000 claims description 5
- 241000196324 Embryophyta Species 0.000 claims description 5
- 239000004568 cement Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 235000020681 well water Nutrition 0.000 claims description 5
- 239000002349 well water Substances 0.000 claims description 5
- 241000186046 Actinomyces Species 0.000 claims description 4
- 244000025254 Cannabis sativa Species 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 235000015099 wheat brans Nutrition 0.000 claims description 3
- 239000012634 fragment Substances 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 abstract description 5
- 244000046052 Phaseolus vulgaris Species 0.000 abstract description 4
- 235000010627 Phaseolus vulgaris Nutrition 0.000 abstract description 4
- 240000008042 Zea mays Species 0.000 abstract description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 4
- 235000005822 corn Nutrition 0.000 abstract description 4
- 241000186361 Actinobacteria <class> Species 0.000 abstract 1
- 241000186000 Bifidobacterium Species 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 11
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 5
- 239000005696 Diammonium phosphate Substances 0.000 description 4
- 241000209140 Triticum Species 0.000 description 4
- 235000021307 Triticum Nutrition 0.000 description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 4
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 4
- 235000019838 diammonium phosphate Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 241000726221 Gemma Species 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 230000000384 rearing effect Effects 0.000 description 1
- 239000002881 soil fertilizer Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Soil Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Fertilizers (AREA)
Abstract
The invention provides a method for producing organic fertilizers by utilizing waste bacteria sticks and excrements. The method comprises the following steps: 1) preparing fermented liquid, namely uniformly mixing, stirring and brewing the following components in parts by weight for 10-24 hours: 0.5-3 parts of culture, 30-100 parts of water, 0.1-1 part of brown sugar, 5-20 parts of corn flour, 5-20 parts of bean flour and 10-40 parts of bran, wherein the culture refers to at least one of bifidobacterium, lactic acid bacteria, bacillus, aspergillus, saccharomycetes, actinomycetes and acetic bacteria; 2) mixing the prepared fermented liquid and waste bacteria sticks and excrements according to a weight ratio of (1):(40-100):(20-150), and uniformly stirring; 3) fermenting, namely adding the mixed fermentation raw materials into a container or compositing into a heap with the height of 1m and width of 2m for fermenting, wherein the temperature is -15 DEG C to 40 DEG C, and the fermentation time is 4-10 days. According to the method, the waste bacteria sticks polluting the environment can be fully utilized, random discard of the bacteria sticks is reduced, and innocent treatment is realized.
Description
Technical field
It is more particularly to a kind of to produce organic fertilizer using obsolete fungus stick and excrement the invention belongs to organic fertilizer technical field
The method of material.
Background technology
Economy is developed rapidly in recent years for China, and the depletion of non-renewable resources such as coal oil increases year by year so that the energy is tight
The problems such as scarce and environmental pollution increasingly shows comes.Nonrenewable resources faces exhaustion has turned into global crisis.To new energy
Exploitation have become one of the Chinese government and scientific research institution's focus of attention problem.China has developed at this stage
Resource mainly including workers and peasants' organic waste, animal residue and cities and towns solid-state fluorescence material etc., service condition is fairly limited.
In the Northeast of China, every household cultivates agaric and mushroom, and the cultivation of agaric and mushroom can produce substantial amounts of giving up
Abandon bacterium rod.Obsolete fungus stick utilization rate is extremely low, in addition to small part is applied to animal feed, soil fertilizer and circulating cultivation, big portion
Divide and directly discarded or burnt, resource is not utilized effectively, while also not allowing the pollution that surrounding environment is caused
Ignore.
The obsolete fungus stick of mushroom and agaric can not be ignored as the scrap feed material after planting edible mushroom, nutritive value.How
Effectively the mushroom using substantial amounts and the obsolete fungus stick of agaric, could preferably embody plant resources higher value application and agricultural
The theory of resource circulation utilization.Sustainable use while this causes to turn waste into wealth to resource also functions to directive function, protection
Certain economic benefit can be brought while environment again.
The content of the invention
In order to solve the above-mentioned technical problem, it is organic using obsolete fungus stick and excrement production it is an object of the invention to provide one kind
The method of fertilizer, the method can make full use of the obsolete fungus stick of pollution environment, reduce the discarding carelessly of bacterium rod, play innoxious place
Reason, while producing organic fertilizer jointly for microbial fermentation provides raw material using the animal wastes and bacterium rod of plant.This is organic
Fertilizer can increase the content of the soil organism, improve soil texture, improve the resistance of soil, while reducing chemical fertilizer and agricultural chemicals
Use, there is provided the quality of crop products, allow the output high-quality crop of the sustainable stabilization in soil, and this method is produced into
This is low, and method is simple and easy to apply.
To achieve the above object, the invention provides a kind of method that utilization obsolete fungus stick and excrement produce organic fertilizer,
The method is comprised the following steps:
1) preparation of zymocyte liquid:By the following brewed 10-24h of component mixing and stirring of weight portion:
Wherein, the strain is double root of Dahurian angelica bacterium, lactic acid bacteria, bacillus, Aspergillus, saccharomycete, in actinomyces and acetic acid bacteria
At least one;
2) zymocyte liquid and obsolete fungus stick that will prepare and excrement with weight ratio be 1:40-100:The ratio of 20-150 is mixed
Close, stir;
3) ferment:Mixed fermentation raw material is put into container or heap is made high 1 meter, 2 meters wide of heap is fermented, temperature
It it is -15 DEG C -40 DEG C, fermentation time is 4-10 days.
Preferably, the step 1) zymocyte liquid be formulated as the component of following parts by weight is mixed:
The preparation of the zymocyte liquid is more preferably:
Preferably, the obsolete fungus stick is the useless rod after black fungus hair bacterium.
It is further preferred that the chaff, bran class can include crop material, cavings, wheat bran, weeds, cauline leaf the like waste;
The stalk, weeds, cauline leaf is being broken for length or fragment that width is 1-3cm using preceding with grass chopper.
Preferably, the step 3) in container be feed vessel or cement pit.
Preferably, in the zymocyte liquid add water for well water or river or boil placement at least 24 hours after
Running water.
Preferably, in step 2) water added in whipping process, be to cause step 3) in mixed fermentation raw material
Wet weight is 45%-65%;, webs water breakthrough but not drop of water agglomerating to hold are mixed, is loosed one's grip and dissipate as optimal.Because if
Water content is more, and the fertilizer after fermentation is easily sour, and moisture content less then ferments not thorough.The wet weight is more preferably
65%.
Preferably, the step 3) in fermentation temperature be 15-35 DEG C.
Preferably, the step 3) in fermentation process need with covered rearing with plastic film container or cement pit, it is small per 10-12
Shi Rengong spades turn over the shovel fermentation raw material so that mixed fermentation fertilizer is contacted fully during the fermentation, and fermentation is complete.
Preferably, fermentation time summer be generally 4 days or so, spring and autumn be 7 days or so, winter be 10 days or so, subzero
Less than 15 DEG C still can normally play warm fermentation, be quickly turned to organic fertilizer.
Microbial organic fertilizer after fermentation, nutrient is complete, being capable of improved soil, the soil that improvement is caused using chemical fertilizer
It is hardened.Improve soil physical and chemical property, enhancing soil water-retaining, fertilizer conservation, the ability of fertilizer.The fertilizer efficiency of the biological organic fertilizer is generalization
Learn fertilizer 1-2 times, per mu yield improves 20-50%.
Specific embodiment
Embodiment 1
1) preparation of zymocyte liquid:By strain, 50 parts of well water, 0.5 part of brown sugar, 15 parts of corn flour, 10 that weight portion is 1 part
Part bean powder, the blending ingredients of 25 parts of cavings stir brewed 24h;Wherein, the strain is double root of Dahurian angelica bacterium, Aspergillus, saccharomycete,
Actinomyces and the mixing of acetic acid bacteria, mixed proportion compare 2 for weight:1:5:1:3;
2) zymocyte liquid and obsolete fungus stick that will prepare and excrement with weight ratio be 1:50:100 ratio mixing, is stirring
Mix and stir in machine;
3) ferment:Mixed fermentation raw material heap is made high 1 meter, 2 meters wide of heap is fermented, temperature is 15 DEG C, hair
The ferment time is 6 days, is containing vinosity until being destitute of smell and fermented successfully.
Embodiment 2
1) preparation of zymocyte liquid:By strain, 80 parts of well water, 0.5 part of brown sugar, 10 parts of corn flour, 15 that weight portion is 1 part
Part bean powder, the blending ingredients of 20 parts of wheat bran stir brewed 24h;Wherein, the strain is double root of Dahurian angelica bacterium, lactic acid bacteria, Aspergillus
Mixing, mixed proportion compares 2 for weight:2:5;
2) zymocyte liquid and obsolete fungus stick that will prepare and excrement with weight ratio be 1:50:50 ratio mixing, is stirring
Mix and stir in machine;
3) ferment:Mixed fermentation raw material is put into cement pit and is fermented, temperature is -15 DEG C, fermentation time is
10 days, it is containing vinosity until being destitute of smell and is fermented successfully.
Embodiment 3
1) preparation of zymocyte liquid:By strain that weight portion is 1 part, 100 parts of well water, 0.5 portion of brown sugar, 12 portions of corn flour,
15 parts of bean powderes, the blending ingredients of 30 parts of cavings stir brewed 24h;Wherein, the strain is double root of Dahurian angelica bacterium, lactic acid bacteria, gemma
The mixing of bacillus, Aspergillus, saccharomycete, actinomyces and acetic acid bacteria, mixed proportion compares 1 for weight:2:5:1:2:2:1;
2) zymocyte liquid and obsolete fungus stick that will prepare and excrement with weight ratio be 1:100:100 ratio mixing,
Stirred in mixer;
3) ferment:Mixed fermentation raw material is put into cement pit and is fermented, temperature is 25 DEG C, and fermentation time is 4
My god, it is containing vinosity until being destitute of smell and is fermented successfully.
Test and comparative example
Used the fertilizer of above-mentioned preparation as base fertilizer, concomitant fertilizer and topdressing.When being used as base fertilizer, 3- before planting
10 angels are used in underground, and every mu of wheat is with 1 ton of fertilizer;Concomitant fertilizer, every mu of 500 kilogram of fertilizer of wheat seed are done at seeding time;With
With 1 ton of above-mentioned fertilizer when topdressing, applied fertilizer stage by stage in wheat growth stage, specific fertilising process applies common with local
Fertilizer is identical.
The fertilizer of above-described embodiment 1-3 is administered in the essentially identical field of matrix respectively, wherein with common urea and
Diammonium phosphate (DAP) is contrast, and fertilization mode and consumption are above-mentioned same way and consumption.Concrete outcome is as follows.
The effect of the different fertilizer of table 1
Fertilizer | Wheat per mu yield (jin) |
Embodiment 1 | 956 |
Embodiment 2 | 936 |
Embodiment 3 | 987 |
Urea | 753 |
Diammonium phosphate (DAP) | 641 |
Under conditions of being -15 DEG C -40 DEG C in outdoor temperature, the organic fertilizer that the present invention is produced using obsolete fungus stick and excrement
Embody per mu yield higher.In the soil hardening that improved soil, improvement are caused using chemical fertilizer, enhancing soil water-retaining, fertilizer conservation, confession
While the ability of fertilizer, the fertilizer efficiency of biological organic fertilizer prepared by the present invention is 1-2 times of general chemistry fertilizer, and per mu yield is improved
20-50%.
It is described above various embodiments of the present invention, described above is exemplary, and non-exclusive, and
It is not limited to disclosed each embodiment.In the case of without departing from the scope and spirit of illustrated each embodiment, for this skill
Many modifications and changes will be apparent from for the those of ordinary skill in art field.
Claims (9)
1. a kind of method that utilization obsolete fungus stick and excrement produce organic fertilizer, the method is comprised the following steps:
1) preparation of zymocyte liquid:By the following brewed 10-24h of component mixing and stirring of weight portion:
Wherein, the strain is double root of Dahurian angelica bacterium, lactic acid bacteria, bacillus, Aspergillus, saccharomycete, in actinomyces and acetic acid bacteria extremely
Few one kind;
2) zymocyte liquid and obsolete fungus stick that will prepare and excrement with weight ratio be 1:40‐100:The ratio mixing of 20-150,
Stir;
3) ferment:Mixed fermentation raw material is put into container or heap is made high 1 meter, 2 meters wide of heap is fermented, temperature for-
15 DEG C -40 DEG C, fermentation time is 4-10 days.
2. method according to claim 1, it is characterised in that the step 1) zymocyte liquid is formulated as following weight
The component mixing of number:
3. method according to claim 2, it is characterised in that the step 1) zymocyte liquid is formulated as following weight
The component mixing of number:
4. method according to claim 1, it is characterised in that the obsolete fungus stick is the useless rod after black fungus hair bacterium.
5. method according to claim 1, it is characterised in that the chaff, bran class include crop material, cavings, wheat bran is miscellaneous
Grass, cauline leaf discarded object;The stalk, weeds, cauline leaf is to be broken for length or width with grass chopper be 1-3cm's using preceding
Fragment.
6. method according to claim 1, it is characterised in that the water added in the zymocyte liquid is well water or river
Or boil the running water after placing at least 24 hours.
7. method according to claim 1, it is characterised in that in step 2) water added in whipping process is to make
Step 3) in mixed fermentation raw material wet weight be 45%-65%.
8. method according to any one of claim 1 to 7, it is characterised in that the step 3) in fermentation temperature be
15‐35℃。
9. method according to claim 8, it is characterised in that the step 3) in fermentation process need to use plastic sheeting
Covering container or cement pit, per 10-12 hours, artificial spade turned over the shovel fermentation raw material.
Priority Applications (1)
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CN201710156343.0A CN106699267A (en) | 2017-03-16 | 2017-03-16 | Method for producing organic fertilizers by utilizing waste bacteria sticks and excrements |
Applications Claiming Priority (1)
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CN201710156343.0A CN106699267A (en) | 2017-03-16 | 2017-03-16 | Method for producing organic fertilizers by utilizing waste bacteria sticks and excrements |
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Publication Number | Publication Date |
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CN201710156343.0A Pending CN106699267A (en) | 2017-03-16 | 2017-03-16 | Method for producing organic fertilizers by utilizing waste bacteria sticks and excrements |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111875449A (en) * | 2020-08-10 | 2020-11-03 | 孙文东 | Fermentation culture material, fermentation method, fermentation product and application of waste mushroom sticks |
CN114409471A (en) * | 2022-01-21 | 2022-04-29 | 窑街煤电集团有限公司 | Mineral source biochar soil conditioner and preparation method thereof |
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CN102241532A (en) * | 2010-05-15 | 2011-11-16 | 夏道广 | Method for producing organic fertilizer with biological bacteria and agricultural wastes |
CN103274782A (en) * | 2013-06-01 | 2013-09-04 | 浙江大学 | Method for producing pig manure organic fertilizer by employing waste bacteria stick |
CN104370584A (en) * | 2013-08-12 | 2015-02-25 | 天津蓟县龙善源农业生态科技有限公司 | Organic fertilizer prepared from waste mushroom sticks and preparation method thereof |
CN104774054A (en) * | 2015-04-28 | 2015-07-15 | 永州万喜登农业发展有限公司 | Bio-organic fertilizer |
CN105218254A (en) * | 2015-11-04 | 2016-01-06 | 广西多得乐生物科技有限公司 | A kind of Microbial and ecological organic fertilizers material and preparation method thereof |
-
2017
- 2017-03-16 CN CN201710156343.0A patent/CN106699267A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102241532A (en) * | 2010-05-15 | 2011-11-16 | 夏道广 | Method for producing organic fertilizer with biological bacteria and agricultural wastes |
CN103274782A (en) * | 2013-06-01 | 2013-09-04 | 浙江大学 | Method for producing pig manure organic fertilizer by employing waste bacteria stick |
CN104370584A (en) * | 2013-08-12 | 2015-02-25 | 天津蓟县龙善源农业生态科技有限公司 | Organic fertilizer prepared from waste mushroom sticks and preparation method thereof |
CN104774054A (en) * | 2015-04-28 | 2015-07-15 | 永州万喜登农业发展有限公司 | Bio-organic fertilizer |
CN105218254A (en) * | 2015-11-04 | 2016-01-06 | 广西多得乐生物科技有限公司 | A kind of Microbial and ecological organic fertilizers material and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111875449A (en) * | 2020-08-10 | 2020-11-03 | 孙文东 | Fermentation culture material, fermentation method, fermentation product and application of waste mushroom sticks |
CN114409471A (en) * | 2022-01-21 | 2022-04-29 | 窑街煤电集团有限公司 | Mineral source biochar soil conditioner and preparation method thereof |
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RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170524 |
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