CN106350308B - A kind of salt composite for cleaning metal and porcelain and clean method is carried out to metal and porcelain - Google Patents
A kind of salt composite for cleaning metal and porcelain and clean method is carried out to metal and porcelain Download PDFInfo
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- CN106350308B CN106350308B CN201610721773.8A CN201610721773A CN106350308B CN 106350308 B CN106350308 B CN 106350308B CN 201610721773 A CN201610721773 A CN 201610721773A CN 106350308 B CN106350308 B CN 106350308B
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- porcelain
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- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 111
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 100
- 239000002184 metal Substances 0.000 title claims abstract description 100
- 238000004140 cleaning Methods 0.000 title claims abstract description 54
- 150000003839 salts Chemical class 0.000 title claims abstract description 38
- 239000002131 composite material Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000001509 sodium citrate Substances 0.000 claims abstract description 6
- 235000011083 sodium citrates Nutrition 0.000 claims abstract description 6
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims abstract description 6
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid group Chemical class S(N)(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920002752 Konjac Polymers 0.000 claims description 22
- 102000003886 Glycoproteins Human genes 0.000 claims description 10
- 108090000288 Glycoproteins Proteins 0.000 claims description 10
- 239000007853 buffer solution Substances 0.000 claims description 8
- 235000013312 flour Nutrition 0.000 claims description 8
- 230000001376 precipitating effect Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000004515 gallic acid Nutrition 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001868 water Inorganic materials 0.000 claims description 6
- WZHCOOQXZCIUNC-UHFFFAOYSA-N cyclandelate Chemical class C1C(C)(C)CC(C)CC1OC(=O)C(O)C1=CC=CC=C1 WZHCOOQXZCIUNC-UHFFFAOYSA-N 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 4
- 235000000346 sugar Nutrition 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 235000010485 konjac Nutrition 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 3
- 238000002137 ultrasound extraction Methods 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 15
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 7
- 238000010186 staining Methods 0.000 abstract description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 208000037656 Respiratory Sounds Diseases 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 235000015165 citric acid Nutrition 0.000 description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- 208000010392 Bone Fractures Diseases 0.000 description 3
- 206010017076 Fracture Diseases 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 210000003298 dental enamel Anatomy 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical compound O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000006481 Colocasia esculenta Nutrition 0.000 description 1
- 240000004270 Colocasia esculenta var. antiquorum Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- IWYDHOAUDWTVEP-UHFFFAOYSA-N R-2-phenyl-2-hydroxyacetic acid Natural products OC(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229960002510 mandelic acid Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3726—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention provides a kind of salt composite for cleaning metal and porcelain and carries out clean method to metal and porcelain, the salt composite includes the component of following parts by weight: 50 ~ 70 parts of crude salts, 15 ~ 35 parts of sulfamic acids, 5 ~ 10 parts of sodium citrates and 1 ~ 8 part of citric acid, and the method is used to clean metal described in and the salt composite of porcelain cleans metal and porcelain.Metal and porcelain are cleaned using salt composite of the present invention; the spot and rust staining of metal, porcelain surface can be removed with deep layer; and metal and porcelain will not be caused to corrode; avoid the occurrence of cracked fracture of metal is corroded with porcelain surface; metal and porcelain after being cleaned using salt composite of the present invention long-acting can also be guaranteed to be not easy to be infected with spot and got rusty, and have protection effect to metal and porcelain.
Description
Technical field
The invention belongs to detergent technical fields, and in particular to a kind of salt composite for cleaning metal and porcelain and right
Metal and porcelain carry out clean method.
Background technique
Metal causes metal surface because easily reacting with the oxygen in air, and then be easy to appear the phenomenon that getting rusty
It has rusty stains, has seriously affected and used texture and beauty.There are many subtle apertures, use of these apertures in porcelain in porcelain
It is easy to absorb the color and ingredient for installing substance in porcelain in the process, and then be easy to cause in porcelain to be formed and can not much clean
The spot removed, and the glaze on porcelain surface also will receive the influence of extraneous humidity, temperature and illumination ultraviolet light in use,
And then it is easy to make the glaze decoloration on porcelain surface or fall off, and then make porcelain itself to be easier to be exposed in external environment.
Based on this, the prior art develops detergent for cleaning metal and porcelain, but the acid that existing cleaning agent uses
Class, which cleans the multipair metal of ingredient and porcelain, has deep-etching effect, can react with metal and generate hydrogen, and the hydrogen of generation is expanded
It is scattered in the lattice voids of metal, metal is made to be easy to appear crackle, and can also react with ingredients such as calcium carbonate in porcelain,
Make to generate more tiny micropores in porcelain, cause the total quality of porcelain to be deteriorated, be easily broken, these tiny micropores are also more
It is easy to absorb coloring matter, the porcelain after making cleaning is easier absorption spot in later period use.In addition, existing detergent is only
In order to obtain instant cleaning effect, and do not have the function that the article after protection cleaning no longer got rusty easily or be infected with spot.It is comprehensive
The upper existing metal and the cleaning products of porcelain of can be seen that has certain shortcoming.
Summary of the invention
In view of the above shortcomings of the prior art, the technical problem to be solved by the present invention is being directed to existing cleaning agent
Metal and porcelain are easily corroded, so that metal is easy to appear crackle, porcelain, which generates more tiny micropores, causes porcelain total quality to become
Difference, and do not have the technical issues of article after protection cleaning no longer gets rusty easily or is infected with spot, and providing one kind will not be right
Metal and porcelain cause to corrode, and can it is long-acting keep cleaning after article no longer get rusty or be infected with spot for clean metal with
The salt composite of porcelain and clean method is carried out to metal and porcelain.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical scheme: it is a kind of for cleaning metal and porcelain
Salt composite, the component including following parts by weight: 50 ~ 70 parts of crude salts, 15 ~ 35 parts of sulfamic acids, 5 ~ 10 parts of sodium citrates and 1 ~ 8
Part citric acid.When using salt composite of the present invention, the frosted and suction-operated that can use crude salt are to metal and porcelain surface
Spot is purged and adsorbs, and crude salt also has dissipation effect to the bacterium of metal, porcelain surface, after cleaning is effectively ensured
Product surface flora sum is reduced, and there is no there is pathogenic bacteria, and that more crucially present invention is particularly directed to the prior arts is clear
Acid used in clean dose is easy to react with metal and generates hydrogen, and then metal is caused to be easy to generate crackle, or in which acid hold
It is easily reacted with ingredients such as calcium carbonate in porcelain, makes the technical issues of hole increases, quality is deteriorated in porcelain, especially through research
It was found that compound with citric acid as acid clean ingredient using sulfamic acid, acid can guaranteed to metal, porcelain surface
Spot while effectively cleaned, metal will not be caused to corrode and crack metal surface, will not be with porcelain
In the ingredients such as calcium carbonate react, the cavity in porcelain will not be made to become more, the enamel on porcelain surface will not be corroded, clear
It is clean while rigid injury is not caused to porcelain and metal, effectively extend the service life of porcelain and metal.
It further, further include 2 ~ 5 parts of mandelic acids and 3 ~ 8 parts of gallic acids.Pass through mandelic acid, gallic acid, sulfamic acid
With the collaboration compatibility effect of citric acid, the coloured stains for aoxidizing rust staining and porcelain surface of metal surface can also be carried out deeply
Degree cleaning, the metal surface after making cleaning is smooth, and the porcelain after cleaning is without local color spot, and cleaning effect is more preferably.
It further, further include 4 ~ 9 parts of aqueous polyurethanes.The present invention can be used to fill up metal by compounding aqueous polyurethane
With the already existing crackle in porcelain surface, makes the smooth non-notch of metal and porcelain surface after repairing, effectively prevent because existing
Crackle and the generation for leading to metal and porcelain phenomenon of rupture, and the aqueous polyurethane added can also completely cut off to a certain extent air and
Metal porcelain reduces external environment adverse effect caused by metal, porcelain.
It further include 2 ~ 7 parts of konjaku glycoprotein as optimization；The konjaku glycoprotein is made with the following method:
1) it by konjaku cleaning, peeling, is crushed after dry 8 ~ 12h at 60 ~ 80 DEG C, obtains konjaku flour；
2) by konjaku flour described in step 1) and Na2HPO4-NaH2PO4Buffer solution is with the mass body of the mL of 1 g:200 ~ 400
Product after 50 ~ 70 DEG C of 2 ~ 4 h of extraction, takes leaching liquor to filter than mixing, collects clear liquid；
3) clear liquid that step 2 is collected is mixed with ethyl alcohol according to the volume ratio of 1:2 ~ 4 and stands 5 ~ 8h at room temperature
Afterwards, precipitating is collected；
4) it washes with water precipitating at least twice, dry 6 ~ 8 h will be deposited at 60 ~ 80 DEG C after cleaning, obtain the evil spirit
Taro glycoprotein.
The present invention also only has instant cleaning effect particular for detergent in the prior art, and cannot long-acting guarantee porcelain
The technical issues of no longer getting rusty with metal or be infected with spot, by research discovery by compounding konjaku glycoprotein can in porcelain and
Metallic surface forms layer protecting film, metal and porcelain can be opened with external environment isolation, and then avoid air and water
Vapour directly forms rust staining with metal reaction, also avoid external environment to porcelain impact and caused by porcelain disorganization
The problem of with turning yellow；And the konjaku glycoprotein of addition also has certain bacteriostasis, it can be raw to avoid metal and porcelain surface
Long mould and moss.
As another optimization, the Na of pH6.0 ~ 7.2 is used in step 22HPO4-NaH2PO4Buffer solution.Using such pH
The buffer solution of range can be to avoid because pH is improper to make glycoprotein activity fail the problem of, and then sugar obtained is effectively ensured
Albumen can form protective film in article surface.
Optimize as another, by konjaku flour described in step 1) and Na in step 22HPO4-NaH2PO4Buffer solution is with 1 g:
The mass volume ratio of 200 ~ 400 mL is uniformly mixed, 2 ~ 4 h of ultrasound extraction at 50 ~ 70 DEG C, wherein the power of the ultrasound is
300~450 W.It is extracted using ultrasonic wave, extraction efficiency can be made higher, extracted more konjaku glycoprotein, make to produce
Cost reduces.
The method that a kind of pair of metal and porcelain are cleaned, using described for cleaning the salt composite pair of metal and porcelain
Metal and porcelain are cleaned.Metal and porcelain are cleaned using salt composite of the present invention, metal, porcelain can be removed with deep layer
The spot and rust staining on device surface, and metal and porcelain will not be caused to corrode, avoid the cracked fracture of metal and porcelain table
The occurrence of face is corroded, metal and porcelain after being cleaned using salt composite of the present invention long-acting can also guarantee to be not easy contaminant
It provides and gets rusty, there is protection effect to metal and porcelain.
As optimization, by the salt composite for being used to clean metal and porcelain and water according to the quality of the mL of 1g:10 ~ 50
Volume ratio is hybridly prepared into cleaning solution, is cleaned using the cleaning solution to metal and porcelain.Present aspect salt composite is matched
It after aqueous solution, then pays metal and porcelain is cleaned, the elimination effect of compound can be made more preferable, cleaning effect is more excellent.
Compared with prior art, the invention has the following beneficial effects: use to remove when salt composite of the present invention with deep layer
Metal, the spot on porcelain surface and rust staining, and acid crucially more can guaranteed using the formula of salt composite of the present invention
While effectively clean the spot of metal, porcelain surface, metal will not be caused to corrode and generate metal surface to split
Line will not react with ingredients such as calcium carbonate in porcelain, and the cavity in porcelain will not be made to become more, will not corrode porcelain
The enamel on surface in cleaning while not causing rigid injury to porcelain and metal, effectively extends the use of porcelain and metal
Time limit.In addition, Component Source is extensive in inventive formulation, price is more cheap, receives use by vast producer, has good
Good market application prospect.
Specific embodiment
Invention is further described in detail combined with specific embodiments below.The implementation case is being with the technology of the present invention
Under the premise of implemented, now provide detailed embodiment and specific operating process illustrate the present invention it is creative, but
Protection scope of the present invention embodiment not limited to the following.
Embodiment 1
It is a kind of for cleaning the salt composite of metal and porcelain, the component including following parts by weight: 50 parts of crude salts, 15 parts of ammonia
Base sulfonic acid, 5 parts of sodium citrates, 1 part of citric acid, 2 parts of mandelic acids and 3 parts of gallic acids.
Metal and porcelain are cleaned using the present embodiment salt composite, the metal surface after cleaning as the result is shown is without dirt
Stain has apparent metallic luster, and cleaning does not make metal surface cracked, and the porcelain after cleaning is restored to this by yellow
Color, and cleaning does not make porcelain decoloration, enamel the phenomenon that falling off occur avoids pair while guaranteeing good cleaning effect
Metal and porcelain damage.
Embodiment 2
It is a kind of for cleaning the salt composite of metal and porcelain, the component including following parts by weight: 60 parts of crude salts, 25 parts of ammonia
Base sulfonic acid, 8 parts of sodium citrates, 5 parts of citric acids, 4 parts of mandelic acids, 5 parts of gallic acids and 7 parts of aqueous polyurethanes.
Metal and porcelain are cleaned using the present embodiment salt composite, the metal surface after cleaning as the result is shown is without dirt
Stain and rust staining have apparent metallic luster, and cleaning does not make metal surface cracked, also to original existing metal surface
Crackle is filled up, and keeps metallic surface smooth, avoids Metal Crack bring metal fracture risk existing for original；Cleaning
Porcelain afterwards is restored to true qualities by yellow and is existed without the coloured color spot precipitating in part, and cleaning does not make porcelain decoloration, glaze occur
The phenomenon that matter falls off, and hole existing for the original surface of porcelain is repaired, it ensure that the smooth complete of porcelain surface,
While guaranteeing good cleaning effect, avoids and metal and porcelain are damaged.
Embodiment 3
It is a kind of for cleaning the salt composite of metal and porcelain, the component including following parts by weight: 70 parts of crude salts, 35 parts of ammonia
Base sulfonic acid, 10 parts of sodium citrates, 8 parts of citric acids, 5 parts of mandelic acids, 8 parts of gallic acids, 9 parts of aqueous polyurethanes and 2 parts of konjak sugars
Albumen；The konjaku glycoprotein is made with the following method:
1) it by konjaku cleaning, peeling, is crushed after dry 8h at 60 DEG C, obtains konjaku flour；
2) by the Na of konjaku flour described in step 1) and pH7.02HPO4-NaH2PO4Buffer solution is with the quality of 1 g:200 mL
Volume ratio mixing takes leaching liquor to filter, collects clear liquid after 50 DEG C of 2 h of ultrasound extraction；Wherein, the power of the ultrasound is 300
W；
3) after the clear liquid that step 2 is collected being mixed with ethyl alcohol according to the volume ratio of 1:2 and standing 5h at room temperature,
Collect precipitating；
4) it washes with water precipitating at least twice, dry 8 h will be deposited at 60 DEG C after cleaning, obtain the konjak sugar egg
It is white.
Metal and porcelain are cleaned using the present embodiment salt composite, the metal surface after cleaning as the result is shown is without dirt
Stain and rust staining have apparent metallic luster, and cleaning does not make metal surface cracked, also to original existing metal surface
Crackle is filled up, and keeps metallic surface smooth, avoids Metal Crack bring metal fracture risk existing for original；Cleaning
Porcelain afterwards is restored to true qualities by yellow and is existed without the coloured color spot precipitating in part, and cleaning does not make porcelain decoloration, glaze occur
The phenomenon that matter falls off, and hole existing for the original surface of porcelain is repaired, it ensure that the smooth complete of porcelain surface,
While guaranteeing good cleaning effect, avoids and metal and porcelain are damaged.It can also be in gold using the present embodiment cleaning
Belong to and a protective layer is brought on the surface of porcelain, directly contacts, long-acting can be protected with metal and porcelain to completely cut off external environment
Card metal and porcelain are no longer contaminated and be infected with spot or react with oxygen and cause to get rusty.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with
Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this
In the scope of the claims of invention.
Claims (6)
1. a kind of for cleaning the salt composite of metal and porcelain, which is characterized in that the component including following parts by weight: 50 ~ 70
Part crude salt, 15 ~ 35 parts of sulfamic acids, 5 ~ 10 parts of sodium citrates, 1 ~ 8 part of citric acid, 2 ~ 5 parts of mandelic acids, 3 ~ 8 parts of gallic acids, 4
~ 9 parts of aqueous polyurethanes and 2 ~ 7 parts of konjaku glycoprotein.
2. according to claim 1 for cleaning the salt composite of metal and porcelain, which is characterized in that the konjaku glycoprotein
It is made with the following method:
1) konjaku cleaning, peeling are crushed to obtain konjaku flour at 60 ~ 80 DEG C after dry 8 ~ 12h；
2) by konjaku flour described in step 1) and Na2HPO4-NaH2PO4Buffer solution is mixed with the mass volume ratio of 1g:200 ~ 400mL
Uniformly, after 50 ~ 70 DEG C of 2 ~ 4 h of extraction, leaching liquor is taken to filter, collects clear liquid；
3) after the clear liquid that step 2 is collected being mixed with ethyl alcohol according to the volume ratio of 1:2 ~ 4 and standing 5 ~ 8h at room temperature,
Collect precipitating；
4) it washes with water precipitating at least twice, dry 6 ~ 8h will be deposited at 60 ~ 80 DEG C after cleaning, obtain the konjak sugar egg
It is white.
3. according to claim 2 for cleaning the salt composite of metal and porcelain, which is characterized in that use pH in step 2
For 6.0 ~ 7.2 Na2HPO4-NaH2PO4Buffer solution.
4. according to claim 2 for cleaning the salt composite of metal and porcelain, which is characterized in that by step in step 2
1) konjaku flour and Na2HPO4-NaH2PO4Buffer solution is uniformly mixed with the mass volume ratio of the mL of 1g:200 ~ 400, in 50 ~
2 ~ 4h of ultrasound extraction at 70 DEG C, wherein the power of the ultrasound is 300 ~ 450 W.
5. the method that a kind of pair of metal and porcelain are cleaned, which is characterized in that any described for clear using claim 1 ~ 4
The salt composite of clean metal and porcelain cleans metal and porcelain.
6. the method cleaned according to claim 5 to metal and porcelain, which is characterized in that be used to clean gold by described
Belong to and the salt composite and water of porcelain are hybridly prepared into cleaning solution according to the mass volume ratio of 1g:10 ~ 50mL, using the cleaning
Liquid cleans metal and porcelain.
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