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CN105785590A - Preparation method and products for color-changing wearable self-cleaning concave lens - Google Patents

Preparation method and products for color-changing wearable self-cleaning concave lens Download PDF

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Publication number
CN105785590A
CN105785590A CN201610344996.7A CN201610344996A CN105785590A CN 105785590 A CN105785590 A CN 105785590A CN 201610344996 A CN201610344996 A CN 201610344996A CN 105785590 A CN105785590 A CN 105785590A
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China
Prior art keywords
preparation
concave lens
wear
eyeglass
variable color
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Application number
CN201610344996.7A
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Chinese (zh)
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CN105785590B (en
Inventor
王继亮
倪念英
江源源
李钰
赵梓汐
桂俊萍
瞿梦巧
张慧婷
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Sichuan Mei Saier Science And Technology Ltd
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Sichuan Mei Saier Science And Technology Ltd
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    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/02Lenses; Lens systems ; Methods of designing lenses
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/16Optical coatings produced by application to, or surface treatment of, optical elements having an anti-static effect, e.g. electrically conducting coatings
    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/10Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Ophthalmology & Optometry (AREA)
  • General Health & Medical Sciences (AREA)
  • Eyeglasses (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

The invention discloses a preparation method and products for a color-changing wearable self-cleaning concave lens. The preparation method comprises the following steps: (1) under the condition of 230-320 DEG C, heating and fusing thermoplastic plastic resin and additives by a thermoplastic machine and then filling into a forming chamber of a lens film, cooling and solidifying, opening the mold and taking out the lens; (2) putting silver bromide and copper oxide into a crucible of vacuum coating equipment, bombarding with electron beams under the condition of 2000 DEG C and evaporating, and then plating on the lens in the form of a film; and (3) putting diamond-like carbon, tin antimony oxide and titanium dioxide wrapped with silicon dioxide into the crucible of the vacuum coating equipment, vaporizing the three materials under the condition of 2000 DEG C to form a layer of uniform gas film, cooling and depositing on the lens. The raw materials adopted according to the preparation method are cheap and complete in function, and the products are suitable for vast people.

Description

The preparation method of a kind of variable color wear-resisting automatically cleaning concave lens and product
Technical field
Present invention relates particularly to preparation method and the product of a kind of variable color wear-resisting automatically cleaning concave lens.
Background technology
The most domestic material as lens mainly has a three major types: spar, optical glass and optical resin.Compared with optical glass, optical resin lens has the advantages such as light weight, shock resistance and easy machine-shaping, and once release, instead of optical glass soon becomes the main product of lens.
American invention in 1964 photo chromic glass.The color-changing lens of high-quality should be transparent, and without emulsifying color and luster, the time of partly recovering lost eyesight is short, recovers lost eyesight fast.The original transmitance of color-changing lens without primary colours is up to about 90%.The original transmitance of color-changing lens having primary colours can as little as 60~70%.Transmitance after general sun mirror-type color-changing lens light color is reduced to 20~30%.The color-changing lens variable color of comfortable type is shallower, the transmitance 40~about 50% after light color.
Antistatic coating is the main application market of nano ATO (Antimony Tin Oxide) powder.ATO nanometer ultramicron powder body, with the transparent conductivity of the non-resistive in semiconductor applications, there is the most excellent antistatic property, and can effectively intercept infrared and ultraviolet radiation, and nano ATO particle is the most weak to the absorbance of visible ray so that it is have the good transparency.Can be applicable to various anti-static plastic, coating, fiber, transparent heat insulating dope, display antiradiation coating, solaode, automotive windshield etc..And various resin plays transparent, conduction, antistatic radiation, every ultraviolet and infrared effect.
Within 1971, first Aisenberg and Chabot report, obtains a kind of physical and chemical performance hard carbon film approximating or similar to diamond under room temperature condition, their named diamond like carbon (DLC) film.Diamond like carbon (DLC) has graphite-structure sp2 key and diamond lattic structure sp3 key, so DLC has the good characteristic that some are similar to diamond thin, and such as high rigidity and highly thermally conductive property, wide optics passes through scope (refractive index is generally 1.5-2.6) and good electric property (resistivity is up to 1000 cm), biocompatibility etc..There is the performance being different from diamond thin, such as film-forming temperature low (can as little as room temperature) simultaneously, the features such as surface smoothness is high, good friction and wear behavior (coefficient of friction as little as less than 0.2).Diamond-film-like has high rigidity and high elastic modulus, and DLC film hardness prepared by different deposition process is widely different, and DLC film has the wearability of excellence, low-friction coefficient, is the surface abrasion Modified Membrane of a kind of excellence.
Having had the research much about self-cleaning glass at present, they technology used are the most all the films containing titanium dioxide at glass surface plating last layer, and when solar irradiation is above, organic dirt above will be degraded, and then reaches light-catalysed purpose.But this technology is difficult to use on glasses, because eyeglass is resin, being organic high molecular polymer, and titanium dioxide is as a kind of widely used photocatalyst, it but has the biggest shortcoming: its photocatalytic degradation does not have selectivity.If being applied on glasses, then it is likely to decompose the structural component of eyeglass.So finding a kind of photocatalyst with suitable selective and to be applied to the plated film film layer of eyeglass the most necessary.
Summary of the invention
It is an object of the invention to the preparation method of a kind of variable color wear-resisting automatically cleaning concave lens proposed for prior art deficiency, it is characterized in improving the material of conventional myopic glasses, change high-abrasive material into diamond like carbon, anti-static material is changed into tin-antiomony oxide, and adulterate in glasses film Silver monobromide, copper oxide and selective photocatalysis agent.
The present invention is achieved through the following technical solutions:
The preparation method of a kind of variable color wear-resisting automatically cleaning concave lens, comprises the following steps:
(1) under conditions of 230~320 DEG C, injecting the die cavity of eyeglass film after theRMOPLASTIC RESINS and additive being added heat fusing with thermoplastic machine, after cooling and solidifying, eyeglass is taken out in die sinking;
(2) Silver monobromide and copper oxide are placed at the crucible of vacuum coating equipment, make it evaporate with beam bombardment under conditions of 2000 DEG C, and be plated in the form of a film on eyeglass;
(3) being placed at the crucible of vacuum coating equipment by the titanium dioxide of diamond like carbon, tin-antiomony oxide and parcel silicon dioxide, make three vaporize under conditions of 2000 DEG C, form one layer of uniform air film, cooling is deposited on eyeglass.
Further, the preparation method of the titanium dioxide being enclosed with silicon dioxide described in is as follows:
A, by hexadecyltrimethylammonium chloride, deionized water, methanol, the ammonia of 28% and titanium dioxide mix homogeneously, obtain mixture;
B, by mixture under conditions of 20 DEG C by ultrasonic Treatment 3 hours;
C, addition tetraethoxysilane, keep 3 hours after being cooled to 3 DEG C, is then centrifuged for separating, obtains solid particle;
D, wash solid particle with methanol, then be dried 24 hours under the conditions of 60 DEG C;
E, in atmosphere with the temperature calcination solid particle 10 hours of 550 DEG C, the titanium dioxide of silicon dioxide must be enclosed with.
Yet further, the one during described theRMOPLASTIC RESINS is allyl diglycol acid esters, polymethyl methacrylate, Merlon.
Further, described additive includes TiO2, one or both in PbO.
It addition, the mol ratio of described tetraethoxysilane, hexadecyltrimethylammonium chloride, deionized water, the ammonia of 28%, methanol is: 1:0.4:596:72:2993.
The variable color wear-resisting automatically cleaning concave lens that the preparation method of the present invention prepares.
The present invention has the following advantages and beneficial effect:
The present invention uses diamond like carbon, it is possible to increase eyeglass wear-resistant;The eyeglass of the present invention has wrapped up silicon dioxide on the basis of tradition photocatalyst, makes photocatalysis have selectivity;It addition, present invention employs tin-antiomony oxide so that eyeglass has the antistatic property of excellence.
Accompanying drawing explanation
Fig. 1 is the structural formula of PC in the present invention.
Fig. 2 is the mechanism of selective photocatalysis agent in the present invention.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and embodiments of the present invention include but not limited to the following example.
Embodiment 1
As shown in Fig. 1~2, the preparation method of a kind of variable color wear-resisting automatically cleaning concave lens, comprise the following steps:
(1) under conditions of 230~320 DEG C, injecting the die cavity of eyeglass film after adding heat fusing with Merlon and additive, after cooling and solidifying, eyeglass is taken out in die sinking;Wherein, additive is TiO2And PbO.
(2) Silver monobromide and copper oxide are placed at the crucible of vacuum coating equipment, make it evaporate with beam bombardment under conditions of 2000 DEG C, and be plated in the form of a film on eyeglass.
(3) being placed at the crucible of vacuum coating equipment by the titanium dioxide of diamond like carbon, tin-antiomony oxide and parcel silicon dioxide, make three vaporize under conditions of 2000 DEG C, form one layer of uniform air film, cooling is deposited on eyeglass.
The preparation method of the described titanium dioxide being enclosed with silicon dioxide is as follows:
A, by hexadecyltrimethylammonium chloride, deionized water, methanol, the ammonia of 28% and titanium dioxide mix homogeneously, obtain mixture;
B, by mixture under conditions of 20 DEG C by ultrasonic Treatment 3 hours;
C, addition tetraethoxysilane, keep 3 hours after being cooled to 3 DEG C, is then centrifuged for separating, obtains solid particle;
D, wash solid particle with methanol, then be dried 24 hours under the conditions of 60 DEG C;
E, in atmosphere with the temperature calcination solid particle 10 hours of 550 DEG C, the titanium dioxide of silicon dioxide must be enclosed with.
Above-mentioned tetraethoxysilane, hexadecyltrimethylammonium chloride, deionized water, the ammonia of 28%, the mol ratio of methanol be: 1:0.4:596:72:2993.
Embodiment 2
As shown in Fig. 1~2, the preparation method of a kind of variable color wear-resisting automatically cleaning concave lens, comprise the following steps:
(1) under conditions of 230~320 DEG C, injecting the die cavity of eyeglass film after adding heat fusing with allyl diglycol acid esters and additive, after cooling and solidifying, eyeglass is taken out in die sinking;Wherein, additive is TiO2And PbO.
(2) Silver monobromide and copper oxide are placed at the crucible of vacuum coating equipment, make it evaporate with beam bombardment under conditions of 2000 DEG C, and be plated in the form of a film on eyeglass.
(3) being placed at the crucible of vacuum coating equipment by the titanium dioxide of diamond like carbon, tin-antiomony oxide and parcel silicon dioxide, make three vaporize under conditions of 2000 DEG C, form one layer of uniform air film, cooling is deposited on eyeglass.
The preparation method of the described titanium dioxide being enclosed with silicon dioxide is as follows:
A, by hexadecyltrimethylammonium chloride, deionized water, methanol, the ammonia of 28% and titanium dioxide mix homogeneously, obtain mixture;
B, by mixture under conditions of 20 DEG C by ultrasonic Treatment 3 hours;
C, addition tetraethoxysilane, keep 3 hours after being cooled to 3 DEG C, is then centrifuged for separating, obtains solid particle;
D, wash solid particle with methanol, then be dried 24 hours under the conditions of 60 DEG C;
E, in atmosphere with the temperature calcination solid particle 10 hours of 550 DEG C, the titanium dioxide of silicon dioxide must be enclosed with.
Above-mentioned tetraethoxysilane, hexadecyltrimethylammonium chloride, deionized water, the ammonia of 28%, the mol ratio of methanol be: 1:0.4:596:72:2993.
Embodiment 3
As shown in Fig. 1~2, the preparation method of a kind of variable color wear-resisting automatically cleaning concave lens, comprise the following steps:
(1) under conditions of 230~320 DEG C, injecting the die cavity of eyeglass film after adding heat fusing with polymethyl methacrylate and additive, after cooling and solidifying, eyeglass is taken out in die sinking;Wherein, additive is TiO2And PbO.
(2) Silver monobromide and copper oxide are placed at the crucible of vacuum coating equipment, make it evaporate with beam bombardment under conditions of 2000 DEG C, and be plated in the form of a film on eyeglass.
(3) being placed at the crucible of vacuum coating equipment by the titanium dioxide of diamond like carbon, tin-antiomony oxide and parcel silicon dioxide, make three vaporize under conditions of 2000 DEG C, form one layer of uniform air film, cooling is deposited on eyeglass.
The preparation method of the described titanium dioxide being enclosed with silicon dioxide is as follows:
A, by hexadecyltrimethylammonium chloride, deionized water, methanol, the ammonia of 28% and titanium dioxide mix homogeneously, obtain mixture;
B, by mixture under conditions of 20 DEG C by ultrasonic Treatment 3 hours;
C, addition tetraethoxysilane, keep 3 hours after being cooled to 3 DEG C, is then centrifuged for separating, obtains solid particle;
D, wash solid particle with methanol, then be dried 24 hours under the conditions of 60 DEG C;
E, in atmosphere with the temperature calcination solid particle 10 hours of 550 DEG C, the titanium dioxide of silicon dioxide must be enclosed with.
Above-mentioned tetraethoxysilane, hexadecyltrimethylammonium chloride, deionized water, the ammonia of 28%, the mol ratio of methanol be: 1:0.4:596:72:2993.
Embodiment 4
As shown in Fig. 1~2, the preparation method of a kind of variable color wear-resisting automatically cleaning concave lens, comprise the following steps:
(1) in the case of processing temperature is 230~320 DEG C, with thermoplastic machine 5.2 × 10-3Kg Merlon and additive inject the die cavity of eyeglass film after adding heat fusing, after cooling and solidifying, eyeglass is taken out in die sinking.
(2) eyeglass is placed on the substrate of vacuum coater, Silver monobromide and copper oxide are put at the crucible of vacuum coater, with the evaporation source of temperature > more than 2000 DEG C by its carburation by evaporation, form one layer of color-changing membrane at lens surface.
(3) according to mol ratio it is: tetraethoxysilane: hexadecyltrimethylammonium chloride: deionized water: the ammonia of 28%: methanol=1:0.4:596:72:2993, proceed as follows: by hexadecyltrimethylammonium chloride, deionized water, methanol, the ammonia of 28% and titanium dioxide mix homogeneously, obtain mixture;By mixture under conditions of 20 DEG C by ultrasonic Treatment 3 hours, then with the temperature calcination solid obtained above 10 hours of 550 DEG C, porous can be obtained;Add tetraethoxysilane, keep 3 hours after being cooled to 3 DEG C;Centrifugation afterwards, obtains solid particle;Then wash solid particle with methanol, be dried under the conditions of 60 DEG C afterwards 24 hours, the most in atmosphere with the temperature calcination solid obtained above 10 hours of 550 DEG C, i.e. obtain porous by the mesoporous photocatalytic agent of coated with silica titanium dioxide.Last according to diamond like carbon, tin-antiomony oxide and the boiling point of the titanium dioxide of coated silica and vapour pressure, three is placed at the crucible of vacuum coating equipment, at a temperature of 2000 DEG C, above-mentioned substance is vaporized, form one layer of uniform air film, cooling is deposited on eyeglass, obtains product.
Should be noted that, above example is only in order to illustrative not limiting technical scheme, although the present invention being described in detail with reference to above-described embodiment, it will be understood by those within the art that: still the present invention can be modified or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained in scope of the presently claimed invention.

Claims (6)

1. the preparation method of a variable color wear-resisting automatically cleaning concave lens, it is characterised in that comprise the following steps:
(1) under conditions of 230~320 DEG C, injecting the die cavity of eyeglass film after theRMOPLASTIC RESINS and additive being added heat fusing with thermoplastic machine, after cooling and solidifying, eyeglass is taken out in die sinking;
(2) Silver monobromide and copper oxide are placed at the crucible of vacuum coating equipment, make it evaporate with beam bombardment under conditions of 2000 DEG C, and be plated in the form of a film on eyeglass;
(3) being placed at the crucible of vacuum coating equipment by the titanium dioxide of diamond like carbon, tin-antiomony oxide and parcel silicon dioxide, make three vaporize under conditions of 2000 DEG C, form one layer of uniform air film, cooling is deposited on eyeglass.
The preparation method of a kind of variable color the most according to claim 1 wear-resisting automatically cleaning concave lens, it is characterised in that described in be enclosed with silicon dioxide the preparation method of titanium dioxide as follows:
A, by hexadecyltrimethylammonium chloride, deionized water, methanol, the ammonia of 28% and titanium dioxide mix homogeneously, obtain mixture;
B, by mixture under conditions of 20 DEG C by ultrasonic Treatment 3 hours;
C, addition tetraethoxysilane, keep 3 hours after being cooled to 3 DEG C, is then centrifuged for separating, obtains solid particle;
D, wash solid particle with methanol, then be dried 24 hours under the conditions of 60 DEG C;
E, in atmosphere with the temperature calcination solid particle 10 hours of 550 DEG C, the titanium dioxide of silicon dioxide must be enclosed with.
The preparation method of a kind of variable color the most according to claim 1 and 2 wear-resisting automatically cleaning concave lens, it is characterised in that described theRMOPLASTIC RESINS is the one in allyl diglycol acid esters, polymethyl methacrylate, Merlon.
The preparation method of a kind of variable color the most according to claim 1 and 2 wear-resisting automatically cleaning concave lens, it is characterised in that described additive includes TiO2, one or both in PbO.
The preparation method of a kind of variable color the most according to claim 2 wear-resisting automatically cleaning concave lens, it is characterized in that, described tetraethoxysilane, hexadecyltrimethylammonium chloride, deionized water, the ammonia of 28%, the mol ratio of methanol be: 1:0.4:596:72:2993.
6. a variable color wear-resisting automatically cleaning concave lens, it is characterised in that the variable color wear-resisting automatically cleaning concave lens prepared by the preparation method according to any one of Claims 1 to 5.
CN201610344996.7A 2016-05-20 2016-05-20 A kind of preparation method and product of the wear-resisting automatically cleaning concave lens of discoloration Active CN105785590B (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4163609A (en) * 1978-10-10 1979-08-07 Neefe Charles W Self cleaning contact lens
JPH0634801A (en) * 1992-07-20 1994-02-10 Fuji Photo Optical Co Ltd Conductive antireflection film
WO2005110938A1 (en) * 2004-05-19 2005-11-24 Murakami Corporation Anticlouding device, anticlouding mirror and electrochromic mirror
CN101550533A (en) * 2009-05-07 2009-10-07 厦门美澜光电科技有限公司 Antistatic optical substrate preparation method
CN102898035A (en) * 2011-07-28 2013-01-30 比亚迪股份有限公司 Composite film, its preparation method and composite material
CN103717535A (en) * 2011-06-03 2014-04-09 日产化学工业株式会社 Metal oxide particles containing titanium oxide coated with silicon dioxide-tin(iv) oxide complex oxide
CN105372837A (en) * 2015-12-03 2016-03-02 丹阳市特洛依眼镜有限公司 Shading color variable glasses

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4163609A (en) * 1978-10-10 1979-08-07 Neefe Charles W Self cleaning contact lens
JPH0634801A (en) * 1992-07-20 1994-02-10 Fuji Photo Optical Co Ltd Conductive antireflection film
WO2005110938A1 (en) * 2004-05-19 2005-11-24 Murakami Corporation Anticlouding device, anticlouding mirror and electrochromic mirror
CN101550533A (en) * 2009-05-07 2009-10-07 厦门美澜光电科技有限公司 Antistatic optical substrate preparation method
CN103717535A (en) * 2011-06-03 2014-04-09 日产化学工业株式会社 Metal oxide particles containing titanium oxide coated with silicon dioxide-tin(iv) oxide complex oxide
CN102898035A (en) * 2011-07-28 2013-01-30 比亚迪股份有限公司 Composite film, its preparation method and composite material
CN105372837A (en) * 2015-12-03 2016-03-02 丹阳市特洛依眼镜有限公司 Shading color variable glasses

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