CN105420743A - Material composition and preparation method of metal shell surface cleaning agent - Google Patents
Material composition and preparation method of metal shell surface cleaning agent Download PDFInfo
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- CN105420743A CN105420743A CN201510974735.9A CN201510974735A CN105420743A CN 105420743 A CN105420743 A CN 105420743A CN 201510974735 A CN201510974735 A CN 201510974735A CN 105420743 A CN105420743 A CN 105420743A
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- CN
- China
- Prior art keywords
- parts
- weight
- sodium
- benzene sulfonate
- cleaning agent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 34
- 239000002184 metal Substances 0.000 title claims abstract description 34
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 33
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 81
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 54
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 27
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 27
- 239000011734 sodium Substances 0.000 claims abstract description 27
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 27
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 27
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 27
- 239000000600 sorbitol Substances 0.000 claims abstract description 27
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000012964 benzotriazole Substances 0.000 claims abstract description 26
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 26
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 24
- -1 sodium alkyl benzene Chemical class 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000002156 mixing Methods 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 17
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000004519 grease Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011538 cleaning material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a material composition and preparation method of a metal shell surface cleaning agent, wherein the composition comprises the following components in parts by weight: 100 parts of water, 1-5 parts of sodium silicate, 1-5 parts of sorbitol, 3-10 parts of sodium hydroxide, 2-5 parts of sodium alkyl benzene sulfonate, 2-10 parts of sodium carbonate, 0.1-1 part of benzotriazole and 0.5-3 parts of sodium dodecyl benzene sulfonate. Due to the adoption of the design, grease on the surface of a metal shell can be effectively cleared; and the metal shell surface cleaning agent is convenient to operate and has time-saving and labor-saving effects.
Description
Technical Field
The invention relates to the field of metal material surface cleaning materials, in particular to a metal shell surface cleaning agent material composition and a preparation method of a cleaning agent.
Background
The metal is as the production facility raw materials commonly used, and the application in production facility is very extensive, simultaneously, in the use of production facility, often can inevitably touch a lot of grease to make equipment surface be infected with more grease, and grease clearance process is very inconvenient, not only wastes time and energy, and greatly increased work load.
Therefore, the present invention provides a metal shell surface cleaning agent material composition and a preparation method of the cleaning agent, which can effectively clean grease on the surface of the metal shell, and is convenient to operate, time-saving and labor-saving, and the present invention is a problem to be solved.
Disclosure of Invention
Aiming at the prior art, the invention aims to overcome the problems that in the prior art, a lot of grease is inevitably contacted in the use process of production equipment, so that more grease is stained on the surface of the equipment, the grease cleaning process is very inconvenient, time and labor are wasted, and the workload is greatly increased, so that the metal shell surface cleaning agent material composition and the preparation method of the cleaning agent can effectively clean the grease on the surface of a metal shell, are convenient to operate, and save time and labor.
In order to achieve the purpose, the invention provides a metal shell surface cleaning agent material composition, wherein the composition comprises water, sodium silicate, sorbitol, sodium hydroxide, sodium alkyl benzene sulfonate, sodium carbonate, benzotriazole and sodium dodecyl benzene sulfonate; wherein,
relative to 100 parts by weight of water, the sodium silicate content is 1-5 parts by weight, the sorbitol content is 1-5 parts by weight, the sodium hydroxide content is 3-10 parts by weight, the sodium alkyl benzene sulfonate content is 2-5 parts by weight, the sodium carbonate content is 2-10 parts by weight, the benzotriazole content is 0.1-1 part by weight, and the sodium dodecyl benzene sulfonate content is 0.5-3 parts by weight.
The invention also provides a preparation method of the metal shell surface cleaning agent, wherein the preparation method comprises the following steps:
1) mixing water, sodium silicate, sorbitol, sodium hydroxide, sodium alkyl benzene sulfonate and sodium carbonate to obtain a mixture M1;
2) adding benzotriazole and sodium dodecyl benzene sulfonate into the mixture M1, and mixing to obtain a metal shell surface cleaning agent; wherein,
relative to 100 parts by weight of water, the sodium silicate is 1-5 parts by weight, the sorbitol is 1-5 parts by weight, the sodium hydroxide is 3-10 parts by weight, the sodium alkyl benzene sulfonate is 2-5 parts by weight, the sodium carbonate is 2-10 parts by weight, the benzotriazole is 0.1-1 part by weight, and the sodium dodecyl benzene sulfonate is 0.5-3 parts by weight.
According to the technical scheme, water, sodium silicate, sorbitol, sodium hydroxide, sodium alkyl benzene sulfonate and sodium carbonate are mixed according to a certain proportion, and then benzotriazole and sodium dodecyl benzene sulfonate are added and mixed to prepare the metal shell surface cleaning agent, so that the cleaning agent prepared by mixing the raw materials can effectively remove grease on the metal surface in actual use, the cleaning efficiency is greatly improved, and the cleaning cost is reduced.
Additional features and advantages of the invention will be set forth in the detailed description which follows.
Detailed Description
The following describes in detail specific embodiments of the present invention. It should be understood that the detailed description and specific examples, while indicating the present invention, are given by way of illustration and explanation only, not limitation.
The invention provides a metal shell surface cleaning agent material composition, wherein the composition comprises water, sodium silicate, sorbitol, sodium hydroxide, sodium alkyl benzene sulfonate, sodium carbonate, benzotriazole and sodium dodecyl benzene sulfonate; wherein,
relative to 100 parts by weight of water, the sodium silicate content is 1-5 parts by weight, the sorbitol content is 1-5 parts by weight, the sodium hydroxide content is 3-10 parts by weight, the sodium alkyl benzene sulfonate content is 2-5 parts by weight, the sodium carbonate content is 2-10 parts by weight, the benzotriazole content is 0.1-1 part by weight, and the sodium dodecyl benzene sulfonate content is 0.5-3 parts by weight.
According to the design, water, sodium silicate, sorbitol, sodium hydroxide, sodium alkyl benzene sulfonate and sodium carbonate are mixed according to a certain proportion, and then benzotriazole and sodium dodecyl benzene sulfonate are added and mixed to prepare the metal shell surface cleaning agent, so that the cleaning agent prepared by mixing the raw materials can effectively remove grease on the metal surface in actual use, the cleaning efficiency is greatly improved, and the cleaning cost is reduced.
In a preferred embodiment of the present invention, in order to make the prepared cleaning agent have better oil removal effect, relative to 100 parts by weight of the water, the content of the sodium silicate is 2-4 parts by weight, the content of the sorbitol is 2-4 parts by weight, the content of the sodium hydroxide is 5-8 parts by weight, the content of the sodium alkyl benzene sulfonate is 3-4 parts by weight, the content of the sodium carbonate is 5-8 parts by weight, the content of the benzotriazole is 0.5-1 part by weight, and the content of the sodium dodecyl benzene sulfonate is 1-2 parts by weight.
In a preferred embodiment of the present invention, the composition may further comprise an antioxidant and an anti-ultraviolet agent.
The invention also provides a preparation method of the metal shell surface cleaning agent, wherein the preparation method comprises the following steps:
1) mixing water, sodium silicate, sorbitol, sodium hydroxide, sodium alkyl benzene sulfonate and sodium carbonate to obtain a mixture M1;
2) adding benzotriazole and sodium dodecyl benzene sulfonate into the mixture M1, and mixing to obtain a metal shell surface cleaning agent; wherein,
relative to 100 parts by weight of water, the sodium silicate is 1-5 parts by weight, the sorbitol is 1-5 parts by weight, the sodium hydroxide is 3-10 parts by weight, the sodium alkyl benzene sulfonate is 2-5 parts by weight, the sodium carbonate is 2-10 parts by weight, the benzotriazole is 0.1-1 part by weight, and the sodium dodecyl benzene sulfonate is 0.5-3 parts by weight.
In a preferred embodiment of the present invention, in order to make the prepared cleaning agent have better oil removal effect, relative to 100 parts by weight of water, the amount of the sodium silicate is 2-4 parts by weight, the amount of the sorbitol is 2-4 parts by weight, the amount of the sodium hydroxide is 5-8 parts by weight, the amount of the sodium alkyl benzene sulfonate is 3-4 parts by weight, the amount of the sodium carbonate is 5-8 parts by weight, the amount of the benzotriazole is 0.5-1 part by weight, and the amount of the sodium dodecyl benzene sulfonate is 1-2 parts by weight.
Likewise, in a preferred embodiment of the present invention, the preparation method may further include adding an antioxidant and an anti-ultraviolet agent to mix in step 2).
The mixing process in step 1) can be carried out in a manner conventionally employed in the art, for example, in a preferred embodiment of the present invention, the mixing process in step 1) is carried out under stirring conditions of stirring rate of 100-.
In another preferred embodiment, the mixing process in step 2) is carried out by stirring and mixing under the condition of stirring speed of 50-100 r/min.
The present invention will be described in detail below by way of examples. In the following examples, the sodium silicate, sorbitol, sodium hydroxide, sodium alkylbenzenesulfonate, sodium carbonate, benzotriazole and sodium dodecylbenzenesulfonate are conventional commercially available products.
Example 1
1) Stirring and mixing 100g of water, 2g of sodium silicate, 2g of sorbitol, 5g of sodium hydroxide, 3g of sodium alkyl benzene sulfonate and 5g of sodium carbonate at the stirring speed of 100r/min to obtain a mixture M1;
2) 0.5g of benzotriazole and 1g of sodium dodecyl benzene sulfonate are added into the mixture M1 and stirred and mixed under the condition that the stirring speed is 50r/min to prepare the metal shell surface cleaning agent A1.
Example 2
1) Stirring and mixing 100g of water, 4g of sodium silicate, 4g of sorbitol, 8g of sodium hydroxide, 4g of sodium alkyl benzene sulfonate and 8g of sodium carbonate at the stirring speed of 200r/min to obtain a mixture M1;
2) and adding 1g of benzotriazole and 2g of sodium dodecyl benzene sulfonate into the mixture M1, and stirring and mixing under the condition that the stirring speed is 100r/min to prepare the metal shell surface cleaning agent A2.
Example 3
1) Stirring and mixing 100g of water, 3g of sodium silicate, 3g of sorbitol, 6g of sodium hydroxide, 3.5g of sodium alkyl benzene sulfonate and 6g of sodium carbonate at the stirring speed of 150r/min to obtain a mixture M1;
2) 0.8g of benzotriazole and 1.5g of sodium dodecyl benzene sulfonate are added into the mixture M1 and stirred and mixed under the condition that the stirring speed is 80r/min to prepare the metal shell surface cleaning agent A3.
Example 4
The preparation method is carried out according to the preparation method of example 1, except that the amount of sodium silicate is 1g, the amount of sorbitol is 1g, the amount of sodium hydroxide is 3g, the amount of sodium alkyl benzene sulfonate is 2g, the amount of sodium carbonate is 2g, the amount of benzotriazole is 0.1g, and the amount of sodium dodecyl benzene sulfonate is 0.5g, so as to prepare the metal shell surface cleaning agent A4.
Example 5
The preparation method is carried out according to the preparation method of the example 2, except that the amount of the sodium silicate is 5g, the amount of the sorbitol is 5g, the amount of the sodium hydroxide is 10g, the amount of the sodium alkyl benzene sulfonate is 5g, the amount of the sodium carbonate is 10g, the amount of the benzotriazole is 1g, and the amount of the sodium dodecyl benzene sulfonate is 3g, so that the metal shell surface cleaning agent A5 is prepared.
Comparative example 1
The preparation was carried out in accordance with the preparation method of example 3 except that the sodium silicate was used in an amount of 0.5g, the sorbitol was used in an amount of 0.5g, the sodium hydroxide was used in an amount of 1g, the sodium alkylbenzenesulfonate was used in an amount of 1g, and the sodium carbonate was used in an amount of 1g, to obtain metal casing surface cleaning agent D1.
Comparative example 2
The preparation method is carried out according to the preparation method of the example 3, except that the sodium silicate is 10g, the sorbitol is 10g, the sodium hydroxide is 20g, the sodium alkyl benzene sulfonate is 10g, the sodium carbonate is 20g, the benzotriazole is 5g, and the sodium dodecyl benzene sulfonate is 5g, so as to prepare the metal shell surface cleaning agent D2.
Test example
And (3) respectively placing the metal with greasy dirt on the surface into the prepared A1-A5, D1 and D2, soaking for 10min, then washing the metal clean with water, and detecting the greasy dirt condition on the metal surface, wherein the obtained results are shown in Table 1.
TABLE 1
| Numbering | Oil stain |
| A1 | No greasy dirt on surface |
| A2 | No greasy dirt on surface |
| A3 | No greasy dirt on surface |
| A4 | No obvious greasy dirt |
| A5 | No obvious greasy dirt |
| D1 | Apparent greasy dirt |
| D2 | Apparent greasy dirt |
The preferred embodiments of the present invention have been described in detail, however, the present invention is not limited to the specific details of the above embodiments, and various simple modifications may be made to the technical solution of the present invention within the technical idea of the present invention, and these simple modifications are within the protective scope of the present invention.
It should be noted that the various technical features described in the above embodiments can be combined in any suitable manner without contradiction, and the invention is not described in any way for the possible combinations in order to avoid unnecessary repetition.
In addition, any combination of the various embodiments of the present invention is also possible, and the same should be considered as the disclosure of the present invention as long as it does not depart from the spirit of the present invention.
Claims (8)
1. The metal shell surface cleaning agent material composition is characterized by comprising water, sodium silicate, sorbitol, sodium hydroxide, sodium alkyl benzene sulfonate, sodium carbonate, benzotriazole and sodium dodecyl benzene sulfonate; wherein,
relative to 100 parts by weight of water, the sodium silicate content is 1-5 parts by weight, the sorbitol content is 1-5 parts by weight, the sodium hydroxide content is 3-10 parts by weight, the sodium alkyl benzene sulfonate content is 2-5 parts by weight, the sodium carbonate content is 2-10 parts by weight, the benzotriazole content is 0.1-1 part by weight, and the sodium dodecyl benzene sulfonate content is 0.5-3 parts by weight.
2. The composition of claim 1, wherein the sodium silicate is 2 to 4 parts by weight, the sorbitol is 2 to 4 parts by weight, the sodium hydroxide is 5 to 8 parts by weight, the sodium alkyl benzene sulfonate is 3 to 4 parts by weight, the sodium carbonate is 5 to 8 parts by weight, the benzotriazole is 0.5 to 1 part by weight, and the sodium dodecyl benzene sulfonate is 1 to 2 parts by weight, based on 100 parts by weight of the water.
3. The composition of claim 1 or 2, wherein the composition further comprises an antioxidant and an anti-ultraviolet agent.
4. The preparation method of the metal shell surface cleaning agent is characterized by comprising the following steps:
1) mixing water, sodium silicate, sorbitol, sodium hydroxide, sodium alkyl benzene sulfonate and sodium carbonate to obtain a mixture M1;
2) adding benzotriazole and sodium dodecyl benzene sulfonate into the mixture M1, and mixing to obtain a metal shell surface cleaning agent; wherein,
relative to 100 parts by weight of water, the sodium silicate is 1-5 parts by weight, the sorbitol is 1-5 parts by weight, the sodium hydroxide is 3-10 parts by weight, the sodium alkyl benzene sulfonate is 2-5 parts by weight, the sodium carbonate is 2-10 parts by weight, the benzotriazole is 0.1-1 part by weight, and the sodium dodecyl benzene sulfonate is 0.5-3 parts by weight.
5. The preparation method of claim 4, wherein the sodium silicate is used in an amount of 2 to 4 parts by weight, the sorbitol is used in an amount of 2 to 4 parts by weight, the sodium hydroxide is used in an amount of 5 to 8 parts by weight, the sodium alkylbenzenesulfonate is used in an amount of 3 to 4 parts by weight, the sodium carbonate is used in an amount of 5 to 8 parts by weight, the benzotriazole is used in an amount of 0.5 to 1 part by weight, and the sodium dodecylbenzenesulfonate is used in an amount of 1 to 2 parts by weight, based on 100 parts by weight of the water.
6. The preparation method according to claim 4 or 5, wherein the preparation method further comprises adding an antioxidant and an anti-ultraviolet agent for mixing in step 2).
7. The preparation method according to claim 4 or 5, wherein the mixing process in step 1) is performed under the condition of stirring speed of 100-200 r/min.
8. The production method according to claim 4 or 5, wherein the mixing in step 2) is carried out by stirring and mixing under a stirring rate of 50 to 100 r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510974735.9A CN105420743A (en) | 2015-12-22 | 2015-12-22 | Material composition and preparation method of metal shell surface cleaning agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510974735.9A CN105420743A (en) | 2015-12-22 | 2015-12-22 | Material composition and preparation method of metal shell surface cleaning agent |
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| CN105420743A true CN105420743A (en) | 2016-03-23 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107488524A (en) * | 2017-08-09 | 2017-12-19 | 山西太钢不锈钢股份有限公司 | Generating set air cooler surface clean medicament |
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