Heterojunction high electron mobility spin fet and manufacture method
Technical field
The present invention relates to a kind of heterojunction high electron mobility spin fet and manufacture method, particularly relate to a kind of utilization and heterojunction high electron mobility spin fet and the manufacture method that source-drain electrode injects reception spinning polarized electron is made to tool defective 3C-SiC doping nitrogen-atoms.
Background technology
Along with the rapid renewal of modern electronic technology, no matter the development of conventional electronics, be the integrated or arithmetic speed aspect of scale, all seriously limit microelectronics the reach of science.Emerging spintronics is to regulate and control electron spin easily for main target, open the frontier in order to realizing information storage and transmission with electron spin, cause physics, the common concern of researcher and broad interest in many scientific domains such as materialogy and electronic informatics.
In recent years, based on the spin field effect pipe that two-dimensional electron gas proposes, its theoretical and experimental study relate to electron spin and transports and the complicated factor of many-sided impact such as material behavior, causes concern and the exploration of numerous researchers.Its basic conception is propose so-called spin traps transistor by the electrical type ratio of electrooptic modulator.The electron spin inputted by source electrode in the x-direction, it can be expressed as the combination of positive and negative automatic rotary component in the z-direction, the electron energy certainly spinning up and the spin downward division caused by the Rashba item in electron effective mass Hamilton, the phase difference of electronics by field effect transistor is produced in transport process, the electronic phase angle can regarded as along the spin of positive and negative z direction spinned in the x-direction received in drain electrode changes, thus carries out current regulation.And the Rashba coefficients R ashba coefficient η in Rashba item is directly proportional to the electric field of heterojunction boundary, therefore size of current can be controlled by adding grid voltage.
But spinning electron is injected in semiconductor by ferromagnetic material by general spin fet, but only has a few percent as Fe and semi-conducting material do not mate as the band structure of Sm the efficiency injected that makes to spin due to ferromagnetic material.Therefore, adopt identical source-drain electrode and channel material make band structure mate thus improve injection efficiency particularly important at the application and research of spin fet device.
N-type doping point defect 3C-SiC material has certain Spin Polarization Effect, can substitute existing technique, improve the efficiency that spin is injected and received, thus improve the performance of device.
Summary of the invention
The object of the invention is the defect for prior art, a kind of heterojunction high electron mobility spin fet and manufacture method are provided.Material spin polarizability at room temperature can be optimized.
For achieving the above object, the invention provides a kind of heterojunction high electron mobility spin fet, comprising: 3C-SiC drain region, 3C-SiC source region, 3C-SiC channel region, Schottky contacts gate electrode, Si substrate, drain electrode, source electrode, SiN separator;
Described 3C-SiC drain region, 3C-SiC source region, 3C-SiC channel region are positioned on described Si substrate; Described source electrode is positioned on described 3C-SiC source region, and described Schottky contacts gate electrode is positioned on described 3C-SiC channel region, and described drain electrode is positioned on described 3C-SiC drain region; Described SiN separator is positioned at source electrode and Schottky contacts gate electrode, and between Schottky contacts gate electrode and drain electrode.
Further, the material in described 3C-SiC drain region is N-type doping content is 1 × 10
17cm
-3-1 × 10
20cm
-3the defective 3C-SiC material of tool, thickness is 0.5 μm.
Further, the material in described 3C-SiC source region is N-type doping content is 1 × 10
17cm
-3-1 × 10
20cm
-3the defective 3C-SiC material of tool, thickness is 0.5 μm.
Further, described 3C-SiC channel region is 1 × 10 by N-type doping content
15-1 × 10
17cm
-3epitaxial loayer is formed.
Further, the Ni Schottky contacts gate electrode of described Schottky contacts gate electrode to be the thickness formed by deposit be 300nm.
Further, described Si substrate is doping content is 1 × 10
14cm
-3si material.
Present invention also offers a kind of manufacture method of heterojunction high electron mobility spin fet, described method comprises:
Step 1, uses acetone, absolute ethyl alcohol and deionized water to carry out ultrasonic cleaning to Si substrate successively;
Step 2, the on a si substrate lightly doped 3C-SiC epitaxial loayer of chemical vapour deposition (CVD) 0.5 μm, doping content is 1 × 10
15-1 × 10
17cm
-3; Reaction temperature is 1570 DEG C, and pressure is 100mbar, and reacting gas adopts silane and propane, and carrier gas adopts pure hydrogen, and impurity source adopts gaseous nitrogen atmosphere;
Four Nitrogen ion Selective implantations are formed drain region and source region by step 3:
Step 4, carries out gluing, development to whole silicon carbide epitaxial layers, above source region and drain region, form ohmic contact regions, the Ni metal of deposit 300nm, is peeled off afterwards make it form source electrode and drain metal layer by ultrasonic wave; In the argon gas atmosphere of 1100 DEG C, whole sample is annealed 3 minutes, form source, leak Ohm contact electrode;
Step 5, utilizes the plasma enhanced CVD method SiN layer that deposit 200nm is thick above epitaxial loayer, uses photoetching and CF afterwards
4plasma etching goes out the grid region of 1 μm;
Step 6, utilizes the method for magnetron sputtering at 3C-SiC channel surface splash-proofing sputtering metal 300nm W metal as Schottky contacts gate electrode, then short annealing process in argon gas atmosphere.
Further, described step 3 specifically comprises:
Step 31, on silicon carbide epitaxial layers deposit a layer thickness be the Al of 1 μm as the barrier layer of drain region and source region ion implantation, form drain region and injection region, source region by photoetching and etching;
Step 32, carries out four N~+ implantation to silicon carbide epitaxial layers, successively adopts the Implantation Energy of 200keV, 140keV, 100keV and 65keV, be injected into silicon carbide epitaxial layers at the temperature of 500 DEG C, and Formation Depth is 0.5 μm, and doping content is 1 × 10
17cm
-3-1 × 10
20cm
-3drain region and source region;
Step 33, adopts the Al on phosphoric acid removal silicon carbide epitaxial layers;
Step 34, adopts RCA standard of cleaning to clean silicon carbide epitaxial layers surface, makes the protection of C film after drying; And then in 850 DEG C of argon atmospheres, carry out ion-activated annealing 10min.
Heterojunction high electron mobility spin fet of the present invention and manufacture method, by regulating the dosage of ion implantation and annealing time to change doping content in source and drain material and defect concentration, thus the spin polarizability of material under optimizing room temperature.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of heterojunction high electron mobility spin fet of the present invention;
Fig. 2 is the flow chart of the manufacture method of heterojunction high electron mobility spin fet of the present invention.
Embodiment
Below by drawings and Examples, technical scheme of the present invention is described in further detail.
Fig. 1 is the schematic diagram of heterojunction high electron mobility spin fet of the present invention, as shown in the figure, 3C-SiC drain region 1,3C-SiC source region 2,3C-SiC channel region 3, Schottky contacts gate electrode 4, Si substrate 5, drain electrode 6, source electrode 7 and SiN separator 8 is specifically comprised.
3C-SiC drain region 1,3C-SiC source region 2,3C-SiC channel region 3 are positioned on Si substrate 5; Source electrode 7 is positioned on 3C-SiC source region 2, and Schottky contacts gate electrode 4 is positioned on 3C-SiC channel region 3, and drain electrode 6 is positioned on 3C-SiC drain region 1; SiN separator 8 is positioned at source electrode 7 and Schottky contacts gate electrode 4, and between Schottky contacts gate electrode 4 and drain electrode 6.
Wherein, 3C-SiC drain region 1 and 3C-SiC source region 2 are thickness is 0.5 μm, and N-type doping content is 1 × 10
17cm
-3-1 × 10
20cm
-3, preferably 1 × 10
19cm
-3, there is the 3C-SiC material of defects, formed by three times or four Nitrogen ion selectivity ion implantations; 3C-SiC channel region 3 is 1 × 10 by N-type doping content
15-1 × 10
17cm
-3epitaxial loayer is formed.The Ni Schottky contacts grid 4 of to be the thickness formed by deposit above 3C-SiC channel region 3 be 300nm; Drain electrode 6 and source electrode 7 are positioned at above drain region 1 and source region 2, are formed by the Ni of deposit 300nm, SiN as separator at Schottky contacts grid 4 and source electrode 6 with drain between 7, the generation of using plasma chemical vapor deposition.
Si substrate 5 is doping contents is 1 × 10
14cm
-3si material.
Heterojunction high electron mobility spin fet of the present invention changes doping content in source and drain material and defect concentration by regulating the dosage of ion implantation and annealing time, thus optimizes material spin polarizability at room temperature.
Fig. 2 is the flow chart of the manufacture method of heterojunction high electron mobility spin fet of the present invention, as shown in the figure, specifically comprises the steps:
Step 1, uses acetone, absolute ethyl alcohol and deionized water to carry out ultrasonic cleaning to Si substrate successively;
Step 2, growth thickness is 0.5 μm of lightly doped 3C-SiC epitaxial loayer on a si substrate, and doping content is 1 × 10
15-1 × 10
17cm
-3, its process conditions are: reaction temperature is 1570 DEG C, and pressure is 100mbar, and reacting gas adopts silane and propane, and carrier gas adopts pure hydrogen, and impurity source adopts gaseous nitrogen atmosphere;
Step 3, four times Nitrogen ion Selective implantation forms drain region and source region:
Concrete, comprising: step 3.1, on silicon carbide epitaxial layers deposit a layer thickness be the Al of 1 μm as the barrier layer of drain region and source region ion implantation, form drain region and injection region, source region by photoetching and etching;
Step 3.2, carries out four N~+ implantation to silicon carbide epitaxial layers, successively adopts the Implantation Energy of 200keV, 140keV, 100keV and 65keV, be injected into silicon carbide epitaxial layers at the temperature of 500 DEG C, and Formation Depth is 0.5 μm, and doping content is 1 × 10
17cm
-3-1 × 10
20cm
-3drain region and source region;
Step 3.3, adopts the Al on phosphoric acid removal silicon carbide epitaxial layers;
Step 3.4, adopts RCA standard of cleaning to clean silicon carbide epitaxial layers surface, makes the protection of C film after drying; Then in 850 DEG C of argon atmospheres, carry out ion-activated annealing 10min.
Step 4, carries out gluing, development to whole silicon carbide epitaxial layers, above source region and drain region, form ohmic contact regions, the Ni metal of deposit 300nm, is peeled off afterwards make it form source electrode and drain metal layer by ultrasonic wave; In the argon gas atmosphere of 1100 DEG C, whole sample is annealed 3 minutes, form source, leak Ohm contact electrode;
Specifically comprise:
Step 4.1, carries out gluing, development to whole silicon carbide epitaxial layers, above source region and drain region, form ohmic contact regions, the Ni metal of deposit 300nm, is peeled off afterwards make it form source electrode and drain metal layer by ultrasonic wave;
Step 4.2, in the argon gas atmosphere of 1100 DEG C, anneals 3 minutes to whole sample, forms source, leaks Ohm contact electrode;
Step 5, utilizes the plasma enhanced CVD method SiN layer that deposit 200nm is thick above epitaxial loayer, uses photoetching and CF afterwards
4plasma etching goes out the grid region of 1 μm;
Step 6, utilizes the method for magnetron sputtering at 3C-SiC channel surface splash-proofing sputtering metal 300nm W metal as Schottky contacts gate electrode, then short annealing process in argon gas atmosphere.
Heterojunction high electron mobility spin fet manufacture method of the present invention, because raceway groove and source and drain adopt commaterial, directly can carry out epitaxial growth on substrate, source and drain adopts the mode of selected zone ion implantation nitrogen-atoms to be formed simultaneously, have with common process compatible, manufacture simple, the advantage that skin effect is little, spin can be improved simultaneously and inject and receiving efficiency.
Above-described embodiment; object of the present invention, technical scheme and beneficial effect are further described; be understood that; the foregoing is only the specific embodiment of the present invention; the protection range be not intended to limit the present invention; within the spirit and principles in the present invention all, any amendment made, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.