CN105088772A - Environmentally-friendly anti-yellowing polyester DTY oiling agent and preparation method thereof - Google Patents
Environmentally-friendly anti-yellowing polyester DTY oiling agent and preparation method thereof Download PDFInfo
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- CN105088772A CN105088772A CN201510494790.8A CN201510494790A CN105088772A CN 105088772 A CN105088772 A CN 105088772A CN 201510494790 A CN201510494790 A CN 201510494790A CN 105088772 A CN105088772 A CN 105088772A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
- D06M13/295—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing polyglycol moieties; containing neopentyl moieties
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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Abstract
The invention relates to an environmentally-friendly anti-yellowing polyester DTY oiling agent and a preparation method thereof. The environmentally-friendly anti-yellowing polyester DTY oiling agent consists of, by weight, 80%-92% of smoothing agent, 5%-10% of emulgator, 2%-7% of tow collecting agent and 1%-3% of antistatic agent. The polyester DTY oiling agent is transparent, colorless, tasteless, non-toxic and harmless and does not yellow. The polyester DTY oiling agent is used in a high-speed elasticity-enhancing process, enables spinnability to be good, enables broken ends and broken filaments to be little, and the rate of superior products can be obviously improved under the same process conditions. The environmentally-friendly anti-yellowing polyester DTY oiling agent is good in washability, even in dyeing, good in tow collection property and excellent in winding formation and antistatic property and enables post processing to be smooth. Fiber products produced by means of the environmentally-friendly anti-yellowing polyester DTY oiling agent are long in storage time, fibers do not yellow in the long-distance transportation, and the environmentally-friendly anti-yellowing polyester DTY oiling agent does not bring environment pollution and is non-toxic and harmless to human bodies.
Description
Technical field
The auxiliary agent that the present invention relates in synthetic fiber process technology manufactures field, polyester DTY finish of the particularly anti-yellowing change of a kind of environmental protection and preparation method thereof.
Background technology
At present, due to China's polyester DTY fibre technology fast development, become polyster fibre producing country maximum in the world, the elastic fibre that adds produced not only is sold at home, and constantly export to European and American developed countries, therefore more and more higher to the requirement of product, the DTY finish applied in polyester DTY fiber process, not only requirement can make production process carry out smoothly, reduce the broken end in texturing process, lousiness, the problem that coiling and molding is poor and excellence rate is low, and require that fiber can not xanthochromia in long-distance transport process, not to human body with to the poisonous and hazardous material of environmental protection on fiber.And existing common polyester DTY finish, the processing request of general polyester DTY fiber can only be met, the requirement of the high-grade polyester DTY fiber needed for European and American developed countries cannot be reached.
Summary of the invention
The object of the invention is the difficult problem for existing in prior art, polyester DTY finish of the anti-yellowing change of a kind of environmental protection and preparation method thereof is provided.
In order to realize foregoing invention, the present invention adopts following technical scheme:
A polyester DTY finish for the anti-yellowing change of environmental protection, is made up of the component of following percentage by weight: smooth agent 80-92%, emulsifying agent 5-10%, collecting agent 2-7% and antistatic additive 1-3%.
Further, be made up of the component of following percentage by weight: smooth agent 80%, emulsifying agent 10%, collecting agent 7% and antistatic additive 3%.
Further, be made up of the component of following percentage by weight: smooth agent 88.2%, emulsifying agent 7.5%, collecting agent 2.5% and antistatic additive 1.8%.
Further, be made up of the component of following percentage by weight: smooth agent 90%, emulsifying agent 7%, collecting agent 2% and antistatic additive 1%.
Further, be made up of the component of following percentage by weight: smooth agent 92%, emulsifying agent 5%, collecting agent 2% and antistatic additive 1%.
Further, described smooth agent is one or more in secondary hydrogenation mineral oil, three hydrogenation mineral oil and diethylhexyl stearate.
Further, described emulsifying agent is one or more in coconut alcohol polyoxyethylene ether, cocinic acid polyoxyethylene ester and polyoxyethylene stearic acid ester.
Further, described collecting agent is one or more in glycerol polyoxyethylene ether, sorbitan tristearate and polyoxyethylene pentaerythritol.
Further, described antistatic additive is one or more in laruyl alcohol phosphate first salt, coconut alcohol polyoxyethylene ether phosphate first salt and polyoxyethylene octadecanol phosphate first salt.
Prepare a method for the polyester DTY finish of the anti-yellowing change of above-mentioned environmental protection, comprise the steps:
1) component smooth agent, emulsifying agent, collecting agent and antistatic additive is taken by percentage by weight described above;
2) by step 1) in weigh emulsifying agent, collecting agent and antistatic additive accurately and join in reactor, be heated to 50 ± 5 DEG C, and carry out uniform stirring, each component is fully merged;
3) remaining ingredient smooth agent is joined in reactor, stir after 30-60 minute, cooling, filter, discharging, the packaging i.e. polyester DTY finish of the obtained anti-yellowing change of environmental protection.
Owing to adopting above technical scheme, beneficial effect of the present invention is:
1) polyester DTY finish provided by the invention is transparent, and colorless and odorless is nontoxic, can not xanthochromia.
2) the present invention is used for good spinnability in high speed texturing craft, and little breakage, lousiness is few, can significantly improve excellence rate under same process condition.
3) polyester DTY finish washability provided by the invention is good, and even dyeing, convergence is good, and coiling and molding is excellent, and antistatic behaviour is good, and aft-loaded airfoil is well on.
4) the fiber product resting period of the present invention is long, does not worry that in long-distance transport, fiber can turn yellow, environmentally safe, harmless to human non-toxic.
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is described in further detail.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
embodiment 1
A polyester DTY finish for the anti-yellowing change of environmental protection, is made up of the component of following percentage by weight:
Smooth agent 80%, wherein smooth agent is the mixing of secondary hydrogenation mineral oil 75% and diethylhexyl stearate 5%;
Emulsifying agent 10%, wherein emulsifying agent is the mixing of coconut alcohol polyoxyethylene ether 8% and polyoxyethylene stearic acid ester 2%;
Collecting agent 7%, wherein collecting agent is the mixing of glycerol polyoxyethylene ether 4% and sorbitan tristearate 3%;
Antistatic additive 3%, it is laruyl alcohol phosphate first salt.
The preparation method of the polyester DTY finish of the anti-yellowing change of above-described environmental protection, step is as follows:
1) component smooth agent 80% (secondary hydrogenation mineral oil 75%, diethylhexyl stearate 5%), emulsifying agent 10% (coconut alcohol polyoxyethylene ether 8%, polyoxyethylene stearic acid ester 2%), collecting agent 7% (glycerol polyoxyethylene ether 4%, sorbitan tristearate 3%) and antistatic additive 3% (laruyl alcohol phosphate first salt 3%) is taken by percentage by weight described above;
2) above-mentioned component emulsifying agent 10% (coconut alcohol polyoxyethylene ether 8%, polyoxyethylene stearic acid ester 2%), collecting agent 7% (glycerol polyoxyethylene ether 4%, sorbitan tristearate 3%) and the antistatic additive 3% (laruyl alcohol phosphate first salt 3%) accurately that take is joined in reactor, be heated to 52 DEG C, and carry out uniform stirring, each component is fully merged;
3) remaining ingredient smooth agent 80% (secondary hydrogenation mineral oil 75%, diethylhexyl stearate 5%) is joined in reactor, stir after 45 minutes, cooling, filter, discharging, the polyester DTY finish of packaging and the anti-yellowing change of produced environment friendly.
embodiment 2
A polyester DTY finish for the anti-yellowing change of environmental protection, is made up of the component of following percentage by weight:
Smooth agent 88.2%, wherein smooth agent is the mixing of three hydrogenation mineral oil 78.2% and diethylhexyl stearate ester 10%;
Emulsifying agent 7.5%, wherein emulsifying agent is the mixing of coconut alcohol polyoxyethylene ether 4.5% and stearate acid polyoxyethylene ether 3%;
Collecting agent 2.5%, wherein collecting agent is the mixing of glycerol polyoxyethylene ether 2% and polyoxyethylene pentaerythritol 0.5%;
Antistatic additive 1.8%, it is coconut alcohol polyoxyethylene ether phosphate first salt.
The preparation method of the polyester DTY finish of the anti-yellowing change of above-described environmental protection, step is as follows:
1) component smooth agent 88.2% (three hydrogenation mineral oil 78.2%, diethylhexyl stearate esters 10%), emulsifying agent 7.5% (coconut alcohol polyoxyethylene ether 4.5%, stearate acid polyoxyethylene ether 3%), collecting agent 2.5% (glycerol polyoxyethylene ether 2%, polyoxyethylene pentaerythritol 0.5%) and antistatic additive 1.8% (coconut alcohol polyoxyethylene ether phosphate first salt 1.8%) is taken by percentage by weight described above;
2) above-mentioned component emulsifying agent 7.5% (coconut alcohol polyoxyethylene ether 4.5%, stearate acid polyoxyethylene ether 3%), collecting agent 2.5% (glycerol polyoxyethylene ether 2%, polyoxyethylene pentaerythritol 0.5%) and the antistatic additive 1.8% (coconut alcohol polyoxyethylene ether phosphate first salt 1.8%) accurately that take is joined in reactor, be heated to 50 DEG C, and carry out uniform stirring, each component is fully merged;
3) remaining ingredient smooth agent 88.2% (three hydrogenation mineral oil 78.2%, diethylhexyl stearate esters 10%) is joined in reactor, stir after 35 minutes, cooling, filter, discharging, the packaging i.e. polyester DTY finish of the obtained anti-yellowing change of environmental protection.
embodiment 3
A polyester DTY finish for the anti-yellowing change of environmental protection, is made up of the component of following percentage by weight:
Smooth agent 90%, it is secondary hydrogenation mineral oil 90%;
Emulsifying agent 7%, wherein emulsifying agent is the mixing of coconut alcohol polyoxyethylene ether 5% and cocinic acid polyoxyethylene ester 2%;
Collecting agent 2%, wherein collecting agent is the mixing of glycerol polyoxyethylene ether 1% and sorbitan tristearate 1%;
Antistatic additive 1%, it is laruyl alcohol phosphate first salt.
The preparation method of the polyester DTY finish of the anti-yellowing change of above-described environmental protection, step is as follows:
1) component smooth agent 90% (secondary hydrogenation mineral oil 90%), emulsifying agent 7% (coconut alcohol polyoxyethylene ether 5%, cocinic acid polyoxyethylene ester 2%), collecting agent 2% (glycerol polyoxyethylene ether 1%, sorbitan tristearate 1%) and antistatic additive 1% (laruyl alcohol phosphate first salt 1%) is taken by percentage by weight described above;
2) above-mentioned component emulsifying agent 7% (coconut alcohol polyoxyethylene ether 5%, cocinic acid polyoxyethylene ester 2%), collecting agent 2% (glycerol polyoxyethylene ether 1%, sorbitan tristearate 1%) and the antistatic additive 1% (laruyl alcohol phosphate first salt 1%) accurately that take is joined in reactor, be heated to 55 DEG C, and carry out uniform stirring, each component is fully merged;
3) remaining ingredient smooth agent 90% (secondary hydrogenation mineral oil 90%) is joined in reactor, stir after 30 minutes, cooling, filter, discharging, the packaging i.e. polyester DTY finish of the obtained anti-yellowing change of environmental protection.
embodiment 4
A polyester DTY finish for the anti-yellowing change of environmental protection, is made up of the component of following percentage by weight:
Smooth agent 92%, it is three hydrogenation mineral oil 92%;
Emulsifying agent 5%, wherein emulsifying agent is the mixing of cocinic acid polyoxyethylene ester 2% and polyoxyethylene stearic acid ester 3%;
Collecting agent 2%, it is sorbitan tristearate;
Antistatic additive 1%, wherein antistatic additive is the mixing of laruyl alcohol phosphate first salt 0.8% and polyoxyethylene octadecanol phosphate first salt 0.2%.
The preparation method of the polyester DTY finish of the anti-yellowing change of above-described environmental protection, step is as follows:
1) component smooth agent 92% (three hydrogenation mineral oil 92%), emulsifying agent 5% (cocinic acid polyoxyethylene ester 2%, polyoxyethylene stearic acid ester 3%), collecting agent 2% (sorbitan tristearate 2%) and antistatic additive 1% (laruyl alcohol phosphate first salt 0.8%, polyoxyethylene octadecanol phosphate first salt 0.2%) is taken by percentage by weight described above;
2) above-mentioned component emulsifying agent 5% (cocinic acid polyoxyethylene ester 2%, polyoxyethylene stearic acid ester 3%), collecting agent 2% (sorbitan tristearate 2%) and the antistatic additive 1% (laruyl alcohol phosphate first salt 0.8%, polyoxyethylene octadecanol phosphate first salt 0.2%) accurately that take is joined in reactor, be heated to 51 DEG C, and carry out uniform stirring, each component is fully merged;
3) remaining ingredient smooth agent 92% (three hydrogenation mineral oil 92%) is joined in reactor, stir after 60 minutes, cooling, filter, discharging, the packaging i.e. polyester DTY finish of the obtained anti-yellowing change of environmental protection.
The polyester DTY finish can being demonstrate,proved the anti-yellowing change of environmental protection provided by the invention by above-described embodiment 1-4 can reach following quality index:
Polyester DTY finish provided by the invention changes with the color and luster of existing ordinary polyester DTY finish after different time is deposited and compares in table 1:
Table 1
As can be seen from Table 1, along with the change of number of days, existing ordinary polyester DTY finish can turn yellow gradually, finally become brown, and the color of polyester DTY finish provided by the invention is water white transparency always, without any change, so the anti-yellowing change ability of polyester DTY finish provided by the invention is strong, long-term storage can not variable color.
Soluble metal testing result (Shanghai SGS detects) in polyester DTY finish provided by the invention is in table 2:
Table 2
As can be seen from Table 2, polyester DTY finish provided by the invention is environmentally safe, the finish harmless to human non-toxic.
Therefore, polyester DTY finish clear, colorless provided by the invention is tasteless, nontoxic, can not xanthochromia.The present invention is used in high speed texturing craft, and good spinnability, little breakage, lousiness is few, can significantly improve excellence rate under same process condition.The invention provides polyester DTY finish washability good, even dyeing, convergence is good, and coiling and molding is excellent, and antistatic behaviour is good, and aft-loaded airfoil is well on.The fiber product resting period of the present invention is long, does not worry that in long-distance transport, fiber can turn yellow, environmentally safe, harmless to human non-toxic.
Environmental protection provided by the invention anti-yellowing change polyester DTY finish is applicable to high speed elasticizer is produced thin and high-grade polyester DTY fibre process such as ultra-fine or outlet American-European countries, it oils evenly, work well stable, in process, broken end is few, and lousiness is little, coiling and molding is good, excellence rate is high, practical through Duo Jiajiadan factory, and reaction is good, user's requirement can be met, become long-term customers.
The foregoing is only preferred embodiment of the present invention, be not used for limiting practical range of the present invention; If do not depart from the spirit and scope of the present invention, the present invention is modified or equivalent to replace, in the middle of the protection domain that all should be encompassed in the claims in the present invention.
Claims (10)
1. a polyester DTY finish for the anti-yellowing change of environmental protection, is characterized in that, is made up of the component of following percentage by weight: smooth agent 80-92%, emulsifying agent 5-10%, collecting agent 2-7% and antistatic additive 1-3%.
2. the polyester DTY finish of the anti-yellowing change of environmental protection according to claim 1, is characterized in that, is made up of the component of following percentage by weight: smooth agent 80%, emulsifying agent 10%, collecting agent 7% and antistatic additive 3%.
3. the polyester DTY finish of the anti-yellowing change of environmental protection according to claim 1, is characterized in that, is made up of the component of following percentage by weight: smooth agent 88.2%, emulsifying agent 7.5%, collecting agent 2.5% and antistatic additive 1.8%.
4. the polyester DTY finish of the anti-yellowing change of environmental protection according to claim 1, is characterized in that, is made up of the component of following percentage by weight: smooth agent 90%, emulsifying agent 7%, collecting agent 2% and antistatic additive 1%.
5. the polyester DTY finish of the anti-yellowing change of environmental protection according to claim 1, is characterized in that, is made up of the component of following percentage by weight: smooth agent 92%, emulsifying agent 5%, collecting agent 2% and antistatic additive 1%.
6. the polyester DTY finish of the anti-yellowing change of environmental protection according to claim 1, is characterized in that, described smooth agent is one or more in secondary hydrogenation mineral oil, three hydrogenation mineral oil and diethylhexyl stearate.
7. the polyester DTY finish of the anti-yellowing change of environmental protection according to claim 1, is characterized in that, described emulsifying agent is one or more in coconut alcohol polyoxyethylene ether, cocinic acid polyoxyethylene ester and polyoxyethylene stearic acid ester.
8. the polyester DTY finish of the anti-yellowing change of environmental protection according to claim 1, is characterized in that, described collecting agent is one or more in glycerol polyoxyethylene ether, sorbitan tristearate and polyoxyethylene pentaerythritol.
9. the polyester DTY finish of the anti-yellowing change of environmental protection according to claim 1, is characterized in that, described antistatic additive is one or more in laruyl alcohol phosphate first salt, coconut alcohol polyoxyethylene ether phosphate first salt and polyoxyethylene octadecanol phosphate first salt.
10. prepare a method for the polyester DTY finish of the anti-yellowing change of environmental protection according to any one of claim 1-9, it is characterized in that, comprise the steps:
1) component smooth agent, emulsifying agent, collecting agent and antistatic additive is taken by the percentage by weight described in any one of claim 1-5;
2) by step 1) in weigh emulsifying agent, collecting agent and antistatic additive accurately and join in reactor, be heated to 50 ± 5 DEG C, and carry out uniform stirring, each component is fully merged;
3) remaining ingredient smooth agent is joined in reactor, stir after 30-60 minute, cooling, filter, discharging, the packaging i.e. polyester DTY finish of the obtained anti-yellowing change of environmental protection.
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CN201510494790.8A CN105088772A (en) | 2015-08-13 | 2015-08-13 | Environmentally-friendly anti-yellowing polyester DTY oiling agent and preparation method thereof |
PCT/CN2015/000739 WO2017024423A1 (en) | 2015-08-13 | 2015-10-30 | Environmentally-friendly anti-yellowing dacron dty oiling agent and preparation method therefor |
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- 2015-10-30 WO PCT/CN2015/000739 patent/WO2017024423A1/en active Application Filing
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CN105671964A (en) * | 2016-02-25 | 2016-06-15 | 苏州三和开泰花线织造有限公司 | Preparation method of oiling agent for polyester spinning |
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