CN104703492A - 具有凉爽剂包合物的吸烟制品烟嘴 - Google Patents
具有凉爽剂包合物的吸烟制品烟嘴 Download PDFInfo
- Publication number
- CN104703492A CN104703492A CN201380022787.5A CN201380022787A CN104703492A CN 104703492 A CN104703492 A CN 104703492A CN 201380022787 A CN201380022787 A CN 201380022787A CN 104703492 A CN104703492 A CN 104703492A
- Authority
- CN
- China
- Prior art keywords
- compound
- smoking product
- cool agent
- cyclodextrin
- cigarette holder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000391 smoking effect Effects 0.000 title claims abstract description 73
- 239000002826 coolant Substances 0.000 title abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 82
- 150000001875 compounds Chemical class 0.000 claims description 78
- 235000019504 cigarettes Nutrition 0.000 claims description 65
- 229920000858 Cyclodextrin Polymers 0.000 claims description 43
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 37
- 150000001408 amides Chemical class 0.000 claims description 17
- 125000003545 alkoxy group Chemical group 0.000 claims description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 244000246386 Mentha pulegium Species 0.000 claims description 9
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 9
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 9
- 235000001050 hortel pimenta Nutrition 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- -1 carbonyl methyl Chemical group 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000003507 refrigerant Substances 0.000 claims description 5
- VUNOFAIHSALQQH-UHFFFAOYSA-N Ethyl menthane carboxamide Chemical compound CCNC(=O)C1CC(C)CCC1C(C)C VUNOFAIHSALQQH-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 claims description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- WHBMMWSBFZVSSR-UHFFFAOYSA-M 3-hydroxybutyrate Chemical compound CC(O)CC([O-])=O WHBMMWSBFZVSSR-UHFFFAOYSA-M 0.000 claims description 2
- WAIGPJMZARQZDX-UHFFFAOYSA-N 4-(dimethylamino)-4-oxobutanoic acid Chemical compound CN(C)C(=O)CCC(O)=O WAIGPJMZARQZDX-UHFFFAOYSA-N 0.000 claims description 2
- GUCPYIYFQVTFSI-UHFFFAOYSA-N 4-methoxybenzamide Chemical compound COC1=CC=C(C(N)=O)C=C1 GUCPYIYFQVTFSI-UHFFFAOYSA-N 0.000 claims description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 2
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 claims description 2
- WHBMMWSBFZVSSR-UHFFFAOYSA-N R3HBA Natural products CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 claims description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 229930007503 menthone Natural products 0.000 claims description 2
- PCOMMNVANAQDMV-UHFFFAOYSA-N n,2-diethyl-3-methyl-2-propan-2-ylbutanamide Chemical compound CCNC(=O)C(CC)(C(C)C)C(C)C PCOMMNVANAQDMV-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Substances OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 1
- 210000000214 mouth Anatomy 0.000 description 14
- 241000208125 Nicotiana Species 0.000 description 9
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 9
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 8
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 8
- 230000032683 aging Effects 0.000 description 8
- 239000007799 cork Substances 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 229940041616 menthol Drugs 0.000 description 7
- 238000001816 cooling Methods 0.000 description 6
- 239000005022 packaging material Substances 0.000 description 6
- 238000012856 packing Methods 0.000 description 6
- 229940125810 compound 20 Drugs 0.000 description 5
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical compound OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 4
- 229940080345 gamma-cyclodextrin Drugs 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000013508 migration Methods 0.000 description 4
- 230000005012 migration Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 3
- 229940043377 alpha-cyclodextrin Drugs 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical group OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000035597 cooling sensation Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ODHCTXKNWHHXJC-UHFFFAOYSA-N 5-oxoproline Chemical compound OC(=O)C1CCC(=O)N1 ODHCTXKNWHHXJC-UHFFFAOYSA-N 0.000 description 1
- 239000001116 FEMA 4028 Substances 0.000 description 1
- 239000001458 FEMA 4549 Substances 0.000 description 1
- 239000001510 FEMA 4602 Substances 0.000 description 1
- UJNOLBSYLSYIBM-SGUBAKSOSA-N [(1r,2s,5r)-5-methyl-2-propan-2-ylcyclohexyl] 2-hydroxypropanoate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)C(C)O UJNOLBSYLSYIBM-SGUBAKSOSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000011175 beta-cyclodextrine Nutrition 0.000 description 1
- 229960004853 betadex Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 210000003928 nasal cavity Anatomy 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 210000003800 pharynx Anatomy 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000001835 salubrious effect Effects 0.000 description 1
- 230000014860 sensory perception of taste Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/282—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by indirect addition of the chemical substances, e.g. in the wrapper, in the case
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
- A24B15/284—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances the additive being bound to a host by chemical, electrical or like forces, e.g. use of precursors, inclusion complexes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/34—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a carbocyclic ring other than a six-membered aromatic ring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/36—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring
- A24B15/40—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms
- A24B15/403—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms having only oxygen as hetero atoms
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
- A24D1/042—Cigars; Cigarettes with mouthpieces or filter-tips with mouthpieces
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives
-
- A—HUMAN NECESSITIES
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- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
- A24D3/063—Use of materials for tobacco smoke filters characterised by structural features of the fibers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/067—Use of materials for tobacco smoke filters characterised by functional properties
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- A—HUMAN NECESSITIES
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- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
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Abstract
一种吸烟制品包括具有外表面和设置在外表面上的凉爽剂包合物的烟嘴。
Description
本发明涉及带有烟嘴的吸烟制品，烟嘴包括在烟嘴外表面上的凉爽剂包合物。
吸烟制品通常包括烟草基体部分和烟嘴部分。烟嘴部分接触消费者的嘴部或唇部。许多燃烧式吸烟制品，例如香烟，使用包装层，已知为“水松”包装纸将烟嘴包装连接到烟草基体上。该包装层典型地形成吸烟制品的烟嘴部分的外层，或接触消费者嘴部或唇部的层。其他吸烟制品设计为使用热量、空气流、化学反应、或这些机理的结合，来向消费者递送烟草基体的成分。这些非燃烧式吸烟制品也包括围绕烟嘴部分的包装材料，其中包装材料接触消费者的嘴部或唇部。
一些吸烟制品通过使用凉爽剂例如薄荷醇来寻求清爽感。当这些凉爽剂气化并接触人体特别是口腔、鼻腔和咽喉的黏膜时，其提供了生理上的清凉感觉。
对于某些吸烟制品来说，希望的是在吸烟制品烟嘴的外表面上提供稳定的凉爽剂以向使用者提供清凉感。希望的是该凉爽剂保持在吸烟制品烟嘴的预期表面上，使得凉爽剂在吸烟体验过程中可以向使用者的唇部提供可预料的生理清凉感。还希望的是稳定的凉爽剂不提供不想要的挥发性味觉成分，其改变了吸烟制品提供的期望的味觉体验。
根据本发明，提供了一种带有具有外表面和设置在外表面上的凉爽剂包合物的烟嘴的吸烟制品。在许多实施方案中，凉爽剂是非挥发性化合物或非薄荷醇化合物。凉爽剂可以是包含酰胺的化合物或包含薄荷氧基的化合物。凉爽剂和环糊精包合物不会从其所设置的表面上迁移走。在许多实施方案中，包合物包括凉爽剂和环糊精化合物，例如β-环糊精化合物。在吸烟制品的烟嘴的制备中使用凉爽剂和环糊精包合物将在下面进一步描述。
根据本发明的吸烟制品提供了一种向使用者唇部提供可预料的生理清凉感的有效途径。已经发现在吸烟制品的包装材料上设置的非挥发性凉爽化合物倾向于从吸烟制品的表面向内部迁移走，在吸烟制品内部不能与消费者的唇部或手指发生物理接触。本发明的凉爽剂包合物保持稳定并且在吸烟制品烟嘴的外 表面上长期保持。凉爽剂和环糊精包合物是没有气味的，并且不提供不希望的挥发性味觉成分，其改变吸烟制品所提供的预期味觉体验。凉爽剂包合物可以设置在水松纸上并且接着输送通过制造过程和吸烟制品的组装过程而不影响凉爽剂包合物的稳定性。
术语“凉爽剂”指的是这样的化合物，当其接触消费者的人体和，特别是唇部和手指时，提供生理清凉感。
术语“水松”包装纸指的是这样的包装材料，其可以由纸或聚合物或其他材料和其他任选的填充材料制成。水松包装纸没置在吸烟制品烟嘴的至少一部分周围。水松包装纸通常将烟嘴(例如过滤单元)连接到烟草基体。
优选地，凉爽剂是非挥发性的。术语“非挥发性”指的是这样的化合物或材料，其在正常室温和压力下不易蒸发。薄荷醇，其化学名称为2-异丙基-5-甲基环己醇，在这里被视为是挥发性的。术语非挥发性的一个量度是化合物或材料具有小于薄荷醇的蒸气压，即是，小于大约8.5Pa、或小于大约5Pa或小于大约2.5Pa，均在25摄氏度。
术语“烟嘴”指的是设计为接触消费者嘴部的吸烟制品部分。在传统吸烟制品中，它可以是吸烟制品的包括过滤嘴的部分，或在一些情况下，烟嘴由水松纸的延伸长度限定。其他情况下，烟嘴可以限定为从吸烟制品的嘴端延伸大约40mm的吸烟制品的部分，或从吸烟制品的嘴端延伸大约30mm的吸烟制品部分。
根据本发明的吸烟制品包括具有设置在外表面上的凉爽剂包合物的烟嘴。凉爽剂可以为任何有用的非挥发性凉爽剂或非薄荷醇类凉爽剂，或既是非挥发性凉爽剂又是非薄荷醇类凉爽剂。在许多实施方案中凉爽剂的蒸汽压小于薄荷醇的蒸汽压，即是，在25摄氏度时大约8.5Pa。在许多实施方案中凉爽剂的蒸汽压为在25摄氏度时小于大约5Pa。在一些实施方案中，凉爽剂的蒸汽压为在25摄氏度时小于大约2.5Pa。
本文中确定的化学结构和化学式名称不表示特定的立体化学。应理解为每个化学结构和化学式名称的所有立体和光学异构体都被认为包括在本文中。包括以下描述的凉爽剂的凉爽剂的代表性列举和描述在WO2009/027331中提供。
在许多实施方式中，凉爽剂是包含酰胺的化合物。为了清楚，酰胺基团也可以称为氨基羰基基团。在很多这些实施方案中包含酰胺的化合物具有结构 (I)：
其中R是C1-C12直链或支链烷基或烷氧基，或亚芳基或吡啶基。这些R基团可以是独立的未取代的或取代的。这些R基团可以是独立的未取代的或由氧、氮、或羟基取代的。优选地，R是C1-C6直链或支链烷基或烷氧基，或亚芳基或吡啶基，其中的任一个可以是如以上提到的未取代的或取代的。示例性的包含酰胺的化合物结构包括以下结构：
包含酰胺的化合物的示例性列举包括：N-乙基-p-薄荷烷基-3-甲酰胺(I-A也已知为WS-3)；3-(p-薄荷烷-3-甲酰胺)醋酸乙酯(I-B也已知为WS-5)；N-(乙氧基羰甲基)-p-薄荷烷-3-甲酰胺；N-(4-氰甲基苯基)-p-薄荷烷甲酰胺；N-(4-氨基羰基苯基)-p-薄荷烷；或N-(4-甲氧基苯基)-p-薄荷烷甲酰胺(I-C也已知为WS-12)；或N-(2-(吡啶-2-基-)乙基)-3-p-薄荷烷甲酰胺(I-D也已知为FEMA 4549)。优选的包含酰胺的化合物包括N-乙基-p-薄荷烷-3-甲酰胺(I-A)或3-(p-薄荷烷-3-甲酰胺)醋酸乙酯(I-B)。
在其他实施方案中包含酰胺的化合物具有结构(II)：
其中R1为C1-C6直链或支链烷基或烷氧基；且每个R2为独立地选自由C1-C3直链或支链烷基组成的组中。优选地，R1为C1-C4直链或支链烷基或烷氧基，且每个R2为独立地选自由C1-C3直链或支链烷基组成的组中。示例性的包含酰胺的化合物的结构包括以下：
包含酰胺的化合物的示例性列举包括：2-异丙基-N，2，3-三甲基丁酰胺(II-A也已知为WS-23)；N-(2-乙氧乙基)-2，3-二甲基-2-异丙基丁酰胺；或N-(1-异丙基-1-甲基异丁基)茴香酰胺；或N-乙基-2，2-二异丙基丁酰胺(II-B也已知为FEMA 4557)；或N-(2-羟乙基)-2-异丙基-2，3-二甲基丁酰胺(II-C也已知为FEMA 4602)。优选的包含酰胺的化合物包括2-异丙基-N，2，3-三甲基丁酰胺(II-A)。
在许多实施方案中，凉爽剂为包含薄荷烷氧基的化合物。在许多实施方案中凉爽剂和包含薄荷烷氧基的化合物不包括薄荷醇。在许多这些实施方案中包含薄荷烷氧基的化合物具有结构(III)：
其中R3为C1-C6直链或支链烷基或烷氧基。R3可以是未取代的或取代的。在一些实施方案中，R3被氧、氮、或羟基取代。示例性的包含薄荷烷氧基的化合物结构包括以下：
包含薄荷烷氧基的化合物的示例性列举包括：乳酸薄荷基酯(III-C也已知为FEMA 3748)；琥珀酸单薄荷基酯；戊二酸单薄荷基酯；吡咯烷-2-酮-5-羧酸薄荷基酯；4-(N，N-二甲氨基)-4-氧代丁酸薄荷基酯；3-羟基丁酸薄荷基酯；3-薄荷烷氧基丙烷-1，2-二醇；2-薄荷烷氧基乙醇(III-A也已知为FEMA4154)；薄荷酮甘油缩酮；薄荷烷-3，8-二醇；或；或薄荷基甲基醚(III-B也已知为FEMA 4054)。
在许多实施方案中，凉爽剂包合物是环糊精凉爽剂包合物，其包括凉爽剂，例如一种或多种以上所述的凉爽剂和环糊精。环糊精与凉爽剂结合形成了凉爽剂和环糊精之间的包合物。该包合物是笼形配合物或宾主型配合物，其中凉爽剂包合在处于分子水平的环糊精内。环糊精形成了围绕凉爽剂的“阱”，并且通过分子固定化，确保凉爽剂不在整个吸烟制品烟嘴的表面迁移。当使用者将他们的唇部置于吸烟制品烟嘴上并将没置在其上的包合物润湿时，包合物解离并且释放凉爽剂，对使用者的唇部和手指造成生理清凉感。
考虑用于本发明的环糊精具有环形结构，并且能够与以上所述的任何凉爽剂形成包合物。本发明涉及的环糊精包括α-环糊精、β-环糊精、γ-环糊精和它们的混合物。α-环糊精是具有6个吡喃葡萄糖单元的环形结构化合物；β-环糊精是具有7个吡喃葡萄糖单元的环形结构化合物；γ-环糊精是具有8个吡喃葡萄糖的环形结构化合物。在许多实施方案中，用于包合物中的环糊精是β-环糊精和任何以上所述的冷却剂。关于环糊精的进一步的细节在美国专利No.4,751,095中公开。例如，环糊精是商购可得的并且可不经修饰用于本发明中。
在一个实施方案中，提供了一种制备凉爽剂和环糊精的包合物的方法。环糊精选自由α-环糊精、β-环糊精、γ-环糊精和它们的混合物组成的组。优选地，环糊精为β-环糊精。可替代地，环糊精可以为β-环糊精或γ-环糊精。包合物通过将环糊精溶解在适合于包合物形成的介质中来形成。适合的介质包括水性液体，环糊精在其中是可溶的，并且凉爽剂在其中是能够分散的。优选的介质为水。然而，主要是水并具有少量醇的水性液体也是适合的。例如，甲醇、乙醇或异丙醇的水溶液，环糊精在其中是可溶的，是适合的。
在一个示例性实施方案中，环糊精以低于它的溶解度限度水平溶解在水性介质中。将凉爽剂加入该溶液当中，同时搅拌该溶液以将凉爽剂分散并且形成凉爽剂环糊精包合物。最终的包合物产物接着用于吸烟制品烟嘴的制备。
在许多实施方案中，包合物通过印刷、喷涂或涂覆施加到水松包装纸上。在吸烟制品的制备过程中，包合物保持在水松包装纸的施加表面上。在一些实施方案中包合物涂覆的水松包装纸被输送通过水松包装纸辊、转鼓、破碎机(breaker)和包装操作。令人惊奇地包合物经过所有这些操作过程都保持稳定、活性并且保持在水松纸上。接着，水松包装纸可以被施加到吸烟制品的烟嘴上， 例如过滤单元，例如来形成吸烟制品。在其他实施方案中，在吸烟制品的制备过程中，包合物被施加到吸烟制品烟嘴的外表面上。例如，当水松包装纸处于吸烟制品的烟嘴处时，包合物被喷涂或印刷或涂覆到水松包装纸上。
包合物可以包括在传统燃烧式吸烟制品的烟嘴的外表面上，或它可以包括在构造为使用热量、气流或化学反应递送烟草成分的非燃烧式吸烟制品的烟嘴的外表面上。
已经发现，在至少一个实施方案中，凉爽剂和环糊精的包合物保持稳定、活性并且保持在水松包装纸上至少6个月。因此，不使用另外的阻挡层或涂层，凉爽剂不从水松包装纸的施加表面迁移走，并且在吸烟制品6个月的存储时间后，向使用者唇部提供了产生生理性清凉感的吸烟制品。凉爽剂和环糊精的包合物还在抽烟体验过程中不提供令人不快的味觉。
虽然以下就香烟吸烟制品描述了凉爽剂和环糊精的包合物，但是凉爽剂包合物可以用于其他吸烟制品。这些其他吸烟制品设计为使用热量、气流、化学反应或这些机制的结合来向消费者递送烟草基体的成分。许多这些非燃烧式吸烟制品还包括围绕烟嘴部分的包装材料，其中包装材料与消费者的嘴部或唇部接触。凉爽剂和环糊精的包合物可以用在这些吸烟制品的烟嘴上以向消费者的唇部或手指或两者提供生理清凉感。
优选地，吸烟制品包括介于大约0.01mg和大约10mg的所述凉爽剂，更优选地介于大约0.01mg和大约2mg之间，和最优选地介于大约0.05mg和大约1mg之间。在许多实施方案中，凉爽剂设置在吸烟制品的烟嘴的外包装的外表面上，例如穿过外包装的整个表面。在许多实施方案中，凉爽剂均匀地设置在外包装上，以便接触消费者的唇部和指尖。
优选地，凉爽剂仅设置在烟嘴的部分外表面上。例如在一些实施方案中凉爽剂仅被设置在烟嘴的外表面的第一个大约15mm的嘴端部分，优选的仅在烟嘴的外表面的第一个大约12mm的嘴端部分。这可以允许在吸烟制品被使用时，凉爽剂接触消费者的唇部。在一些其他实施方案中凉爽剂仅被设置成超过外包装的第一个大约12mm的嘴端部分，优选地超过外包装的第一个大约15mm的嘴端部分。当吸烟制品被使用时，这可以允许凉爽剂接触消费者的指尖。可替代地，在一些其他实施方案中，凉爽剂可以设置在穿过烟嘴的整个外表面。
下面将参考附图，通过仅示例的方式对本发明进行进一步描述，其中：
图1显示了根据本发明的吸烟制品的横截面示意图，其具有设置在烟嘴的外表面的凉爽剂和环糊精的包合物；
图1中所示的吸烟制品10包括烟草基体或烟草杆12，其连接到烟嘴14，并与之轴向对齐，在这里显示为过滤嘴14。烟嘴或过滤嘴14包括滤塞16，其可以由包装在成型纸18内的醋酸纤维素形成。水松包装纸19将烟草杆12与轴向排列的烟嘴或过滤嘴14连接。
凉爽剂和环糊精的包合物20被设置在烟嘴或过滤嘴14的外表面上。在许多实施方案中凉爽剂和环糊精包合物20被设置在水松包装纸19上，其形成了烟嘴外表面的至少一部分。
如图1所示，凉爽剂和环糊精包合物20不需要阻挡层或任何其他层来防止凉爽剂和环糊精包合物20的迁移。在不需要使用另外的层或涂层的情况下，凉爽剂和环糊精包合物20保持稳定、活性且在水松纸上保持延长的时间段。
实施例
进行感官研究以确定，与已经陈化了6个月的相同的香烟相比，具有设置在水松纸上的凉爽剂包合物是否可以提供更强烈的清凉感觉。
准备三个不同的香烟的组(1P，2P，3P)，并且交给评审小组进行感官研究。每一组由未陈化版本的香烟和已经陈化6个月的相应版本的香烟组成。在每种情况下，在水松纸上使用等量的凉爽剂制备香烟。
表1-香烟分类
评审小组被要求湿润他们的唇部，将第一支香烟的过滤嘴部分塞入他们嘴部的左侧，并且抽吸未点燃的香烟两次，接着移走香烟。评审小组接着被要求重复该过程，但是第二支香烟在他们嘴部的右侧。在两支香烟移走之后几秒，评审小组接着被要求说明哪支香烟提供了更强烈的清凉感。每对香烟以随机顺 序被提供给小组成员7次。每对香烟包括一支未陈化的香烟和一支相应的陈化香烟，如表1所示。
由评审小组提供的结果如以下的表2所示。
表2-评审小组的反应
已经发现对于实施的每次测试，未陈化香烟和陈化香烟之间没显著不同。即是，与已经陈化6个月的相同的香烟相比，评审小组研究完全没有发现具有设置在水松纸上的凉爽剂包合物的香烟将提供更强烈的清凉感。
Claims (15)
1.一种吸烟制品，其包括：
具有外表面的烟嘴；和
设置在该外表面上的凉爽剂包合物。
2.根据权利要求1的吸烟制品，其中凉爽剂包合物是包含环糊精和凉爽剂的环糊精凉爽剂包合物。
3.根据权利要求1或2的吸烟制品，其中凉爽剂是非挥发性的。
4.根据以上任一项权利要求的吸烟制品，其中凉爽剂是包含酰胺的化合物。
5.根据权利要求4的吸烟制品，其中包含酰胺的化合物具有结构(I)：
其中R为C1-C12直链或支链烷基或烷氧基，或亚芳基或吡啶基。
6.根据权利要求4的吸烟制品，其中包含酰胺的化合物为N-乙基-p-薄荷烷-3-甲酰胺；3-(p-薄荷烷-3-甲酰胺基)醋酸乙酯；N-(乙氧基羰甲基)-p-薄荷烷-3-甲酰胺；N-(4-氰甲基苯基)-p-薄荷烷甲酰胺；N-(4-氨基羰基苯基)-p-薄荷烷；或N-(4-甲氧基苯基)-p-薄荷烷甲酰胺或N-(2-(吡啶-2-基-)乙基)-3-p-薄荷烷甲酰胺。
7.根据权利要求4的吸烟制品，其中包含酰胺的化合物为N-乙基-p-薄荷烷基-3-甲酰胺或3-(p-薄荷烷-3-甲酰胺基)醋酸乙酯。
8.根据权利要求4的吸烟制品，其中包含酰胺的化合物具有结构(II)：
其中R1为C1-C6直链或支链烷基或烷氧基；且每个R2为独立地选自由C1-C3直链或支链烷基组成的组中。
9.根据权利要求4的吸烟制品，其中包含酰胺的化合物为2-异丙基-N，2，3-三甲基丁酰胺；N-(2-乙氧乙基)-2，3-二甲基-2-异丙基丁酰胺；或N-(1-异丙基-1-甲基异丁基)茴香酰胺；或N-乙基-2，2-二异丙基丁酰胺；或N-(2-羟乙基)-2-异丙基-2，3-二甲基丁酰胺。
10.根据权利要求4的吸烟制品，其中包含酰胺的化合物为2-异丙基-N，2，3-三甲基丁酰胺。
11.根据权利要求1到3的任一项的吸烟制品，其中凉爽剂为包含薄荷烷氧基的化合物。
12.根据权利要求11的吸烟制品，其中包含薄荷氧基的化合物具有结构(III)：
其中R3为C1-C6直链或支链烷基或烷氧基。
13.根据权利要求11的吸烟制品，其中含薄荷烷氧基的化合物为乳酸薄荷基酯；琥珀酸单薄荷基酯；戊二酸单薄荷基酯；吡咯烷-2-酮-5-甲酸薄荷基酯；4-(N，N-二甲氨基)-4-氧代丁酸的薄荷基酯；3-羟基丁酸薄荷基酯；3-I-薄荷烷氧基丙基-1，2-二醇；2-I-薄荷烷氧基乙醇；薄荷酮甘油缩酮；p-薄荷烷-3，8-二醇；或薄荷基甲基醚。
14.非挥发性凉爽剂和环糊精包合物在吸烟制品的烟嘴的制备中的应用。
15.为在吸烟制品的烟嘴上提供稳定的清凉感的方法，该方法包括在烟嘴上包括环糊精包合物。
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| EP12166193 | 2012-04-30 | ||
| PCT/IB2013/052097 WO2013164706A1 (en) | 2012-04-30 | 2013-03-15 | Smoking article mouthpiece with cooling agent inclusion complex |
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| AT513411B1 (de) * | 2012-09-17 | 2015-05-15 | Tannpapier Gmbh | Mundstückbelagspapier für eine Filterzigarette |
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| KR102758881B1 (ko) | 2017-12-21 | 2025-01-23 | 필립모리스 프로덕츠 에스.에이. | 가열식 에어로졸 발생 물품에서 에어로졸 암모니아의 감소 |
| GB202003093D0 (en) * | 2020-03-04 | 2020-04-15 | British American Tobacco Investments Ltd | Delivery systems and methods of making the same |
| TWM619320U (zh) * | 2020-06-30 | 2021-11-11 | 日商優你 嬌美股份有限公司 | 用後即棄式口罩 |
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| CN108289496A (zh) * | 2015-12-18 | 2018-07-17 | 菲利普莫里斯生产公司 | 强度增强剂和实现电子蒸汽烟装置中的强度增强的方法 |
| CN109996455A (zh) * | 2016-11-30 | 2019-07-09 | 英美烟草(投资)有限公司 | 吸烟制品 |
| CN109996455B (zh) * | 2016-11-30 | 2022-06-07 | 尼科创业贸易有限公司 | 吸烟制品 |
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| Publication number | Publication date |
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| AU2013255554B2 (en) | 2016-07-28 |
| MX2014013227A (es) | 2015-01-15 |
| AU2013255554A1 (en) | 2014-11-13 |
| CN111084419B (zh) | 2023-03-17 |
| SG11201406966TA (en) | 2014-11-27 |
| KR20150010945A (ko) | 2015-01-29 |
| CN111084419A (zh) | 2020-05-01 |
| JP2018057390A (ja) | 2018-04-12 |
| JP2015516816A (ja) | 2015-06-18 |
| MY164531A (en) | 2017-12-29 |
| BR112014027156B1 (pt) | 2021-03-16 |
| WO2013164706A1 (en) | 2013-11-07 |
| US20150107608A1 (en) | 2015-04-23 |
| BR112014027156A2 (pt) | 2017-06-27 |
| EP2844094A1 (en) | 2015-03-11 |
| RU2618043C2 (ru) | 2017-05-02 |
| PH12014502338B1 (en) | 2014-12-22 |
| RU2014148181A (ru) | 2016-06-20 |
| US9949505B2 (en) | 2018-04-24 |
| US20180220699A1 (en) | 2018-08-09 |
| UA116203C2 (uk) | 2018-02-26 |
| KR102158056B1 (ko) | 2020-09-22 |
| PH12014502338A1 (en) | 2014-12-22 |
| JP6564703B2 (ja) | 2019-08-21 |
| EP2844094B1 (en) | 2021-01-27 |
| HK1208132A1 (zh) | 2016-02-26 |
| US10506824B2 (en) | 2019-12-17 |
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