CN104593169B - A kind of disinfection cleaning agent containing guanidinesalt and preparation method thereof - Google Patents
A kind of disinfection cleaning agent containing guanidinesalt and preparation method thereof Download PDFInfo
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- CN104593169B CN104593169B CN201510028529.9A CN201510028529A CN104593169B CN 104593169 B CN104593169 B CN 104593169B CN 201510028529 A CN201510028529 A CN 201510028529A CN 104593169 B CN104593169 B CN 104593169B
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Abstract
A kind of disinfection cleaning agent containing guanidinesalt includes following composition：Guanidine radicals modified quaternary ammonium salt surfactant 6 ~ 10%, nonionic surfactant 2 ~ 5%, citric acid 5 ~ 10%, ethanol 5 ~ 8%, other deionized waters of auxiliary agent 0.5 ~ 1.5% are surpluses.The present invention has the advantages of efficient, safe, to skin fanout free region.
Description
Technical field
The invention belongs to a kind of disinfection cleaning agent and preparation method thereof, and in particular to a kind of disinfection cleaning agent containing guanidinesalt and
Its preparation method.
Background technology
Sterilization cleaning is always to prevent the effective way of pathogen transmission and sprawling.Hotel, guest room, catering trade, airport, business
The populations such as building, supermarket, hospital, school, place of public amusement are densely square, often the place of human contact carried out disinfection
Cleaning.Disinfectant in disinfection cleaning agent is from the most key, because disinfectant usage time is grown, bacterium will produce necessarily
Resistance, it is necessary to be used alternatingly with the disinfectant or various types of disinfectant of higher concentration and can be only achieved antibacterial purpose.
Cationic surfactant disinfectant is one of dominant direction of sterilizing product development in the world, U.S.'s quaternary ammonium salt
Cationic surfactant accounts for more than the 15% of whole elimination agent markets, and the domestic cationic surfactant as elimination agent produces
Amount is also up to more than 40,000 tons.But traditional product, using for many years, there is the problem of resistance in the field of being normally applied, is badly in need of out
New varieties are sent out, meet application demand.
Also layer goes out not group to guanidine bactericide, and the A of Chinese patent CN 101926353 disclose guanidine hydrochloride, guanidine carbonate, phosphoric acid
Guanidine, poly (hexamethylene) hydrochloride, hexamethylene, poly hexamethylene biguanide phosphate, polyhexamethylene are double
A kind of disinfectant of and quaternary surfactant compounding in guanidine carbonate, evil non-toxic to humans and stimulation, can in nature
Fast degradation, belong to environmentally friendly product, the safety and sanitation applied in sterilization and the cleaning of food manufacturing apparatus can be reached
Rank.The A of patent CN 1357235 disclose the mixture of polyoxy alkylene guanidine and borneol, nontoxic, tasteless and nonirritant, efficiently,
Low concentration, stability are high, suitable for the sterilizing of various apparatuses.The B of patent CN 102428946 then disclose the oil containing poly- guanidine
Field bactericide.The A of patent CN 102388905 disclose guanidinesalt family macromolecule antiseptic, and it is certain relative molecular weight (molecule
Measure 1000~10000) the chloro- 2- Hydroxyproyl Trimethyls alkyl quaternary ammonium salts of poly- guanidinesalt and 3- addition reaction, obtained season occurs
The bactericide of ammonium salt grafted guanidine salt, because molecular weight ranges are very big, performance difference is big.
The content of the invention
It is an object of the invention to provide it is a kind of efficiently, safety, to disinfection cleaning agent of the skin fanout free region containing guanidinesalt and its
Preparation method.
The present invention is to introduce new guanidine radicals modified quaternary ammonium salt surfactant, and the guanidine radicals modified quaternary ammonium salt has point determined
Minor structure, there is stronger electropositive, bactericidal effect is notable, especially there is good killing effect, good water solubility, compounding to fungi
Property is good, and eco-toxicity is low, easily biological-degradable, and good compatibility is respectively provided with environment and skin.
The present invention is realized by following technology：
A kind of disinfection cleaning agent containing guanidinesalt, the percentage by weight composition of its raw material are：
Guanidine radicals modified quaternary ammonium salt surfactant in the invention is the compound for having below formula：
R is C in formula8-12Alkyl, R1For H or CH3, its specific preparation method is shown in patent ZL201210123314.1；
Nonionic surfactant is branched-chain alcoho APEO in foregoing invention, and formula is as follows：
R in formula1For C5-12Alkyl, R2For C3-10Alkyl, n are that 2~4, m is 1~9；
Other auxiliary agents in foregoing invention are pigment and/or essence.
A kind of preparation method of the disinfection cleaning agent containing guanidinesalt is as follows：
Raw materials by weight forms, and adds 1/4-1/3 deionized waters in a reservoir, and is heated to 60-70 DEG C, adds
Guanidine radicals modified quaternary ammonium salt surfactant, is sufficiently stirred, is completely dissolved it；Successively non-ionic surface is added into above-mentioned solution
Activating agent and citric acid, stir；Then remaining whole deionized water and essence, pigment are added, mixing is carried out and stirs
Mix, disinfection cleaning agent is made.
It is of the invention to be had the advantage that compared with existing like product and technology：
1st, guanidine radicals modified quaternary ammonium salt surfactant of the invention, sterilization is efficient, quick, wide spectrum, to body surface and people
Body skin is non-toxic, nonirritant, non-corrosiveness.
2nd, cation and non-ionic compounding, make product storage stability high, good penetrability, can strongly remove dirt, make
Layer protecting film is formed on surface after, prevents dust adsorption.
3rd, the addition of special collateralization nonionic surfactant, has product and suppresses foaming, can extensive use
In modern industry cleaning and sterilizing field.
4th, beneficial effect caused by the present invention is proved below by bacteriostatic experiment.The product to gram positive and negative bacterium,
Fungi has obvious fungistatic effect, and its test data is as follows：
As can be seen from the above table, fungistatic effect of the invention is very strong, this product and above-mentioned three kinds of microbial action 2min,
100% fungistatic effect can be reached.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, these embodiments be merely to illustrate this patent without
For limiting the scope of the present invention.
Embodiment 1：
Preparation method：Raw materials by weight forms, and adds 1/4 deionized water in a reservoir, and is heated to 60 DEG C, adds
Enter N, N- dimethyl-N -s (dimethyl octyl group guanidine-propyl group) octyl group quaternary surfactant, be sufficiently stirred, be completely dissolved it；
2- propyl enanthol APEOs (A is added into above-mentioned solution successively10EO9) and citric acid, stir；Then add remaining
Deionized water and essence, pigment, mixed, disinfection cleaning agent be made.
Embodiment 2：
Preparation method：Raw materials by weight forms, and adds 1/3 deionized water in a reservoir, and is heated to 70 DEG C, adds
Enter N, N- dimethyl-N -s (decyl guanidine-propyl group) decyl quaternary surfactant, be sufficiently stirred, be completely dissolved it；Successively to
2- propyl enanthol APEOs (A is added in above-mentioned solution10EO3) and citric acid, stir；Then add it is remaining go from
Sub- water and essence, pigment, are mixed, disinfection cleaning agent are made.
Embodiment 3：
Preparation method：Raw materials by weight forms, and adds 1/4 deionized water in a reservoir, and is heated to 60 DEG C, adds
Enter N, N- dimethyl-N -s (dodine-propyl group) dodecyl quaternary surfactant, be sufficiently stirred, make it completely molten
Solution；2- hexyl decyl alcohol APEOs (A is added into above-mentioned solution successively16EO3) and citric acid, stir；Then add
Remaining deionized water and essence, are mixed, and disinfection cleaning agent is made.
Embodiment 4：
Preparation method：Raw materials by weight forms, and adds 1/3 deionized water in a reservoir, and is heated to 70 DEG C, adds
Enter N- (dodine-propyl group) dodecyl quaternary surfactant, be sufficiently stirred, be completely dissolved it；It is upward successively
State and 2- hexyl decyl alcohol APEOs (A is added in solution16EO9) and citric acid, stir；Then remaining deionization is added
Water and pigment, are mixed, and disinfection cleaning agent is made.
Embodiment 5：
Preparation method：Raw materials by weight forms, and adds 1/3 deionized water in a reservoir, and is heated to 70 DEG C, adds
Enter N- (dimethyl octyl group guanidine-propyl group) octyl group quaternary surfactant, be sufficiently stirred, be completely dissolved it；Successively to above-mentioned
2- hexyl decyl alcohol APEOs (A is added in solution16EO3) and citric acid, stir；Then remaining deionized water is added
And pigment, mixed, disinfection cleaning agent is made.
Claims (1)
1. a kind of disinfection cleaning agent containing guanidinesalt, it is characterised in that a kind of disinfection cleaning agent, the percentage by weight composition of its raw material
For：
Described guanidine radicals modified quaternary ammonium salt surfactant is the compound for having below formula：
R is C in formula8-12Alkyl, R1For H or CH3；
Described nonionic surfactant is branched-chain alcoho APEO, and formula is as follows：
R in formula1For C5-12Alkyl, R2For C3-10Alkyl, n 2-4, m 1-9；
Described other auxiliary agents are pigment and essence；
And prepare by the following method：
Raw materials by weight forms, and adds 1/4-1/3 deionized waters in a reservoir, and is heated to 60-70 DEG C, adds guanidine radicals
Modified quaternary ammonium salt surfactant, is sufficiently stirred, and is completely dissolved it；Successively non-ionic surface active is added into above-mentioned solution
Agent and citric acid, stir；Then remaining whole deionized water and essence, pigment are added, is mixed, is made
Into disinfection cleaning agent.
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| CN201510028529.9A CN104593169B (en) | 2015-01-20 | 2015-01-20 | A kind of disinfection cleaning agent containing guanidinesalt and preparation method thereof |
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| CN201510028529.9A CN104593169B (en) | 2015-01-20 | 2015-01-20 | A kind of disinfection cleaning agent containing guanidinesalt and preparation method thereof |
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| CN104593169B true CN104593169B (en) | 2017-12-08 |
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| CN105421070A (en) * | 2015-11-19 | 2016-03-23 | 天津天狮生物发展有限公司 | Clothing care agent and preparing method thereof |
| CN111778509B (en) * | 2020-07-16 | 2023-03-21 | 太原工业学院 | Carbon steel corrosion inhibitor containing arginine derivative and preparation method and application thereof |
| CN111778511B (en) * | 2020-07-16 | 2023-02-07 | 太原工业学院 | Carbon steel corrosion inhibitor containing alkyl guanidine salt and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1104423A (en) * | 1993-08-19 | 1995-07-05 | 花王株式会社 | Germicidal-disinfectant detergent composition |
| CN1191156A (en) * | 1996-12-06 | 1998-08-26 | 株式会社日本触媒 | Higher secondary alcohol alkoxylate compound composition, method for production thereof, and detergent and emulsifier using the composition |
| CN1786134A (en) * | 2004-12-07 | 2006-06-14 | 雷金丰 | Multifunction antiseptic sterilizing cleaning agent composition and its preparation method |
| CN102015986A (en) * | 2008-03-16 | 2011-04-13 | 阿尔托斯医疗有限公司 | Cleaning, sanitising and sterilising preparations |
| CN102675155A (en) * | 2012-04-25 | 2012-09-19 | 中国日用化学工业研究院 | Guanidyl modified quaternary ammonium salt and synthetic method thereof |
| CN103977155A (en) * | 2014-05-29 | 2014-08-13 | 上海宇昂水性新材料科技股份有限公司 | Cleaning-free compound hand sanitizer and preparation method thereof |
-
2015
- 2015-01-20 CN CN201510028529.9A patent/CN104593169B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1104423A (en) * | 1993-08-19 | 1995-07-05 | 花王株式会社 | Germicidal-disinfectant detergent composition |
| CN1191156A (en) * | 1996-12-06 | 1998-08-26 | 株式会社日本触媒 | Higher secondary alcohol alkoxylate compound composition, method for production thereof, and detergent and emulsifier using the composition |
| CN1786134A (en) * | 2004-12-07 | 2006-06-14 | 雷金丰 | Multifunction antiseptic sterilizing cleaning agent composition and its preparation method |
| CN102015986A (en) * | 2008-03-16 | 2011-04-13 | 阿尔托斯医疗有限公司 | Cleaning, sanitising and sterilising preparations |
| CN102675155A (en) * | 2012-04-25 | 2012-09-19 | 中国日用化学工业研究院 | Guanidyl modified quaternary ammonium salt and synthetic method thereof |
| CN103977155A (en) * | 2014-05-29 | 2014-08-13 | 上海宇昂水性新材料科技股份有限公司 | Cleaning-free compound hand sanitizer and preparation method thereof |
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