CN104538844B - Terahertz quantum cascaded laser device architecture and preparation method thereof - Google Patents
Terahertz quantum cascaded laser device architecture and preparation method thereof Download PDFInfo
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Abstract
本发明提出了一种太赫兹量子级联激光器器件结构及其制作方法,至少包括:脊波导结构;脊波导结构包括半绝缘GaAs衬底、GaAs缓冲层、下接触层、有源区、上接触层、导热绝缘层、上金属层及下金属层。通过在器件侧面淀积导热绝缘层并覆盖金属,提供了器件横向的散热通道,较以往侧壁未覆盖金属的THz QCL散热能力更强。采用倒装封装方法,支撑基片采用硅等热导率高的材料,比正常封装器件的半绝缘GaAs衬底散热能力提高,同时具有更大的电极面积,也利于器件散热。新结构提高了THz QCL的温度特性、能量效率,有利于器件在连续或高占空比的脉冲状态下工作;器件制作方法可由标准半导体工艺制作,适于工业量产。
The invention proposes a terahertz quantum cascade laser device structure and a manufacturing method thereof, at least including: a ridge waveguide structure; the ridge waveguide structure includes a semi-insulating GaAs substrate, a GaAs buffer layer, a lower contact layer, an active region, and an upper contact layer, thermal insulation layer, upper metal layer and lower metal layer. By depositing a thermally conductive insulating layer on the side of the device and covering it with metal, a lateral heat dissipation channel for the device is provided, which has a stronger heat dissipation capability than the previous THz QCL whose side walls are not covered with metal. The flip-chip packaging method is adopted, and the supporting substrate is made of silicon and other materials with high thermal conductivity, which improves the heat dissipation capacity of the semi-insulating GaAs substrate of the normal packaging device, and has a larger electrode area, which is also conducive to the heat dissipation of the device. The new structure improves the temperature characteristics and energy efficiency of THz QCL, which is conducive to the device working in a continuous or high duty cycle pulse state; the device manufacturing method can be manufactured by standard semiconductor technology, which is suitable for industrial mass production.
Description
技术领域technical field
本发明属于激光器半导体技术领域,涉及一种太赫兹量子级联激光器,特别是涉及一种太赫兹量子级联激光器器件结构及其制作方法。The invention belongs to the technical field of laser semiconductors, and relates to a terahertz quantum cascade laser, in particular to a terahertz quantum cascade laser device structure and a manufacturing method thereof.
背景技术Background technique
太赫兹(以下简称THz,1 THz=1012 Hz)波段是指电磁波谱中频率从100 GHz到10THz,对应的波长从3毫米到30微米,介于毫米波与红外光之间的电磁波谱区域。THz辐射源是THz技术应用的关键器件。在众多THz辐射产生方式中,THz量子级联激光器(以下简称THzQCL)由于具有能量转换效率高、体积小、轻便和易集成等优点,是THz辐射源的主要采用过的结构之一。其中,太赫兹光谱学、通信、成像等系统中需要具有良好的温度特性、能够连续状态工作的THz QCL。通常THz QCL工作在高偏压和电流下,大部分输入电功率最终转换成了焦耳热。不能从器件中及时散出到热沉的焦耳热会积累在器件中,最终导致有源区温度升高,远远高于热沉温度。而有源区温度升高会使上能级到下能级的非辐射光学声子散射增加,破坏粒子数反转,抑制器件激射,降低辐射效率。另外,在较高温度下,载流子分布在更宽广的能级范围内,也会抑制器件激射。当THz QCL处于连续或高占空比脉冲的工作状态下,热量产生会更多,散热问题更加严重。因此,设计提高器件良好温度特性和散热能力是THz QCL能否在连续或高占空比脉冲的状态下工作的关键。The terahertz (hereinafter referred to as THz, 1 THz=1012 Hz) band refers to the frequency in the electromagnetic spectrum from 100 GHz to 10 THz, and the corresponding wavelength is from 3 millimeters to 30 microns, which is between millimeter waves and infrared light. The electromagnetic spectrum region. THz radiation source is the key device for the application of THz technology. Among many THz radiation generation methods, THz quantum cascade laser (hereinafter referred to as THzQCL) is one of the main structures used for THz radiation sources due to its advantages of high energy conversion efficiency, small size, portability and easy integration. Among them, THz QCLs with good temperature characteristics and capable of working in continuous state are required in systems such as terahertz spectroscopy, communication, and imaging. Usually THz QCL works under high bias voltage and current, and most of the input electric power is finally converted into Joule heat. Joule heat that cannot be dissipated from the device to the heat sink in time will accumulate in the device, eventually causing the temperature of the active region to rise much higher than the heat sink temperature. The increase in the temperature of the active region will increase the scattering of non-radiative optical phonons from the upper energy level to the lower energy level, destroying the population inversion, suppressing the lasing of the device, and reducing the radiation efficiency. In addition, at higher temperatures, the carriers are distributed in a wider range of energy levels, which also inhibits device lasing. When the THz QCL is in the working state of continuous or high duty cycle pulse, more heat will be generated, and the heat dissipation problem will be more serious. Therefore, designing to improve the good temperature characteristics and heat dissipation capability of the device is the key to whether THz QCL can work in the state of continuous or high duty cycle pulse.
发明内容Contents of the invention
鉴于以上所述现有技术的缺点,本发明的目的在于提供一种太赫兹量子级联激光器器件结构及其制作方法,用于解决现有技术中太赫兹量子级联激光器在工作过程中存在的散热不佳的问题。In view of the above-mentioned shortcomings of the prior art, the object of the present invention is to provide a terahertz quantum cascade laser device structure and its manufacturing method, which are used to solve the problems existing in the working process of the terahertz quantum cascade laser in the prior art. Problem with poor heat dissipation.
为实现上述目的及其他相关目的,本发明提供一种太赫兹量子级联激光器器件结构,所述太赫兹量子级联激光器器件结构至少包括:脊波导结构;To achieve the above purpose and other related purposes, the present invention provides a terahertz quantum cascade laser device structure, the terahertz quantum cascade laser device structure at least includes: a ridge waveguide structure;
所述脊波导结构包括半绝缘GaAs衬底、GaAs缓冲层、下接触层、有源区、上接触层、导热绝缘层、上金属层及下金属层;其中,所述半绝缘GaAs衬底、GaAs缓冲层、下接触层、有源区及上接触层由下至上依次层叠,所述有源区及所述上接触层在所述下接触层上形成脊型结构;所述上金属层覆盖于所述脊型结构的顶部与两侧;所述导热绝缘层位于所述脊型结构的两侧,且位于所述上金属层与所述脊型结构及所述下接触层之间;The ridge waveguide structure includes a semi-insulating GaAs substrate, a GaAs buffer layer, a lower contact layer, an active region, an upper contact layer, a thermally conductive insulating layer, an upper metal layer, and a lower metal layer; wherein the semi-insulating GaAs substrate, GaAs buffer layer, lower contact layer, active region and upper contact layer are stacked sequentially from bottom to top, the active region and the upper contact layer form a ridge structure on the lower contact layer; the upper metal layer covers On the top and both sides of the ridge structure; the thermally conductive insulating layer is located on both sides of the ridge structure, and between the upper metal layer, the ridge structure and the lower contact layer;
所述下金属层位于所述上金属层的两侧,且与所述上金属层具有一定的间距。The lower metal layer is located on both sides of the upper metal layer and has a certain distance from the upper metal layer.
优选地,所述脊波导还包括下电极支撑结构;所述下电极支撑结构位于所述下接触层上,包括有源区、上接触层及导热绝缘层;其中,所述有源区及所述上接触层由下至上依次形成于所述下接触层上,且在所述下接触层上形成脊型结构;所述导热绝缘层覆盖于所述脊型结构的顶部与两侧;所述下金属层覆盖于所述导热绝缘层的顶部与两侧。Preferably, the ridge waveguide also includes a lower electrode support structure; the lower electrode support structure is located on the lower contact layer, including an active region, an upper contact layer, and a thermally conductive insulating layer; wherein, the active region and the The upper contact layer is sequentially formed on the lower contact layer from bottom to top, and a ridge structure is formed on the lower contact layer; the thermally conductive insulating layer covers the top and both sides of the ridge structure; the The lower metal layer covers the top and both sides of the heat conducting insulating layer.
优选地,所述导热绝缘层的材料为二氧化硅或氮化硅。Preferably, the material of the thermally conductive insulating layer is silicon dioxide or silicon nitride.
优选地,所述有源区包括束缚态到连续态跃迁结构、共振声子结构或啁啾晶格结构。Preferably, the active region comprises a bound state to continuous state transition structure, a resonant phonon structure or a chirped lattice structure.
优选地,所述脊型波导结构为半绝缘等离子波导结构。Preferably, the ridge waveguide structure is a semi-insulating plasmonic waveguide structure.
优选地,所述器件结构还包括一支撑基片,所述支撑基片上形成有与所述上金属层及所述下金属层相对应的电极引出金属层;所述支撑基片通过所述电极引出金属层焊接于所述上金属层及所述下金属层的上表面。Preferably, the device structure further includes a supporting substrate, on which an electrode lead-out metal layer corresponding to the upper metal layer and the lower metal layer is formed; the supporting substrate passes through the electrode The lead metal layer is welded to the upper surfaces of the upper metal layer and the lower metal layer.
优选地,所述器件结构还包括铟层,所述铟层位于所述上金属层及所述下金属层与所述电极引出金属层之间。Preferably, the device structure further includes an indium layer, and the indium layer is located between the upper metal layer and the lower metal layer and the electrode lead-out metal layer.
优选地,所述支撑基片的材料为硅。Preferably, the material of the supporting substrate is silicon.
本发明还提供一种太赫兹量子级联激光器器件结构的制作方法,至少包括以下步骤:The present invention also provides a method for manufacturing a terahertz quantum cascade laser device structure, which at least includes the following steps:
提供一半绝缘GaAs衬底,在所述半绝缘GaAs衬底上依次生长缓冲层、下接触层、有源区、上接触层;providing a half-insulating GaAs substrate, on which a buffer layer, a lower contact layer, an active region, and an upper contact layer are sequentially grown;
第一次光刻,采用刻蚀工艺形成脊型波导结构及下电极支撑结构;For the first photolithography, an etching process is used to form a ridge waveguide structure and a lower electrode support structure;
在所述脊型波导结构及所述下电极支撑结构上生长导热绝缘层;第二次光刻,并通过刻蚀工艺刻蚀所述导热绝缘层形成上电极窗口,在所述上电极窗口内形成上电极金属,带胶剥离形成的上电极,并覆盖所述脊型波导结构的侧壁;growing a thermally conductive insulating layer on the ridge waveguide structure and the lower electrode supporting structure; second photolithography, and etching the thermally conductive insulating layer through an etching process to form an upper electrode window, within the upper electrode window Forming the upper electrode metal, stripping the upper electrode formed with glue, and covering the side wall of the ridge waveguide structure;
第三次光刻形成下电极窗口,在所述下电极窗口内形成下电极金属,带胶剥离形成下电极,退火形成欧姆接触;Forming the lower electrode window in the third photolithography, forming the lower electrode metal in the lower electrode window, peeling off the adhesive to form the lower electrode, and annealing to form an ohmic contact;
提供一支撑基片,第四次光刻,在所述支撑基片上对应于上下电极倒装焊触处开窗口,在所述开口内溅射生长金属,带胶剥离,形成电极引出金属层;A support substrate is provided, the fourth photolithography is performed, and a window is opened on the support substrate corresponding to the flip-chip welding contacts of the upper and lower electrodes, and metal is sputtered and grown in the opening, and the adhesive is peeled off to form an electrode lead-out metal layer;
减薄所述支撑基片与所述GaAs衬底至一定厚度,解理,进行倒装焊封装,完成器件制作。Thinning the supporting substrate and the GaAs substrate to a certain thickness, cleavage, performing flip-chip packaging, and completing device fabrication.
优选地,在形成电极引出金属层之后,进行倒装焊封装之前,还包括一进行第五次光刻,在所述电极引出金属层处开窗口,电子束蒸发铟层,带胶剥离,用于倒装焊的步骤。Preferably, after forming the electrode lead-out metal layer and before performing flip-chip packaging, it also includes performing a fifth photolithography, opening a window at the electrode lead-out metal layer, evaporating the indium layer by electron beam, peeling off the tape, and using in the step of flip-chip soldering.
如上所述,本发明的太赫兹量子级联激光器器件结构及其制作方法,具有以下有益效果:(1)本发明的太赫兹量子级联激光器器件结构中通过在器件侧面淀积导热绝缘层并覆盖金属,导热绝缘层既起到钝化作用,保护器件,又可以将覆盖的金属与有源区绝缘;由于有源区量子阱结构的热导率是各向异性的,且热导率横向分量大于垂直方向的热导率分量,以往并未加以利用,在器件侧壁覆盖金属,加上中间的导热绝缘层,提供了器件横向的散热通道,较以往侧壁未覆盖金属的THz QCL散热能力更强。As mentioned above, the terahertz quantum cascade laser device structure and its manufacturing method of the present invention have the following beneficial effects: (1) In the terahertz quantum cascade laser device structure of the present invention, by depositing a thermally conductive insulating layer on the side of the device and Covering the metal, the thermally conductive insulating layer not only plays a passivation role, protects the device, but also insulates the covered metal from the active area; because the thermal conductivity of the quantum well structure in the active area is anisotropic, and the thermal conductivity is transverse The component is larger than the thermal conductivity component in the vertical direction, which has not been used in the past. The sidewall of the device is covered with metal, and the middle thermal insulation layer provides a lateral heat dissipation channel for the device, which is better than the previous THz QCL with no metal on the sidewall. more capable.
(2)在支撑基片上制作电极引线,将器件倒装焊在支撑基片上,支撑基片采用硅等热导率高的材料,较正常封装器件的半绝缘GaAs衬底散热能力得到提高,可以将器件有源区产生的热量更快散到支撑基片下面的热沉上。在焊线封装时,由于采用倒装焊后,支撑基片电极引线面积更大,电极可以更多地焊接金线,利用焊接在热沉上外部导热陶瓷片也可以将器件产生热量更好地散出。(2) Make electrode leads on the support substrate, and flip-chip solder the device on the support substrate. The support substrate is made of a material with high thermal conductivity such as silicon, which improves the heat dissipation capacity of the semi-insulating GaAs substrate of the normal package device, and can The heat generated in the active area of the device is dissipated more quickly to the heat sink under the supporting substrate. In the wire bonding package, due to the use of flip-chip welding, the electrode lead area of the supporting substrate is larger, and the electrodes can be welded with more gold wires. The external heat-conducting ceramic sheet welded on the heat sink can also make the device generate heat better. shed.
(3)本发明的太赫兹量子级联激光器器件结构制作方法可由标准半导体工艺制作,适于工业量产。(3) The manufacturing method of the terahertz quantum cascade laser device structure of the present invention can be manufactured by standard semiconductor technology, and is suitable for industrial mass production.
附图说明Description of drawings
图1显示为本发明的太赫兹量子级联激光器器件结构中脊型波导结构的横截面示意图。FIG. 1 is a schematic cross-sectional view of a ridge waveguide structure in a terahertz quantum cascade laser device structure of the present invention.
图2显示为本发明的太赫兹量子级联激光器器件结构中支撑基片的俯视示意图。Fig. 2 is a schematic top view of the supporting substrate in the device structure of the terahertz quantum cascade laser of the present invention.
图3显示为本发明的太赫兹量子级联激光器器件结构倒装封装后的俯视示意图。Fig. 3 is a schematic top view of the terahertz quantum cascade laser device structure flip-chip packaged according to the present invention.
图4显示为图3沿AA’方向的横截面示意图。Figure 4 is a schematic cross-sectional view of Figure 3 along the direction AA'.
图5显示为本发明的太赫兹量子级联激光器器件结构制作方法的流程图。Fig. 5 is a flow chart showing the manufacturing method of the terahertz quantum cascade laser device structure of the present invention.
元件标号说明Component designation description
1 上金属层1 upper metal layer
2 上接触层2 upper contact layer
3 有源区3 active area
4 下接触层4 lower contact layer
5 GaAs缓冲层5 GaAs buffer layer
6 半绝缘GaAs衬底6 Semi-insulating GaAs substrate
7 导热绝缘层7 thermal insulation layer
8 下金属层8 lower metal layer
9 支撑基片9 Support substrate
10 电极引出接触层10 Electrode lead-out contact layer
11 脊型波导结构11 Ridge waveguide structure
具体实施方式Detailed ways
以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。Embodiments of the present invention are described below through specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the content disclosed in this specification. The present invention can also be implemented or applied through other different specific embodiments, and various modifications or changes can be made to the details in this specification based on different viewpoints and applications without departing from the spirit of the present invention.
请参阅图1至图5。需要说明的是,本实施例中所提供的图示仅以示意方式说明本发明的基本构想,虽图示中仅显示与本发明中有关的组件而非按照实际实施时的组件数目、形状及尺寸绘制,其实际实施时各组件的型态、数量及比例可为一种随意的改变,且其组件布局型态也可能更为复杂。See Figures 1 through 5. It should be noted that the diagrams provided in this embodiment are only schematically illustrating the basic concept of the present invention, although only the components related to the present invention are shown in the diagrams rather than the number, shape and Dimensional drawing, the type, quantity and proportion of each component can be changed arbitrarily during actual implementation, and the component layout type may also be more complicated.
实施例一Embodiment one
请参阅图1,本发明提供一种太赫兹量子级联激光器器件结构,所述太赫兹量子级联激光器器件结构至少包括:脊波导结构11;所述脊波导结构11包括半绝缘GaAs衬底6、GaAs缓冲层5、下接触层4、有源区3、上接触层2、导热绝缘层7、上金属层1(即上电极)及下金属层8(即下电极);其中,所述半绝缘GaAs衬底6、GaAs缓冲层5、下接触层4、有源区3及上接触层2由下至上依次层叠,所述有源区3及所述上接触层2在所述下接触层4上形成脊型结构;所述上金属层1覆盖于所述脊型结构的顶部与两侧;所述导热绝缘层7位于所述脊型结构的两侧,且位于所述上金属层1与所述脊型结构及所述下接触层4之间;所述下金属层8位于所述上金属层1的两侧,且与所述上金属层1具有一定的间距。Please refer to FIG. 1, the present invention provides a terahertz quantum cascade laser device structure, the terahertz quantum cascade laser device structure at least includes: a ridge waveguide structure 11; the ridge waveguide structure 11 includes a semi-insulating GaAs substrate 6 , GaAs buffer layer 5, lower contact layer 4, active region 3, upper contact layer 2, thermally conductive insulating layer 7, upper metal layer 1 (ie upper electrode) and lower metal layer 8 (ie lower electrode); wherein, the The semi-insulating GaAs substrate 6, the GaAs buffer layer 5, the lower contact layer 4, the active region 3 and the upper contact layer 2 are sequentially stacked from bottom to top, and the active region 3 and the upper contact layer 2 are in the lower contact layer. A ridge structure is formed on the layer 4; the upper metal layer 1 covers the top and both sides of the ridge structure; the thermally conductive insulating layer 7 is located on both sides of the ridge structure, and is located on the upper metal layer 1 between the ridge structure and the lower contact layer 4; the lower metal layer 8 is located on both sides of the upper metal layer 1, and has a certain distance from the upper metal layer 1.
所述脊型波导结构11通过在侧面淀积所述导热绝缘层7,并在所述导热绝缘层7上覆盖所述上金属层1,所述导热绝缘层7既起到钝化作用,保护器件,又可以将覆盖的所述上金属层1与所述有源区3绝缘。由于所述有源区3量子阱结构的热导率是各向异性的,且热导率横向分量大于垂直方向的热导率分量,以往并未加以利用,在器件侧壁覆盖所述上金属层1,加上中间的所述导热绝缘层7,提供了器件横向的散热通道,较以往侧壁未覆盖所述上金属层1的器件结构散热能力更强。The ridge waveguide structure 11 deposits the thermally conductive insulating layer 7 on the side and covers the upper metal layer 1 on the thermally conductive insulating layer 7. The thermally conductive insulating layer 7 not only plays a passivation role, but also protects device, and insulate the covered upper metal layer 1 from the active region 3 . Since the thermal conductivity of the quantum well structure in the active region 3 is anisotropic, and the lateral component of thermal conductivity is greater than the thermal conductivity component in the vertical direction, it has not been used in the past. The layer 1, together with the heat-conducting insulating layer 7 in the middle, provides a lateral heat dissipation channel for the device, which has a stronger heat dissipation capability than the previous device structure whose side walls do not cover the upper metal layer 1 .
具体的,所述导热绝缘层7的横截面形状为L型,所述导热绝缘层7不仅位于所述上金属层1与所述脊型结构之间,还位于所述上金属层1与所述下接触层4之间,即所述导热绝缘层7将所述上金属层1与所述下接触层4之间隔离开,以保证所述上金属层1不与所述下接触层4直接接触,进而避免了所述上金属层1与所述下接触层8直接接触,避免了短路问题的发生。Specifically, the cross-sectional shape of the thermally conductive insulating layer 7 is L-shaped, and the thermally conductive insulating layer 7 is not only located between the upper metal layer 1 and the ridge structure, but also located between the upper metal layer 1 and the Between the lower contact layer 4, that is, the thermally conductive insulating layer 7 isolates the upper metal layer 1 from the lower contact layer 4, so as to ensure that the upper metal layer 1 is not directly connected to the lower contact layer 4. Contact, thereby avoiding the direct contact between the upper metal layer 1 and the lower contact layer 8, avoiding the occurrence of short circuit problems.
具体的,所述导热绝缘层7的上表面与所述上接触层2的上表面平齐,所述导热绝缘层7的下表面与所述有源区3的下表面相平齐。Specifically, the upper surface of the thermally conductive insulating layer 7 is flush with the upper surface of the upper contact layer 2 , and the lower surface of the thermally conductive insulating layer 7 is flush with the lower surface of the active region 3 .
请参阅图2,所述脊波导结构11还包括下电极支撑结构,所述下电极支撑结构位于所述上金属层1的两侧,且与所述上金属层1具有一定的间距;所述下电极支撑结构位于所述下接触层4上,包括有源区3、上接触层2及导热绝缘层7;其中,所述有源区3及所述上接触层2由下至上依次形成于所述下接触层4上,且在所述下接触层4上形成脊型结构;所述导热绝缘层7覆盖于所述脊型结构的顶部与两侧;所述下金属层8覆盖于所述导热绝缘层7的顶部与两侧,即所述下电极支撑结构位于所述下金属层8的下方。Please refer to FIG. 2, the ridge waveguide structure 11 also includes a lower electrode support structure, the lower electrode support structure is located on both sides of the upper metal layer 1, and has a certain distance from the upper metal layer 1; The lower electrode support structure is located on the lower contact layer 4, including an active region 3, an upper contact layer 2, and a thermally conductive insulating layer 7; wherein, the active region 3 and the upper contact layer 2 are sequentially formed on the On the lower contact layer 4, a ridge structure is formed on the lower contact layer 4; the thermally conductive insulating layer 7 covers the top and both sides of the ridge structure; the lower metal layer 8 covers the The top and both sides of the thermally conductive insulating layer 7 , that is, the lower electrode support structure is located below the lower metal layer 8 .
所述下电极支撑结构为脊型结构,其可以将所述下金属层8引到与所述上金属层1相近的高度,在后续倒装封装时,可以保证将所述脊型波导结构11平整地焊接到支撑基片对应的电极引线上。The lower electrode support structure is a ridge structure, which can lead the lower metal layer 8 to a height close to that of the upper metal layer 1, and can ensure that the ridge waveguide structure 11 Weld flatly to the corresponding electrode leads of the supporting substrate.
所述下电极支撑结构通过在侧面淀积所述导热绝缘层7,并在所述导热绝缘层7上覆盖所述下金属层8,所述导热绝缘层7既起到钝化作用,保护器件,又可以将覆盖的所述下金属层8与所述有源区3绝缘。由于所述有源区3量子阱结构的热导率是各向异性的,且热导率横向分量大于垂直方向的热导率分量,以往并未加以利用,在所述下电极支撑结构侧壁覆盖所述下金属层8,加上中间的所述导热绝缘层7,提供了器件横向的散热通道,散热能力更强。The lower electrode support structure deposits the thermally conductive insulating layer 7 on the side and covers the lower metal layer 8 on the thermally conductive insulating layer 7. The thermally conductive insulating layer 7 not only plays a passivation role, but also protects the device. , and insulate the covered lower metal layer 8 from the active region 3 . Since the thermal conductivity of the quantum well structure in the active region 3 is anisotropic, and the lateral component of thermal conductivity is greater than the vertical thermal conductivity component, it has not been used in the past, and the sidewall of the lower electrode support structure Covering the lower metal layer 8, together with the thermally conductive insulating layer 7 in the middle, provides a lateral heat dissipation channel for the device, and has a stronger heat dissipation capability.
具体的,所述脊型波导结构11为半绝缘等离子波导结构,半绝缘等离子波导结构可以很好地束缚电磁波,具有良好的传输特性,较双面金属波导结构的THz QCL具有较高的输出功率和光束质量。Specifically, the ridge waveguide structure 11 is a semi-insulating plasmonic waveguide structure, the semi-insulating plasmonic waveguide structure can well restrain electromagnetic waves, has good transmission characteristics, and has higher output power than THz QCL with double-sided metal waveguide structure and beam quality.
具体的,所述有源区3包括但不限于束缚态到连续态跃迁结构、共振声子结构或啁啾晶格结构。Specifically, the active region 3 includes, but is not limited to, a transition structure from a bound state to a continuous state, a resonant phonon structure, or a chirped lattice structure.
具体的,所述导热绝缘层7的材料包括但不限于二氧化硅或氮化硅等常用的钝化材料。所述导热绝缘层7既起到钝化作用,保护器件,又可以将覆盖的金属与所述有源区3绝缘。空气是热的不良导体,该层材料的热导率比空气高很多,且所述有源区3的材料在横向热导率分量更高,因而较以往侧壁未钝化器件,热量在横向(x轴方向)多了散热的通道,器件散热能力增强,提高了器件的温度特性。Specifically, the material of the thermally conductive insulating layer 7 includes, but is not limited to, commonly used passivation materials such as silicon dioxide or silicon nitride. The thermally conductive insulating layer 7 not only plays a passivation role, protects the device, but also insulates the covered metal from the active region 3 . Air is a poor conductor of heat, the thermal conductivity of the material of this layer is much higher than that of air, and the material of the active region 3 has a higher lateral thermal conductivity component, so compared with the previous device without passivation on the side wall, the heat in the lateral direction (in the x-axis direction) there are more heat dissipation channels, the heat dissipation capability of the device is enhanced, and the temperature characteristics of the device are improved.
请参阅图3,所述太赫兹量子级联激光器器件结构还包括一支撑基片9,所述支撑基片9上形成有与所述上金属层1及所述下金属层8相对应的电极引出金属层10;所述支撑基片9可以通过所述电极引出金属层10焊接于所述上金属层1及所述下金属层8的上表面。Please refer to FIG. 3 , the structure of the terahertz quantum cascade laser device also includes a support substrate 9 on which electrodes corresponding to the upper metal layer 1 and the lower metal layer 8 are formed. Lead out metal layer 10 ; the support substrate 9 can be welded to the upper surfaces of the upper metal layer 1 and the lower metal layer 8 through the electrode lead out metal layer 10 .
具体的,所述支撑基片9的材料包括但不限于硅,优选地,本实施例中,所述支撑基片9的材料为硅。所述支撑基片9采用硅基片,硅具有比GaAs材料更高的热导率,这将有利于将所述有源区3产生的热量散到所述支撑基片9下面的热沉上。Specifically, the material of the supporting substrate 9 includes but not limited to silicon. Preferably, in this embodiment, the material of the supporting substrate 9 is silicon. The supporting substrate 9 adopts a silicon substrate, and silicon has a higher thermal conductivity than GaAs material, which will help dissipate the heat generated by the active region 3 to the heat sink below the supporting substrate 9 .
请参阅图4,所述脊型波导结构11通过倒装封装工艺倒装于所述支撑基片9上。此时,所述脊型波导结构11内的所述上金属层1及所述下金属层8与所述支撑基片9上的所述电极引出金属层10接触连接。具体的,可以采用焊接工艺将所述上金属层1及所述下金属层8焊接至所述电极引出金属层10上,以实现器件的倒装封装。Please refer to FIG. 4 , the ridge waveguide structure 11 is flip-chip mounted on the supporting substrate 9 through a flip-chip packaging process. At this time, the upper metal layer 1 and the lower metal layer 8 in the ridge waveguide structure 11 are in contact with the electrode lead-out metal layer 10 on the support substrate 9 . Specifically, the upper metal layer 1 and the lower metal layer 8 may be welded to the electrode lead-out metal layer 10 by a welding process, so as to realize flip-chip packaging of the device.
采用倒装封装方法,在所述支撑基片9上制作电极引出金属层10(即电极引线),将所述脊型波导结构11倒装焊在所述支撑基片9上,所述支撑基片9采用硅等热导率高的材料,较正常封装器件的半绝缘GaAs衬底散热能力得到提高,可以将器件有源区产生的热量更快散到所述支撑基片9下面的热沉上。在焊线封装时,由于采用倒装焊后,所述支撑基片9中的所述电极引出金属层10面积更大,所述电极引出金属层10可以更多地焊接金线,利用焊接在热沉上外部导热陶瓷片也可以将器件产生热量更好地散出。Using the flip-chip packaging method, the electrode lead-out metal layer 10 (i.e. electrode leads) is made on the support substrate 9, and the ridge waveguide structure 11 is flip-chip welded on the support substrate 9, and the support substrate Sheet 9 is made of materials with high thermal conductivity such as silicon, which improves the heat dissipation capability of the semi-insulating GaAs substrate of the normal packaging device, and can dissipate the heat generated by the active area of the device to the heat sink below the supporting substrate 9 more quickly. superior. During wire bonding packaging, due to the use of flip-chip bonding, the electrode lead-out metal layer 10 in the support substrate 9 has a larger area, and the electrode lead-out metal layer 10 can be welded with more gold wires. The external heat-conducting ceramic sheet on the heat sink can also dissipate the heat generated by the device better.
具体的,所述太赫兹量子级联激光器器件结构还包括铟层(未示出),所述铟层位于所述上金属层1及所述下金属层8与所述电极引出金属层10之间。由于在加热时,铟具有一定流动性,焊接时施加一定压力即可以使所述脊型波导结构11平整地焊接在所述支撑基片9上。Specifically, the terahertz quantum cascade laser device structure further includes an indium layer (not shown), and the indium layer is located between the upper metal layer 1 and the lower metal layer 8 and the electrode lead-out metal layer 10 between. Since indium has a certain fluidity when heated, applying a certain pressure during welding can make the ridge waveguide structure 11 welded on the supporting substrate 9 flatly.
本发明可以应用于各种有源区结构的太赫兹量子级联激光器,在气体检测、射电天文学、高分辨率光谱等领域上具有重要的应用价值。The invention can be applied to terahertz quantum cascade lasers with various active region structures, and has important application value in the fields of gas detection, radio astronomy, high-resolution spectroscopy and the like.
可以看出,本发明的太赫兹量子级联激光器器件结构通过在器件侧面淀积导热绝缘层并覆盖金属,提供了器件横向的散热通道,较以往侧壁未覆盖金属的THz QCL散热能力更强。采用倒装封装方法,支撑基片采用硅等热导率高的材料,比正常封装器件的半绝缘GaAs衬底散热能力提高,同时具有更大的电极面积,也利于器件散热。新结构提高了THzQCL的温度特性、能量效率,有利于器件在连续或高占空比的脉冲状态下工作。It can be seen that the terahertz quantum cascade laser device structure of the present invention provides a lateral heat dissipation channel for the device by depositing a thermally conductive insulating layer on the side of the device and covering the metal, which is stronger than the previous THz QCL whose side wall is not covered with metal. . The flip-chip packaging method is adopted, and the supporting substrate is made of silicon and other materials with high thermal conductivity, which improves the heat dissipation capacity of the semi-insulating GaAs substrate of the normal packaging device, and has a larger electrode area, which is also conducive to the heat dissipation of the device. The new structure improves the temperature characteristics and energy efficiency of THzQCL, which is conducive to the operation of the device in continuous or pulsed state with high duty cycle.
实施例二Embodiment two
本实施例还提供一种太赫兹量子级联激光器器件结构的制作方法,如图5所示,所述太赫兹量子级联激光器器件结构的制作方法包括以下步骤:This embodiment also provides a method for manufacturing a terahertz quantum cascade laser device structure. As shown in FIG. 5 , the method for manufacturing a terahertz quantum cascade laser device structure includes the following steps:
步骤一:在半绝缘GaAs衬底上生长缓冲层、n型重掺杂下接触层、有源区、n型重掺杂上接触层;Step 1: growing a buffer layer, a heavily n-type doped lower contact layer, an active region, and an n-type heavily doped upper contact layer on a semi-insulating GaAs substrate;
步骤二:第一次光刻,采用干法或湿法刻蚀工艺刻蚀脊波导,形成脊形波导结构及下电极支撑结构;Step 2: For the first photolithography, the ridge waveguide is etched by a dry or wet etching process to form a ridge waveguide structure and a lower electrode support structure;
步骤三:在所述脊型波导结构及所述下电极支撑结构上采用等离子体增强化学气相沉积法(PECVD)生长导热绝缘层,所述导热绝缘层的材料优选为硅,所述导热绝缘层的厚度为300nm;第二次光刻,并通过干法刻蚀工艺刻蚀所述导热绝缘层形成上电极窗口,在所述上电极窗口内溅射上电极金属,带胶剥离形成的上电极(即上层金属层),并覆盖所述脊型波导结构的侧壁;Step 3: growing a thermally conductive insulating layer on the ridge waveguide structure and the lower electrode supporting structure by plasma-enhanced chemical vapor deposition (PECVD), the material of the thermally conductive insulating layer is preferably silicon, and the thermally conductive insulating layer The thickness of the upper electrode is 300nm; the second photolithography, and the thermal insulating layer is etched by a dry etching process to form an upper electrode window, and the upper electrode metal is sputtered in the upper electrode window, and the upper electrode formed by stripping with glue (i.e. the upper metal layer), and cover the sidewall of the ridge waveguide structure;
步骤四:第三次光刻形成下电极窗口,在所述下电极窗口内电子束蒸发下电极金属,带胶剥离形成下电极(即下层金属层),退火形成欧姆接触;Step 4: Forming the lower electrode window by photolithography for the third time, evaporating the lower electrode metal by electron beam in the lower electrode window, peeling off the adhesive to form the lower electrode (ie, the lower metal layer), and annealing to form an ohmic contact;
步骤五:提供一支撑基片,第四次光刻,在所述支撑基片上对应于上下电极倒装焊触处开窗口,在所述开口内溅射生长金属,带胶剥离,形成电极引出金属层;Step 5: Provide a supporting substrate, the fourth photolithography, open a window on the supporting substrate corresponding to the flip-chip welding contacts of the upper and lower electrodes, grow metal by sputtering in the opening, peel off with glue, and form electrode leads metal layer;
步骤六:第五次光刻,在所述电极引出金属层处开窗口,电子束蒸发铟层,带胶剥离,用于倒装焊;Step 6: In the fifth photolithography, a window is opened at the metal layer where the electrode is drawn out, the indium layer is evaporated by an electron beam, and the tape is peeled off for flip-chip welding;
步骤七:减薄所述支撑基片与所述半绝缘GaAs衬底至一定厚度,并将所述支撑基片及形成于所述GaAs衬底上的结构解理成适当尺寸的小片,进行倒装焊封装,完成器件制作。Step 7: Thinning the supporting substrate and the semi-insulating GaAs substrate to a certain thickness, and cleaving the supporting substrate and the structure formed on the GaAs substrate into small pieces of appropriate size, and performing flip-chip welding Encapsulate and complete the device fabrication.
综上所述,本发明提出了一种太赫兹量子级联激光器器件结构及其制作方法,本发明的太赫兹量子级联激光器器件结构中通过在器件侧面淀积导热绝缘层并覆盖金属,导热绝缘层既起到钝化作用,保护器件,又可以将覆盖的金属与有源区绝缘。由于有源区量子阱结构的热导率是各向异性的,且热导率横向分量大于垂直方向的热导率分量,以往并未加以利用,在器件侧壁覆盖金属,加上中间的导热绝缘层,提供了器件横向的散热通道,较以往侧壁未覆盖金属的THz QCL散热能力更强。在支撑基片上制作电极引线,将器件倒装焊在支撑基片上,支撑基片采用硅等热导率高的材料,较正常封装器件的半绝缘GaAs衬底散热能力得到提高,可以将器件有源区产生的热量更快散到支撑基片下面的热沉上。在焊线封装时,由于采用倒装焊后,支撑基片电极引线面积更大,电极可以更多地焊接金线,利用焊接在热沉上外部导热陶瓷片也可以将器件产生热量更好地散出。本发明的太赫兹量子级联激光器器件结构制作方法可由标准半导体工艺制作,适于工业量产。In summary, the present invention proposes a terahertz quantum cascade laser device structure and its manufacturing method. In the terahertz quantum cascade laser device structure of the present invention, a thermally conductive insulating layer is deposited on the side of the device and covered with metal to conduct heat. The insulating layer not only plays a passivation role, protects the device, but also insulates the covered metal from the active area. Since the thermal conductivity of the quantum well structure in the active region is anisotropic, and the lateral component of thermal conductivity is greater than the vertical component of thermal conductivity, it has not been used in the past. The sidewall of the device is covered with metal, and the thermal conductivity in the middle The insulating layer provides a lateral heat dissipation channel for the device, and has a stronger heat dissipation capability than the previous THz QCL whose side walls are not covered with metal. Make electrode leads on the support substrate, and flip-chip solder the device on the support substrate. The support substrate is made of silicon and other materials with high thermal conductivity, which improves the heat dissipation capacity of the semi-insulating GaAs substrate of the normal packaging device, and can effectively protect the device. The heat generated in the source area is dissipated more quickly to the heat sink below the supporting substrate. In the wire bonding package, due to the use of flip-chip welding, the electrode lead area of the supporting substrate is larger, and the electrodes can be welded with more gold wires. The external heat-conducting ceramic sheet welded on the heat sink can also make the device generate heat better. shed. The manufacturing method of the terahertz quantum cascade laser device structure of the present invention can be manufactured by a standard semiconductor process, and is suitable for industrial mass production.
上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。The above-mentioned embodiments only illustrate the principles and effects of the present invention, but are not intended to limit the present invention. Anyone skilled in the art can modify or change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or changes made by those skilled in the art without departing from the spirit and technical ideas disclosed in the present invention should still be covered by the claims of the present invention.
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