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CN104356496A - 一种抗静电和抗湿滑的橡塑发泡鞋底及其制备方法 - Google Patents

一种抗静电和抗湿滑的橡塑发泡鞋底及其制备方法 Download PDF

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CN104356496A
CN104356496A CN201410639415.3A CN201410639415A CN104356496A CN 104356496 A CN104356496 A CN 104356496A CN 201410639415 A CN201410639415 A CN 201410639415A CN 104356496 A CN104356496 A CN 104356496A
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卢鑫
丁思博
罗显发
郭彩莲
张先顺
周小兰
林荷香
林江
金校红
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Maotai Fujian New Material Technology Co ltd
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Abstract

本发明涉及有机高分子化合物技术领域,提供一种抗静电和抗湿滑的橡塑发泡鞋底及其制备方法,所述抗静电和抗湿滑的橡塑发泡鞋底,由下述组分按重量份原料制得:聚烯烃弹性体POE、丁腈橡胶、发泡剂、交联剂、氧化锌、硬脂酸锌、硬脂酸、耐磨剂、橡胶抗静电剂、纳米碳酸钙,经过密炼、开炼、造粒,再经一次射出成型,得到抗静电和抗湿滑的橡塑发泡鞋底,所述抗静电和抗湿滑的橡塑发泡鞋底的电阻率小于1兆欧,可以永久性的防静电,不受潮湿的坏境影响,并且具有比重小、高抗湿滑性能,特别适合在鞋底等方面应用。

Description

一种抗静电和抗湿滑的橡塑发泡鞋底及其制备方法
技术领域
 本发明属于有机高分子化合物技术领域,特别涉及一种抗静电和抗湿滑的橡塑发泡鞋底的制备方法。
背景技术
高分子材料具有绝缘性,当其表面受到摩擦时,处于静止状态的电荷积聚而形成静电。当电荷积累到一定数量时,会造成电击。为了保障人身安全,在这种场合必须穿着能清除静电的抗静电鞋,尤其是医院手术室、高级试验室等重要工作场所。
目前国内一线品牌的成品鞋大都是采用橡胶鞋底,但近年来,随着人们生活水平的提高,人们对橡胶鞋底的一些特殊要求就凸显出来,橡胶鞋底比重大,穿着笨重,只能满足普通工作场所的要求,无法同时符合质轻、抗静电、抗湿滑性能等要求。
发明内容
本发明的目的在于提供一种制得具有电阻率小于1兆欧、永久性防静电、比重小、高抗湿滑性能等特点的抗静电和抗湿滑橡塑发泡鞋底,以及前述抗静电和抗湿滑橡塑发泡鞋底的制备方法。
为实现上述目的,本发明采取的解决方案为:一种抗静电和抗湿滑的橡塑发泡鞋底,由以下原料组成制得:聚烯烃弹性体POE、丁腈橡胶、发泡剂、交联剂、氧化锌、硬脂酸锌、硬脂酸、耐磨剂、橡胶抗静电剂、纳米碳酸钙。
进一步的是,各原料的重量份如下:
聚烯烃弹性体POE                  50份
丁腈橡胶                         25 - 45 份        
发泡剂                           3.6 - 5 份    
交联剂                           1.2 - 1.5份    
氧化锌                           1.5 - 2 份    
硬脂酸锌                         1.2 – 1.5 份     
硬脂酸                           1.3– 1.5 份     
耐磨剂                           1 - 3 份   
橡胶抗静电剂                     3 - 10 份
    纳米碳酸钙                       5- 12 份。     
进一步优选的,各组分按下列重量份配置:
聚烯烃弹性体POE                  50份
丁腈橡胶                         30 - 35 份        
发泡剂                           4.2 - 4.5 份    
交联剂                           1.4 - 1.5份    
氧化锌                           1.7 份    
硬脂酸锌                         1.4 份     
硬脂酸                           1.5 份     
耐磨剂                           1.5 - 2 份  
橡胶抗静电剂                     4 - 6 份
纳米碳酸钙                       8- 10 份。  
进一步的是:所述聚烯烃弹性体POE的熔融温度不低于72度。
进一步的是:所述丁腈橡胶的丙烯腈含量高于32%。
进一步的是:所述发泡剂是发泡剂、微胶囊发泡剂的混合物。
进一步的是:所述交联剂至少包括DCP交联剂、BIBP交联剂中的一种。
进一步的是:所述橡胶抗静电剂至少包括聚醚-聚酰胺共聚物抗静电剂、离子键聚合物抗静电剂、聚氧乙烯醚类抗静电剂中的一种。
一种制备前述抗静电和抗湿滑橡塑发泡鞋底的制备方法:先将除了交联剂以及发泡剂之外的其他原料混合进行密炼,调整密炼温度控制为 98-101℃,保持 4-6min,然后加入架桥剂以及发泡剂,继续密炼升温,出料温度为117-120℃,密炼结束后进行开炼、造粒,得到抗静电和抗湿滑的橡塑发泡粒子,再经过射出机台一次射出成型,控制成型温度为180-185℃,时间为350-500秒,得到抗静电和抗湿滑的橡塑发泡鞋底。
通过采取前述技术方案,本发明具有如下有益效果:
1,本发明抗静电和抗湿滑的橡塑发泡鞋底的抗静电效果显著,可以永久性的防静电,不受潮湿的坏境影响,可以生产各种颜色的抗静电和抗湿滑的橡塑发泡鞋底,而且不使用有害表面活性剂,提高鞋底的环保性能。
2,本发明在提高材料抗静电性能的同时,保留了材料的质轻、高抗湿滑性能、尺寸稳定性好、综合力学性能好等特点,特别适合在鞋底等方面应用,有很好的市场前景。
具体实施方式
现结合具体实施例对本发明进一步说明。
实施例1:
本实施例中, 抗静电和抗湿滑的橡塑发泡鞋底由以下组分按重量份组成:
聚烯烃弹性体POE 0203             50份
丁腈橡胶NBR4975                  35 份        
发泡剂AC                         2.1 份
微胶囊发泡剂                     2.1 份
交联剂BIBP                       1.5 份    
氧化锌                           1.7 份    
硬脂酸锌                         1.4 份     
硬脂酸                           1.5 份     
耐磨剂FY-500                     1.5 份  
橡胶抗静电剂E-XCB                6 份
纳米碳酸钙                       8 份。
步骤1:先将除了交联剂以及发泡剂之外的其他原料混合进行密炼,调整密炼温度控制为98℃,保持 6min,然后加入交联剂以及发泡剂,继续密炼升温,出料温度为119℃,密炼结束后进行开炼、造粒,得到抗静电和抗湿滑的橡塑发泡粒子;
步骤2:抗静电和抗湿滑的橡塑发泡粒子再经过射出机台一次射出成型,控制成型温度为180℃,时间为480秒,得到抗静电和抗湿滑的橡塑发泡鞋底。
上述制备得到的抗静电和抗湿滑橡塑发泡鞋底,密度0.41g/cm3,邵氏硬度61,DIN耐磨136 mm3,尺寸收缩0.9%,拉伸强度3.8MPa,撕裂强度16.7N/mm,动态止滑系数平滑干式1.11湿式0.83,静态止滑系数干式0.78湿式0.64,电阻率0.26MΩ。
实施例2:
本实施例中,一种抗静电和抗湿滑的橡塑发泡鞋底的制备方法与实施例1中的制备方法相同,所不同的是:
丁腈橡胶NBR 1401 40份、橡胶抗静电剂E-XCB 8份、纳米碳酸钙12份。
上述制备得到的抗静电和抗湿滑橡塑发泡鞋底,密度0.43g/cm3,邵氏硬度64,DIN耐磨172 mm3,尺寸收缩0.8%,拉伸强度3.7MPa,撕裂强度19.3N/mm,动态止滑系数平滑干式0.78湿式0.62,静态止滑系数干式0.60湿式0.51,电阻率1.5MΩ。
实施例3:
本实施例中,一种抗静电和抗湿滑的橡塑发泡鞋底的制备方法与实施例1中的制备方法相同,所不同的是:
POE 8450 50份、丁腈橡胶NBR DN003 25份、发泡剂AC 1.8份、微胶囊发泡剂1.8份、交联剂BIBP 1.2份、耐磨剂FY-500 3份、橡胶抗静电剂E-XCB 6份、聚醚-聚酰胺共聚物抗静电剂4份;
步骤1中的密炼温度100度、出料温度117度;步骤2中成型温度181度时间360秒。
上述制备得到的抗静电和抗湿滑橡塑发泡鞋底,密度0.43g/cm3,邵氏硬度67,DIN耐磨113 mm3,尺寸收缩1.1%,拉伸强度3.3MPa,撕裂强度13.8N/mm,动态止滑系数平滑干式0.61湿式0.50,静态止滑系数干式0.56湿式0.47,电阻率0.45MΩ。
实施例4:
本实施例中,一种抗静电和抗湿滑的橡塑发泡鞋底的制备方法与实施例1中的制备方法相同,所不同的是:
 POE 8003 50份、丁腈橡胶NBR 3250 45份、发泡剂AC 2.5份、微胶囊发泡剂2.5份、耐磨剂AG-209 1份、橡胶抗静电剂E-XCB 3份、纳米碳酸钙5份;
步骤1中的密炼温度101度、出料温度120度;步骤2中的成型温度185度,时间500秒。
上述制备得到的抗静电和抗湿滑橡塑发泡鞋底,密度0.39g/cm3,邵氏硬度60,DIN耐磨147 mm3,尺寸收缩1.8%,拉伸强度4.2MPa,撕裂强度20.1N/mm,动态止滑系数平滑干式1.12湿式0.85,静态止滑系数干式0.80湿式0.68,电阻率7.9MΩ。
将上述实施例1 ~ 4 的数据整理后,得到如下表1(注:邵氏硬度A按照ISO7619:1997测试,DIN耐磨按照TM174:1994测试,尺寸收缩按照ISO 20873:2001测试,拉伸强度按照GB/T 10654-2001测试,撕裂强度按照GB/T 10808-2006测试,动态止滑系数按照TM144:2011测试,静态止滑系数按照F1677:2005测试,电阻率按照ISO 20344:2011测试):
实施例 1 2 3 4
密度 (g/cm3) 0.41 0.43 0.43 0.39
邵氏硬度 61 64 67 60
DIN耐磨 (mm3) 136 172 113 147
尺寸收缩 (%) 0.9 0.8 1.1 1.8
拉伸强度(MPa) 3.8 3.7 3.3 4.2
撕裂强度(N/mm) 16.7 19.3 13.8 20.1
动态止滑系数(平滑干式) 1.11 0.78 0.61 1.12
动态止滑系数(平滑湿式) 0.83 0.62 0.50 0.85
静态止滑系数(干式) 0.78 0.60 0.56 0.80
静态止滑系数(湿式) 0.64 0.51 0.47 0.68
电阻率(MΩ ) 0.26 1.5 0.45 7.9
表1 :实施例1~4制备的抗静电和抗湿滑橡塑发泡鞋底的性能参数对照表。
综上所述,按照本发明的抗静电和抗湿滑橡塑发泡鞋底的制备方法,制得的抗静电和抗湿滑的橡塑发泡鞋底获得电阻率小于1兆欧、永久性防静电、高抗湿滑性能等特点,并且具有优良尺寸稳定性好、综合力学性能好等特点,特别适合在鞋底等方面应用。
以上所记载,仅为利用本创作技术内容的实施例,任何熟悉本项技艺者运用本创作所做的修饰、变化,皆属本创作主张的专利范围,而不限于实施例所揭示者。

Claims (9)

1.一种抗静电和抗湿滑的橡塑发泡鞋底,其特征在于:由以下原料组成制得:聚烯烃弹性体POE、丁腈橡胶、发泡剂、交联剂、氧化锌、硬脂酸锌、硬脂酸、耐磨剂、橡胶抗静电剂、纳米碳酸钙。
2.根据权利要求1所述的抗静电和抗湿滑的橡塑发泡鞋底,其特征在于:各原料的重量份如下:
聚烯烃弹性体POE                  50份
丁腈橡胶                         25 - 45 份        
发泡剂                           3.6 - 5 份    
交联剂                           1.2 - 1.5份    
氧化锌                           1.5 - 2 份    
硬脂酸锌                         1.2 – 1.5 份     
硬脂酸                           1.3– 1.5 份     
耐磨剂                           1 - 3 份   
橡胶抗静电剂                     3 - 10 份
纳米碳酸钙                       5- 12 份。
3.根据权利要求2所述的抗静电和抗湿滑的橡塑发泡鞋底,其特征在于:由以下组分按下列重量份原料制备而成:
聚烯烃弹性体POE                  50份
丁腈橡胶                         30 - 35 份        
发泡剂                           4.2 - 4.5 份    
交联剂                           1.4 - 1.5份    
氧化锌                           1.7 份    
硬脂酸锌                         1.4 份     
硬脂酸                           1.5 份     
耐磨剂                           1.5 - 2 份  
橡胶抗静电剂                     4 - 6 份
纳米碳酸钙                       8- 10 份。
4.根据权利要求1或2所述抗静电和抗湿滑的橡塑发泡鞋底,其特征在于:所述聚烯烃弹性体POE的熔融温度不低于72度;所述丁腈橡胶的丙烯腈含量高于32%。
5.根据权利要求1或2所述抗静电和抗湿滑的橡塑发泡鞋底,其特征在于:所述发泡剂是AC发泡剂、微胶囊发泡剂的混合物;所述交联剂至少包括交联剂DCP、交联剂BIBP中的一种。
6.根据权利要求1或2所述抗静电和抗湿滑的橡塑发泡鞋底的制备方法,其特征在于:所述橡胶抗静电剂至少包括聚醚-聚酰胺共聚物抗静电剂、离子键聚合物抗静电剂、聚氧乙烯醚类抗静电剂中的一种。
7.一种制备权利要求1-6任一所述抗静电和抗湿滑的橡塑发泡鞋底的制备方法,其特征在于:包括如下步骤,
步骤1:制作抗静电和抗湿滑的橡塑发泡粒子,所述橡塑发泡粒子由以下原料组成制得:聚烯烃弹性体POE、丁腈橡胶、发泡剂、交联剂、氧化锌、硬脂酸锌、硬脂酸、耐磨剂、橡胶抗静电剂、纳米碳酸钙;
步骤2:将步骤1所得的抗静电和抗湿滑的橡塑发泡粒子经射出机台一次射出成型,制得所述抗静电和抗湿滑的橡塑发泡鞋底。
8.根据权利要求7所述抗静电和抗湿滑的橡塑发泡鞋底的制备方法,其特征在于:步骤1中是先将除了交联剂以及发泡剂之外的其他原料混合进行密炼,调整密炼温度控制为98-101℃,保持4-6min,然后加入架桥剂以及发泡剂,继续密炼升温,出料温度为117-120℃,密炼结束后进行开炼、造粒,得到抗静电和抗湿滑的橡塑发泡粒子。
9.根据权利要求7所述抗静电和抗湿滑的橡塑发泡鞋底的制备方法,其特征在于:步骤2中射出机台的成型温度为180-185℃,时间为350-500秒。
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EP3190149A1 (en) * 2016-01-05 2017-07-12 Nexans Microcellular foamed nanocomposite and preparation method thereof
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CN105254939A (zh) * 2015-11-14 2016-01-20 际华三五一五皮革皮鞋有限公司 双密度固特异大底内部定时定量发泡橡胶及其制备方法
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CN111225579A (zh) * 2017-10-13 2020-06-02 株式会社爱世克私 外底和鞋
CN111225579B (zh) * 2017-10-13 2021-12-07 株式会社爱世克私 外底和鞋
CN111057279A (zh) * 2019-12-31 2020-04-24 东莞市特谱峰实业有限公司 一种鞋底用的减震橡塑发泡材料及其制备工艺

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