CN104277620A - Environment-friendly wall coating - Google Patents
Environment-friendly wall coating Download PDFInfo
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- CN104277620A CN104277620A CN201410449251.8A CN201410449251A CN104277620A CN 104277620 A CN104277620 A CN 104277620A CN 201410449251 A CN201410449251 A CN 201410449251A CN 104277620 A CN104277620 A CN 104277620A
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- deionized water
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- 239000011248 coating agent Substances 0.000 title claims abstract description 25
- 238000000576 coating method Methods 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 12
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 10
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004203 carnauba wax Substances 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000004693 Polybenzimidazole Substances 0.000 claims abstract description 4
- 229960000892 attapulgite Drugs 0.000 claims abstract description 4
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229960002401 calcium lactate Drugs 0.000 claims abstract description 4
- 235000011086 calcium lactate Nutrition 0.000 claims abstract description 4
- 239000001527 calcium lactate Substances 0.000 claims abstract description 4
- 239000010433 feldspar Substances 0.000 claims abstract description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 4
- 229920002480 polybenzimidazole Polymers 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- 230000007613 environmental effect Effects 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 239000004160 Ammonium persulphate Substances 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 claims description 7
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 claims description 7
- 235000011124 aluminium ammonium sulphate Nutrition 0.000 claims description 7
- LCQXXBOSCBRNNT-UHFFFAOYSA-K ammonium aluminium sulfate Chemical compound [NH4+].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LCQXXBOSCBRNNT-UHFFFAOYSA-K 0.000 claims description 7
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 7
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 7
- 229940117972 triolein Drugs 0.000 claims description 7
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 claims description 6
- 239000004159 Potassium persulphate Substances 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 235000019394 potassium persulphate Nutrition 0.000 claims description 6
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 6
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 4
- 229920000126 latex Polymers 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 244000057114 Sapium sebiferum Species 0.000 claims description 3
- 235000005128 Sapium sebiferum Nutrition 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- 230000001680 brushing effect Effects 0.000 abstract description 2
- 230000002147 killing effect Effects 0.000 abstract description 2
- 244000005700 microbiome Species 0.000 abstract description 2
- 239000003440 toxic substance Substances 0.000 abstract description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 241000526900 Camellia oleifera Species 0.000 abstract 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- -1 polytetrafluoroethylene Polymers 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 239000000473 propyl gallate Substances 0.000 abstract 1
- 229940075579 propyl gallate Drugs 0.000 abstract 1
- 235000010388 propyl gallate Nutrition 0.000 abstract 1
- 229950000975 salicylanilide Drugs 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 9
- 238000005034 decoration Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an environment-friendly wall coating which is prepared from the following raw materials in parts by weight: 2-3 parts of polypropylene oxide glycol, 1-2 parts of propylgallate, 0.8-1 part of seed oil of camellia oleifera abel, 0.7-1 part of n-salicylanilide, 1-2 parts of calcium lactate, 2-3 parts of palm wax, 3-4 parts of polypropylene glycol adipate, 2-3 parts of polytetrafluoroethylene, 0.7-2 parts of polybenzimidazole, 5-7 parts of attapulgite, 10-13 parts of feldspar powder, 100-140 parts of butyl acrylate, 160-200 parts of vinyl acetate, 4-6 parts of polyvinyl alcohol, 0.5-2 parts of potassium persulfate, 500-700 parts of deionized water, 2-4 parts of sodium dodecyl sulfate and 4-6 parts of a bonding auxiliary. The coating disclosed by the invention is good in environment-friendliness and free of volatile toxic substances, can be widely applied to brushing indoor and outdoor exterior walls, further has killing and inhibiting effects on some microorganisms and is strong in weather resistance and good in bonding strength and resistance.
Description
?
Technical field
The present invention relates generally to paint field, particularly relates to a kind of environmental protection wall surface coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of environmental protection wall surface coating.
The present invention is achieved by the following technical solutions:
A kind of environmental protection wall surface coating, is characterized in that what it was made up of the raw material of following weight parts:
Polyoxypropyleneglycol 2-3, Tenox PG 1-2, Chinese vegetable tallow 0.8-1, n-Salicylanlide 0.7-1, calcium lactate 1-2, palm wax 2-3, hexanodioic acid propanediol polyester 3-4, tetrafluoroethylene 2-3, polybenzimidazole 0.7-2, attapulgite 5-7, feldspar in powder 10-13, butyl acrylate 100-140, vinyl acetate 160-200, polyvinyl alcohol 4-6, Potassium Persulphate 0.5-2, deionized water 500-700, sodium laurylsulfonate 2-4, adhesive aid 4-6;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 30-35, methyl methacrylate 2-4, exsiccated ammonium alum 1-2, emulsifier op-10 0.5-1, ammonium persulphate 0.7-1, Triethylene glycol dimethacrylate 2-3, triolein 1-2, titania powder 2-4, deionized water 10-14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, 3-4 minute is uniformly mixed at 70-75 DEG C, add 40-50%, the ammonium persulphate of above-mentioned deionized water weight, 100-150 rev/min of dispersed with stirring 10-13 minute, obtains dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 60-70 DEG C, are uniformly mixed 3-5 minute, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
A preparation method for environmental protection wall surface coating, comprises the following steps:
(1) mixed by the 10-15% of Potassium Persulphate with above-mentioned deionized water weight, stirring and dissolving, obtains initiator solution;
(2) by sodium laurylsulfonate, polyoxypropyleneglycol, Tenox PG, polyvinyl alcohol mixing, add the 70-80% of residue deionized water weight, insulated and stirred 30-40 minute at 80-90 DEG C, is cooled to normal temperature, obtains pre-emulsion;
(3) the 40-50% mixing of the 30-40% of aforesaid propylene acid butyl ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add above-mentioned initiator solution, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, add palm wax, hexanodioic acid propanediol polyester, insulated and stirred 20-30 minute at 70-80 DEG C, obtains mix monomer;
(5) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 90-120 minute, after dropwising, at 80-90 DEG C, is incubated 50-60 minute, cooling, filters discharging with 200-250 eye mesh screen;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described environmental protection wall surface coating.
Advantage of the present invention is:
The coating feature of environmental protection of the present invention is good, not containing volatile toxic substance, can be widely used in indoor and outdoor body of wall brushing, and for the effect that some microorganisms also have killing and suppress, durability of coating is strong, cohesive strength, better resistance.The titania powder added in adhesive aid of the present invention can improve resistivity against fire and surface resistive, methyl methacrylate, exsiccated ammonium alum, emulsifier op-10, triolein mix with organosilicon crylic acid latex and effectively can improve cohesive strength, ammonium persulphate can promote the consistency between each raw material, improves the surface stability of finished product.
Embodiment
Embodiment 1
A kind of environmental protection wall surface coating, is characterized in that what it was made up of the raw material of following weight parts:
Polyoxypropyleneglycol 3, Tenox PG 2, Chinese vegetable tallow 0.8, n-Salicylanlide 0.7-, calcium lactate 2, palm wax 2, hexanodioic acid propanediol polyester 4, tetrafluoroethylene 3, polybenzimidazole 0.7, attapulgite 7, feldspar in powder 13, butyl acrylate 140, vinyl acetate 200, polyvinyl alcohol 4, Potassium Persulphate 0.5, deionized water 500, sodium laurylsulfonate 2-4, adhesive aid 4;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 35, methyl methacrylate 2, exsiccated ammonium alum 2, emulsifier op-10 0.5, ammonium persulphate 0.7, Triethylene glycol dimethacrylate 2, triolein 2, titania powder 2, deionized water 14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, at 75 DEG C, be uniformly mixed 4 minutes, add 40-50%, the ammonium persulphate of above-mentioned deionized water weight, 150 revs/min of dispersed with stirring 13 minutes, obtain dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 70 DEG C, are uniformly mixed 3 minutes, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
A preparation method for environmental protection wall surface coating, is characterized in that comprising the following steps:
(1) mixed with 15% of above-mentioned deionized water weight by Potassium Persulphate, stirring and dissolving, obtains initiator solution;
(2) by sodium laurylsulfonate, polyoxypropyleneglycol, Tenox PG, polyvinyl alcohol mixing, add 80% of residue deionized water weight, at 90 DEG C, insulated and stirred 40 minutes, is cooled to normal temperature, obtains pre-emulsion;
(3) get 40% of aforesaid propylene acid butyl ester weight, 50% mixing of vinyl acetate weight, add above-mentioned pre-emulsion, at 65 DEG C, be uniformly mixed 35 minutes, raised temperature is 75 DEG C, adds above-mentioned initiator solution, treats that emulsion is blue phase, be incubated 70 minutes, obtain seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, add palm wax, hexanodioic acid propanediol polyester, at 80 DEG C, insulated and stirred 30 minutes, obtains mix monomer;
(5) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 120 minutes, after dropwising, at 90 DEG C, be incubated 60 minutes, and cooling filters discharging with 250 eye mesh screens;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 30 minutes, obtain described environmental protection wall surface coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. an environmental protection wall surface coating, is characterized in that what it was made up of the raw material of following weight parts:
Polyoxypropyleneglycol 2-3, Tenox PG 1-2, Chinese vegetable tallow 0.8-1, n-Salicylanlide 0.7-1, calcium lactate 1-2, palm wax 2-3, hexanodioic acid propanediol polyester 3-4, tetrafluoroethylene 2-3, polybenzimidazole 0.7-2, attapulgite 5-7, feldspar in powder 10-13, butyl acrylate 100-140, vinyl acetate 160-200, polyvinyl alcohol 4-6, Potassium Persulphate 0.5-2, deionized water 500-700, sodium laurylsulfonate 2-4, adhesive aid 4-6;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 30-35, methyl methacrylate 2-4, exsiccated ammonium alum 1-2, emulsifier op-10 0.5-1, ammonium persulphate 0.7-1, Triethylene glycol dimethacrylate 2-3, triolein 1-2, titania powder 2-4, deionized water 10-14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, 3-4 minute is uniformly mixed at 70-75 DEG C, add 40-50%, the ammonium persulphate of above-mentioned deionized water weight, 100-150 rev/min of dispersed with stirring 10-13 minute, obtains dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 60-70 DEG C, are uniformly mixed 3-5 minute, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
2. a preparation method for environmental protection wall surface coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) mixed by the 10-15% of Potassium Persulphate with above-mentioned deionized water weight, stirring and dissolving, obtains initiator solution;
(2) by sodium laurylsulfonate, polyoxypropyleneglycol, Tenox PG, polyvinyl alcohol mixing, add the 70-80% of residue deionized water weight, insulated and stirred 30-40 minute at 80-90 DEG C, is cooled to normal temperature, obtains pre-emulsion;
(3) the 40-50% mixing of the 30-40% of aforesaid propylene acid butyl ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add above-mentioned initiator solution, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, add palm wax, hexanodioic acid propanediol polyester, insulated and stirred 20-30 minute at 70-80 DEG C, obtains mix monomer;
(5) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 90-120 minute, after dropwising, at 80-90 DEG C, is incubated 50-60 minute, cooling, filters discharging with 200-250 eye mesh screen;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described environmental protection wall surface coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410449251.8A CN104277620A (en) | 2014-09-04 | 2014-09-04 | Environment-friendly wall coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410449251.8A CN104277620A (en) | 2014-09-04 | 2014-09-04 | Environment-friendly wall coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104277620A true CN104277620A (en) | 2015-01-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410449251.8A Pending CN104277620A (en) | 2014-09-04 | 2014-09-04 | Environment-friendly wall coating |
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| Country | Link |
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| CN (1) | CN104277620A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366713A (en) * | 2016-08-26 | 2017-02-01 | 安徽钰锦生态木材料有限公司 | Delicate-fragrant-type environment-friendly wall surface coating |
| CN110379292A (en) * | 2019-07-13 | 2019-10-25 | 广州彩邦印刷有限公司 | High temperature resistant labels |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1454949A (en) * | 2003-05-19 | 2003-11-12 | 复旦大学 | Self-cleaning external wall organic coating for building and preparing method thereof |
| CN1696219A (en) * | 2004-05-11 | 2005-11-16 | 张海波 | Environmental protection type Nano Coating |
| CN103965716A (en) * | 2014-02-28 | 2014-08-06 | 北京东方雨虹防水技术股份有限公司 | Water-based quick-drying acrylic acid protective coating and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1454949A (en) * | 2003-05-19 | 2003-11-12 | 复旦大学 | Self-cleaning external wall organic coating for building and preparing method thereof |
| CN1696219A (en) * | 2004-05-11 | 2005-11-16 | 张海波 | Environmental protection type Nano Coating |
| CN103965716A (en) * | 2014-02-28 | 2014-08-06 | 北京东方雨虹防水技术股份有限公司 | Water-based quick-drying acrylic acid protective coating and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366713A (en) * | 2016-08-26 | 2017-02-01 | 安徽钰锦生态木材料有限公司 | Delicate-fragrant-type environment-friendly wall surface coating |
| CN110379292A (en) * | 2019-07-13 | 2019-10-25 | 广州彩邦印刷有限公司 | High temperature resistant labels |
| CN110379292B (en) * | 2019-07-13 | 2021-06-25 | 广州彩邦印刷有限公司 | High temperature resistant label |
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Application publication date: 20150114 |
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