CN104263112A - Fluorine-containing styrene-acrylic coating - Google Patents
Fluorine-containing styrene-acrylic coating Download PDFInfo
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- CN104263112A CN104263112A CN201410451880.4A CN201410451880A CN104263112A CN 104263112 A CN104263112 A CN 104263112A CN 201410451880 A CN201410451880 A CN 201410451880A CN 104263112 A CN104263112 A CN 104263112A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a fluorine-containing styrene-acrylic coating. The fluorine-containing styrene-acrylic coating comprises the following raw materials in parts by weight: 6-7 parts of perfluoroalkyl ethyl acrylate, 0.7-2 parts of oregano oil, 1-2 parts of tea saponin, 0.6-1 part of tetrabutyl titanate, 1-3 parts of dimethylaminopropylamine, 2-3 parts of decabromodiphenyl ether, 1-2 parts of sodium fluorosilicate, 2-3 parts of 1-methylpentanol, 2-4 parts of stalactite powder, 10-14 parts of light calcium carbonate, 2-4 parts of isooctyl acrylate, 0.5-1 part of tetramethylthiourea, 150-200 parts of styrene, 500-600 parts of deionized water, 150-200 parts of butyl acrylate, 3-6 parts of ammonium persulfate, 6-10 parts of polyethylene glycol octylphenol ether and 4-5 parts of bonding additives. By introducing a fluorine-containing group into the coating disclosed by the invention, the fluorine-containing group can be positioned on the surface of a coated film in a film-forming process, so that the water resistance of the coated film can be significantly improved. The coating disclosed by the invention is safe, high in surface strength and good in resistance and has no toxic and side effects.
Description
Technical field
The present invention relates generally to paint field, particularly relates to a kind of fluorine-containing styrene-acrylic coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of fluorine-containing styrene-acrylic coating.
The present invention is achieved by the following technical solutions:
A kind of fluorine-containing styrene-acrylic coating, is characterized in that what it was made up of the raw material of following weight parts:
Perfluor alkyl ethyl acrylate 6-7, wild marjoram oil 0.7-2, tea saponin 1-2, tetrabutyl titanate 0.6-1, dimethylaminopropylamine 1-3, decabromodiphenyl oxide 2-3, Sodium Silicofluoride 1-2,1-methyl amyl alcohol 2-3, Stalactitum powder 2-4, light calcium carbonate 10-14, Isooctyl acrylate monomer 2-4, tetramethyl thiourea 0.5-1, vinylbenzene 150-200, deionized water 500-600, butyl acrylate 150-200, ammonium persulphate 3-6, Triton X-100 6-10, adhesive aid 4-5;
Described adhesive aid is made up of each raw material of following weight parts:
Alumina gel 20-30, exsiccated ammonium alum 1-3, lanolin 1-2, polyethylene glycol dimethacrylate 0.6-1, dehydrated alcohol 3-4, Isooctyl acrylate monomer 2-4, Potassium Persulphate 2-3, emulsifier op-10 0.5-1, Camphorwood micro mist 2-4, deionized water 15-20;
Dehydrated alcohol is heated to 70-75 DEG C, adds lanolin, stir, obtain alcohol lipoprotein solution;
Join in Alumina gel by Camphorwood micro mist, add polyethylene glycol dimethacrylate, raised temperature is 55-60 DEG C, 100-200 rev/min of dispersed with stirring 3-5 minute, obtains dispersion liquid;
Potassium Persulphate is mixed with Isooctyl acrylate monomer, 2-3 minute is uniformly mixed at 60-70 DEG C, add dispersion liquid, be stirred to normal temperature, add above-mentioned alcohol lipoprotein solution, 60-100 rev/min is uniformly mixed 5-10 minute, adds each raw material of residue, 200-400 rev/min of dispersed with stirring 3-5 minute, obtains described adhesive aid.
A preparation method for fluorine-containing styrene-acrylic coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) get above-mentioned vinylbenzene, butyl acrylate mixing, obtain monomer a;
(2) by Triton X-100, ammonium persulphate mixing, add the 30-40% of above-mentioned deionized water weight, at 50-70 DEG C of insulated and stirred 15-20 minute, be cooled to normal temperature, obtain pre-emulsion;
(3) get the above-mentioned 70-80% of monomer a weight, the 40-50% of pre-emulsion weight, mixing, adds 1-methyl amyl alcohol, tea saponin, insulated and stirred 10-20 minute at 75-80 DEG C, obtains premix monomer;
(4) by remaining monomer a, the mixing of remaining pre-emulsion, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, regulate pH value to 7-8, filter with 200-250 order filter sieve;
(5) material above-mentioned steps (4) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described fluorine-containing styrene-acrylic coating.
Advantage of the present invention is:
Fluoro-containing group introduced by coating of the present invention, and be positioned in film process on the surface of film, can improve the water tolerance of film significantly, coating safe without toxic side effect of the present invention, surface strength is high, better resistance.The Camphorwood micro mist added in adhesive aid of the present invention has good resistance to abrasion, Heat stability is good chemical stability, Alumina gel mixes with exsiccated ammonium alum, lanolin, Isooctyl acrylate monomer, Potassium Persulphate, there is excellent adhesive property, coatingsurface resistance and stability can be strengthened.
Embodiment
Embodiment 1
A kind of fluorine-containing styrene-acrylic coating, is characterized in that what it was made up of the raw material of following weight parts:
Perfluor alkyl ethyl acrylate 6, wild marjoram oil 0.7, tea saponin 1, tetrabutyl titanate 0.6, dimethylaminopropylamine 3, decabromodiphenyl oxide 3, Sodium Silicofluoride 1,1-methyl amyl alcohol 2, Stalactitum powder 2, light calcium carbonate 14, Isooctyl acrylate monomer 4, tetramethyl thiourea 0.5, vinylbenzene 200, deionized water 600, butyl acrylate 200, ammonium persulphate 3, Triton X-100 10, adhesive aid 4;
Described adhesive aid is made up of each raw material of following weight parts:
Alumina gel 30, exsiccated ammonium alum 3, lanolin 2, polyethylene glycol dimethacrylate 0.6, dehydrated alcohol 4, Isooctyl acrylate monomer 4, Potassium Persulphate 3, emulsifier op-10 0.5, Camphorwood micro mist 4, deionized water 20;
Dehydrated alcohol is heated to 75 DEG C, adds lanolin, stir, obtain alcohol lipoprotein solution;
Join in Alumina gel by Camphorwood micro mist, add polyethylene glycol dimethacrylate, raised temperature is 60 DEG C, and 100-200 rev/min of dispersed with stirring 5 minutes, obtains dispersion liquid;
Potassium Persulphate is mixed with Isooctyl acrylate monomer, at 70 DEG C, is uniformly mixed 3 minutes, adds dispersion liquid, be stirred to normal temperature, add above-mentioned alcohol lipoprotein solution, 100 revs/min are uniformly mixed 10 minutes, add each raw material of residue, 400 revs/min of dispersed with stirring 5 minutes, obtain described adhesive aid.
A preparation method for fluorine-containing styrene-acrylic coating, is characterized in that comprising the following steps:
(1) get above-mentioned vinylbenzene, butyl acrylate mixing, obtain monomer a;
(2) by Triton X-100, ammonium persulphate mixing, add 40% of above-mentioned deionized water weight, 70 DEG C of insulated and stirred 20 minutes, be cooled to normal temperature, obtain pre-emulsion;
(3) get above-mentioned 80% of monomer a weight, 50% of pre-emulsion weight, mixing, add 1-methyl amyl alcohol, tea saponin, at 75-80 DEG C, insulated and stirred 20 minutes, obtains premix monomer;
(4) by remaining monomer a, the mixing of remaining pre-emulsion, insulated and stirred 50 minutes at 90 DEG C, drips above-mentioned premix monomer, time for adding is 3 hours, is incubated 3 hours after dropwising at 85 DEG C, reduces temperature to 50 DEG C, regulate pH value to 8, filter with 250 order filter sieve;
(5) material above-mentioned steps (4) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 30 minutes, obtain described fluorine-containing styrene-acrylic coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. a fluorine-containing styrene-acrylic coating, is characterized in that what it was made up of the raw material of following weight parts:
Perfluor alkyl ethyl acrylate 6-7, wild marjoram oil 0.7-2, tea saponin 1-2, tetrabutyl titanate 0.6-1, dimethylaminopropylamine 1-3, decabromodiphenyl oxide 2-3, Sodium Silicofluoride 1-2,1-methyl amyl alcohol 2-3, Stalactitum powder 2-4, light calcium carbonate 10-14, Isooctyl acrylate monomer 2-4, tetramethyl thiourea 0.5-1, vinylbenzene 150-200, deionized water 500-600, butyl acrylate 150-200, ammonium persulphate 3-6, Triton X-100 6-10, adhesive aid 4-5;
Described adhesive aid is made up of each raw material of following weight parts:
Alumina gel 20-30, exsiccated ammonium alum 1-3, lanolin 1-2, polyethylene glycol dimethacrylate 0.6-1, dehydrated alcohol 3-4, Isooctyl acrylate monomer 2-4, Potassium Persulphate 2-3, emulsifier op-10 0.5-1, Camphorwood micro mist 2-4, deionized water 15-20;
Dehydrated alcohol is heated to 70-75 DEG C, adds lanolin, stir, obtain alcohol lipoprotein solution;
Join in Alumina gel by Camphorwood micro mist, add polyethylene glycol dimethacrylate, raised temperature is 55-60 DEG C, 100-200 rev/min of dispersed with stirring 3-5 minute, obtains dispersion liquid;
Potassium Persulphate is mixed with Isooctyl acrylate monomer, 2-3 minute is uniformly mixed at 60-70 DEG C, add dispersion liquid, be stirred to normal temperature, add above-mentioned alcohol lipoprotein solution, 60-100 rev/min is uniformly mixed 5-10 minute, adds each raw material of residue, 200-400 rev/min of dispersed with stirring 3-5 minute, obtains described adhesive aid.
2. a preparation method for fluorine-containing styrene-acrylic coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) get above-mentioned vinylbenzene, butyl acrylate mixing, obtain monomer a;
(2) by Triton X-100, ammonium persulphate mixing, add the 30-40% of above-mentioned deionized water weight, at 50-70 DEG C of insulated and stirred 15-20 minute, be cooled to normal temperature, obtain pre-emulsion;
(3) get the above-mentioned 70-80% of monomer a weight, the 40-50% of pre-emulsion weight, mixing, adds 1-methyl amyl alcohol, tea saponin, insulated and stirred 10-20 minute at 75-80 DEG C, obtains premix monomer;
(4) by remaining monomer a, the mixing of remaining pre-emulsion, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, regulate pH value to 7-8, filter with 200-250 order filter sieve;
(5) material above-mentioned steps (4) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described fluorine-containing styrene-acrylic coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410451880.4A CN104263112A (en) | 2014-09-05 | 2014-09-05 | Fluorine-containing styrene-acrylic coating |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410451880.4A CN104263112A (en) | 2014-09-05 | 2014-09-05 | Fluorine-containing styrene-acrylic coating |
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| CN104263112A true CN104263112A (en) | 2015-01-07 |
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| CN201410451880.4A Withdrawn CN104263112A (en) | 2014-09-05 | 2014-09-05 | Fluorine-containing styrene-acrylic coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752780A (en) * | 2016-12-05 | 2017-05-31 | 安徽永川电气设备有限公司 | A kind of power switch cabinet antibacterial powdery paints and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101542018A (en) * | 2006-11-21 | 2009-09-23 | 日本帕卡濑精株式会社 | Aqueous surface treatment for environment-friendly precoated metal materials, surface-treated metal materials, and environment-friendly precoated metal materials |
| CN101781479A (en) * | 2009-12-04 | 2010-07-21 | 上海瓷龙化工有限公司 | Environment-friendly nano ceramic film coating with self heat radiating function and preparation method thereof |
| CN102060952A (en) * | 2010-10-29 | 2011-05-18 | 华南理工大学 | Styrene-acrylate emulsion with hydrophobic oleophylic fluorine-silicon-modified nuclear shell structure and preparation method thereof |
| CN102250280A (en) * | 2011-05-20 | 2011-11-23 | 锦州惠发天合化学有限公司 | Perfluoro alkyl ethyl acrylic ester-modified single-component acrylic resin and preparation method as well as application thereof |
| CN102863578A (en) * | 2011-07-05 | 2013-01-09 | 张颖菲 | Preparation method of styrene-acrylic emulsion |
-
2014
- 2014-09-05 CN CN201410451880.4A patent/CN104263112A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101542018A (en) * | 2006-11-21 | 2009-09-23 | 日本帕卡濑精株式会社 | Aqueous surface treatment for environment-friendly precoated metal materials, surface-treated metal materials, and environment-friendly precoated metal materials |
| CN101781479A (en) * | 2009-12-04 | 2010-07-21 | 上海瓷龙化工有限公司 | Environment-friendly nano ceramic film coating with self heat radiating function and preparation method thereof |
| CN102060952A (en) * | 2010-10-29 | 2011-05-18 | 华南理工大学 | Styrene-acrylate emulsion with hydrophobic oleophylic fluorine-silicon-modified nuclear shell structure and preparation method thereof |
| CN102250280A (en) * | 2011-05-20 | 2011-11-23 | 锦州惠发天合化学有限公司 | Perfluoro alkyl ethyl acrylic ester-modified single-component acrylic resin and preparation method as well as application thereof |
| CN102863578A (en) * | 2011-07-05 | 2013-01-09 | 张颖菲 | Preparation method of styrene-acrylic emulsion |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752780A (en) * | 2016-12-05 | 2017-05-31 | 安徽永川电气设备有限公司 | A kind of power switch cabinet antibacterial powdery paints and preparation method thereof |
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