CN104152010A - Ultraviolet-curable pollution-resistant coating - Google Patents
Ultraviolet-curable pollution-resistant coating Download PDFInfo
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- CN104152010A CN104152010A CN201410437620.1A CN201410437620A CN104152010A CN 104152010 A CN104152010 A CN 104152010A CN 201410437620 A CN201410437620 A CN 201410437620A CN 104152010 A CN104152010 A CN 104152010A
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- antifouling paint
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- 238000000016 photochemical curing Methods 0.000 claims abstract description 17
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000728 polyester Polymers 0.000 claims abstract description 16
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- 239000004593 Epoxy Substances 0.000 claims description 29
- 239000003973 paint Substances 0.000 claims description 27
- 238000006116 polymerization reaction Methods 0.000 claims description 23
- 230000003373 anti-fouling effect Effects 0.000 claims description 20
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- -1 polydimethylsiloxane Polymers 0.000 claims description 16
- 238000012986 modification Methods 0.000 claims description 15
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000012467 final product Substances 0.000 claims description 10
- 238000009775 high-speed stirring Methods 0.000 claims description 10
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 6
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 claims description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 5
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 4
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 claims description 4
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 claims description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- 238000001723 curing Methods 0.000 abstract description 10
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052740 iodine Inorganic materials 0.000 abstract description 5
- 239000011630 iodine Substances 0.000 abstract description 5
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 abstract 1
- XQAVYBWWWZMURF-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO XQAVYBWWWZMURF-UHFFFAOYSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 238000004134 energy conservation Methods 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 239000000463 material Substances 0.000 description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000011521 glass Substances 0.000 description 4
- 229940098465 tincture Drugs 0.000 description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical class CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
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- 238000002474 experimental method Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses an ultraviolet-curable pollution-resistant coating. The ultraviolet-curable pollution-resistant coating is prepared from the following components in parts by weight: 60-75 parts of modified epoxy acrylate, 58-68 parts of epoxy acrylate, 20-25 parts of urethane acrylate, 30-35 parts of polyester modified acrylate, 12-18 parts of pentaerythritol pentaacrylate, 13-23 parts of tripropylene glycol diacrylate, 7-8 parts of pollution-resistant photocuring auxiliary, 1-8 parts of photoinitiator, 32-39 parts of diluent and 2-4 parts of a flatting agent. The ultraviolet-curable pollution-resistant coating is an ultraviolet-curable coating which can be cured instantaneously under ultraviolet irradiation at a room temperature; besides, the ultraviolet-curable pollution-resistant coating has excellent pollution resistance and iodine resistance, and is capable of achieving the purposes of energy conservation, environmental protection and fast curing.
Description
Technical field
The present invention relates to a kind of ultraviolet light polymerization antifouling paint, belong to paint field.
Background technology
Ultraviolet-curing paint is mainly made up of oligopolymer, monomer, light trigger and auxiliary agent.The principal reaction course of ultraviolet light polymerization is to cause that by radiation light trigger decomposes, and generates living radical trigger monomer/oligopolymer polymerization crosslinking.In the past few years, ultraviolet-curing paint has development very rapidly in fibre coating, CD coating/DVD tackiness agent, credit card, timber, beverages can, food product pack, journal surface, medicine equipment and automobile industry.Ultraviolet-curing paint has huge market potential, and its ratio in whole coating products is just at increase year after year.Along with the expanding day of ultraviolet light polymerization range of application, also there is technically important breakthrough.
Traditional coating needs at high temperature could solidify, and consumes mass energy.Although general ultraviolet-curing paint has the feature of luster, high-hardness and high, also there is following defect in it: easily by fingerprint besmirch, oil pen's trace is not easy to remove, stain resistance is poor.This has limited its application to a certain extent.Due to similar compatibility principle, macromolecular material just has good affinity to oily material itself, use conventional macromolecular material to be difficult to reach this requirement, therefore domestic other producers produce no breakthroughs for this performance always, and the sector is monopolized towards optical coating Co., Ltd. by KCC group of Korea S and Korea S always.
Summary of the invention
For solving the deficiencies in the prior art, the object of the present invention is to provide a kind of ultraviolet light polymerization antifouling paint, at room temperature just can instantaneous solidification by UV-irradiation, and there is the ultraviolet-curing paint of resistant to pollution characteristic.
In order to realize above-mentioned target, the present invention adopts following technical scheme:
Ultraviolet light polymerization antifouling paint, meter, composed of the following components: 60～75 parts of modified epoxy acrylic esters, 58～68 parts of epoxy acrylates by weight, 20～25 parts of urethane acrylates, 30～35 parts of polyester modification acrylate, 12～18 parts of Dipentaerythritol five acrylate, 13～23 parts of tripropylene glycol diacrylates, 7～8 parts of resistance to crocking photocuring auxiliary agents, 1～8 part of light trigger, 32～39 parts of thinners, 2～4 parts of flow agents.
Preferably, meter, composed of the following components: 65～68 parts of modified epoxy acrylic esters, 60～63 parts of epoxy acrylates by weight, 22～23 parts of urethane acrylates, 33～34 parts of polyester modification acrylate, 14～16 parts of Dipentaerythritol five acrylate, 17～19 parts of tripropylene glycol diacrylates, 8 parts of resistance to crocking photocuring auxiliary agents, 4～5 parts of light triggers, 36～37 parts of thinners, 3 parts of flow agents.
Further preferably, meter, composed of the following components: 66 parts of modified epoxy acrylic esters, 62 parts of epoxy acrylates by weight, 23 parts of urethane acrylates, 34 parts of polyester modification acrylate, 15 parts of Dipentaerythritol five acrylate, 18 parts of tripropylene glycol diacrylates, 8 parts of resistance to crocking photocuring auxiliary agents, 5 parts of light triggers, 37 parts of thinners, 3 parts of flow agents.
Aforementioned resistance to crocking photocuring auxiliary agent be in polydimethylsiloxane, PSI or organic radical modified polyorganosiloxane one or more, light trigger is 1-hydroxy-cyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 2-hydroxy-2-methyl-1-[4-(2-hydroxyl-oxethyl) phenyl] one or more in-1-acetone, benzoin isopropyl ether or isopropyl thioxanthone.
Aforementioned thinner be in tetramethylol methane tetraacrylate, tetramethylolmethane six acrylate, Hydroxyethyl acrylate, hydroxyethyl methylacrylate one or more, flow agent is acrylate type flow agent.
The method of preparing ultraviolet light polymerization antifouling paint is: each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 60～90 minutes, is heated to 75 DEG C～90 DEG C, and high-speed stirring is disperseed 3.5～5.5 hours and be get final product.
In the present invention, modified epoxy acrylic ester is selected permanent light 6101, permanent light 6106, permanent light 6116 or the permanent light 6118 of Jiangmen city Heng Guang novel material company limited.Have that curing speed is fast, good leveling property, the good feature of sticking power.
Epoxy acrylate is to be made through esterification by ring opening by epoxy resin and acrylic or methacrylic acid, its strong adhesion, and chemical resistance is good, and hardness of film is high, price is cheap.That a class is at ultra-violet curing field application utmost point prepolymer widely.
In the molecule of urethane acrylate, contain acrylic-functional and amino-formate bond, sizing agent after solidifying has high-wearing feature, adhesive power, snappiness, high-peeling strength and good resistance to low temperature and optical property and the weathering resistance of polyacrylic ester brilliance of urethane, is a kind of radiation curing material of high comprehensive performance.Select permanent light 7402 or the permanent light 7402-6 of Jiangmen city Heng Guang novel material company limited.
Polyester modification acrylate is selected permanent light 5212 or the permanent light 5218 of Jiangmen city Heng Guang novel material company limited.All the other reagent are commercially available prod.
Usefulness of the present invention is: the invention provides a kind of ultraviolet light polymerization antifouling paint, ultraviolet-curing paint that at room temperature just can instantaneous solidification by UV-irradiation, and there is good resistant to pollution characteristic and resistance to tincture of iodine characteristic, can reach energy-saving and environmental protection, quick-setting object.
Embodiment
Below in conjunction with specific embodiment, the present invention is done to concrete introduction.
Embodiment 1
Ultraviolet light polymerization antifouling paint, meter by weight, composed of the following components: 6,101 60 parts of the permanent light of modified epoxy acrylic ester, 58 parts of epoxy acrylates, 7,402 20 parts of the permanent light of urethane acrylate, 5,212 30 parts of the permanent light of polyester modification acrylate, 12 parts of Dipentaerythritol five acrylate, 13 parts of tripropylene glycol diacrylates, 7 parts of resistance to crocking photocuring auxiliary agent polydimethylsiloxanes, 1 part of light trigger 1-hydroxy-cyclohexyl phenyl ketone, 32 parts of thinner tetramethylol methane tetraacrylates, esters of acrylic acid flow agent MONENG-11542 part.Each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 60 minutes, is heated to 75 DEG C, and high-speed stirring is disperseed 3.5 hours and be get final product.
Embodiment 2
Ultraviolet light polymerization antifouling paint, meter by weight, composed of the following components: 6,106 66 parts of the permanent light of modified epoxy acrylic ester, 62 parts of epoxy acrylates, 23 parts of the permanent light 7402-6 of urethane acrylate, 5,218 34 parts of the permanent light of polyester modification acrylate, 15 parts of Dipentaerythritol five acrylate, 18 parts of tripropylene glycol diacrylates, 8 parts of resistance to crocking photocuring auxiliary agent PSIs, light trigger 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl] 5 parts ,-1-acetone, 37 parts of thinner tetramethylolmethane six acrylate, 3 parts of esters of acrylic acid flow agent MONENG-1154.Each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 65 minutes, is heated to 80 DEG C, and high-speed stirring is disperseed 5.5 hours and be get final product.
Embodiment 3
Ultraviolet light polymerization antifouling paint, meter by weight, composed of the following components: 6,116 75 parts of the permanent light of modified epoxy acrylic ester, 68 parts of epoxy acrylates, 7,402 25 parts of the permanent light of urethane acrylate, 5,212 35 parts of the permanent light of polyester modification acrylate, 18 parts of Dipentaerythritol five acrylate, 23 parts of tripropylene glycol diacrylates, 8 parts of resistance to crocking photocuring auxiliary agent organic radical modified polyorganosiloxanes, light trigger 2-hydroxy-2-methyl-1-[4-(2-hydroxyl-oxethyl) phenyl] 8 parts ,-1-acetone, 39 parts of thinner Hydroxyethyl acrylates, 4 parts of esters of acrylic acid flow agent MONENG-1154.Each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 70 minutes, is heated to 85 DEG C, and high-speed stirring is disperseed 4 hours and be get final product.
Embodiment 4
Ultraviolet light polymerization antifouling paint, meter by weight, composed of the following components: 6,118 62 parts of the permanent light of modified epoxy acrylic ester, 64 parts of epoxy acrylates, 21 parts of the permanent light 7402-6 of urethane acrylate, 5,218 33 parts of the permanent light of polyester modification acrylate, 16 parts of Dipentaerythritol five acrylate, 17 parts of tripropylene glycol diacrylates, 7 parts of resistance to crocking photocuring auxiliary agent polydimethylsiloxane and PSIs, 2 parts of light trigger benzoin isopropyl ethers, 35 parts of thinner hydroxyethyl methylacrylates, 2 parts of esters of acrylic acid flow agent MONENG-1154.Each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 75 minutes, is heated to 90 DEG C, and high-speed stirring is disperseed 5 hours and be get final product.
Embodiment 5
Ultraviolet light polymerization antifouling paint, meter by weight, composed of the following components: 6,101 73 parts of the permanent light of modified epoxy acrylic ester, 61 parts of epoxy acrylates, 7,402 24 parts of the permanent light of urethane acrylate, 5,212 31 parts of the permanent light of polyester modification acrylate, 14 parts of Dipentaerythritol five acrylate, 15 parts of tripropylene glycol diacrylates, 8 parts of resistance to crocking photocuring auxiliary agent polydimethylsiloxane and organic radical modified polyorganosiloxanes, 3 parts of light trigger isopropyl thioxanthones, 38 parts of thinner tetramethylol methane tetraacrylate and tetramethylolmethane six acrylate, 3 parts of esters of acrylic acid flow agent MONENG-1154.Each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 80 minutes, is heated to 75 DEG C, and high-speed stirring is disperseed 3.5 hours and be get final product.
Embodiment 6
Ultraviolet light polymerization antifouling paint, meter by weight, composed of the following components: 6,106 71 parts of the permanent light of modified epoxy acrylic ester, 67 parts of epoxy acrylates, 21 parts of the permanent light 7402-6 of urethane acrylate, 5,218 32 parts of the permanent light of polyester modification acrylate, 13 parts of Dipentaerythritol five acrylate, 16 parts of tripropylene glycol diacrylates, 7 parts of resistance to crocking photocuring auxiliary agent PSI and organic radical modified polyorganosiloxanes, light trigger 1-hydroxy-cyclohexyl phenyl ketone and 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl] 4 parts ,-1-acetone, 36 parts of thinner Hydroxyethyl acrylate and hydroxyethyl methylacrylates, 4 parts of esters of acrylic acid flow agent MONENG-1154.Each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 85 minutes, is heated to 80 DEG C, and high-speed stirring is disperseed 4 hours and be get final product.
Embodiment 7
Ultraviolet light polymerization antifouling paint, meter by weight, composed of the following components: 6,116 69 parts of the permanent light of modified epoxy acrylic ester, 65 parts of epoxy acrylates, 7,402 24 parts of the permanent light of urethane acrylate, 5,212 31 parts of the permanent light of polyester modification acrylate, 15 parts of Dipentaerythritol five acrylate, 20 parts of tripropylene glycol diacrylates, resistance to crocking photocuring auxiliary agent polydimethylsiloxane, 8 parts of PSI and organic radical modified polyorganosiloxanes, light trigger 2-hydroxy-2-methyl-1-[4-(2-hydroxyl-oxethyl) phenyl]-1-acetone, with 6 parts of benzoin isopropyl ethers, 33 parts of thinner tetramethylolmethane six acrylate and Hydroxyethyl acrylates, 3 parts of esters of acrylic acid flow agent MONENG-1154.Each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 90 minutes, is heated to 85 DEG C, and high-speed stirring is disperseed 4.5 hours and be get final product.
Embodiment 8
Ultraviolet light polymerization antifouling paint, meter by weight, composed of the following components: 6,118 63 parts of the permanent light of modified epoxy acrylic ester, 64 parts of epoxy acrylates, 22 parts of the permanent light 7402-6 of urethane acrylate, 5,218 34 parts of the permanent light of polyester modification acrylate, 17 parts of Dipentaerythritol five acrylate, 21 parts of tripropylene glycol diacrylates, resistance to crocking photocuring auxiliary agent polydimethylsiloxane, 7 parts of PSI and organic radical modified polyorganosiloxanes, 7 parts of light trigger benzoin isopropyl ether and isopropyl thioxanthones, 34 parts of thinner tetramethylolmethane six acrylate and hydroxyethyl methylacrylates, 2 parts of esters of acrylic acid flow agent MONENG-1154.Each component is added in reaction vessel by parts by weight separately, and ultrasonic dispersion, after 75 minutes, is heated to 90 DEG C, and high-speed stirring is disperseed 5.5 hours and be get final product.
Embodiment 1-8 is carried out to following performance test:
1, static contact angle; Test mode: embodiment 1～8 is coated on glass baseplate, and film-forming under the irradiation of 1000w ultraviolet lamp, uses the method for dripping of lying, solvent is water test; Test result is as shown in table 1,
Table 1
As shown in Table 1, embodiment 1～8 obviously has hydrophobicity.
2, resistance to tincture of iodine wiping experiment; Test condition: commercially available prod and embodiment 1～8 are coated on glass baseplate, film-forming under the irradiation of 1000w ultraviolet lamp, the tincture of iodine is coated in cured film surface, after finish-drying, wipes with paper handkerchief; Result is as shown in table 2,
Table 2
As shown in Table 2, commercially available prod wiping is unclean, leaves vestige, and than commercially available prod, embodiment 1-8 has the good resistance to tincture of iodine.
3, an oil-proofness wiping experiment, test condition: commercially available prod and embodiment 1～8 are coated on glass baseplate, film-forming under the irradiation of 1000w ultraviolet lamp, write " just " word of 3cm*3cm with oil pen, room temperature is used non-dust cloth wiping after waiting for 5 minutes, the circle statistics number of times of resistance to wiping result is as shown in table 3 according to this
Table 3
Can be learnt by table 3, than commercially available prod, embodiment 1-8 has good stain resistance.
4, cure test under room temperature.Commercially available prod and embodiment 1～8 are coated on glass baseplate, and room temperature is film-forming under the irradiation of 1000w ultraviolet lamp.Embodiment 1-8 can instantaneous solidification, and commercially available prod is not yet curing.Embodiment 1-8 is obviously short than commercially available prod set time.
More than show and described ultimate principle of the present invention, principal character and advantage.The technician of the industry should understand, and above-described embodiment does not limit the present invention in any form, and all employings are equal to replaces or technical scheme that the mode of equivalent transformation obtains, all drops in protection scope of the present invention.
Claims (6)
1. ultraviolet light polymerization antifouling paint, it is characterized in that: meter by weight, composed of the following components: 60 ~ 75 parts of modified epoxy acrylic esters, 58 ~ 68 parts of epoxy acrylates, 20 ~ 25 parts of urethane acrylates, 30 ~ 35 parts of polyester modification acrylate, 12 ~ 18 parts of Dipentaerythritol five acrylate, 13 ~ 23 parts of tripropylene glycol diacrylates, 7 ~ 8 parts of resistance to crocking photocuring auxiliary agents, 1 ~ 8 part of light trigger, 32 ~ 39 parts of thinners, 2 ~ 4 parts of flow agents.
2. ultraviolet light polymerization antifouling paint according to claim 1, it is characterized in that: meter by weight, composed of the following components: 65 ~ 68 parts of modified epoxy acrylic esters, 60 ~ 63 parts of epoxy acrylates, 22 ~ 23 parts of urethane acrylates, 33 ~ 34 parts of polyester modification acrylate, 14 ~ 16 parts of Dipentaerythritol five acrylate, 17 ~ 19 parts of tripropylene glycol diacrylates, 8 parts of resistance to crocking photocuring auxiliary agents, 4 ~ 5 parts of light triggers, 36 ~ 37 parts of thinners, 3 parts of flow agents.
3. ultraviolet light polymerization antifouling paint according to claim 1, it is characterized in that: meter by weight, composed of the following components: 66 parts of modified epoxy acrylic esters, 62 parts of epoxy acrylates, 23 parts of urethane acrylates, 34 parts of polyester modification acrylate, 15 parts of Dipentaerythritol five acrylate, 18 parts of tripropylene glycol diacrylates, 8 parts of resistance to crocking photocuring auxiliary agents, 5 parts of light triggers, 37 parts of thinners, 3 parts of flow agents.
4. according to the ultraviolet light polymerization antifouling paint described in claim 1 ~ 3 any one, it is characterized in that: described resistance to crocking photocuring auxiliary agent be in polydimethylsiloxane, PSI or organic radical modified polyorganosiloxane one or more, light trigger is 1-hydroxy-cyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 2-hydroxy-2-methyl-1-[4-(2-hydroxyl-oxethyl) phenyl] one or more in-1-acetone, benzoin isopropyl ether or isopropyl thioxanthone.
5. according to the ultraviolet light polymerization antifouling paint described in claim 1 ~ 3 any one, it is characterized in that: described thinner be in tetramethylol methane tetraacrylate, tetramethylolmethane six acrylate, Hydroxyethyl acrylate, hydroxyethyl methylacrylate one or more, flow agent is acrylate type flow agent.
6. the method for the ultraviolet light polymerization antifouling paint of preparation as described in claim 1-3 any one, it is characterized in that: each component is added in reaction vessel by parts by weight separately, ultrasonic dispersion, after 60 ~ 90 minutes, is heated to 75 DEG C ~ 90 DEG C, and high-speed stirring is disperseed 3.5 ~ 5.5 hours and be get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410437620.1A CN104152010B (en) | 2014-08-29 | 2014-08-29 | Ultraviolet light polymerization antifouling paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410437620.1A CN104152010B (en) | 2014-08-29 | 2014-08-29 | Ultraviolet light polymerization antifouling paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104152010A true CN104152010A (en) | 2014-11-19 |
| CN104152010B CN104152010B (en) | 2016-08-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410437620.1A Expired - Fee Related CN104152010B (en) | 2014-08-29 | 2014-08-29 | Ultraviolet light polymerization antifouling paint |
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|---|---|
| CN (1) | CN104152010B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104530924A (en) * | 2014-12-22 | 2015-04-22 | 湖州南浔双林振森实木加工厂 | Ultraviolet curing coating and preparation method thereof |
| CN105925170A (en) * | 2016-06-29 | 2016-09-07 | 海盐三田科技有限公司 | Solvent-free ultraviolet photocuring anti-flouring easily cleaned paint as well as preparation method and application thereof |
| CN106571192A (en) * | 2016-11-11 | 2017-04-19 | 惠州市金龙羽电缆实业发展有限公司 | Conductor preformation fireproof type cable and preparation method thereof |
| CN108384406A (en) * | 2018-05-29 | 2018-08-10 | 四川理工学院 | A kind of graphene oxide UV is coating material solidified and preparation method thereof |
| CN111630114A (en) * | 2018-01-24 | 2020-09-04 | 株式会社大赛璐 | Resin composition for forming hard coat layer |
| CN112852283A (en) * | 2021-02-24 | 2021-05-28 | 东莞大宝化工制品有限公司 | Self-extinction UV wood coating and preparation method thereof |
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| EP0046354A1 (en) * | 1980-08-15 | 1982-02-24 | Scott Bader Company Limited | Coating compositions |
| CN101407651A (en) * | 2008-11-27 | 2009-04-15 | 中国乐凯胶片集团公司 | UV curing color decorative coating |
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| CN103059697A (en) * | 2012-12-28 | 2013-04-24 | 上海乘鹰新材料有限公司 | Ultraviolet curing coating composition for metallic yarn protective layer |
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| EP0046354A1 (en) * | 1980-08-15 | 1982-02-24 | Scott Bader Company Limited | Coating compositions |
| CN101407651A (en) * | 2008-11-27 | 2009-04-15 | 中国乐凯胶片集团公司 | UV curing color decorative coating |
| CN102634267A (en) * | 2012-04-12 | 2012-08-15 | 番禺南沙殷田化工有限公司 | Antifouling and anti-fingerprint coating composite capable of being applied to touch screen panel and preparation method of antifouling and anti-fingerprint coating |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530924A (en) * | 2014-12-22 | 2015-04-22 | 湖州南浔双林振森实木加工厂 | Ultraviolet curing coating and preparation method thereof |
| CN105925170A (en) * | 2016-06-29 | 2016-09-07 | 海盐三田科技有限公司 | Solvent-free ultraviolet photocuring anti-flouring easily cleaned paint as well as preparation method and application thereof |
| CN106571192A (en) * | 2016-11-11 | 2017-04-19 | 惠州市金龙羽电缆实业发展有限公司 | Conductor preformation fireproof type cable and preparation method thereof |
| CN111630114A (en) * | 2018-01-24 | 2020-09-04 | 株式会社大赛璐 | Resin composition for forming hard coat layer |
| CN108384406A (en) * | 2018-05-29 | 2018-08-10 | 四川理工学院 | A kind of graphene oxide UV is coating material solidified and preparation method thereof |
| CN112852283A (en) * | 2021-02-24 | 2021-05-28 | 东莞大宝化工制品有限公司 | Self-extinction UV wood coating and preparation method thereof |
| CN112852283B (en) * | 2021-02-24 | 2022-04-19 | 东莞大宝化工制品有限公司 | Self-extinction UV wood coating and preparation method thereof |
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| CN104152010B (en) | 2016-08-17 |
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