CN103031034A - White finish coat photocurable UV (ultraviolet) paint and preparation method thereof - Google Patents
White finish coat photocurable UV (ultraviolet) paint and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the field of chemical industry, and particularly discloses white finish coat photocurable UV (ultraviolet) paint and a preparation method thereof. The photocurable UV paint comprises the following components in percentage by weight: 20-60% of epoxy acrylate, 20-60% of polyurethane acrylate, 2-5% of phenyl acetone photoinitiator, 0.2-1% of diphenyl phosphine oxide photoinitiator, 0.2-1% of dispersant, 0.2-1% of leveling agent, 1-40% of titanium white TiO2, 5-15% of two-functional-group reactive diluent and 5-30% of three-functional-group reactive diluent. The paint has the characteristics of favorable gloss, adhesive force and leveling property, thus ensuring that the white UV paint can be better applied.
Description
Technical field
The present invention relates to chemical technology field, more particularly, the present invention relates to white finish paint optical curing of UV coating and preparation method thereof.
Background technology
The optical curing of UV coating products is applicable to multiple substrate surface: paper, woodenware, stone material, leather, pottery, metal, glass, plastics, concrete etc., and especially applicable to some thermo-responsive materials especially.Photocuring technology is the surface treatment technology of material of a kind of efficient, environment, energy-conservation, high-quality, it is to utilize UV-light to cause to have chemically reactive liquid material rapid polymerization crosslinked, instantaneous solidification becomes solid material, therefore it does not contain volatile solvent (VOC) substantially, can not cause atmospheric pollution and to the harm of human body and the danger of fire.Photocuring only needs the radiating capacity for light trigger, and also will evaporate solvent or the water of removing dilution usefulness unlike thermofixation or volatile paint, expends large energy, saved space that work in-process stack and enhanced productivity and save the waste resource.A kind of UV curing glass plated film coating is disclosed such as Chinese patent CN201110047998.7, comprise priming paint and finish paint, described priming paint comprises epoxy acrylate resin, Gao Guanneng reunion chlorinated polyethylene, high monomer, simple function group monomer, thermoplastic acrylic resin, light trigger 184, silicone based leveling auxiliary agent, amido organosilane multipolymer and organic solvent; Described finish paint comprises: hexafunctional aliphatic urethane acrylates resin, phenol aldehyde modified epoxy acrylate, thermoplastic acrylic resin, trifunctional monomer, light trigger 184, silicone based leveling auxiliary agent, amido organosilane multipolymer and organic solvent.But still there are the problems such as gloss is low, levelling is poor, sticking power is bad in this coating.
Summary of the invention
For above-mentioned technical problem, technical problem solved by the invention provide a kind ofly have high gloss, snappiness is good, hardness is strong, the white finish paint optical curing of UV coating of strong adhesion.
For solving the problems of the technologies described above, technical scheme of the present invention is achieved in that a kind of white finish paint optical curing of UV coating, be by weight percentage: epoxy acrylate 20%～60 ﹪, polyurethane acroleic acid fat 20%～60 ﹪, phenyl-acetone light trigger 2%～5 ﹪, basic phosphine oxide photoinitiator 0.2%～1 ﹪, dispersion agent 0.2%～1 ﹪, flow agent 0.2%～1 ﹪, titanium dioxide TiO2 1%～40,2 functional group's reactive thinners, 5%～15 ﹪, 3 functional group's reactive thinners, 5%～30 ﹪, the kind of the component of above-mentioned each material is 100%.
Further: in above-mentioned white finish paint optical curing of UV coating, preferred weight percent is amine-modified epoxy resin 33%～37%, aliphatic polyurethane resin 23%～27%, 2-hydroxy-2-methyl-phenyl-acetone light trigger 2.3%～2.7%, diphenyl phosphine oxide light trigger 0.3%～0.7%, modified polyurethane high polymer dispersant 0.5%～0.7%, polysiloxane polyether copolymer flow agent 0.3%～0.5%, titanium dioxide TiO
2Titanium dioxide 8%～12%, 1,6 hexanediol diacrylate reactive thinner 11%～13%, Viscoat 295 reactive thinner 13%～15%, the kind of the component of above-mentioned each material are 100%.
Further again: in above-mentioned white finish paint optical curing of UV coating, described epoxy acrylate is the epoxy acrylate of primary amine or secondary amine modification, functionality is 3, molecular weight is 40,000～60,000, the viscosity under 25 ° is 30000-50000 mPa.s, preferably peaceful 3660, the cyanogen spy 2200 of section, Sartomer CN2100.Described polyurethane acroleic acid fat is the naphthenic hydrocarbon aliphatic polyurethane resin, and functionality is 6, molecular weight is 40,000～100,000, and the viscosity under 25 ° is 30000 ± mPa.s, and preferably Changxing is 6145-100, Bayer VA2959, BASF UA9030V.Described light trigger is that 2-hydroxy-2-methyl-phenyl-acetone, molecular weight are 250～450, and preferably vapour clings at least a in the 2959 light trigger diphenyl phosphine oxides, preferred Sartomer 819.Described dispersion agent is the modified polyurethane superpolymer, and preferably EFKA 4010, the modest DP983 of DS, enlightening are high by 168.Described flow agent is polysiloxane polyether copolymer.Modest 432, the BYK371 of high by 440, the DS of enlightening preferably.Described reactive thinner is 1,6 hexanediol diacrylate, Viscoat 295, functionality 2～3, preferably Changxing HDDA and TMPTA, loose tail HDDA and TMPTA.Among the present invention in each the code name of material all be that producer is to the concrete code name of related products or the code name of commercially available prod.
The present invention also provides the preparation method of above-mentioned 8 white finish paint optical curing of UV coating, and its preparation process is followed successively by,
A, the amine-modified epoxy resin of getting 38 ﹪～42 ﹪ join in the system lacquer cylinder with aliphatic polyurethane, drop into the modified polyurethane high polymer dispersant under the condition that stirs, and stir;
B, in the mixture of steps A, add titanium dioxide, after stirring, through the shredder sand milling, to the mixture of fineness at 10～15 microns;
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, the polysiloxane polyether copolymer flow agent put in the system lacquer cylinder, after stirring, detect packing again.
Compared with prior art, white finish paint optical curing of UV coating of the present invention selects a kind ofly have polymer or amine modified epoxy, polyethers, urethane, polyester acrylic resin etc. to do main film forming oligopolymer, and it shows good hardness, snappiness, high gloss, anti-xanthochromia, chemical resistant properties etc. simultaneously; Select that oil number is little, transparency good, anti-settling performance is good, good dispersity, titanium dioxide that whiteness is good, can play like that brighten, the effect of dilatation, reduction cost.Select polyacrylate, silicone resin, fluorocarbon resin etc. to make levelling property, improve the wettability to base material, change the smooth planarization of filming, do not affect recoatability.Select high molecular polymer, contain acidic-group multipolymer, polyacrylate etc., they can be fine compatible with paint binder, in dispersion and process of lapping, and the caking of can again not reuniting.The production dispersing technology of selecting sand mill to grind, make dispersion after the fineness of UV coating accomplish 10～15 microns, just avoid the ill effects such as particle, lustre lacking uniformity, shrinkage cavity, tangerine peel in filming like that.White finish paint optical curing of UV coating of the present invention is by in Polyurethane CALCIUM ACRYLATE and the epoxy acrylate molecule ammoniacum key being arranged, can between macromolecular chain, form multiple hydrogen bond, main chain is saturated alkane and naphthenic hydrocarbon, it is with polyisocyanates, long chain diol and crylic acid hydroxy ester two-step reaction, the hydroxyl of side chain is conducive to adhering to of polar substrates simultaneously, also favourable pigment is wetting, makes the photocuring film forming have high gloss, sticking power, is difficult for xanthochromia, the excellent physicalies such as snappiness, hardness, levelling property.Among the preparation method of the present invention, its production efficiency is high, energy consumption is low and the uv equipment investment is relatively low, easily realizes streamline production; Save great amount of investment, reduce pollute, saving resource, the white UV coating of producing with the method can have and better is used in various base materials top layer and forms the physics protective membrane.
Embodiment
Below in conjunction with embodiment content of the present invention is described in further detail.
Embodiment 1
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 40%
Aliphatic polyurethane resin (photocuring): 20%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2.5%
Diphenyl phosphine oxide (light trigger): 0.5%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, 40 ﹪ amine-modified epoxy resins are joined in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir.
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
According to the examination criteria of national standard " indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009) ", performance test is as described in Table 1:
Table 1
1: after drawing hundred lattice, do not come off with 3 hours paint films of (100 ℃) poach, good sticking power is arranged
2: paint film can demixing phenomenon not reduce the polishing time by fine recoat yet
3: the bad sample at the bottom of fine opacifying power reduces the sand leakage is like that arranged
4: paint film has high gloss, opacifying power, levelling, hardness, sticking power, pliable and tough texts
5: fineness will be ground to 10UM can reduce particle point and lustre lacking uniformity phenomenon like that, to precipitating, store, transport, have more stability
Embodiment 2
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 35%
Aliphatic polyurethane resin (photocuring): 25%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2.5%
Diphenyl phosphine oxide (light trigger): 0.5%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, 40 ﹪ amine-modified epoxy resins are joined in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir.
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
Performance test such as table 2: indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009)
Table 2
1: minimizing amine modified epoxy 5 ﹪ add in the 5 ﹪ aliphatic polyurethanes and can provide better snappiness, gloss.
2: some are wanted snappiness, can be suitable for the base material of the high paint film of folding endurance
3: to precipitating, store, transport, have more stability
Embodiment 3
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 28%
Aliphatic polyurethane resin (photocuring): 32%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2.5%
Diphenyl phosphine oxide (light trigger): 0.5%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, 40 ﹪ amine-modified epoxy resins are joined in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir.
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
Performance test is as shown in table 3: indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009)
Table 3
| Test event | Test result |
| Grindometer (hand is scraped) 〉=15/um | 10 (UM) are without crystalline polamer |
| Non-volatile part of % (105 ± 2 ℃ of 1h) | 1MG |
| Package stability [(50 ± 2) ℃, 7d] | Not rotten |
| Glossometer (60 °) 〉=1 | 97° |
| Hardness (scratch) | 3H |
| Pliable and tough (bending) 15 mm | 1-2mm |
| Sticking power (drawing hundred lattice) 〉=1 | 〉=0 grade |
| Opacifying power (hand stripping) | Lose the black and white lattice |
| Hot water resistance (100 ℃) | (poach 3 hours) is without unusual |
| Alkali resistance (50g/L, NaHCO 3） | Without unusual |
| Alcohol resistance (50%, 1h) | Without unusual |
| Anti-vinegar (1h) | Without unusual |
| Anti-green tea (1h) | Without unusual |
| Dry heat resistance [(70 ± 2) ℃, 15min] | Without unusual |
1: snappiness, sticking power, levelling property, hardness texts can improve, and anti-xanthochromia can be than adding the not good enough of amine modified epoxy
2: to precipitating, store, transport, have more stability
Embodiment 4
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 26%
Aliphatic polyurethane resin (photocuring): 34%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2%
Diphenyl phosphine oxide (light trigger): 0.3%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12.7%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, get 40 ﹪ amine-modified epoxy resins and join in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir.
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
Performance is following as shown in table 4: indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009)
Table 4
| Test event | Test result |
| Grindometer (hand is scraped) 〉=15/um | 10 (UM) are without crystalline polamer |
| Non-volatile part of % (105 ± 2 ℃ of 1h) | ≥1MG |
| Package stability [(50 ± 2) ℃, 7d] | Not rotten |
| Glossometer (60 °) 〉=1 | 97° |
| Sclerometer (scratch) | 3H |
| Pliable and tough meter (bending) 15mm | 1mm |
| Sticking power (drawing hundred lattice) | 〉=0 grade |
| Opacifying power (hand stripping) | Lose the black and white lattice |
| Hot water resistance (100 ℃) | (poach 3 hours) is without unusual |
| Alkali resistance (50g/L, NaHCO 3） | Without unusual |
| Alcohol resistance (50%, 1h) | Without unusual |
| Anti-vinegar (1h) | Without unusual |
| Anti-green tea (1h) | Without unusual |
| Dry heat resistance [(70 ± 2) ℃, 15min] | Without unusual |
1: curing speed can improve the use that can reduce light trigger can reduce cost
2: paint film has better snappiness, sticking power, levelling property, hardness, opacifying power texts
3: to precipitating, store, transport, have more stability
Embodiment 5
A kind of white finish paint optical curing of UV coating is by weight percentage:
Amine-modified epoxy resin (photocuring): 20%
Aliphatic polyurethane resin (photocuring): 40%
2-hydroxy-2-methyl-phenyl-acetone (light trigger): 2%
Diphenyl phosphine oxide (light trigger): 0.3%
Modified polyurethane superpolymer (dispersion agent): 0.6%
Polysiloxane polyether copolymer (flow agent): 0.4%
Titanium dioxide (TiO
2) (titanium dioxide): 10%
1,6 hexanediol diacrylate (reactive thinner): 12.7%
Viscoat 295 (reactive thinner): 14%
The preparation method is as follows:
A, 40 ﹪ amine-modified epoxy resins are joined in the system lacquer cylinder with aliphatic polyurethane, under the condition that stirs, drop into the modified polyurethane high polymer dispersant, stir;
B, under agitation condition, add titanium dioxide, after stirring, through the shredder sand milling, to fineness at 10～15 microns;
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir;
D, under agitation condition, organic silicone polyether multipolymer flow agent put in the system lacquer cylinder, after stirring, detect the paint performance qualified keep sample again filter and package
Performance test is as shown in table 5: indoor decorating solvent shape polyurethane woodware coating (GB/T23997-2009)
Table 5
| Test event | Test result |
| Grindometer (hand is scraped) 〉=15/um | 10 (UM) are without crystalline polamer |
| Non-volatile part of % (105 ± 2 ℃ of 1h) | ≥1MG |
| Package stability [(50 ± 2) ℃, 7d] | Not rotten |
| Glossometer (60 °) 〉=1 | 98° |
| Hardness (scratch) HB | 3H |
| Pliable and tough (bending) 15mm | 1mm |
| Sticking power (drawing hundred lattice) 〉=5 | 〉=0 grade |
| Opacifying power (hand stripping) | Lose the black and white lattice |
| Hot water resistance (100 ℃) | (poach 3 hours) is without unusual |
| Alkali resistance (50g/L, NaHCO 3） | Without unusual |
| Alcohol resistance (50%, 1h) | Without unusual |
| Anti-vinegar (1h) | Without unusual |
| Anti-green tea (1h) | Without unusual |
| Dry heat resistance [(70 ± 2) ℃, 15min] | Without unusual |
There are change, its stability of resin not have unusual variation, still provide the physical and chemical performances such as high gloss, sticking power, opacifying power, levelling property, hardness in the above example; the above is that institute obtains in experiment and the practice; do not contain volatility and harmful material that waits, be meet national environmental protection, European standard, be that country advocates efficiently, environmental protection, energy-conservation, high-quality coating.
Claims (9)
1. white finish paint optical curing of UV coating is: epoxy acrylate 20%～60 ﹪, polyurethane acroleic acid fat 20%～60 ﹪, phenyl-acetone light trigger 2%～5 ﹪, basic phosphine oxide photoinitiator 0.2%～1 ﹪, dispersion agent 0.2%～1 ﹪, flow agent 0.2%～1 ﹪, titanium dioxide TiO by weight percentage
21%～40%, 2 functional group's reactive thinners, 5%～15 ﹪, 3 functional group's reactive thinners, 5%～30 ﹪, the kind of the component of above-mentioned each material is 100%.
2. white finish paint optical curing of UV coating according to claim 1, it is characterized in that: preferred weight percent is amine-modified epoxy resin 33%～37%, aliphatic polyurethane resin 23%～27%, 2-hydroxy-2-methyl-phenyl-acetone light trigger 2.3%～2.7%, diphenyl phosphine oxide light trigger 0.3%～0.7%, modified polyurethane high polymer dispersant 0.5%～0.7%, polysiloxane polyether copolymer flow agent 0.3%～0.5%, titanium dioxide TiO
2Titanium dioxide 8%～12%, 1,6 hexanediol diacrylate reactive thinner 11%～13%, Viscoat 295 reactive thinner 13%～15%, the kind of the component of above-mentioned each material are 100%.
3. white finish paint optical curing of UV coating according to claim 2, it is characterized in that: described epoxy acrylate is the epoxy acrylate of primary amine or secondary amine modification, and functionality is 3, molecular weight is 40,000～60,000, the viscosity under 25 ° is 30000-50000 mPa.s.
4. white finish paint optical curing of UV coating according to claim 3, it is characterized in that: described polyurethane acroleic acid fat is the naphthenic hydrocarbon aliphatic polyurethane resin, functionality is 6, molecular weight is 40,000～100,000, the viscosity under 25 ° is 30000 ± mPa.s.
5. white finish paint optical curing of UV coating according to claim 4, it is characterized in that: described phenyl-acetone light trigger is that 2-hydroxy-2-methyl-phenyl-acetone, molecular weight are 250～450; Described basic phosphine oxide photoinitiator is at least a in the diphenyl phosphine oxide.
6. white finish paint optical curing of UV coating according to claim 5, it is characterized in that: described dispersion agent is the modified polyurethane superpolymer.
7. white finish paint optical curing of UV coating according to claim 6, it is characterized in that: described flow agent is polysiloxane polyether copolymer.
8. white finish paint optical curing of UV coating according to claim 7, it is characterized in that: described 2 functional group's reactive thinners are 1,6 hexanediol diacrylates; Described 3 functional group's reactive thinners are Viscoat 295s.
9. method for preparing the described white finish paint optical curing of UV coating of any one among the claim 1-7, it is characterized in that: preparation process is followed successively by,
A, the amine-modified epoxy resin of getting 38 ﹪～42 ﹪ join in the system lacquer cylinder with aliphatic polyurethane, drop into the modified polyurethane high polymer dispersant under the condition that stirs, and stir;
B, in the mixture of steps A, add titanium dioxide, after stirring, through the shredder sand milling, to the mixture of fineness at 10～15 microns;
C, with 1,6 hexanediol diacrylate, Viscoat 295, under agitation condition, put in the system lacquer cylinder, more remaining amine-modified epoxy resin and aliphatic polyurethane, 2-hydroxy-2-methyl-phenyl-acetone, diphenyl phosphine oxide are put in the system lacquer cylinder, stir;
D, under agitation condition, the polysiloxane polyether copolymer flow agent put in the system lacquer cylinder, after stirring, detect packing again.
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| CN111690310A (en) * | 2020-06-19 | 2020-09-22 | 广东立邦长润发科技材料有限公司 | UV white primer for spraying mechanical arm and preparation method thereof |
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