CA2651877A1 - Electrolytic apparatus with polymeric electrode and methods of preparation and use - Google Patents
Electrolytic apparatus with polymeric electrode and methods of preparation and use Download PDFInfo
- Publication number
- CA2651877A1 CA2651877A1 CA002651877A CA2651877A CA2651877A1 CA 2651877 A1 CA2651877 A1 CA 2651877A1 CA 002651877 A CA002651877 A CA 002651877A CA 2651877 A CA2651877 A CA 2651877A CA 2651877 A1 CA2651877 A1 CA 2651877A1
- Authority
- CA
- Canada
- Prior art keywords
- carbon
- electrolytic
- electrode
- electrolytic apparatus
- polymeric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 46
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 36
- 239000003792 electrolyte Substances 0.000 claims description 20
- -1 polyethylene Polymers 0.000 claims description 18
- 239000004698 Polyethylene Substances 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 235000002639 sodium chloride Nutrition 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 239000007800 oxidant agent Substances 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 4
- 229910001919 chlorite Inorganic materials 0.000 claims description 3
- 229910052619 chlorite group Inorganic materials 0.000 claims description 3
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010442 halite Substances 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 14
- 239000010936 titanium Substances 0.000 description 14
- 229910052719 titanium Inorganic materials 0.000 description 14
- 241000894007 species Species 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000010439 graphite Substances 0.000 description 10
- 229910002804 graphite Inorganic materials 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000004155 Chlorine dioxide Substances 0.000 description 9
- 235000019398 chlorine dioxide Nutrition 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 230000001590 oxidative effect Effects 0.000 description 9
- 239000002243 precursor Substances 0.000 description 8
- 230000000249 desinfective effect Effects 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- 239000011780 sodium chloride Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000334993 Parma Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001247 Reticulated foam Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- BPKGOZPBGXJDEP-UHFFFAOYSA-N [C].[Zn] Chemical compound [C].[Zn] BPKGOZPBGXJDEP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000009296 electrodeionization Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74670306P | 2006-05-08 | 2006-05-08 | |
| US60/746,703 | 2006-05-08 | ||
| PCT/US2007/011091 WO2007133535A2 (en) | 2006-05-08 | 2007-05-08 | Electrolytic apparatus with polymeric electrode and methods of preparation and use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2651877A1 true CA2651877A1 (en) | 2007-11-22 |
Family
ID=38694424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002651877A Abandoned CA2651877A1 (en) | 2006-05-08 | 2007-05-08 | Electrolytic apparatus with polymeric electrode and methods of preparation and use |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20070256932A1 (es) |
| EP (1) | EP2016639A4 (es) |
| JP (1) | JP2009536689A (es) |
| CN (1) | CN101438438A (es) |
| BR (1) | BRPI0709789A2 (es) |
| CA (1) | CA2651877A1 (es) |
| MX (1) | MX2008014300A (es) |
| WO (1) | WO2007133535A2 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5355572B2 (ja) * | 2008-07-31 | 2013-11-27 | 三菱電機株式会社 | 殺菌・抗菌装置 |
| US20120021303A1 (en) * | 2010-07-21 | 2012-01-26 | Steven Amendola | Electrically rechargeable, metal-air battery systems and methods |
| US8802304B2 (en) | 2010-08-10 | 2014-08-12 | Eos Energy Storage, Llc | Bifunctional (rechargeable) air electrodes comprising a corrosion-resistant outer layer and conductive inner layer |
| US9680193B2 (en) | 2011-12-14 | 2017-06-13 | Eos Energy Storage, Llc | Electrically rechargeable, metal anode cell and battery systems and methods |
| US10597313B2 (en) | 2017-02-16 | 2020-03-24 | Saudi Arabian Oil Company | Chlorination-assisted coagulation processes for water purification |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US635622A (en) * | 1899-02-27 | 1899-10-24 | Wilson Waring | Acid-proof bag for fertilizers. |
| US2163793A (en) * | 1937-06-08 | 1939-06-27 | Mathieson Alkall Works Inc | Production of chlorine dioxide |
| US3389200A (en) * | 1966-03-30 | 1968-06-18 | Dow Chemical Co | Process for producing compressed vermicular graphite structures |
| US3507773A (en) * | 1966-12-27 | 1970-04-21 | Kimberly Clark Co | Electrode for use in electrolytes |
| AU414112B2 (en) * | 1969-04-28 | 1971-06-16 | Kimberly-Clark Corporation | Paraffin-active carbon electrode and method of producing same |
| US4502929A (en) * | 1981-06-12 | 1985-03-05 | Raychem Corporation | Corrosion protection method |
| IT1151365B (it) * | 1982-03-26 | 1986-12-17 | Oronzio De Nora Impianti | Anodo per procedimenti elettrilitici |
| US4473450A (en) * | 1983-04-15 | 1984-09-25 | Raychem Corporation | Electrochemical method and apparatus |
| DE3423605A1 (de) * | 1984-06-27 | 1986-01-09 | W.C. Heraeus Gmbh, 6450 Hanau | Verbundelektrode, verfahren zu ihrer herstellung und ihre anwendung |
| US5098543A (en) * | 1985-05-07 | 1992-03-24 | Bennett John E | Cathodic protection system for a steel-reinforced concrete structure |
| DE3610388A1 (de) * | 1986-03-27 | 1987-10-01 | Bernhard Dr Wessling | Stabile elektroden auf basis makromolekularer werkstoffe und verfahren zu ihrer verwendung |
| FR2652943B1 (fr) * | 1989-10-05 | 1994-07-01 | Electricite De France | Materiau conducteur pour electrode, composant electrique et leur procede de fabrication. |
| US5292411A (en) * | 1990-09-07 | 1994-03-08 | Eltech Systems Corporation | Method and apparatus for cathodically protecting reinforced concrete structures |
| US6132645A (en) * | 1992-08-14 | 2000-10-17 | Eeonyx Corporation | Electrically conductive compositions of carbon particles and methods for their production |
| US5879817A (en) * | 1994-02-15 | 1999-03-09 | Eltech Systems Corporation | Reinforced concrete structure |
| US5478676A (en) * | 1994-08-02 | 1995-12-26 | Rexam Graphics | Current collector having a conductive primer layer |
| CZ37998A3 (cs) * | 1995-08-09 | 1998-07-15 | The Procter & Gamble Company | Čisticí a dezinfekční přípravky obsahující iontovou látku zvyšující dezinfekční účinek |
| US5973913A (en) * | 1997-08-12 | 1999-10-26 | Covalent Associates, Inc. | Nonaqueous electrical storage device |
| US6139705A (en) * | 1998-05-06 | 2000-10-31 | Eltech Systems Corporation | Lead electrode |
| US6395153B1 (en) * | 1998-12-02 | 2002-05-28 | Eltech Systems Corporation | Diaphragm cell |
| US6733639B2 (en) * | 2000-11-13 | 2004-05-11 | Akzo Nobel N.V. | Electrode |
| US7048842B2 (en) * | 2001-06-22 | 2006-05-23 | The Procter & Gamble Company | Electrolysis cell for generating chlorine dioxide |
| US20030042134A1 (en) * | 2001-06-22 | 2003-03-06 | The Procter & Gamble Company | High efficiency electrolysis cell for generating oxidants in solutions |
| US6436345B1 (en) * | 2001-03-23 | 2002-08-20 | Chemtreat, Inc. | Method for generating chlorine dioxide |
| US6921743B2 (en) * | 2001-04-02 | 2005-07-26 | The Procter & Gamble Company | Automatic dishwashing compositions containing a halogen dioxide salt and methods for use with electrochemical cells and/or electrolytic devices |
| US7008523B2 (en) * | 2001-07-16 | 2006-03-07 | Miox Corporation | Electrolytic cell for surface and point of use disinfection |
| US20040149571A1 (en) * | 2001-09-06 | 2004-08-05 | The Procter & Gamble Company | Electrolysis cell for generating halogen (and particularly chlorine) dioxide in an appliance |
| US6991876B2 (en) * | 2001-10-05 | 2006-01-31 | Sri International | Metal/active oxygen batteries |
| US7413637B2 (en) * | 2002-05-17 | 2008-08-19 | The Procter And Gamble Company | Self-contained, self-powered electrolytic devices for improved performance in automatic dishwashing |
| US20030213503A1 (en) * | 2002-05-17 | 2003-11-20 | The Procter & Gamble Company | Signal-based electrochemical methods for automatic dishwashing |
| US6869518B2 (en) * | 2002-06-12 | 2005-03-22 | Ecolab Inc. | Electrochemical generation of chlorine dioxide |
| CN1247448C (zh) * | 2002-10-21 | 2006-03-29 | 绵阳高新区鑫天科技有限公司 | 一种制备二氧化氯同时联产无机盐和/或复合肥的方法 |
| US7083708B2 (en) * | 2003-07-31 | 2006-08-01 | The Regents Of The University Of California | Oxygen-consuming chlor alkali cell configured to minimize peroxide formation |
| US7179363B2 (en) * | 2003-08-12 | 2007-02-20 | Halox Technologies, Inc. | Electrolytic process for generating chlorine dioxide |
-
2007
- 2007-05-08 MX MX2008014300A patent/MX2008014300A/es unknown
- 2007-05-08 CA CA002651877A patent/CA2651877A1/en not_active Abandoned
- 2007-05-08 WO PCT/US2007/011091 patent/WO2007133535A2/en active Application Filing
- 2007-05-08 EP EP07776872A patent/EP2016639A4/en not_active Withdrawn
- 2007-05-08 BR BRPI0709789-1A patent/BRPI0709789A2/pt not_active IP Right Cessation
- 2007-05-08 US US11/745,743 patent/US20070256932A1/en not_active Abandoned
- 2007-05-08 JP JP2009509806A patent/JP2009536689A/ja active Pending
- 2007-05-08 CN CNA200780016601XA patent/CN101438438A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007133535A2 (en) | 2007-11-22 |
| US20070256932A1 (en) | 2007-11-08 |
| EP2016639A4 (en) | 2011-09-14 |
| JP2009536689A (ja) | 2009-10-15 |
| BRPI0709789A2 (pt) | 2011-07-26 |
| MX2008014300A (es) | 2008-11-26 |
| WO2007133535A3 (en) | 2008-01-31 |
| CN101438438A (zh) | 2009-05-20 |
| EP2016639A2 (en) | 2009-01-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Dead |