CA2372056A1 - Highly crystalline eaodm interpolymers - Google Patents
Highly crystalline eaodm interpolymers Download PDFInfo
- Publication number
- CA2372056A1 CA2372056A1 CA002372056A CA2372056A CA2372056A1 CA 2372056 A1 CA2372056 A1 CA 2372056A1 CA 002372056 A CA002372056 A CA 002372056A CA 2372056 A CA2372056 A CA 2372056A CA 2372056 A1 CA2372056 A1 CA 2372056A1
- Authority
- CA
- Canada
- Prior art keywords
- interpolymer
- composition
- ethylene
- comp
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 claims abstract description 237
- 229920000642 polymer Polymers 0.000 claims abstract description 131
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000005977 Ethylene Substances 0.000 claims abstract description 64
- 239000000178 monomer Substances 0.000 claims abstract description 44
- 150000004291 polyenes Chemical class 0.000 claims abstract description 28
- 229920005615 natural polymer Polymers 0.000 claims abstract description 12
- 229920001059 synthetic polymer Polymers 0.000 claims abstract description 12
- 150000002978 peroxides Chemical class 0.000 claims description 56
- 238000004132 cross linking Methods 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 46
- -1 propylene-1 Chemical compound 0.000 claims description 44
- 238000010894 electron beam technology Methods 0.000 claims description 27
- 229920001684 low density polyethylene Polymers 0.000 claims description 24
- 239000004702 low-density polyethylene Substances 0.000 claims description 24
- 229920001903 high density polyethylene Polymers 0.000 claims description 23
- 239000004700 high-density polyethylene Substances 0.000 claims description 23
- 229920000573 polyethylene Polymers 0.000 claims description 23
- 239000004698 Polyethylene Substances 0.000 claims description 19
- 230000005855 radiation Effects 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 16
- 229920001577 copolymer Polymers 0.000 claims description 16
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 14
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- 239000004707 linear low-density polyethylene Substances 0.000 claims description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 10
- 230000004927 fusion Effects 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical class [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 8
- 238000010382 chemical cross-linking Methods 0.000 claims description 7
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- 229920001519 homopolymer Polymers 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 6
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- 150000005673 monoalkenes Chemical group 0.000 claims description 6
- 229920003052 natural elastomer Polymers 0.000 claims description 6
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- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 5
- 244000043261 Hevea brasiliensis Species 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 5
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 claims description 5
- 150000004707 phenolate Chemical class 0.000 claims description 5
- 239000004014 plasticizer Substances 0.000 claims description 5
- 229920002857 polybutadiene Polymers 0.000 claims description 5
- 239000004711 α-olefin Substances 0.000 claims description 5
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 claims description 3
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
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- 229920001179 medium density polyethylene Polymers 0.000 claims description 3
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- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 claims description 3
- FPAZNLSVMWRGQB-UHFFFAOYSA-N 1,2-bis(tert-butylperoxy)-3,4-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=C(OOC(C)(C)C)C(OOC(C)(C)C)=C1C(C)C FPAZNLSVMWRGQB-UHFFFAOYSA-N 0.000 claims description 2
- HORSMXKHNFGFAY-UHFFFAOYSA-N 1-(1-phenylethylperoxy)ethylbenzene Chemical compound C=1C=CC=CC=1C(C)OOC(C)C1=CC=CC=C1 HORSMXKHNFGFAY-UHFFFAOYSA-N 0.000 claims description 2
- TUAPLLGBMYGPST-UHFFFAOYSA-N 2,5-dimethyl-2,5-bis(2-methylbutan-2-ylperoxy)hexane Chemical compound CCC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)CC TUAPLLGBMYGPST-UHFFFAOYSA-N 0.000 claims description 2
- WNHRZDKOZAQNLX-UHFFFAOYSA-N [2,5-bis(tert-butylperoxy)-5-phenylhexan-2-yl]benzene Chemical compound C=1C=CC=CC=1C(C)(OOC(C)(C)C)CCC(C)(OOC(C)(C)C)C1=CC=CC=C1 WNHRZDKOZAQNLX-UHFFFAOYSA-N 0.000 claims description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 claims description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 2
- 230000009477 glass transition Effects 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- 230000005865 ionizing radiation Effects 0.000 claims 2
- 150000003464 sulfur compounds Chemical class 0.000 claims 2
- 229920002367 Polyisobutene Polymers 0.000 claims 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims 1
- 150000001733 carboxylic acid esters Chemical class 0.000 claims 1
- 150000001734 carboxylic acid salts Chemical class 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- 230000000704 physical effect Effects 0.000 abstract description 13
- 229920002959 polymer blend Polymers 0.000 abstract description 6
- 238000012360 testing method Methods 0.000 description 50
- 239000006260 foam Substances 0.000 description 38
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 34
- 239000011593 sulfur Substances 0.000 description 34
- 235000001508 sulfur Nutrition 0.000 description 34
- 229910052717 sulfur Inorganic materials 0.000 description 34
- 229960005349 sulfur Drugs 0.000 description 34
- 238000002156 mixing Methods 0.000 description 29
- 229920000098 polyolefin Polymers 0.000 description 25
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 23
- 150000001875 compounds Chemical class 0.000 description 21
- 239000000463 material Substances 0.000 description 19
- 239000000155 melt Substances 0.000 description 19
- 239000004743 Polypropylene Substances 0.000 description 18
- 229920001971 elastomer Polymers 0.000 description 18
- 229920001155 polypropylene Polymers 0.000 description 18
- 238000009472 formulation Methods 0.000 description 17
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 15
- 238000007906 compression Methods 0.000 description 14
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- 239000003921 oil Substances 0.000 description 14
- 239000006229 carbon black Substances 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- 238000004073 vulcanization Methods 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 11
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 11
- 239000011787 zinc oxide Substances 0.000 description 11
- 239000008188 pellet Substances 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- 235000021355 Stearic acid Nutrition 0.000 description 9
- 239000000806 elastomer Substances 0.000 description 9
- 238000005227 gel permeation chromatography Methods 0.000 description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 9
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 9
- 235000013824 polyphenols Nutrition 0.000 description 9
- 239000005060 rubber Substances 0.000 description 9
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- 239000000126 substance Substances 0.000 description 9
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 8
- 229920013619 Plioflex Polymers 0.000 description 8
- 239000003570 air Substances 0.000 description 8
- 150000008064 anhydrides Chemical class 0.000 description 8
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 8
- 150000001993 dienes Chemical class 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
- 230000004044 response Effects 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
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- 239000000945 filler Substances 0.000 description 7
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
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- 238000000465 moulding Methods 0.000 description 6
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- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 5
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- 238000013329 compounding Methods 0.000 description 5
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- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
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-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13436099P | 1999-05-14 | 1999-05-14 | |
US60/134,360 | 1999-05-14 | ||
PCT/US2000/013159 WO2000069930A1 (en) | 1999-05-14 | 2000-05-12 | Highly crystalline eaodm interpolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2372056A1 true CA2372056A1 (en) | 2000-11-23 |
Family
ID=22463018
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002372056A Abandoned CA2372056A1 (en) | 1999-05-14 | 2000-05-12 | Highly crystalline eaodm interpolymers |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP1183286A1 (ja) |
JP (1) | JP2002544344A (ja) |
KR (1) | KR20010113933A (ja) |
CN (1) | CN1367801A (ja) |
AU (1) | AU4847500A (ja) |
BR (1) | BR0011524A (ja) |
CA (1) | CA2372056A1 (ja) |
MX (1) | MXPA01011557A (ja) |
WO (1) | WO2000069930A1 (ja) |
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US6875813B2 (en) | 1999-05-19 | 2005-04-05 | Exxonmobil Chemical Patents Inc. | Isobutylene-based elastomer blends |
JP2004501231A (ja) * | 2000-05-11 | 2004-01-15 | エクソンモービル・ケミカル・パテンツ・インク | イソブチレン系エラストマーブレンド |
CA2323307A1 (en) | 2000-10-16 | 2002-04-16 | Peter Jackson | Crosslinked, heat shrinkable polypropylene compositions |
ES2296810T3 (es) * | 2000-10-16 | 2008-05-01 | Shawcor Ltd. | Composiciones de propileno entrecruzadas y termorretractiles. |
ATE279326T1 (de) * | 2001-04-13 | 2004-10-15 | Pirelli | Reifen mit hoher strassenhaftung, lauffläche und darin benutzte elastomermischung |
JP5086637B2 (ja) | 2003-07-09 | 2012-11-28 | ランクセス エラストマーズ ビー.ブイ. | エチレン、α−オレフィン、およびビニルノルボルネンのモノマー単位を含むポリマーの製造方法 |
US7737205B2 (en) | 2003-07-28 | 2010-06-15 | Dow Global Technologies Inc | Thermoplastic vulcanizates and process to prepare them |
US7741397B2 (en) | 2004-03-17 | 2010-06-22 | Dow Global Technologies, Inc. | Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof |
EP1746113A4 (en) * | 2004-04-28 | 2008-11-12 | Mitsui Chemicals Inc | NON-CONJUGATED POLYENE COPOLYMER, RUBBER COMPOSITION AND USES THEREOF |
DE602004031890D1 (de) * | 2004-07-30 | 2011-04-28 | Dow Global Technologies Inc | Hren dafür |
US20060041071A1 (en) * | 2004-08-19 | 2006-02-23 | Sandstrom Paul H | Pneumatic tire having a rubber component containing polyethylene terpolymer |
US7456231B2 (en) | 2005-02-02 | 2008-11-25 | Shawcor Ltd. | Radiation-crosslinked polyolefin compositions |
CN101365742B (zh) * | 2005-03-17 | 2012-02-08 | 陶氏环球技术有限责任公司 | 由乙烯/α-烯烃共聚体制备的填充聚合物组合物及其用途 |
US7655728B2 (en) * | 2005-06-27 | 2010-02-02 | Exxonmobil Chemical Patents Inc. | Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders |
JP2009040998A (ja) | 2007-07-18 | 2009-02-26 | Sumitomo Chemical Co Ltd | ポリプロピレン樹脂組成物およびそれからなる成形体 |
EP2291450A4 (en) | 2008-06-18 | 2012-04-04 | Dow Global Technologies Llc | POLYMERIC COMPOSITIONS, METHOD FOR THE PRODUCTION THEREOF AND ARTICLES PRODUCED THEREFROM |
US8110619B2 (en) | 2008-08-29 | 2012-02-07 | The Goodyear Tire & Rubber Company | Tire compounds with improved tear, flex fatigue, and ozone resistance |
JP2013515823A (ja) | 2009-12-24 | 2013-05-09 | ダウ グローバル テクノロジーズ エルエルシー | ポリマー組成物、その作製方法、及びそれから調製される物品 |
AU2013202461B2 (en) * | 2009-12-29 | 2014-12-11 | Saint-Gobain Performance Plastics Corporation | A flexible tubing material and method of forming the material |
WO2011090759A2 (en) | 2009-12-29 | 2011-07-28 | Saint-Gobain Performance Plastics Corporation | A flexible tubing material and method of forming the material |
KR20110100018A (ko) * | 2010-03-03 | 2011-09-09 | 엘에스전선 주식회사 | 내열 변형성을 갖는 절연재용 수지 조성물 및 이를 이용한 케이블 |
JP2011213822A (ja) * | 2010-03-31 | 2011-10-27 | Mitsui Chemicals Inc | エチレン・ブテン・非共役ポリエン共重合体、該共重合体を含むゴム組成物および該組成物の用途 |
JP5706668B2 (ja) * | 2010-11-09 | 2015-04-22 | ポリプラスチックス株式会社 | 架橋オレフィン系エラストマー |
TW201302821A (zh) * | 2011-04-21 | 2013-01-16 | Daicel Corp | 環狀烯烴系樹脂的交聯體及其製造方法 |
JP5808166B2 (ja) * | 2011-06-28 | 2015-11-10 | 三井化学株式会社 | エチレン系共重合体、発泡体用組成物およびそれからなる発泡成形体 |
US8993681B2 (en) | 2011-07-14 | 2015-03-31 | Exxonmobil Research And Engineering Company | Dendritic ethylene polymers and processes for making |
GB2494616B (en) * | 2011-08-12 | 2014-05-07 | Innovia Films Ltd | In-mould labelling |
US10266684B2 (en) | 2012-03-12 | 2019-04-23 | Colorado State University Research Foundation | Glycosaminoglycan and synthetic polymer materials for blood-contacting applications |
EP2825203B1 (en) | 2012-03-12 | 2020-11-18 | Colorado State University Research Foundation | Glycosaminoglycan and synthetic polymer materials for blood-contacting applications |
MX2014014515A (es) | 2012-06-06 | 2015-04-08 | Saint Gobain Performance Plast | Tuberia de elastomero termoplastico y metodo para fabricar y usar la misma. |
GB2525453A (en) * | 2014-04-23 | 2015-10-28 | Uponor Innovation Ab | Polyolefin pipe |
CN104031304B (zh) * | 2014-04-30 | 2016-02-24 | 中国科学院化学研究所 | 一种用于3d打印的紫外光交联聚合物材料及其制备方法和应用 |
CN103980594B (zh) * | 2014-04-30 | 2016-02-24 | 中国科学院化学研究所 | 一种用于3d打印的紫外辐射交联聚合物材料及其制备方法和制品 |
CN107108814B (zh) * | 2015-01-12 | 2019-04-23 | 普立万公司 | 用于聚合物配混物的3d印刷的支撑材料 |
CN106916383B (zh) | 2015-12-25 | 2019-06-25 | 比亚迪股份有限公司 | 一种隔音材料组合物和车用隔音片材 |
US10525675B2 (en) * | 2016-03-04 | 2020-01-07 | Solutia Inc. | Polymeric interlayers and multiple layer panels made therefrom exhibiting enhanced properties and performance |
US11193030B2 (en) | 2016-06-24 | 2021-12-07 | Avient Corporation | COC polymer compounds for 3D printing |
CA3068492A1 (en) | 2017-06-29 | 2019-01-03 | Dow Global Technologies Llc | Polyolefin composition |
EP3672811A1 (en) * | 2017-08-24 | 2020-07-01 | Dow Global Technologies LLC | Ethylene/c5-c10 alpha-olefin/ polyene interpolymers |
EP4090703A1 (en) * | 2020-01-13 | 2022-11-23 | INEOS Styrolution Group GmbH | Styrene butadiene block copolymers with low crosslinking |
CN117903372A (zh) * | 2024-03-19 | 2024-04-19 | 拓烯科技(衢州)有限公司 | 一种极性环烯烃共聚物和复合膜及其制备方法 |
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US4978720A (en) * | 1983-06-15 | 1990-12-18 | Exxon Research And Engineering Company | Olefinic chlorosilane and olefinic halide functional group containing polymers and method of forming the same |
US5910464A (en) * | 1992-06-18 | 1999-06-08 | Montell Technology Company Bv | Catalysts for the polymerization of olefins |
DE69427410T2 (de) * | 1993-12-28 | 2002-06-06 | Idemitsu Kosan Co. Ltd., Tokio/Tokyo | Verfahren zur herstellung eines olefinpolymers und eines ethylenpolymers |
IT1270253B (it) * | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
US6300451B1 (en) * | 1994-10-24 | 2001-10-09 | Exxon Chemical Patents Inc. | Long-chain branched polymers and their production |
TW383313B (en) * | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Preparation of ethylene-alpha-olefin-nonconjugate polyene random copolymers, the copolymers obtaining which, and the use of the copolymers |
TW326450B (en) * | 1995-06-28 | 1998-02-11 | Mitsui Petroleum Chemicals Ind | Ethylene copolymer rubber, vulcanizable rubber composition containing the copolymer rubber, and process for preparing the same |
US5914372A (en) * | 1997-01-23 | 1999-06-22 | Jsr Corporation | Ethylene copolymer rubber composition |
EP0891993B1 (en) * | 1997-07-18 | 2003-05-02 | Mitsui Chemicals, Inc. | Unsaturated copolymers, processes for preparing the same, and compositions containing the same |
-
2000
- 2000-05-12 CA CA002372056A patent/CA2372056A1/en not_active Abandoned
- 2000-05-12 BR BR0011524-0A patent/BR0011524A/pt not_active IP Right Cessation
- 2000-05-12 EP EP00930700A patent/EP1183286A1/en not_active Withdrawn
- 2000-05-12 JP JP2000618345A patent/JP2002544344A/ja active Pending
- 2000-05-12 MX MXPA01011557A patent/MXPA01011557A/es not_active Application Discontinuation
- 2000-05-12 CN CN00810065A patent/CN1367801A/zh active Pending
- 2000-05-12 AU AU48475/00A patent/AU4847500A/en not_active Abandoned
- 2000-05-12 WO PCT/US2000/013159 patent/WO2000069930A1/en not_active Application Discontinuation
- 2000-05-12 KR KR1020017014450A patent/KR20010113933A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
BR0011524A (pt) | 2002-03-26 |
AU4847500A (en) | 2000-12-05 |
KR20010113933A (ko) | 2001-12-28 |
WO2000069930A1 (en) | 2000-11-23 |
MXPA01011557A (es) | 2002-07-30 |
JP2002544344A (ja) | 2002-12-24 |
CN1367801A (zh) | 2002-09-04 |
EP1183286A1 (en) | 2002-03-06 |
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