CA2266527A1 - Detergents liquides contenant un enzyme proteolytique, un aldehyde peptidique et des ions calcium - Google Patents
Detergents liquides contenant un enzyme proteolytique, un aldehyde peptidique et des ions calcium Download PDFInfo
- Publication number
- CA2266527A1 CA2266527A1 CA002266527A CA2266527A CA2266527A1 CA 2266527 A1 CA2266527 A1 CA 2266527A1 CA 002266527 A CA002266527 A CA 002266527A CA 2266527 A CA2266527 A CA 2266527A CA 2266527 A1 CA2266527 A1 CA 2266527A1
- Authority
- CA
- Canada
- Prior art keywords
- ala
- leu
- gly
- calcium
- liquid detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 67
- 108090000765 processed proteins & peptides Proteins 0.000 title claims abstract description 61
- 102000035195 Peptidases Human genes 0.000 title claims abstract description 48
- 108091005804 Peptidases Proteins 0.000 title claims abstract description 48
- 239000007788 liquid Substances 0.000 title claims abstract description 43
- 229910001424 calcium ion Inorganic materials 0.000 title claims abstract description 25
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title claims abstract 8
- 239000000203 mixture Substances 0.000 claims abstract description 153
- 239000004094 surface-active agent Substances 0.000 claims abstract description 37
- 239000000137 peptide hydrolase inhibitor Substances 0.000 claims abstract description 11
- 229940124158 Protease/peptidase inhibitor Drugs 0.000 claims abstract description 6
- -1 phosphinamides Chemical class 0.000 claims description 67
- 125000000217 alkyl group Chemical group 0.000 claims description 55
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 16
- 235000001014 amino acid Nutrition 0.000 claims description 13
- 150000001413 amino acids Chemical class 0.000 claims description 13
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 11
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 6
- 125000003275 alpha amino acid group Chemical group 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 6
- 235000013877 carbamide Nutrition 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 4
- 235000019255 calcium formate Nutrition 0.000 claims description 4
- 239000004281 calcium formate Substances 0.000 claims description 4
- 229940044172 calcium formate Drugs 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000005541 phosphonamide group Chemical group 0.000 claims description 4
- 229940124530 sulfonamide Drugs 0.000 claims description 4
- 150000003456 sulfonamides Chemical class 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical group NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 3
- 239000001639 calcium acetate Substances 0.000 claims description 3
- 235000011092 calcium acetate Nutrition 0.000 claims description 3
- 229960005147 calcium acetate Drugs 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 235000011148 calcium chloride Nutrition 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- RCPKXZJUDJSTTM-UHFFFAOYSA-L calcium;2,2,2-trifluoroacetate Chemical compound [Ca+2].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F RCPKXZJUDJSTTM-UHFFFAOYSA-L 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 claims description 3
- PTMHPRAIXMAOOB-UHFFFAOYSA-L phosphoramidate Chemical compound NP([O-])([O-])=O PTMHPRAIXMAOOB-UHFFFAOYSA-L 0.000 claims description 3
- 125000006239 protecting group Chemical group 0.000 claims description 3
- 229910006069 SO3H Inorganic materials 0.000 claims description 2
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 claims description 2
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 2
- PUJDIJCNWFYVJX-UHFFFAOYSA-N benzyl carbamate Chemical compound NC(=O)OCC1=CC=CC=C1 PUJDIJCNWFYVJX-UHFFFAOYSA-N 0.000 claims description 2
- RJNJWHFSKNJCTB-UHFFFAOYSA-N benzylurea Chemical compound NC(=O)NCC1=CC=CC=C1 RJNJWHFSKNJCTB-UHFFFAOYSA-N 0.000 claims description 2
- 229960002713 calcium chloride Drugs 0.000 claims description 2
- YCWCGQPKVXYDDX-UHFFFAOYSA-N dihydroxy-imino-phenylmethoxy-$l^{5}-phosphane Chemical compound NP(O)(=O)OCC1=CC=CC=C1 YCWCGQPKVXYDDX-UHFFFAOYSA-N 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- ABOYDMHGKWRPFD-UHFFFAOYSA-N phenylmethanesulfonamide Chemical compound NS(=O)(=O)CC1=CC=CC=C1 ABOYDMHGKWRPFD-UHFFFAOYSA-N 0.000 claims description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 claims description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 2
- 150000003460 sulfonic acids Chemical class 0.000 claims description 2
- 150000003585 thioureas Chemical group 0.000 claims description 2
- 150000003672 ureas Chemical group 0.000 claims description 2
- VOLGAXAGEUPBDM-UHFFFAOYSA-N $l^{1}-oxidanylethane Chemical compound CC[O] VOLGAXAGEUPBDM-UHFFFAOYSA-N 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 1
- 235000019256 formaldehyde Nutrition 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 150000008298 phosphoramidates Chemical group 0.000 claims 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 claims 1
- 239000011575 calcium Substances 0.000 abstract description 15
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 14
- 229910052791 calcium Inorganic materials 0.000 abstract description 14
- 230000008901 benefit Effects 0.000 abstract description 8
- 230000002797 proteolythic effect Effects 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 65
- 239000000243 solution Substances 0.000 description 64
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 51
- 239000000047 product Substances 0.000 description 49
- 150000001299 aldehydes Chemical class 0.000 description 46
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 42
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
- 235000019439 ethyl acetate Nutrition 0.000 description 32
- 150000003839 salts Chemical class 0.000 description 30
- 102000004190 Enzymes Human genes 0.000 description 27
- 108090000790 Enzymes Proteins 0.000 description 27
- 229940088598 enzyme Drugs 0.000 description 27
- 102000004882 Lipase Human genes 0.000 description 26
- 108090001060 Lipase Proteins 0.000 description 26
- 239000004367 Lipase Substances 0.000 description 25
- 235000019421 lipase Nutrition 0.000 description 25
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 24
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 24
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 24
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 23
- 150000001875 compounds Chemical class 0.000 description 21
- 235000019341 magnesium sulphate Nutrition 0.000 description 21
- 239000002904 solvent Substances 0.000 description 21
- 125000004432 carbon atom Chemical group C* 0.000 description 20
- 239000004365 Protease Substances 0.000 description 18
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 17
- 235000014113 dietary fatty acids Nutrition 0.000 description 17
- 239000000194 fatty acid Substances 0.000 description 17
- 229930195729 fatty acid Natural products 0.000 description 17
- 150000004665 fatty acids Chemical class 0.000 description 17
- NKLCNNUWBJBICK-UHFFFAOYSA-N dess–martin periodinane Chemical compound C1=CC=C2I(OC(=O)C)(OC(C)=O)(OC(C)=O)OC(=O)C2=C1 NKLCNNUWBJBICK-UHFFFAOYSA-N 0.000 description 16
- 229920005646 polycarboxylate Polymers 0.000 description 16
- 238000003756 stirring Methods 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 14
- 235000010338 boric acid Nutrition 0.000 description 14
- 229910052708 sodium Inorganic materials 0.000 description 14
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- 238000003786 synthesis reaction Methods 0.000 description 14
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- 108010059892 Cellulase Proteins 0.000 description 12
- 229910000323 aluminium silicate Inorganic materials 0.000 description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 12
- 239000004327 boric acid Substances 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 12
- 239000002002 slurry Substances 0.000 description 12
- 229910001868 water Inorganic materials 0.000 description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 11
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 11
- 239000002253 acid Substances 0.000 description 11
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- 239000000463 material Substances 0.000 description 11
- 229910052700 potassium Inorganic materials 0.000 description 11
- 239000011591 potassium Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 229940024606 amino acid Drugs 0.000 description 10
- 150000001768 cations Chemical class 0.000 description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 10
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- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 9
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- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 9
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- 238000004587 chromatography analysis Methods 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
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- YXRMSKDLRGNVGS-YUMQZZPRSA-N methyl (2s)-2-[[(2s)-2-aminopropanoyl]amino]-4-methylpentanoate Chemical compound COC(=O)[C@H](CC(C)C)NC(=O)[C@H](C)N YXRMSKDLRGNVGS-YUMQZZPRSA-N 0.000 description 6
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 6
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- 230000001225 therapeutic effect Effects 0.000 description 1
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000001665 trituration Methods 0.000 description 1
- 108010036927 trypsin-like serine protease Proteins 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Peptides Or Proteins (AREA)
- Detergent Compositions (AREA)
Abstract
L'invention a pour objet des compositions de détergents liquides aqueux, qui contiennent un enzyme protéolytique. L'activité protéolytique est inhibée de manière réversible par un aldéhyde peptidique et du calcium. L'invention concerne plus spécifiquement des compositions de détergents liquides qui contiennent un tensioactif détergent, un enzyme protéolytique, un aldéhyde peptidique et des ions calcium. La combinaison d'aldéhyde peptidique et d'ions calcium procure les avantages synergiques de l'inhibiteur de protéase.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2664696P | 1996-09-24 | 1996-09-24 | |
| US60/026,646 | 1996-09-24 | ||
| PCT/US1997/016622 WO1998013459A1 (fr) | 1996-09-24 | 1997-09-19 | Detergents liquides contenant un enzyme proteolytique, un aldehyde peptidique et des ions calcium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2266527A1 true CA2266527A1 (fr) | 1998-04-02 |
Family
ID=21833031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002266527A Abandoned CA2266527A1 (fr) | 1996-09-24 | 1997-09-19 | Detergents liquides contenant un enzyme proteolytique, un aldehyde peptidique et des ions calcium |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0929639B1 (fr) |
| JP (1) | JP2000506930A (fr) |
| CN (1) | CN1238001A (fr) |
| AR (1) | AR009816A1 (fr) |
| AT (1) | ATE227769T1 (fr) |
| CA (1) | CA2266527A1 (fr) |
| DE (1) | DE69717133T2 (fr) |
| WO (1) | WO1998013459A1 (fr) |
Families Citing this family (103)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1307547B1 (fr) | 2000-07-28 | 2005-10-26 | Henkel Kommanditgesellschaft auf Aktien | Nouvelle enzyme amylolytique issue de bacillus sp. a 7-7 (dsm 12368) et lessive et agent de nettoyage contenant cette enzyme amylolytique |
| ES2290184T3 (es) | 2000-11-28 | 2008-02-16 | Henkel Kommanditgesellschaft Auf Aktien | Ciclodextrina-glucanotransferasa (cgtasa) a partir de bacillus agaradherens (dsm 9948) asi como agentes para el lavado y la limpeiza con esta nueva ciclodextrina-glucanotransferasa. |
| DE10163884A1 (de) | 2001-12-22 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus sp. (DSM 14392) und Wasch- und Reinigungsmittel enthaltend diese neue Alkalische Protease |
| GB0207430D0 (en) * | 2002-03-28 | 2002-05-08 | Unilever Plc | Liquid cleaning compositionsand their use |
| DE10257387A1 (de) | 2002-12-06 | 2004-06-24 | Henkel Kgaa | Mehrkomponenten-Flüssigwaschmittel |
| US8361946B2 (en) | 2004-04-08 | 2013-01-29 | Akzo Nobel N.V. | Detergent composition |
| EP2038393A2 (fr) * | 2006-06-05 | 2009-03-25 | The Procter and Gamble Company | Stabilisation d'enzymes |
| JP2009540042A (ja) * | 2006-06-05 | 2009-11-19 | ザ プロクター アンド ギャンブル カンパニー | 酵素の安定化 |
| GB0611206D0 (en) | 2006-06-07 | 2006-07-19 | Reckitt Benckiser Nv | Detergent composition |
| US20090209447A1 (en) | 2008-02-15 | 2009-08-20 | Michelle Meek | Cleaning compositions |
| RU2510662C2 (ru) | 2008-03-26 | 2014-04-10 | Новозимс А/С | Стабилизированные жидкие ферментные композиции |
| DE102008038479A1 (de) * | 2008-08-20 | 2010-02-25 | Henkel Ag & Co. Kgaa | Wasch- oder Reinigungsmittel mit gesteigerter Waschkraft |
| WO2011005730A1 (fr) | 2009-07-09 | 2011-01-13 | The Procter & Gamble Company | Composition catalytique de détergent pour le linge comprenant des taux relativement faibles d'électrolyte soluble dans l'eau |
| JP2012532246A (ja) | 2009-07-09 | 2012-12-13 | ザ プロクター アンド ギャンブル カンパニー | 比較的低濃度の水溶性電解質を含む触媒性洗濯洗剤組成物 |
| CA2775048A1 (fr) | 2009-09-25 | 2011-03-31 | Novozymes A/S | Utilisation de variants de subtilisine en vue de creer des souches proteineuses sur des surfaces dures |
| EP2480650B1 (fr) | 2009-09-25 | 2017-03-22 | Novozymes A/S | Variants de subtilase |
| US20120149625A1 (en) * | 2009-09-25 | 2012-06-14 | Novozymes A/S | Detergent Composition |
| US20130071913A1 (en) | 2009-12-22 | 2013-03-21 | Novozymes A/S | Use of amylase variants at low temperature |
| EP2343310A1 (fr) | 2010-01-08 | 2011-07-13 | Novozymes A/S | Formulation d'hydrolase de sérine |
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| EP2357220A1 (fr) | 2010-02-10 | 2011-08-17 | The Procter & Gamble Company | Compositions de nettoyage comprenant des variantes de l'amylase de grande stabilité en présence d'un agent chélateur |
| CA2791252C (fr) | 2010-03-12 | 2014-09-02 | The Procter & Gamble Company | Gelifiant di-amido utilise dans des compositions de produit de consommation |
| BR112012023054A2 (pt) | 2010-03-12 | 2017-07-25 | Procter & Gamble | composições detergentes líquidas que compreendem amido-gelificantes de ph sintonizável, e processos para a fabricação das mesmas |
| EP2540824A1 (fr) | 2011-06-30 | 2013-01-02 | The Procter & Gamble Company | Compositions de nettoyage comprenant une référence de variantes dýamylase à une liste de séquences |
| CN103649292B (zh) * | 2011-07-01 | 2017-11-28 | 诺维信公司 | 稳定化的枯草杆菌蛋白酶组合物 |
| EP2726590B1 (fr) | 2011-07-01 | 2017-10-18 | Novozymes A/S | Composition de détergent liquide |
| US20130303427A1 (en) | 2011-09-13 | 2013-11-14 | Susana Fernandez Prieto | MICROCAPSULE COMPOSITIONS COMPRISING pH TUNEABLE DI-AMIDO GELLANTS |
| CN104271726B (zh) * | 2012-05-01 | 2018-08-24 | 诺维信公司 | 洗涤剂组合物 |
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| EP2992076B1 (fr) | 2013-05-03 | 2018-10-24 | Novozymes A/S | Microencapsulation d'enzymes détergentes |
| WO2014207227A1 (fr) | 2013-06-27 | 2014-12-31 | Novozymes A/S | Variants de subtilase et polynucléotides codant pour ceux-ci |
| EP3013955A1 (fr) | 2013-06-27 | 2016-05-04 | Novozymes A/S | Variants de subtilase et polynucléotides codant pour ceux-ci |
| WO2016001319A1 (fr) | 2014-07-03 | 2016-01-07 | Novozymes A/S | Stabilisation améliorée d'enzyme autre que la protéase |
| EP3164486B1 (fr) | 2014-07-04 | 2020-05-13 | Novozymes A/S | Variants de subtilase et polynucléotides codant pour ceux-ci |
| US10550381B2 (en) | 2014-07-04 | 2020-02-04 | Novozymes A/S | Variant proteases and amylases having enhanced storage stability |
| CA2963331A1 (fr) | 2014-12-04 | 2016-06-09 | Novozymes A/S | Variants de subtilase et polynucleotides codant pour ceux-ci |
| EP3227425A1 (fr) | 2014-12-04 | 2017-10-11 | Novozymes A/S | Compositions de nettoyage liquides comprenant des variants de protéase |
| ES2763235T3 (es) | 2014-12-15 | 2020-05-27 | Henkel Ag & Co Kgaa | Composición detergente que comprende variantes de subtilasa |
| EP3234093B1 (fr) | 2014-12-19 | 2020-05-27 | Novozymes A/S | Variantes de protéases et polynucléotides les codant |
| DE102015208655A1 (de) * | 2015-05-11 | 2016-11-17 | Henkel Ag & Co. Kgaa | Enzymstabilisatoren |
| EP3106508B1 (fr) | 2015-06-18 | 2019-11-20 | Henkel AG & Co. KGaA | Composition détergente comprenant des variantes de subtilase |
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| WO2017207762A1 (fr) | 2016-06-03 | 2017-12-07 | Novozymes A/S | Variants de subtilase et polynucléotides codant pour ceux-ci |
| US20200140786A1 (en) | 2016-09-29 | 2020-05-07 | Novozymes A/S | Use of enzyme for washing, method for washing and warewashing composition |
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| WO2018069158A1 (fr) | 2016-10-11 | 2018-04-19 | Basf Se | Protéase résistante aux inhibiteurs naturels |
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| EP3704219B1 (fr) | 2017-11-01 | 2024-01-10 | Novozymes A/S | Polypeptides et compositions comprenant de tels polypeptides |
| US11512268B2 (en) | 2017-11-29 | 2022-11-29 | Basf Se | Storage-stable enzyme preparations, their production and use |
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| MX2021003930A (es) | 2018-10-05 | 2021-06-04 | Basf Se | Compuestos estabilizadores de hidrolasas en liquidos. |
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| KR102652712B1 (ko) | 2019-07-01 | 2024-03-28 | 아사히 가세이 파마 가부시키가이샤 | 페로시안화물의 산화 환원 전위를 크게 하는 프로테아제의 안정화제를 포함하는 당화 단백질 측정 시약, 당화 단백질의 측정 방법, 당화 단백질 측정 시약의 보존 방법, 및 당화 단백질 측정 시약의 안정화 방법 |
| US20230220308A1 (en) | 2019-09-23 | 2023-07-13 | Basf Se | Mannanase for formulations having ph 5-12 |
| EP4034651A1 (fr) | 2019-09-23 | 2022-08-03 | Basf Se | Mannanase pour formulations ayant un ph 5-12 |
| EP4045625A1 (fr) | 2019-10-18 | 2022-08-24 | Basf Se | Liquides contenant une hydrolase stable au stockage |
| WO2021115912A1 (fr) | 2019-12-09 | 2021-06-17 | Basf Se | Formulations comprenant une polyéthylèneimine modifiée de manière hydrophobe et une ou plusieurs enzymes |
| US20220411773A1 (en) | 2019-12-20 | 2022-12-29 | Novozymes A/S | Polypeptides having proteolytic activity and use thereof |
| CA3160579A1 (fr) | 2019-12-23 | 2021-07-01 | Neil Joseph Lant | Compositions comprenant des enzymes |
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| WO2021239818A1 (fr) | 2020-05-26 | 2021-12-02 | Novozymes A/S | Variants de subtilase et compositions les comprenant |
| WO2022008732A1 (fr) | 2020-07-10 | 2022-01-13 | Basf Se | Amélioration de l'activité de conservateurs antimicrobiens |
| JP2023538740A (ja) | 2020-08-25 | 2023-09-11 | ノボザイムス アクティーゼルスカブ | ファミリー４４キシログルカナーゼの変異体 |
| US20230323330A1 (en) | 2020-08-28 | 2023-10-12 | Novozymes A/S | Polyester degrading protease variants |
| EP4217367A1 (fr) | 2020-09-22 | 2023-08-02 | Basf Se | Composition liquide comprenant un aldéhyde peptidique |
| WO2022094164A1 (fr) | 2020-10-29 | 2022-05-05 | The Procter & Gamble Company | Composition nettoyante contenant des enzymes alginate lyases |
| WO2022189521A1 (fr) | 2021-03-12 | 2022-09-15 | Novozymes A/S | Variants polypeptidiques |
| CA3199985A1 (fr) | 2021-03-15 | 2022-09-22 | Lars Lehmann Hylling Christensen | Compositions de nettoyage contenant des variants polypeptidiques |
| JP2024515660A (ja) | 2021-05-05 | 2024-04-10 | ザ プロクター アンド ギャンブル カンパニー | 洗浄組成物の作製及び汚れの検出の方法 |
| EP4108767A1 (fr) | 2021-06-22 | 2022-12-28 | The Procter & Gamble Company | Compositions de nettoyage ou de traitement contenant des enzymes nucléases |
| EP4273210A1 (fr) | 2022-05-04 | 2023-11-08 | The Procter & Gamble Company | Compositions détergentes contenant des enzymes |
| EP4273209A1 (fr) | 2022-05-04 | 2023-11-08 | The Procter & Gamble Company | Compositions pour le nettoyage des machines contenant des enzymes |
| WO2024121070A1 (fr) | 2022-12-05 | 2024-06-13 | Novozymes A/S | Variants de protéase et polynucléotides codant pour ceux-ci |
| WO2024131880A2 (fr) | 2022-12-23 | 2024-06-27 | Novozymes A/S | Composition détergente comprenant une catalase et une amylase |
| WO2024163695A1 (fr) | 2023-02-01 | 2024-08-08 | The Procter & Gamble Company | Compositions détergentes contenant des enzymes |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0028866B1 (fr) * | 1979-11-09 | 1984-07-11 | THE PROCTER & GAMBLE COMPANY | Composition enzymatique aqueuse stabilisée contenant un des ions formiate et calcium |
| JPS61108387A (ja) * | 1984-10-30 | 1986-05-27 | Showa Denko Kk | 酵素の安定化法及び安定化組成物 |
| JPH0657151B2 (ja) * | 1986-05-15 | 1994-08-03 | 昭和電工株式会社 | 酵素の安定化法 |
| DK204290D0 (da) * | 1990-08-24 | 1990-08-24 | Novo Nordisk As | Enzymatisk detergentkomposition og fremgangsmaade til enzymstabilisering |
| US5284829A (en) * | 1991-11-26 | 1994-02-08 | The Regents Of The University Of California | Synthetic tetrapeptides for the prevention of schistosome parasite infection |
| DK0583534T3 (da) * | 1992-08-14 | 1997-06-16 | Procter & Gamble | Flydende detergenter, der indeholder et peptidaldehyd |
-
1997
- 1997-09-19 CA CA002266527A patent/CA2266527A1/fr not_active Abandoned
- 1997-09-19 CN CN97199886.8A patent/CN1238001A/zh active Pending
- 1997-09-19 JP JP10515729A patent/JP2000506930A/ja not_active Withdrawn
- 1997-09-19 DE DE69717133T patent/DE69717133T2/de not_active Expired - Lifetime
- 1997-09-19 EP EP97942579A patent/EP0929639B1/fr not_active Expired - Lifetime
- 1997-09-19 WO PCT/US1997/016622 patent/WO1998013459A1/fr active IP Right Grant
- 1997-09-19 AT AT97942579T patent/ATE227769T1/de not_active IP Right Cessation
- 1997-09-24 AR ARP970104392A patent/AR009816A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0929639A1 (fr) | 1999-07-21 |
| DE69717133D1 (de) | 2002-12-19 |
| CN1238001A (zh) | 1999-12-08 |
| JP2000506930A (ja) | 2000-06-06 |
| AR009816A1 (es) | 2000-05-03 |
| DE69717133T2 (de) | 2003-07-10 |
| WO1998013459A1 (fr) | 1998-04-02 |
| EP0929639B1 (fr) | 2002-11-13 |
| ATE227769T1 (de) | 2002-11-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |