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BR112017027866A2 - polímeros baseados em etileno com extraíveis de baixo hexano - Google Patents

polímeros baseados em etileno com extraíveis de baixo hexano

Info

Publication number
BR112017027866A2
BR112017027866A2 BR112017027866A BR112017027866A BR112017027866A2 BR 112017027866 A2 BR112017027866 A2 BR 112017027866A2 BR 112017027866 A BR112017027866 A BR 112017027866A BR 112017027866 A BR112017027866 A BR 112017027866A BR 112017027866 A2 BR112017027866 A2 BR 112017027866A2
Authority
BR
Brazil
Prior art keywords
ethylene
based polymers
hexane extractables
log
low hexane
Prior art date
Application number
BR112017027866A
Other languages
English (en)
Other versions
BR112017027866B1 (pt
Inventor
F J Den Doelder Cornelis
T Y Dang Nhi
J Berbee Otto
Hinrichs Stefan
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of BR112017027866A2 publication Critical patent/BR112017027866A2/pt
Publication of BR112017027866B1 publication Critical patent/BR112017027866B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • C08F4/32Organic compounds
    • C08F4/38Mixtures of peroxy-compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00Characteristics for processes of polymerization
    • C08F2400/02Control or adjustment of polymerization parameters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08Low density, i.e. < 0.91 g/cm3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17Viscosity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

a invenção fornece um homopolímero de etileno formado de um processo de polimerização de pressão alta, de radical livre em um sistema de reator tubular, o homopolímero compreendendo as seguintes propriedades: (a) uma densidade de 0,9190 a 0,9250 g/cm3; (b) um nível de extraível de hexano que é menor que, ou igual a 2,6% em peso com base no peso total do polímero; (c) um g? (a g?? = 500 pa, 170ºc) que atende a seguinte equação: g? = d + e[log (i2)], onde d = 150 pa e e = -60 pa/[log(g/min)]; e (d) um índice de fusão (12) de 1,0 a 20 g/min.
BR112017027866-9A 2015-06-25 2016-06-23 Processo para produzir um homopolímero de etileno, formado de um radical livre BR112017027866B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562184344P 2015-06-25 2015-06-25
US62/184,344 2015-06-25
PCT/US2016/038900 WO2016210055A1 (en) 2015-06-25 2016-06-23 Ethylene-based polymers with low hexane extractables

Publications (2)

Publication Number Publication Date
BR112017027866A2 true BR112017027866A2 (pt) 2018-08-28
BR112017027866B1 BR112017027866B1 (pt) 2022-05-24

Family

ID=56409164

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112017027866-9A BR112017027866B1 (pt) 2015-06-25 2016-06-23 Processo para produzir um homopolímero de etileno, formado de um radical livre
BR112017027564-3A BR112017027564B1 (pt) 2015-06-25 2016-06-23 Processo para produzir polímero à base de etileno

Family Applications After (1)

Application Number Title Priority Date Filing Date
BR112017027564-3A BR112017027564B1 (pt) 2015-06-25 2016-06-23 Processo para produzir polímero à base de etileno

Country Status (8)

Country Link
US (2) US10358512B2 (pt)
EP (2) EP3313904B1 (pt)
JP (5) JP7436135B2 (pt)
KR (2) KR102577959B1 (pt)
CN (2) CN107787334B (pt)
BR (2) BR112017027866B1 (pt)
ES (2) ES2869983T3 (pt)
WO (2) WO2016210075A1 (pt)

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ES2869983T3 (es) * 2015-06-25 2021-10-26 Dow Global Technologies Llc Polímeros a base de etileno con bajo contenido de extraíbles con hexano
JP6998217B2 (ja) * 2015-06-25 2022-02-10 ダウ グローバル テクノロジーズ エルエルシー 低ヘキサン抽出物及び低密度を有するエチレン系ポリマー
EP3168238A1 (en) 2015-11-10 2017-05-17 Dow Global Technologies LLC Ethylene-based polymers formed by high pressure free radical polymerizations
CN109071686B (zh) * 2016-04-22 2021-11-02 陶氏环球技术有限责任公司 用于生产用于清洁挤出涂层加工的低挥发性管式低密度基于乙烯的聚合物的方法
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CN110240654A (zh) 2018-03-07 2019-09-17 复旦大学 结合cd73的抗体-药物偶联物

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Also Published As

Publication number Publication date
US20180127523A1 (en) 2018-05-10
KR102577959B1 (ko) 2023-09-14
KR20180021070A (ko) 2018-02-28
EP3313903A1 (en) 2018-05-02
BR112017027564A2 (pt) 2018-09-04
JP7510740B2 (ja) 2024-07-04
CN107787334B (zh) 2020-07-24
JP2024056727A (ja) 2024-04-23
ES2869983T3 (es) 2021-10-26
EP3313904A1 (en) 2018-05-02
CN107787334A (zh) 2018-03-09
JP2022008573A (ja) 2022-01-13
US20180112017A1 (en) 2018-04-26
WO2016210055A1 (en) 2016-12-29
CN107810208A (zh) 2018-03-16
ES2775506T3 (es) 2020-07-27
JP7436135B2 (ja) 2024-02-21
WO2016210075A1 (en) 2016-12-29
EP3313904B1 (en) 2021-04-21
EP3313903B1 (en) 2020-01-01
CN107810208B (zh) 2020-07-24
BR112017027866B1 (pt) 2022-05-24
BR112017027564B1 (pt) 2022-02-01
JP2018518577A (ja) 2018-07-12
JP2018522972A (ja) 2018-08-16
JP2024037861A (ja) 2024-03-19
US10358512B2 (en) 2019-07-23
KR20180021067A (ko) 2018-02-28
US10494460B2 (en) 2019-12-03
KR102612773B1 (ko) 2023-12-12

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B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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