ATE263223T1 - Carbamatfunktionelle harze mit verbesserter adhäsion, verfahren zu deren herstellung und verfahren zur verbesserung der zwischenhaftung - Google Patents
Carbamatfunktionelle harze mit verbesserter adhäsion, verfahren zu deren herstellung und verfahren zur verbesserung der zwischenhaftungInfo
- Publication number
- ATE263223T1 ATE263223T1 AT00968506T AT00968506T ATE263223T1 AT E263223 T1 ATE263223 T1 AT E263223T1 AT 00968506 T AT00968506 T AT 00968506T AT 00968506 T AT00968506 T AT 00968506T AT E263223 T1 ATE263223 T1 AT E263223T1
- Authority
- AT
- Austria
- Prior art keywords
- carbamate
- adhesion
- functional
- weight
- percent
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
- C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3823—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/025—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/04—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31645—Next to addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15716699P | 1999-09-30 | 1999-09-30 | |
US15716599P | 1999-09-30 | 1999-09-30 | |
US15716499P | 1999-09-30 | 1999-09-30 | |
PCT/US2000/026905 WO2001023484A2 (en) | 1999-09-30 | 2000-09-29 | Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE263223T1 true ATE263223T1 (de) | 2004-04-15 |
Family
ID=27387970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT00968506T ATE263223T1 (de) | 1999-09-30 | 2000-09-29 | Carbamatfunktionelle harze mit verbesserter adhäsion, verfahren zu deren herstellung und verfahren zur verbesserung der zwischenhaftung |
Country Status (13)
Country | Link |
---|---|
US (5) | US6531560B1 (de) |
EP (1) | EP1216280B1 (de) |
JP (1) | JP2003510445A (de) |
KR (1) | KR20020034204A (de) |
AT (1) | ATE263223T1 (de) |
AU (1) | AU7840900A (de) |
BR (1) | BR0013169A (de) |
CA (1) | CA2384441C (de) |
DE (1) | DE60009523T2 (de) |
ES (1) | ES2218230T3 (de) |
MX (1) | MXPA02002280A (de) |
PL (1) | PL357373A1 (de) |
WO (1) | WO2001023484A2 (de) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6512069B1 (en) * | 1999-09-30 | 2003-01-28 | Basf Corporation | Durable refinish coating |
CA2425385C (fr) * | 2000-10-13 | 2009-12-15 | Rhodia Chimie | Utilisation comme catalyseur pour la formation d'urethanes, de sels d'acide fluores et de metal trivalent, composition en contenant et procede les utilisant |
DE10122390A1 (de) * | 2001-05-09 | 2002-11-28 | Basf Coatings Ag | Carbamat-und/oder Allophanatgruppen enthaltende, thermisch härtbare, thixotrope Gemische |
DE10129969A1 (de) * | 2001-06-21 | 2003-01-09 | Basf Coatings Ag | Carbamat- und/oder Allophanatgruppen enthaltende, thermisch und mit aktinischer Strahlung härtbare Gemische |
WO2003091350A1 (de) * | 2002-04-24 | 2003-11-06 | Basf Coatings Ag | Carbamat- und/oder allophanatgruppen enthaltende, thermisch härtbare, thixotrope gemische |
US20040006185A1 (en) * | 2002-07-01 | 2004-01-08 | Basf Corporation | Carbamate-functional polymer, curable coating composition thereof, and method of preparing the polymer |
US20040087728A1 (en) * | 2002-10-31 | 2004-05-06 | Donald Campbell | Carbamate functional addition polymers and a method for their preparation |
US20050032978A1 (en) * | 2003-08-06 | 2005-02-10 | O'dwyer James B. | Etherified carbamate functional copolymers of isobutylene type monomers, and their use in curable compositions |
RU2394819C2 (ru) * | 2004-10-20 | 2010-07-20 | Кумиай Кемикал Индастри Ко., Лтд. | Инсектицид, акарицид и нематоцид, содержащие в качестве активного компонента производное 3-триазолилфенилсульфида |
DE102005010109A1 (de) | 2005-03-02 | 2006-09-07 | Basf Ag | Modifizierte Polyolefinwachse |
US20070224355A1 (en) * | 2006-03-23 | 2007-09-27 | Basf Corporation | Clearcoat coatings with carbinol-functional siloxane resin |
US8318849B2 (en) * | 2006-04-21 | 2012-11-27 | Basf Coatings Gmbh | High solids nonaqueous dispersion clearcoats |
US7807743B2 (en) * | 2006-09-22 | 2010-10-05 | Basf Corporation | Coating composition and film system therefrom |
US7772304B2 (en) * | 2006-11-17 | 2010-08-10 | Basf Corporation | Plasticizing component and a curable coating composition including the same |
CA2675576A1 (en) * | 2007-02-13 | 2008-08-21 | Basf Corporation | Coating system for achieving excellent mvss adhesion |
US20080293901A1 (en) * | 2007-05-25 | 2008-11-27 | Basf Corporation | Polymers and compounds prepared with alpha-methylene lactones, methods therefor, and coatings |
US20090053420A1 (en) * | 2007-08-20 | 2009-02-26 | Basf Corporation | Thermosetting coating compositions with multiple cure mechanisms |
US20090074978A1 (en) * | 2007-09-13 | 2009-03-19 | Basf Corporation | Method of making carbamate functional materials |
US7989070B2 (en) * | 2007-12-20 | 2011-08-02 | Basf Coatings Gmbh | Coating composition for achieving excellent MVSS adhesion |
US20100104769A1 (en) * | 2008-10-23 | 2010-04-29 | Boisseau John E | Automotive coating surface enhancement using a plasma treatment technique |
JP5573578B2 (ja) * | 2009-10-16 | 2014-08-20 | 信越化学工業株式会社 | パターン形成方法及びレジスト材料 |
US20110097482A1 (en) * | 2009-10-27 | 2011-04-28 | Basf Coatings Ag | Compact coating system and process |
US8946367B2 (en) | 2010-06-22 | 2015-02-03 | Isp Investments Inc. | Polymerizable carbamate and thiocarbamate compounds, polymers derived from them, and compositions thereof |
US10784455B2 (en) | 2012-08-08 | 2020-09-22 | 3M Innovative Properties Company | Coatings for barrier films and methods of making and using the same |
WO2014025383A1 (en) | 2012-08-08 | 2014-02-13 | 3M Innovative Properties Company | Photovoltaic devices with encapsulating barrier film |
WO2014025386A1 (en) | 2012-08-08 | 2014-02-13 | 3M Innovative Properties Company | Urea (multi)-urethane (meth)acrylate-silane compositions and articles including the same |
BR112017013266A2 (pt) | 2014-12-22 | 2018-02-27 | Basf Se | processo para preparação de um composto, composto, e, usos de um composto e de uma dispersão. |
WO2019015953A1 (en) | 2017-07-18 | 2019-01-24 | Basf Coatings Gmbh | LOW-CURING COMPONENT LAYER AT LOW TEMPERATURE AND METHOD OF COATING A SUBSTRATE WITH THE SUBSTRATE LAYER OF A COMPONENT |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2026822C3 (de) * | 1970-06-02 | 1974-11-14 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung durchsichtiger, Polyamidschichten enthaltender Sicherheitsschichtkörper, die wie Verbundsicherheits- oder Verbundpanzergläser verwendbar sind |
US4340497A (en) * | 1980-03-21 | 1982-07-20 | Union Carbide Corporation | (N-Substituted carbamoyloxy) alkanoyloxyalkyl acrylate esters |
US4303581A (en) * | 1980-07-16 | 1981-12-01 | Ppg Industries, Inc. | Water dispersed primer-surfacer composition |
EP0099335B1 (de) | 1982-07-10 | 1986-02-05 | Ciba-Geigy Ag | Verfahren zur Herstellung einer geschützten Schicht |
US4758632A (en) * | 1984-02-17 | 1988-07-19 | American Cyanamid Company | Self-cross-linkable acrylic polymer containing hydroxyalkyl carbamate groups and coating compositions containing the same |
US5356669A (en) * | 1992-10-23 | 1994-10-18 | Basf Corporation | Composite color-plus-clear coating utilizing carbamate-functional polymer composition in the clearcoat |
US5412049A (en) * | 1994-03-31 | 1995-05-02 | Union Carbide Chemicals & Plastics Technology Corporation | Polymer compositions containing hydroxyl functional (meth)acrylates and hydroxyalkyl carbamate (meth)acrylates and mixtures thereof |
US5559195A (en) * | 1994-12-21 | 1996-09-24 | Basf Corporation | Coating composition containing carbamate functional and acrylamide functional components |
JP2955488B2 (ja) * | 1995-04-25 | 1999-10-04 | セメダイン株式会社 | 速硬化接着方法 |
US5593785A (en) | 1995-06-26 | 1997-01-14 | Ppg Industries, Inc. | Coating compositions containing acrylic polymers with pendant carbamate groups exhibiting improved intercoat adhesion |
US5866259A (en) * | 1997-06-30 | 1999-02-02 | Basf Corporation | Primer coating compositions containing carbamate-functional acrylic polymers |
JPH1158612A (ja) * | 1997-08-19 | 1999-03-02 | Daito Kemitoronikusu Kk | 異材合せガラス板及びその製造方法 |
-
2000
- 2000-09-29 AT AT00968506T patent/ATE263223T1/de not_active IP Right Cessation
- 2000-09-29 US US09/677,063 patent/US6531560B1/en not_active Expired - Lifetime
- 2000-09-29 DE DE60009523T patent/DE60009523T2/de not_active Expired - Lifetime
- 2000-09-29 EP EP00968506A patent/EP1216280B1/de not_active Expired - Lifetime
- 2000-09-29 CA CA002384441A patent/CA2384441C/en not_active Expired - Fee Related
- 2000-09-29 MX MXPA02002280A patent/MXPA02002280A/es active IP Right Grant
- 2000-09-29 PL PL00357373A patent/PL357373A1/xx unknown
- 2000-09-29 AU AU78409/00A patent/AU7840900A/en not_active Abandoned
- 2000-09-29 KR KR1020027004123A patent/KR20020034204A/ko not_active Application Discontinuation
- 2000-09-29 BR BR0013169-5A patent/BR0013169A/pt active Pending
- 2000-09-29 ES ES00968506T patent/ES2218230T3/es not_active Expired - Lifetime
- 2000-09-29 JP JP2001526872A patent/JP2003510445A/ja active Pending
- 2000-09-29 WO PCT/US2000/026905 patent/WO2001023484A2/en active IP Right Grant
-
2003
- 2003-01-21 US US10/348,491 patent/US6696159B2/en not_active Expired - Lifetime
- 2003-01-21 US US10/348,492 patent/US6696535B2/en not_active Expired - Lifetime
- 2003-03-25 US US10/348,484 patent/US6855789B2/en not_active Expired - Lifetime
- 2003-06-24 US US10/602,852 patent/US6858693B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US20030171521A1 (en) | 2003-09-11 |
KR20020034204A (ko) | 2002-05-08 |
DE60009523D1 (de) | 2004-05-06 |
ES2218230T3 (es) | 2004-11-16 |
US6855789B2 (en) | 2005-02-15 |
JP2003510445A (ja) | 2003-03-18 |
US20030171520A1 (en) | 2003-09-11 |
US6858693B2 (en) | 2005-02-22 |
MXPA02002280A (es) | 2002-08-12 |
US6531560B1 (en) | 2003-03-11 |
AU7840900A (en) | 2001-04-30 |
DE60009523T2 (de) | 2005-02-03 |
CA2384441C (en) | 2008-01-29 |
US6696535B2 (en) | 2004-02-24 |
WO2001023484A2 (en) | 2001-04-05 |
US20030171519A1 (en) | 2003-09-11 |
US6696159B2 (en) | 2004-02-24 |
PL357373A1 (en) | 2004-07-26 |
WO2001023484A3 (en) | 2002-01-17 |
US20030236341A1 (en) | 2003-12-25 |
CA2384441A1 (en) | 2001-04-05 |
EP1216280B1 (de) | 2004-03-31 |
EP1216280A2 (de) | 2002-06-26 |
BR0013169A (pt) | 2002-05-28 |
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