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MX2024004688A - Proceso para producir espumas rigidas de poliisocianurato mejoradas basadas en polioles de poliester aromaticos y polioles de polieter basados en oxido de etileno. - Google Patents

Proceso para producir espumas rigidas de poliisocianurato mejoradas basadas en polioles de poliester aromaticos y polioles de polieter basados en oxido de etileno.

Info

Publication number
MX2024004688A
MX2024004688A MX2024004688A MX2024004688A MX2024004688A MX 2024004688 A MX2024004688 A MX 2024004688A MX 2024004688 A MX2024004688 A MX 2024004688A MX 2024004688 A MX2024004688 A MX 2024004688A MX 2024004688 A MX2024004688 A MX 2024004688A
Authority
MX
Mexico
Prior art keywords
ethylene oxide
rigid polyisocyanurate
component
aromatic polyester
blowing agent
Prior art date
Application number
MX2024004688A
Other languages
English (en)
Inventor
Olaf Jacobmeier
Sebastian Koch
Tobias Kaluschke
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2024004688A publication Critical patent/MX2024004688A/es

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0038—Use of organic additives containing phosphorus
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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    • C08G18/08—Processes
    • C08G18/14—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
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    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
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    • C—CHEMISTRY; METALLURGY
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  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

La presente invención se refiere a un proceso para producir espumas rígidas de poliisocianurato, en donde (A) poliisocianatos se mezclan con (B) compuestos que tienen átomos de hidrógeno reactivos con isocianato, (C) pirorretardantes, (D) agentes de soplado, (E) catalizador a un índice de isocianato de al menos 220 para obtener una mezcla de reacción y curado para obtener la espuma rígida de poliisocianurato, en donde el Componente (B) contiene al menos un poliol de poliéster aromático (b1) y al menos un poliol de poliéter (b2), el poliol de poliéster (b1) tiene una funcionalidad promedio total de = 3.0 y = 1.7 y el poliol de poliéter (b2) tiene un número de hidroxilo de 160-350 mg de KOH/g y se produce mediante alcoxilación de un iniciador o mezcla de inicio que tiene una funcionalidad promedio total = 3.5 y = 1.5, en donde como el óxido de alquileno para producir poliol de poliéter (b2) se usa al menos 80% en peso de óxido de etileno y comprende al menos 90% de grupos terminales hidroxilo primarios y en donde la relación de masa del Componente (b1) con respecto al Componente (b2) es = 3 y = 1 y el agente de soplado (D) contiene agentes de soplado químicos y físicos, en donde el agente de soplado químico se selecciona del grupo que consiste en mezclas de ácido fórmico y agua y ácido fórmico. La presente invención se refiere además a una espuma rígida de poliisocianurato que se puede obtener mediante el proceso de acuerdo con la invención.
MX2024004688A 2021-10-18 2022-10-17 Proceso para producir espumas rigidas de poliisocianurato mejoradas basadas en polioles de poliester aromaticos y polioles de polieter basados en oxido de etileno. MX2024004688A (es)

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PCT/EP2022/078775 WO2023066838A1 (de) 2021-10-18 2022-10-17 Verfahren zur herstellung von verbesserten polyisocyanurat-hartschaumstoffen auf basis von aromatischen polyesterpolyolen und ethylenoxid basierten polyetherpolyolen

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BRPI0820852B1 (pt) 2007-12-17 2019-11-05 Basf Se processo para a produção de compósitos, e, aparelhagem para a aplicação das misturas de reação líquidas a uma camada externa
EP2184305A1 (de) 2008-11-07 2010-05-12 Bayer MaterialScience AG PIR-Hartschaumstoffe, ein Verfahren zu deren Herstellung und deren Verwendung
WO2011163113A1 (en) * 2010-06-23 2011-12-29 Dow Global Technologies Llc High air flow polyurethane viscoelastic foam
EP2461022A1 (de) * 2010-12-01 2012-06-06 Basf Se Kernschäume aus Polyurethan für die Herstellung von Flügeln, insbesondere für Windkraftanlagen
MX2013006815A (es) 2010-12-16 2013-07-15 Dow Global Technologies Llc Espumas de poliuretano y poliisocianurato.
JP2015504113A (ja) 2012-01-02 2015-02-05 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 硬質ポリウレタンフォームの製造方法、サンドイッチ要素の製造方法及びポリオール成分
CN104080827B (zh) 2012-01-18 2016-04-27 巴斯夫欧洲公司 制备硬质聚氨酯泡沫的方法
EP2828309B1 (de) 2012-03-23 2018-10-10 Basf Se Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen
RU2637027C2 (ru) * 2012-06-01 2017-11-29 Стора Энсо Ойй Композиция в виде содержащей лигнин дисперсии, способ ее изготовления и применение
BR112016012851A2 (pt) * 2013-12-05 2017-08-08 Stora Enso Oyj Uma composição na forma de uma lignina poliol, um método para a produção da mesma e uso da mesma
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US20220098358A1 (en) * 2019-01-31 2022-03-31 Dow Global Technologies Llc Isocyanate reactive compositions
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EP4419574A1 (de) 2024-08-28
TW202317655A (zh) 2023-05-01
US20240309162A1 (en) 2024-09-19
JP2024536549A (ja) 2024-10-04
AU2022372298A1 (en) 2024-05-02

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