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MX2020006629A - Catalizador heterogeneo para produccion de metacrilato de metilo mediante esterificacion oxidativa. - Google Patents

Catalizador heterogeneo para produccion de metacrilato de metilo mediante esterificacion oxidativa.

Info

Publication number
MX2020006629A
MX2020006629A MX2020006629A MX2020006629A MX2020006629A MX 2020006629 A MX2020006629 A MX 2020006629A MX 2020006629 A MX2020006629 A MX 2020006629A MX 2020006629 A MX2020006629 A MX 2020006629A MX 2020006629 A MX2020006629 A MX 2020006629A
Authority
MX
Mexico
Prior art keywords
heterogeneous catalyst
production
methyl methacrylate
oxidative esterification
noble metal
Prior art date
Application number
MX2020006629A
Other languages
English (en)
Inventor
Christopher D Frick
Kirk W Limbach
Jeffrey Herron
Victor J Sussman
Wen Sheng Lee
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of MX2020006629A publication Critical patent/MX2020006629A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/035—Precipitation on carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B01J35/53—Spheres with a core-shell structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un catalizador heterogéneo que comprende un soporte y un metal noble, en donde el soporte comprende silicio, y en donde el catalizador comprende de 0.1 a 40% molar de titanio y de 0.1 a 10% molar de al menos un metal noble en función de los mol totales de átomos de silicio y átomos de metal. El metal noble puede ser, por ejemplo, oro en sílice.
MX2020006629A 2018-01-10 2018-12-13 Catalizador heterogeneo para produccion de metacrilato de metilo mediante esterificacion oxidativa. MX2020006629A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862615502P 2018-01-10 2018-01-10
PCT/US2018/065372 WO2019139719A1 (en) 2018-01-10 2018-12-13 Heterogeneous catalyst for the production of methyl methacrylate by oxidative esterification

Publications (1)

Publication Number Publication Date
MX2020006629A true MX2020006629A (es) 2020-09-22

Family

ID=65041907

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2020006629A MX2020006629A (es) 2018-01-10 2018-12-13 Catalizador heterogeneo para produccion de metacrilato de metilo mediante esterificacion oxidativa.

Country Status (11)

Country Link
US (1) US11577225B2 (es)
EP (1) EP3737496A1 (es)
JP (2) JP2021510344A (es)
KR (1) KR20200105854A (es)
CN (1) CN111511468B (es)
BR (1) BR112020011829B1 (es)
CA (1) CA3085928A1 (es)
MX (1) MX2020006629A (es)
SA (1) SA520412331B1 (es)
SG (1) SG11202005796UA (es)
WO (1) WO2019139719A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112020023925A2 (pt) 2018-06-28 2021-02-09 Dow Global Technologies Llc catalisador heterogêneo, leito de catalisador, e, método para preparar metacrilato de metila.
CN112165987B (zh) * 2018-06-28 2024-05-17 陶氏环球技术有限责任公司 非均相催化剂
BR112022018497A2 (pt) * 2020-03-17 2022-11-01 Dow Global Technologies Llc Catalisador, e, método para preparar metacrilato de metila

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3238894B2 (ja) * 1998-02-09 2001-12-17 三菱レイヨン株式会社 メタクリル酸メチルの製造方法
JP4069242B2 (ja) * 2001-06-04 2008-04-02 株式会社日本触媒 金属粒子担持体及びカルボン酸エステルの製造方法
US7326806B2 (en) * 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
JP2004181359A (ja) * 2002-12-03 2004-07-02 Nippon Shokubai Co Ltd カルボン酸エステル製造用触媒及びカルボン酸エステル製造方法
JP2004181357A (ja) * 2002-12-03 2004-07-02 Nippon Shokubai Co Ltd 金微粒子の剥離抑制方法
BRPI0815166A8 (pt) * 2007-08-13 2016-12-20 Asahi Kasei Chemicals Corp Catalisador para uso na produção de éster de ácido carboxílico, processos para produzir o mesmo, e, para produzir éster de ácido carboxílico
US7531675B1 (en) * 2007-10-24 2009-05-12 Lyondell Chemical Technology, L.P. Direct epoxidation process using improved catalyst composition
BRPI0818684B1 (pt) * 2007-10-26 2018-01-09 Asahi Kasei Kabushiki Kaisha Material suportado de partícula compósita, processos para produzir o mesmo, e , para produzir éster de ácido carboxílico
CN201294443Y (zh) 2008-12-01 2009-08-19 东元总合科技（杭州）有限公司 永磁自启动同步电机转子
MY176555A (en) * 2013-04-19 2020-08-16 Roehm Gmbh Method for producing methylmethacrylate
TW201512168A (zh) * 2013-07-29 2015-04-01 Rohm & Haas 氧化酯化方法
EP2886529A1 (en) * 2013-12-20 2015-06-24 Evonik Industries AG Process for producing methyl methacrylate
US10232353B2 (en) 2015-01-16 2019-03-19 Evonik Röhm Gmbh Gold-based catalyst for the oxidative esterification of aldehydes to obtain carboxylic esters
EP3170558A1 (de) * 2015-11-19 2017-05-24 Evonik Röhm GmbH Gold-basierten katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern
CN107519892B (zh) * 2016-06-20 2019-11-22 中国科学院大连化学物理研究所 一种负载型氧化酯化催化剂及其制备方法和应用
US11111204B2 (en) * 2018-01-10 2021-09-07 Dow Global Technologies Llc Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CN112165987B (zh) * 2018-06-28 2024-05-17 陶氏环球技术有限责任公司 非均相催化剂

Also Published As

Publication number Publication date
JP2021510344A (ja) 2021-04-22
EP3737496A1 (en) 2020-11-18
CN111511468A (zh) 2020-08-07
CA3085928A1 (en) 2019-07-18
BR112020011829A2 (pt) 2020-11-24
KR20200105854A (ko) 2020-09-09
CN111511468B (zh) 2023-07-11
BR112020011829B1 (pt) 2023-05-09
US11577225B2 (en) 2023-02-14
SA520412331B1 (ar) 2024-02-19
SG11202005796UA (en) 2020-07-29
US20200330959A1 (en) 2020-10-22
JP2023175730A (ja) 2023-12-12
WO2019139719A1 (en) 2019-07-18

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