Nguyen et al., 2009 - Google Patents
New efficient reaction media for SET‐LRP produced from binary mixtures of organic solvents and H2ONguyen et al., 2009
- Document ID
- 345621777355103485
- Author
- Nguyen N
- Rosen B
- Jiang X
- Fleischmann S
- Percec V
- Publication year
- Publication venue
- Journal of Polymer Science Part A: Polymer Chemistry
External Links
Snippet
SET‐LRP is mediated by a combination of solvent and ligand that promotes disproportionation of Cu (I) X into Cu (0) and Cu (II) X2. Therefore, the diversity of solvents suitable for SET‐LRP is limited. SET‐LRP of MA in a library of solvents with different …
- 239000000203 mixture 0 title abstract description 29
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
Similar Documents
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|---|---|---|
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| Nguyen et al. | Dramatic acceleration of SET‐LRP of methyl acrylate during catalysis with activated Cu (0) wire | |
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| Zhang et al. | Iron‐Mediated ICAR ATRP of Styrene and Methyl Methacrylate in the Absence of Thermal Radical Initiator | |
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| Percec et al. | Ultrafast synthesis of poly (methyl acrylate) and poly (methyl acrylate)‐b‐poly (vinyl chloride)‐b‐poly (methyl acrylate) by the Cu (0)/tris (2‐dimethylaminoethyl) amine‐catalyzed living radical polymerization and block copolymerization of methyl acrylate initiated with 1, 1‐chloroiodoethane and α, ω‐Di (iodo) poly (vinyl chloride) in dimethyl sulfoxide | |
| Becer et al. | Optimization of the nitroxide‐mediated radical polymerization conditions for styrene and tert‐butyl acrylate in an automated parallel synthesizer | |
| Liu et al. | Copper (0)‐mediated living radical polymerization of acrylonitrile: SET‐LRP or AGET‐ATRP | |
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