[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

Fleischmann et al., 2010 - Google Patents

Copolymerization of methacrylic acid with methyl methacrylate by SET‐LRP

Fleischmann et al., 2010

Document ID
6108701880848213726
Author
Fleischmann S
Percec V
Publication year
Publication venue
Journal of Polymer Science Part A: Polymer Chemistry

External Links

Snippet

Single‐electron transfer living radical polymerization (SET‐LRP) has developed as a reliable, robust and straight forward method for the construction well‐defined polymers. To span an even larger variety of functional monomers, we investigated the copolymerization of …
Continue reading at onlinelibrary.wiley.com (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/16—Halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation

Similar Documents

Publication Publication Date Title
Fleischmann et al. Copolymerization of methacrylic acid with methyl methacrylate by SET‐LRP
Fleischmann et al. SET‐LRP of methyl methacrylate initiated with CCl4 in the presence and absence of air
Fleischmann et al. Set‐LRP of MMA in acetic acid
Nguyen et al. New efficient reaction media for SET‐LRP produced from binary mixtures of organic solvents and H2O
Nguyen et al. SET‐LRP of N, N‐dimethylacrylamide and of N‐isopropylacrylamide at 25° C in protic and in dipolar aprotic solvents
Fleischmann et al. SET‐LRP of acrylates in air
Fleischmann et al. SET‐LRP of methyl methacrylate initiated with sulfonyl halides
Jiang et al. Mimicking “nascent” Cu (0) mediated SET‐LRP of methyl acrylate in DMSO leads to complete conversion in several minutes
Nguyen et al. Dramatic acceleration of SET‐LRP of methyl acrylate during catalysis with activated Cu (0) wire
Jiang et al. Cooperative and synergistic solvent effects in SET‐LRP of MA
Nguyen et al. SET‐LRP of methyl acrylate catalyzed with activated Cu (0) wire in methanol in the presence of air
Nguyen et al. Disproportionating versus nondisproportionating solvent effect in the SET‐LRP of methyl acrylate during catalysis with nonactivated and activated cu (0) wire
Lligadas et al. Ultrafast SET‐LRP of methyl acrylate at 25° C in alcohols
Leng et al. SET-LRP of 2-hydroxyethyl acrylate in protic and dipolar aprotic solvents
Nguyen et al. Acid dissolution of copper oxides as a method for the activation of Cu (0) wire catalyst for SET‐LRP
Zaborniak et al. Temporally controlled ultrasonication‐mediated atom transfer radical polymerization in miniemulsion
Jiang et al. Immortal SET–LRP mediated by Cu (0) wire
Nguyen et al. TREN versus Me6‐TREN as ligands in SET‐LRP of methyl acrylate
Whittaker et al. Synthesis of linear and 4‐arm star block copolymers of poly (methyl acrylate‐b‐solketal acrylate) by SET‐LRP at 25 C
Nguyen et al. The effect of ligand on the rate of propagation of Cu (0)‐wire catalyzed SET‐LRP of MA in DMSO at 25° C
Liu et al. Synthesis of polyacrylonitrile by single‐electron transfer‐living radical polymerization using Fe (0) as catalyst and its adsorption properties after modification
Nilles et al. RAFT polymerization of activated 4‐vinylbenzoates
Nicol et al. Synthesis of double hydrophilic poly (ethylene oxide)‐b‐poly (2‐hydroxyethyl acrylate) by single‐electron transfer–living radical polymerization
Zhai et al. Synthesis of well‐defined pH‐responsive PPEGMEA‐g‐P2VP double hydrophilic graft copolymer via sequential SET‐LRP and ATRP
Rocha et al. Facile Synthesis of Well‐Defined Telechelic Alkyne‐Terminated Polystyrene in Polar Media Using ATRP With Mixed Fe/Cu Transition Metal Catalyst