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Miyaura et al., 1985 - Google Patents

Novel and convenient method for the stereo-and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction …

Miyaura et al., 1985

Document ID
3444309932306578949
Author
Miyaura N
Yamada K
Suginome H
Suzuki A
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

Details of a new and general method for the stereo-and regiospecific synthesis of conjugated alkadienes and alkenynes are described. The reactionof (£)-or (Z)-1- alkenyldisiamylboranes, or 2-((£)-1-alkenyl)-1, 3, 2-benzodioxaboroles readily obtainable by …
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    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/025—Boronic and borinic acid compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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    • C07F17/00—Metallocenes
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    • C07C67/00—Preparation of carboxylic acid esters
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