[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

Ishiyama et al., 1993 - Google Patents

Palladium (0)-catalyzed thioboration of terminal alkynes with 9-(alkylthio)-9-borabicyclo [3.3. 1] nonane derivatives: stereoselective synthesis of vinyl sulfides via the …

Ishiyama et al., 1993

Document ID
7044143712909940003
Author
Ishiyama T
Nishijima K
Miyaura N
Suzuki A
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

The addition of 9-(alkylthio)-9-borabicyclo [3.3. l] nonanes (9-(RS)-9-BBN) Ito terminal alkynes was catalyzed by Pd (PPh3) 4 (3 mol%) to produce 9-[(Z)-2-(alkylthio)-1-alkenyl]-9- BBN derivatives 2 in high yields. The reactions were highly regio-and stereoselective, and …
Continue reading at pubs.acs.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2101/00—Systems containing only non-condensed rings
    • C07C2101/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2101/16—The ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/025—Boronic and borinic acid compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C07F3/10—Mercury compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2102/00—Systems containing two condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2103/00—Systems containing at least three condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms

Similar Documents

Publication Publication Date Title
Ishiyama et al. Palladium (0)-catalyzed thioboration of terminal alkynes with 9-(alkylthio)-9-borabicyclo [3.3. 1] nonane derivatives: stereoselective synthesis of vinyl sulfides via the thioboration-cross-coupling sequence
Semmelhack et al. Reaction of aryl and vinyl halides with zerovalent nickel-preparative aspects and the synthesis of alnusone
Wu et al. Organocalcium chemistry: preparation and reactions of highly reactive calcium
McDermott et al. Thermal decomposition of bis (phosphine) platinum (II) metallocycles
Tückmantel et al. 1, 4‐Addition of triorganozincates and silyldiorganozincates to α, β‐unsaturated ketones
Baba et al. A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium-or nickel-catalyzed reaction of alkenylalanes with alkenyl halides
Morrell et al. Mechanistic studies of nickel catalysis in the cross coupling of aryl halides with alkylmetals. Role of arylalkylnickel (II) species as intermediates
Miyaura et al. Novel and convenient method for the stereo-and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with bromoalkenes and bromoalkynes
Gell et al. Preparation of zirconium (II) complexes by ligand-induced reductive elimination. Bis (. eta. 5-cyclopentadienyl) bis (phosphine) zirconium (II) complexes and their reactions
Chin et al. Control of. eta. 2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies
Russell et al. Reactions of alkylmercurials with heteroatom-centered acceptor radicals
Thomas et al. Metal clusters in catalysis. 6. Synthesis and chemistry of heptakis (tert-butylisocyanide) tetranickel and related clusters
Köbrich Eliminations from olefins
Dhillon Hydroboration and organic synthesis: 9-Borabicyclo [3.3. 1] Nonane (9-BBN)
Jones et al. . alpha.-Lithiosilanes. 4. Silaethylene cycloadditions with conjugated dienes
Imamoto et al. Reactions of Phosphine-Monoiodoboranes with 4, 4'-Di-tert-butylbiphenylide and Electrophiles. Trial of Generation of Tricoordinate Boron Anions and Synthesis of B-Functionalized Phosphine-Boranes
Cohen et al. Copper (I)-promoted thiophenoxide ionization in solution. Simple synthesis of vinyl phenyl sulfides
Card et al. Arene-metal complexes. 12. Reaction of (. eta. 6-benzene) tricarbonylchromium with n-butyllithium
O'Connor et al. (. eta. 5-C5H5)(CO) 2FeCH2S+ (CH3) 2 BF4-: a methylene transfer reagent for the direct cyclopropanation of alkenes
Graybill et al. The Preparation and Reactions of B9H13 (Ligand) Anions
Nakazawa et al. Stepwise displacement of the tertiary phosphine ligand in square-planar [PdR2L2]-type complexes by organolithium reagents with stereochemical retention affording organopalladate complexes
Negishi et al. General one-carbon homologation of organoboranes via. alpha.-thioorganoborate anions
Mochida et al. Platinum-catalyzed bis-germylation of alkynes with organodigermanes and cyclic oligogermanes
Rathke et al. Reaction of organozinc compounds with carbon monoxide
Sietzen et al. Benzylene-linked [PNP] scaffolds and their cyclometalated zirconium and hafnium complexes