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Functionalization of Polyurethane/Urea Copolymers with Amide Groups by Polymer Treatment with Ammonia Plasma

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Abstract

Samples of porous foam from polyurethane/urea copolymers based on polyethylene glycol (PURPEG) were prepared in the form of 1-mm-thick discs of diameter 10 cm and exposed to ammonia plasma created by inductively coupled radiofrequency discharge in either low density (E mode) or high density (H mode). The evolution of surface composition and structure upon plasma treatment was characterized by X-ray photoelectron spectroscopy. Treatment in the H mode caused depletion of oxygen even after 2 s of treatment, whereas treatment in the E mode caused gentle functionalization with amide groups. The concentration of functional groups depended on the discharge power, and the best results were obtained at moderately high power just before the transition from E to H modes.

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Acknowledgments

The research was funded by Slovenian Research Agency ARRS (Project Grant No. L2-6767) and the National Science Foundation of China (NSFC Project No. 21274083) and bilateral project Bi-CN-10-01 and 10-1 (2014).

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Authors and Affiliations

  1. Jozef Stefan Institute, Jamova cesta 39, 1000, Ljubljana, Slovenia

    Alenka Vesel, Rok Zaplotnik, Gregor Primc & Miran Mozetic

  2. Multidisciplinary Research Center, Shantou University, Shantou, 515063, Guangdong, China

    Xiangyu Liu, Kaitian Xu, Kevin C. Chen & Chiju Wei

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  1. Alenka Vesel
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  2. Rok Zaplotnik
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  3. Gregor Primc
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Correspondence to Alenka Vesel.

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Figure S1

XPS spectrum of an untreated PURPEG sample and the calculated surface composition (JPEG 1199 kb)

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Vesel, A., Zaplotnik, R., Primc, G. et al. Functionalization of Polyurethane/Urea Copolymers with Amide Groups by Polymer Treatment with Ammonia Plasma. Plasma Chem Plasma Process 36, 835–848 (2016). https://doi.org/10.1007/s11090-016-9696-3

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  • DOI: https://doi.org/10.1007/s11090-016-9696-3

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