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Search Results (341)

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21 pages, 10062 KiB  
Article
Geochronology and Genesis of the Shuigou Gold Deposit, Qixia-Penglai-Fushan Metallogenic Area, Jiaodong Peninsula, Eastern China: Constraints from SHRIMP U-Pb, 40Ar/39Ar Age, and He-Ar Isotopes
by Zhenjiang Liu, Shaobo Cheng, Changrong Liu, Benjie Gu and Yushan Xue
Minerals 2025, 15(1), 14; https://doi.org/10.3390/min15010014 - 26 Dec 2024
Viewed by 216
Abstract
The Jiaodong Peninsula is renowned for its significant gold reserves, which exceed 4500 tons. In this study, we conducted zircon SHRIMP U-Pb dating, 40Ar/39Ar geochronology, electron probe microanalysis (EPMA) analysis, and He-Ar isotope analysis on samples from the Shuigou gold [...] Read more.
The Jiaodong Peninsula is renowned for its significant gold reserves, which exceed 4500 tons. In this study, we conducted zircon SHRIMP U-Pb dating, 40Ar/39Ar geochronology, electron probe microanalysis (EPMA) analysis, and He-Ar isotope analysis on samples from the Shuigou gold deposit located in the Qixia-Penglai-Fushan metallogenic area of central Jiaodong. This quartz vein-type gold deposit is characterized by three mineralization stages: (I) the quartz-pyrite stage, (II) the quartz-polymetallic sulfide stage, and (III) the calcite stage. In stages I and II, gold primarily exists as native gold or electrum. Preliminary analysis suggests that the deposit contains rare critical metals, including bismuth (Bi), tellurium (Te), and antimony (Sb). The Sb is found as pyrargyrite in stage III, while the other critical elements occur as isomorphisms or nanoparticles within host minerals such as pyrite, native gold, and electrum. Geochronology data indicate that the pre-mineralization Guojialing monzogranite formed around 126 ± 1.6 Ma, the syn-mineralization muscovite formed at approximately 125 Ma, and the post-mineralization diorite porphyrite formed at 120.4 ± 1.8 Ma. The 3He/4He ratios of fluid inclusions in the main-stage pyrite range from 0.26 to 1.26 Ra, and the 40Ar/36Ar ratios vary from 383 to 426.6. These findings suggest that the Shuigou gold deposit formed during the destruction of the North China Craton (NCC), similar to other super-large gold deposits in the Jiaodong Mesozoic gold metallogenic province. Gold mineralization has been influenced by mantle, crustal, and meteoric fluids. Full article
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Figure 1

Figure 1
<p>(<b>a</b>) Tectonic location of the Jiaodong Peninsula; (<b>b</b>) Simplified geological map of the Jiaodong Peninsula, showing the distribution of major tectonic units, Mesozoic igneous rocks, faults, and Au deposits (modified from [<a href="#B7-minerals-15-00014" class="html-bibr">7</a>]). The division of the Northwest Jiaodong, Qixia-Penglai-Fushan, and Mouping-Rushan Metallogenic Areas is based on [<a href="#B2-minerals-15-00014" class="html-bibr">2</a>].</p>
Full article ">Figure 2
<p>(<b>a</b>) Geological sketch map of the Shuigou gold deposit; (<b>b</b>) cross-section of Exploration Line No. 0 in the Shuigou gold deposit.</p>
Full article ">Figure 3
<p>Mine shaft outcrop, hand specimen and microscopic photographs showing the ore texture and structure of the Shuigou Au deposit. (<b>a</b>) Gold-bearing quartz vein cutting the beresite and Guojialing monzogranite. (<b>b</b>) Hand specimens of Guojialing monzogranite. (<b>c</b>) Hand specimens of beresite. (<b>d</b>,<b>e</b>) Hand specimens of stages I and II. (<b>f</b>–<b>h</b>) Photomicrograph of a polished thin section of stage I. (<b>i</b>,<b>j</b>) Photomicrograph of a polished thin section of stage II. (<b>k</b>) Photomicrograph of a polished thin section of stage III. (<b>l</b>) Photomicrograph of a polished thin section of stage I epigenetic oxidized ore. Abbreviations: Arn—argentite, Au—native gold or electrum, Ccp—chalcopyrite, Cv—covellite, Gn—galena, Py—pyrite, Po—pyrrhotite, Pyr—pyrargyrite, Q—quartz, Ser—sericite, and Sp—sphalerite. The diameter of the coin is 19 mm.</p>
Full article ">Figure 4
<p>Mineralization stages and paragenetic sequence of the Shuigou gold deposit.</p>
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<p>EPMA maps of ore minerals from mineralization stage I. The mapped area is pyrite with gold minerals and chalcopyrite.</p>
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<p>EPMA maps of ore minerals from mineralization stage II. The main mineral is sphalerite with chalcopyrite blebs and pyrite. Gold minerals are isolated or in sphalerite.</p>
Full article ">Figure 7
<p>Representative CL images (<b>a</b>,<b>c</b>)and concordia diagrams (<b>b</b>,<b>d</b>) of zircon grains from the Shuigou gold deposit. The dashed-line ellipses labeled 12, 13, and 16 are inherited zircons.</p>
Full article ">Figure 8
<p><sup>40</sup>Ar/<sup>39</sup>Ar plateau and isochron ages for muscovite from the Shuigou gold deposit.</p>
Full article ">Figure 9
<p>(<b>a</b>) Diagrams of <sup>3</sup>He vs. <sup>4</sup>He and (<b>b</b>) <sup>3</sup>He/<sup>4</sup>He vs. <sup>40</sup>Ar/<sup>36</sup>Ar for fluid inclusions in the main-stage pyrites from the Shuigou gold deposit.</p>
Full article ">
18 pages, 11461 KiB  
Article
Identification and Geological Significance of Late Cambrian OIB-Type Volcanic Rocks in the Nailenggeledaban Area, Northern Yili Block
by Da Xu, Ming Cao, Meng Wang, Youxin Chen, Shaowei Zhao, Shengqiang Zhu, Tai Wen and Zhi’an Bao
Minerals 2025, 15(1), 7; https://doi.org/10.3390/min15010007 - 25 Dec 2024
Viewed by 188
Abstract
Paleozoic igneous rocks exposed in the northern Yili Block are thought to have resulted from the subduction of the North Tianshan oceanic crust. However, the exact timing of the transition of the northern margin of the Yili Block from a passive to an [...] Read more.
Paleozoic igneous rocks exposed in the northern Yili Block are thought to have resulted from the subduction of the North Tianshan oceanic crust. However, the exact timing of the transition of the northern margin of the Yili Block from a passive to an active continental margin remains unknown. In this paper, the petrological and geochemical features, zircon U-Pb chronology, Lu-Hf isotopes, and Sr-Nd isotopes of volcanic rocks in the Nailenggeledaban area on the northern margin of the Yili Block were studied. Zircon U-Pb dating results show that the crystallization ages of the volcanic rocks in the Nailenggeledaban area on the northern margin of the Yili Block are 491 ± 2 Ma and 500 ± 2 Ma, suggesting they were formed during the Late Cambrian. Geochemical features show that the volcanic rocks are alkaline basalts with rare earth and trace element distribution patterns similar to OIB, although they exhibit some degree of Zr and Hf depletion. The εHf(t) values of alkaline basalts in the Nailenggeledaban area at the northern Yili Block range from −3.48 to −1.00, with a TDM1 age of 1152 to 1263 Ma. The εNd(t) values range from −3.53 to −0.96, with a TDM1 age of 1471 to 2162 Ma. Combined with geochemical data, the alkaline basalt magma in the Nailenggeledaban area on the northern margin of the Yili Block may be derived from the Mesoproterozoic enriched lithospheric mantle. The composition of the mantle source area is potentially garnet lherzolite, and the magma appears to have been either unaffected or only minimally contaminated by crustal materials during the ascending process. On the basis of the research results of the Early Paleozoic tectonic evolution in the northern margin of the Yili Block, this paper proposes that the volcanic rocks in the Nailenggeledaban area, located on the northern margin of the Yili Block, were formed in a back-arc extensional environment resulting from the subduction of the North Tianshan Ocean (or Junggar Ocean) beneath the northern margin of the Yili Block during the Late Cambrian. Full article
(This article belongs to the Special Issue Geochronology and Geochemistry of Alkaline Rocks)
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Figure 1

Figure 1
<p>(<b>a</b>) Structural architecture of the Central Asian Orogenic Belt and (<b>b</b>) concise geological map outlining the Western Tianshan Orogen Belt in China (according to Gao et al., 2009a [<a href="#B21-minerals-15-00007" class="html-bibr">21</a>]).</p>
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<p>Location map of Late Cambrian basalt samples in the Nailenggeledaban area on the northern YB (modified after Dong et al., 2009 [<a href="#B36-minerals-15-00007" class="html-bibr">36</a>]).</p>
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<p>(<b>a</b>) TS21-02, (<b>b</b>) TS2207 field photos, and (<b>c</b>) TS21-02, (<b>d</b>) TS2207 microscope photos of basalts in the Nailenggeledaban area. Pl: plagioclase, Px: pyroxene.</p>
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<p>(<b>a</b>) Chondrite-normalized REE patterns and (<b>b</b>) space primitive mantle-normalized trace element (normalization values are from Sun et al., 1989 [<a href="#B48-minerals-15-00007" class="html-bibr">48</a>]).</p>
Full article ">Figure 5
<p>Zircon CL images of basalts (in the figure, the red solid circle represents the laser ablation position of zircon age, and the yellow dotted circle represents the analysis position of zircon Lu-Hf isotope).</p>
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<p>Zircon U-Pb age concordia diagrams of basalts in the Nailenggeledaban area.</p>
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<p>ε<sub>Hf</sub>(t)-t-plot for the zircon crystals of basalts in the Nailenggeledaban area.</p>
Full article ">Figure 8
<p>(<sup>87</sup>Sr/<sup>86</sup>Sr)<span class="html-italic"><sub>i</sub></span>-ε<sub>Nd</sub>(t) plot for the basalts in the Nailenggeledaban area (modified after Zimmer et al., 1995 [<a href="#B50-minerals-15-00007" class="html-bibr">50</a>]). DM: depleted mantle, MORB: Mid-Ocean Ridge Basalt, OIB: Ocean Island Basalt.</p>
Full article ">Figure 9
<p>(<b>a</b>) Nb/La-(Th/Nb)<sub>N</sub> diagram and (<b>b</b>) La/Ba-La/Nb diagram of basalt in the Nailenggeledaban area (base map according to Fitton et al., 1991, 1995 [<a href="#B57-minerals-15-00007" class="html-bibr">57</a>,<a href="#B58-minerals-15-00007" class="html-bibr">58</a>]). OIB: Ocean Island Basalt.</p>
Full article ">Figure 10
<p>Harker variation diagram of the basalts in Nailenggeledaban area.</p>
Full article ">Figure 11
<p>Sm/Yb-Sm diagram of basalt in the Nailenggeledaban area (the trends of the partial melting models are derived from Aldanmaz et al., 2000 [<a href="#B61-minerals-15-00007" class="html-bibr">61</a>]). DM: depleted mantle, PM: enriched mantle, N-MORB: Normal Mid-Ocean Ridge Basalt, E-MORB: Enriched Mid-Ocean Ridge Basalt.</p>
Full article ">Figure 12
<p>(<b>a</b>) Zr/Nb-La/Y diagram and (<b>b</b>) La/Ba-La/Nb diagram of basalts in the Nailenggeledaban area (modified after Xia et al., 2019 [<a href="#B62-minerals-15-00007" class="html-bibr">62</a>]). OIB: Ocean Island Basalt, MORB: Mid-Ocean Ridge Basalt, N-MORB: Normal Mid-Ocean Ridge Basalt.</p>
Full article ">Figure 13
<p>(<b>a</b>) Zr/Y-Zr/Nb diagram and (<b>b</b>) Zr/Y-Y/Nb-Zr/Nb diagram of basalts in the Naile-nggeledaban area (modified after Fodor et al., 1984 [<a href="#B63-minerals-15-00007" class="html-bibr">63</a>]).</p>
Full article ">Figure 14
<p>Construction environment discrimination diagram in basalts. (<b>a</b>) [<a href="#B75-minerals-15-00007" class="html-bibr">75</a>]: WPB: within-plate basalt; MORB: mid-ocean ridge basalt; VAB: volcanic arc basalt. (<b>b</b>) [<a href="#B76-minerals-15-00007" class="html-bibr">76</a>]: I: N-MORB area at the edge of plate divergence; II: basalt area at the edge of the convergent plate (II1: ocean island arc basalt; II2: continental margin island arc and continental margin volcanic arc basalt area); III: ocean island, seamount basalt area, and TMORB, E-MORB area; IV: continental intraplate basalt area (IV1: intracontinental rift valley and continental rift valley basalt area; IV2: intracontinental rift alkaline basalt area; IV3: continental extension zone (or initial rift) basalt area); V: mantle plume basalt area. (<b>c</b>) [<a href="#B77-minerals-15-00007" class="html-bibr">77</a>] (Cabanis and Lecolle, 1989). (<b>d</b>) [<a href="#B78-minerals-15-00007" class="html-bibr">78</a>]: AI, AII: in-plate alkaline basalt; AII, C: intraplate tholeiitic basalt, B: enriched mid-ocean ridge basalt, D: depleted mid-ocean ridge basalt; C, D: volcanic arc basalt.</p>
Full article ">
43 pages, 43241 KiB  
Article
Excess 40Ar in Alkali Feldspar and 206,207Pb in Apatite Caused by Fluid-Induced Recrystallisation in a Semi-Closed Environment in Proterozoic (Meta)Granites of the Mt Isa Inlier, NE Australia
by Daniil Popov, Richard Spikings, André Navin Paul, Maria Ovtcharova, Massimo Chiaradia, Martin Kutzschbach, Alexey Ulianov, Gary O’Sullivan, David Chew, Kalin Kouzmanov, Eszter Badenszki, J. Stephen Daly and Joshua H. F. L. Davies
Geosciences 2024, 14(12), 358; https://doi.org/10.3390/geosciences14120358 - 21 Dec 2024
Viewed by 365
Abstract
Interpretation of 40Ar/39Ar dates of alkali feldspar and U-Pb dates of apatite depends on the dominant mechanism of isotopic transport in these minerals, which can be either diffusion or fluid-assisted dissolution-reprecipitation. To clarify the contributions of these processes, we have [...] Read more.
Interpretation of 40Ar/39Ar dates of alkali feldspar and U-Pb dates of apatite depends on the dominant mechanism of isotopic transport in these minerals, which can be either diffusion or fluid-assisted dissolution-reprecipitation. To clarify the contributions of these processes, we have conducted a holistic study of alkali feldspar, apatite and other minerals from the Mt. Isa Inlier in NE Australia. Mineral characterisation by electron microscopy, optical cathodoluminescence imaging and element mapping reveal a complex interplay of textures resulting from magmatic crystallisation, deuteric recrystallisation, local deformation with subsequent higher-temperature alteration, and finally ubiquitous low-temperature alteration. U-Pb and Pb isotopic data for zircon, apatite, fluorite and alkali feldspar suggest that the latter event occurred at ~300 Ma and was associated with fluid-assisted exchange of Pb isotopes between minerals in the same rock, causing some apatite grains to have 207Pb-corrected U-Pb dates that exceed their crystallisation age. However, this event had no unequivocal effect on the 40Ar/39Ar or Rb-Sr systematics of the alkali feldspar, which were disturbed by higher-temperature alteration at ~1450 Ma. The age of the latter event is derived from Rb-Sr data. 40Ar/39Ar dates are very scattered and suggest that 40Ar redistribution proceeded by diffusion in the presence of traps in some places and by dissolution-reprecipitation with variable amounts of recycling in other places. Our results demonstrate the complex effects that interaction with limited amounts of fluids can have on 40Ar/39Ar dates of alkali feldspar and U-Pb dates of apatite and thereby reinforce previous critique of their suitability for thermochronological reconstructions. We further identify and discuss potential implications for noble gas geochronology of groundwaters and fission track dating of apatite. Full article
(This article belongs to the Section Geochemistry)
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Figure 1

Figure 1
<p>Map of metamorphic grades and the major felsic plutons in the southern part of the Mt. Isa Inlier, adapted from [<a href="#B23-geosciences-14-00358" class="html-bibr">23</a>].</p>
Full article ">Figure 2
<p>CL images of the samples giving an overview of rock textures and mineralogy (<b>a</b>–<b>d</b>).</p>
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<p>Representative BSE images and <sup>206</sup>Pb/<sup>238</sup>U dates of zircon from the sample suite. Note the patchy and veining textures that indicate fluid-mediated recrystallisation. These textures are present in all samples, but are particularly common in the Williams, Kalkadoon and Sybella S samples. Analytical 2σ uncertainties are shown, which represent most of the external uncertainty. Circles without numbers attached to them show locations of bad analyses with noisy signals that did not yield dates. Contrast in (<b>a</b>,<b>b</b>) is mostly structural, and zones with higher U content and thus expected radiation damage appear darker. Contrast in (<b>c</b>) is a mix of structural and compositional: some dark zones are richer in U than bright ones (mostly in recrystallised regions), while other dark zones have less U than bright ones (mostly in regions with magmatic texture). Contrast in (<b>d</b>) is mostly compositional, and zones with high U content appear bright.</p>
Full article ">Figure 4
<p>Representative BSE images of U-Th-bearing silicates other than zircon. (<b>a</b>,<b>b</b>) Examples of patchy textures and decomposition of titanite in the Williams (<b>a</b>) and Sybella S (<b>b</b>) samples. (<b>c</b>) An example of decomposed allanite from the Sybella S sample. (<b>d</b>) An example of thorite from the Sybella S sample.</p>
Full article ">Figure 5
<p>Representative CL images and chemical maps for apatite from the Williams sample (<b>a</b>–<b>p</b>) and a schematic summary of the observed textures (<b>q</b>). Numbers in red are either ID-TIMS bulk-grain (those with unspecified locations) or in situ LA-MC-ICP-MS (those with specified locations) <sup>207</sup>Pb-corrected U-Pb dates with 2σ uncertainties that do not include the uncertainty on the initial Pb composition. Note that some grains have a magmatic appearance due to their regular oscillatory zoning and Th/U ratios of ~10, while other grains have replacement zones and veins with lower Th/U ratios or display lower Th/U ratios throughout.</p>
Full article ">Figure 6
<p>Representative CL images and chemical maps for apatite from the Kalkadoon sample (<b>a</b>–<b>e</b>) and schematic summaries of the observed textures in euhedral (<b>f</b>) and anhedral (<b>g</b>) crystals. The number in red is one of the in situ LA-MC-ICP-MS <sup>207</sup>Pb-corrected U-Pb dates with a 2σ uncertainty that does not include the uncertainty on the initial Pb composition. Note the diversity of textures and chemical compositions, and the uncorrelated differences in zoning patterns revealed by different chemical maps and CL images for the same crystals. In our interpretation, regions with Th/U and La/Y ratios of ~10 and ~2, respectively, are relatively fresh, while regions with lower Th/U and La/Y ratios are affected by one or multiple alteration events.</p>
Full article ">Figure 7
<p>Representative CL images and chemical maps for apatite from the Sybella samples (<b>a</b>–<b>i</b>) and a schematic summary of the observed textures (<b>j</b>). Numbers in red are either ID-TIMS bulk-grain (those with unspecified locations) or in situ LA-MC-ICP-MS (those with specified locations) <sup>207</sup>Pb-corrected U-Pb dates with 2σ uncertainties that do not include the uncertainty on the initial Pb composition. Pure yellow regions in the Th/U and La/Y maps for the crystals in (<b>e</b>,<b>g</b>) have much greater values than indicated on the scalebar (compare with Th, U, La and Y maps). Concentrations in minerals other than apatite are expected to be highly inaccurate because all images were obtained by using Ca as the internal standard and assuming that it is homogeneously distributed in the ablated material. The crystal in (<b>b</b>) has a crack along its <span class="html-italic">c</span> axis that formed during sample preparation and is only visible in BSE and optical microscope images (<a href="#app1-geosciences-14-00358" class="html-app">Supplementary Archive</a>). This contrasts with the cracks in the crystals in (<b>d</b>,<b>e</b>), which are visible in chemical maps and thus existed prior to sample preparation. Note that most grains display textures indicative of alteration, such as replacement zones along crystal edges, anastomosing thin veins in more interior parts of crystals and the cracks that are visible in chemical maps.</p>
Full article ">Figure 8
<p>Representative CL (<b>a</b>) and BSE (<b>b</b>,<b>c</b>) images of alkali feldspar from the Williams sample and a schematic summary of the observed textures (<b>d</b>). The images were taken from the surface near (010), and sub-horizontal cracks in them are the (001) cleavage. Note the complex interplay between the textures formed by magmatic crystallisation with subsequent Na-K interdiffusion, such as the resorption zones and the Na-rich lamellae of various scales, some of which are cut by pull-aparts (see [<a href="#B91-geosciences-14-00358" class="html-bibr">91</a>]), and the two broad generations of textures resulting from fluid-induced recrystallisation, namely the replacement perthite veins and the veins of very porous feldspar.</p>
Full article ">Figure 9
<p>Representative CL (<b>a</b>) and BSE (<b>b</b>,<b>c</b>) images of alkali feldspar from the Kalkadoon sample and a schematic summary of the observed textures (<b>d</b>). The images were taken from the surface near (010), and sub-horizontal cracks in them are the (001) cleavage. Note the complex interplay between different feldspar generations. The earliest phase is K-rich feldspar with two types of Na-rich lamellae, one of which is represented by flat platelets oriented along the Murchison plane and the other by flame-like formations that often have serrated boundaries and align with the (001) cleavage. It is cut first by several generation of thick veins that are predominantly composed of K-feldspar and then by myriads of thin veins of highly porous K-feldspar.</p>
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<p>Representative CL images of alkali feldspar from the Sybella S (<b>a</b>) and Sybella N (<b>b</b>) samples and a schematic summary of the observed textures (<b>c</b>). Note that earlier metamorphic Na and K-rich feldspars with brighter CL are cut by irregular veins and patches of replacive Na and K-rich feldspars with darker CL.</p>
Full article ">Figure 11
<p>Tera-Wasserburg plots summarising Pb and U-Pb isotope data for the Williams (<b>a</b>), Kalkadoon (<b>b</b>), Sybella S (<b>c</b>) and Sybella N (<b>d</b>) samples. In situ LA-ICP-MS U-Pb analyses of zircon from each sample are often discordant, pointing to a Pb loss event at ~300 Ma. <sup>207</sup>Pb/<sup>206</sup>Pb ratios of the released Pb fall slightly below the discordia intercepts with the vertical axes. Other points on the vertical axis are the <sup>207</sup>Pb/<sup>206</sup>Pb ratios in alkali feldspar as measured by bulk-grain MC-ICP-MS analysis and in common Pb as predicted by the model of Stacey and Kramers [<a href="#B40-geosciences-14-00358" class="html-bibr">40</a>] for the crystallisation ages of the samples. These are connected via hand-drawn tie-lines of matching colours to the upper discordia-concordia intercepts. U-Pb results for apatite obtained by both in situ LA-MC-ICP-MS and bulk-grain ID-TIMS analysis are considerably scattered and sometimes plot left of the said tie-lines, suggesting that some <sup>207</sup>Pb-corrected U-Pb dates of apatite exceed the inferred crystallisation ages of the rocks they were derived from. The same applies to bulk-grain ID-TIMS U-Pb analyses of fluorite. Data for U-bearing phases are presented as 95% confidence ellipses, which were constructed using Isoplot [<a href="#B105-geosciences-14-00358" class="html-bibr">105</a>]. The same software was used to calculate intercept dates, which are likewise quoted with 95% uncertainty intervals.</p>
Full article ">Figure 12
<p>Ahrens-Wetherill plot with all of our in situ LA-ICP-MS U-Pb analyses of zircon from Proterozoic (meta)granites of the Mt. Isa Inlier. Different samples are shown in different colours, while lines represent discordia fits that were obtained as explained in the main text. Data are presented as 95% confidence ellipses, which were constructed using Isoplot [<a href="#B105-geosciences-14-00358" class="html-bibr">105</a>]. Note that a significant proportion of discordant data points were obtained for each sample, and that these generally delineate trends intersecting the concordia at ~300 Ma.</p>
Full article ">Figure 13
<p>Rb-Sr analyses of alkali feldspar from the Kalkadoon sample. (<b>a</b>) Isochron plot with all the Rb-Sr data that we have acquired. Data are presented as 95% confidence ellipses that were constructed using Isoplot [<a href="#B105-geosciences-14-00358" class="html-bibr">105</a>]. (<b>b</b>) Isochron dates obtained for different combinations of analyses. Of these only dates with MSWD ≤ 1.8 can be deemed statistically acceptable following the criterion of Wendt and Carl [<a href="#B104-geosciences-14-00358" class="html-bibr">104</a>]. External uncertainties are shown at the 95% confidence level.</p>
Full article ">Figure 14
<p><sup>40</sup>Ar/<sup>39</sup>Ar results for alkali feldspar from the Kalkadoon sample obtained by in situ analysis of the crystal shown in <a href="#geosciences-14-00358-f008" class="html-fig">Figure 8</a> (<b>a</b>,<b>b</b>) and by step-heating of conventionally separated aliquot of 0.3–0.5 mm fragments (<b>c</b>,<b>d</b>). (<b>a</b>) Inverse isochron plot for the in situ <sup>40</sup>Ar/<sup>39</sup>Ar data, showing that virtually all analyses are within uncertainty of the horizontal axis. Vertical lines indicate <sup>39</sup>Ar/<sup>40</sup>Ar ratios that correspond to the inferred crystallisation ages of the feldspar regions having blue (zircon upper intercept) and purple (Rb-Sr isochron date for veins) colour in CL images, and also the <sup>40</sup>Ar/<sup>39</sup>Ar plateau date. (<b>b</b>) Comparison of in situ <sup>40</sup>Ar/<sup>39</sup>Ar dates from the same two feldspar types along with probability density functions that they define. (<b>c</b>) Inverse isochron for step-heating <sup>40</sup>Ar/<sup>39</sup>Ar data with the same vertical lines as in (<b>a</b>). Most of the data lie on the horizontal axis. (<b>d</b>) Age spectrum with a poorly defined plateau that was obtained by step-heating analysis. Age spectrum and inverse isochron plots were made using Isoplot [<a href="#B105-geosciences-14-00358" class="html-bibr">105</a>], which was also used to calculate the plateau date with its external uncertainty. Uncertainties other than that of the plateau date are analytical, which for individual analyses covers most of the full uncertainty. All uncertainties are shown at the 95% confidence level.</p>
Full article ">Figure 15
<p>Schematic representation of the effects of fluid-assisted isotope redistribution in a semi-closed environment on the U-Pb systematics of apatite (<b>a</b>) and <sup>40</sup>Ar/<sup>39</sup>Ar systematics of alkali feldspar (<b>b</b>).</p>
Full article ">Figure 16
<p>Illustration of our approach to model chemical and isotopic effects of fluid-induced dissolution-reprecipitation (<b>a</b>) and the obtained results (<b>b</b>–<b>g</b>). See text for details.</p>
Full article ">
19 pages, 7027 KiB  
Article
The Northernmost Effects of the Neo-Tethys Oceanic Slab Subduction Under the Lhasa Terrane: Evidence from the Mazin Rhyolite Porphyry
by Zhuosheng Wang, Nan Wang, Zhibo Liu and Xudong Ma
Minerals 2024, 14(12), 1292; https://doi.org/10.3390/min14121292 - 20 Dec 2024
Viewed by 342
Abstract
The India–Asia collision represents the most significant geological event in the formation of the Tibetan plateau. The subsidence of the Neo-Tethys oceanic slab and the closure of the ocean basin were precursors of the India–Asia collision. The Linzizong volcanic formations, which range in [...] Read more.
The India–Asia collision represents the most significant geological event in the formation of the Tibetan plateau. The subsidence of the Neo-Tethys oceanic slab and the closure of the ocean basin were precursors of the India–Asia collision. The Linzizong volcanic formations, which range in age from the late Cretaceous to early Cenozoic (70–40 Ma), are widely distributed across the Lhasa terrane and are considered products of the closure of the Neo-Tethys oceanic basin and the India–Asia collision. Here, we report a newly identified series of rhyolite porphyries, which share similar age and geochemical features with typical Linzizong volcanic formations. These porphyries are the northernmost extension of Linzizong volcanic formations discovered to date. Zircon U-Pb dating suggests that they formed between 58.8 and 56.1 Ma. These porphyries are characterized by high SiO2 (75.04%–77.82%), total alkali (K2O: 4.71%–5.03%), and Na2O (2.54%–3.63%) values; relatively low Al2O3 (12.30%–13.62%) and MgO (0.13%–0.33%) values; and low Mg# values (15.8–25.7). They also exhibit strong enrichment in light rare earth elements ([La/Yb]N = 3.76–11.08); negative Eu anomalies (Eu/Eu* = 0.10–0.32); Rb, Ba, Th, U, and Pb enrichments; as well as Nb and Ta depletions. The samples have relatively low εNd(t) values (−6.0 to −3.8) and variable zircon εHf(t) values (−6.3 to +3.6). These features suggest they originated from the remelting of the juvenile lower crust of the North Lhasa terrane under high-temperature and extensional conditions. We propose that the Mazin rhyolite porphyries resulted from mantle-derived magma diapirism, triggering juvenile lower crust remelting during Neo-Tethys oceanic slab rollback at the onset of the India–Asia collision. These findings provide new insights into the magmatic processes associated with early collisional tectonics. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
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<p>(<b>a</b>) Topographic map of Tibetan Plateau. (<b>b</b>) Geological map illustrating spatial distribution of Mesozoic-Cenozoic magmatism (modified from [<a href="#B40-minerals-14-01292" class="html-bibr">40</a>]). (<b>c</b>) Geological map of study area, Baingoin County, northern Lhasa Terrane (modified from [<a href="#B41-minerals-14-01292" class="html-bibr">41</a>]). LMF = Luobadui–Milashan Fault; KF = Karakoram Fault; ATF = Altyn Tagh Fault; IYZS = Indus-Yarlung Zangbo suture zone; SNMZ = Shiquan River–Nam Tso mélange zone; JSS = Jinsha suture zone; BNS = Bangong–Nujiang suture zone.</p>
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<p>(<b>a</b>) Long view of Mazin rhyolite porphyry. (<b>b</b>) Photograph of Mazin rhyolite porphyry outcrop. (<b>c</b>) Close-up image of Mazin rhyolite porphyry. (<b>d</b>) Breccias from wall rock associated with Mazin rhyolite porphyry.</p>
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<p>Zircon U-Pb isotope concordia diagrams and representative cathodoluminescence images of zircon from Mazin rhyolite porphyry, Baingoin County, northern Lhasa Terrane. (<b>a</b>) BGA38-3; (<b>b</b>) BGA40-3; ‘n’ denotes number of samples; ‘MSWD’ represents mean square of weighted deviations.</p>
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<p>Diagram of zircon εHf(t) versus zircon <sup>206</sup>Pb/<sup>238</sup>U age (Ma). Zircon εHf(t) data for Xiongmei granite were compiled from [<a href="#B43-minerals-14-01292" class="html-bibr">43</a>]; for Norite, data were compiled from [<a href="#B44-minerals-14-01292" class="html-bibr">44</a>]; and for Xietongmen rhyolite, data were compiled from [<a href="#B29-minerals-14-01292" class="html-bibr">29</a>].</p>
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<p>(<b>a</b>) Total alkalis versus SiO<sub>2</sub> diagram. (<b>b</b>) Diagram of Zr/TiO<sub>2</sub> × 0.0001 versus Nb/Y. (<b>c</b>) A/NK versus A/CNK [where A/NK = molar Al<sub>2</sub>O<sub>3</sub>/(Na<sub>2</sub>O + K<sub>2</sub>O); A/CNK = molar Al<sub>2</sub>O<sub>3</sub>/(CaO + Na<sub>2</sub>O + K<sub>2</sub>O)] [<a href="#B45-minerals-14-01292" class="html-bibr">45</a>]; (<b>d</b>) K<sub>2</sub>O versus SiO<sub>2</sub> [<a href="#B46-minerals-14-01292" class="html-bibr">46</a>].</p>
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<p>(<b>a</b>) Chondrite-normalized rare earth element spidergram and (<b>b</b>) primitive mantle-normalized trace element spidergram for Mazin rhyolite porphyry, Baingoin County, North Lhasa Terrane. Normalized values were sourced from [<a href="#B47-minerals-14-01292" class="html-bibr">47</a>].</p>
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<p>(<b>a</b>) <span class="html-italic">w</span>(SiO<sub>2</sub>)/% versus <span class="html-italic">w</span>(P<sub>2</sub>O<sub>5</sub>)/%; (<b>b</b>) 10000Ga/Al versus <span class="html-italic">w</span>(Zr)/10<sup>−6</sup>; (<b>c</b>) Zr+Ce+Nb+Y versus10000 Ga/Al; (<b>d</b>) TFeO/MgO versus Zr+Nb+Ce+Y (FG = high-grade metamorphic granite, OGT = undifferentiated I-type, S-type, and M-type granites) [<a href="#B65-minerals-14-01292" class="html-bibr">65</a>,<a href="#B66-minerals-14-01292" class="html-bibr">66</a>].</p>
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<p>(<b>a</b>) Sr\Y versus La/Yb. (<b>b</b>) Al<sub>2</sub>O<sub>3</sub>\(FeO<sup>T</sup> + MgO + TiO<sub>2</sub>) versus Al<sub>2</sub>O<sub>3</sub> + FeO<sup>T</sup> + TiO<sub>2</sub> (HP means high pressure; LP means low pressure) [<a href="#B71-minerals-14-01292" class="html-bibr">71</a>].</p>
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<p>(<b>a</b>) Y × 10<sup>−6</sup> versus SiO<sub>2</sub>; (<b>b</b>) Nb/Zr versus Zr × 10<sup>−6</sup>; (<b>c</b>) R2 versus R1; (<b>d</b>) Rb × 10<sup>−6</sup> versus (Y + Nb) × 10<sup>−6</sup> (modified based on [<a href="#B80-minerals-14-01292" class="html-bibr">80</a>,<a href="#B81-minerals-14-01292" class="html-bibr">81</a>,<a href="#B82-minerals-14-01292" class="html-bibr">82</a>]).</p>
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<p>Schematic illustrations depicting the remote effects of the Paleogene geodynamic evolution processes associated with the Neo-Tethys oceanic tectonic regime in the northern Lhasa Terrane.</p>
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22 pages, 7722 KiB  
Article
Late Paleozoic Tectonics of the NW Tarim Block: Insights from Zircon Geochronology and Geochemistry in Xinjiang, China
by Baozhong Yang, Ao Lv, Xiangrong Zhang, Yejin Zhou, Wenxiao Zhou and Ernest Chi Fru
Minerals 2024, 14(12), 1288; https://doi.org/10.3390/min14121288 - 19 Dec 2024
Viewed by 413
Abstract
The Late Paleozoic strata on the northwestern margin of the Tarim Block provide valuable insights into the subduction and collision processes that formed the Southwest Tianshan Orogenic Belt. This study integrates detrital zircon U-Pb dating and sandstone geochemical analysis of the Balikelike and [...] Read more.
The Late Paleozoic strata on the northwestern margin of the Tarim Block provide valuable insights into the subduction and collision processes that formed the Southwest Tianshan Orogenic Belt. This study integrates detrital zircon U-Pb dating and sandstone geochemical analysis of the Balikelike and Kalundaer formations to examine sedimentary provenance and tectonic settings during the Cisuralian–Guadalupian Epoch in the Keping area on the northwestern margin of the Tarim Block. Three of five Precambrian detrital zircon U-Pb age populations, 2500–2300 and 2000–1800 Ma and 900–600 Ma, are likely related to the fragmentation of the Columbia supercontinent and Rodinia’s assembly, respectively. Two Paleozoic detrital zircons, 500–380 Ma, are associated with Paleozoic magmatism. Among them, ~295 Ma zircons are associated with post-collisional extension and emplacement of the Tarim Large Igneous Province. Geochemical analysis of sandstones, coupled with tectonic reconstruction, indicates a passive continental margin setting in the northwestern margin of the Tarim Block during the Silurian Period, later transitioned to a foreland basin from the Pennsylvanian to the Guadalupian Epochs. The crustal transformation from the Middle-late Devonian to Early Mississippian marked the closure of the South Tianshan Ocean (STO), involving a soft collision and significant uplift, with major orogenesis occurring in the Late Guadalupian. Five key stages are identified in the evolution of the foreland basin: (1) Middle-late Devonian to Early Mississippian initiation (remnant ocean basin stage); (2) Late Mississippian to Early Pennsylvanian early stage; (3) Late Pennsylvanian to Early Cisuralian middle stage; (4) the Late Cisuralian stage; and (5) the terminal Guadalupian stage. These findings provide new constraints on when STO closed and propose an innovative foreland basin evolution model during the late post-collisional phase from the Late Mississippian to Guadalupian. Collectively, the data advance our understanding of the tectonic processes that shaped the northwestern Tarim Block, with broader implications for Paleozoic geodynamics. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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<p>(<b>a</b>) Tectonic location of the study area; (<b>b</b>) tectonic geological map of the northern part of the Tarim Block, the western part of the STOB, and adjacent areas (Modified from Han (2015) [<a href="#B17-minerals-14-01288" class="html-bibr">17</a>]). Major faults: ① Nikolaev Line-North Nalati Fault; ② Atbashy–Inylchek–South Nalati Fault; ③ North Tarim Fault; ④ Talas–Ferghana Fault. (<b>c</b>) Geological map of the Keping area. KKF = Kangkelin Formation, comprising limestone, bioclastic limestone, calcareous sandstone, and mudstone; BLF = Balikelike Formation, comprising greyish limestone, grey-black bioclastic limestone, light grey-black mud-limestone, and an interbedded basalt layer; KLF = Kalundaer Formation, comprising lenticular conglomerates, calcareous sandstones, siltstones, and mudstones. (PM301-Section PM 301; PM106-Section PM106; PM107-Section PM107).</p>
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<p>Stratigraphic division scheme and sedimentary environments in the Keping and adjacent areas. S<sub>1</sub><span class="html-italic">k</span>-Kepingtage Fm.; S<sub>2–4</sub><span class="html-italic">t</span>-Tataaiertage Fm.; C<sub>1</sub><span class="html-italic">b</span>-Bashisuogong Fm.; C<sub>2</sub><span class="html-italic">b</span>-Biegentawu Fm.; P<sub>1</sub><span class="html-italic">ku</span>-Kupukuziman Fm.; P<sub>1–2</sub><span class="html-italic">ka</span>-Kaipaizileike Fm.; P<sub>2</sub><span class="html-italic">s</span>-Shajingzi Fm. Fm. = Formation; Thk. = Thickness; Others shown in text. The horizontal lines in the diagram indicate isochrones, not thickness.</p>
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<p>Sampling position in the stratigraphic column of the Cisuralian–Guadalupian Series in the study area. (<b>a</b>) Section PM301; (<b>b</b>) Section PM106; (<b>c</b>) Section PM107.</p>
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<p>Lithological characteristics of the sandstone of the Balikelike and Kalundaer formations (<b>a</b>,<b>b</b>,<b>e</b>,<b>h</b>) Field photographs; Others are micrographs. (-) Under polarized light microscope; (+) Between crossed polarizers. Lvi: Plate-like plagioclase; Lvm: Fine volcanic rock fragments; Q: Quartz. (<b>a</b>). The unconformity contact between the Kangkelin and Keziertage formations; (<b>b</b>–<b>d</b>). The calcareous fine sandstone of the Balikelike Formation from Sample 106-23; (<b>e</b>–<b>g</b>). The tuffaceous fine lithic sandstone of the Kalundaer Formation from Sample 301-38; (<b>h</b>–<b>j</b>). Calcareous fine sandy siltstone of the Kalundaer Formation from Sample 301-71. Other legends are shown in <a href="#minerals-14-01288-f001" class="html-fig">Figure 1</a>, <a href="#minerals-14-01288-f002" class="html-fig">Figure 2</a> and <a href="#minerals-14-01288-f003" class="html-fig">Figure 3</a>.</p>
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<p>The satellite images (<b>a</b>,<b>d</b>) and the field photographs (<b>b</b>,<b>c</b>,<b>e</b>,<b>f</b>) of the mafic dyke and basalt in the study area. (<b>a</b>–<b>c</b>) The mafic dyke cut through the Devonian system, covered by the Kangkelin Formation, with an age of 308 Ma: (<b>d</b>–<b>f</b>) The basalt in the Balikelike Formation, with an age of 287.6 Ma.</p>
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<p>CL images of representative detrital zircons analyzed for U-Pb ages from the Balikelike and Kalundaer formations, NW Tarim. White circles indicate the location of sample spots measured to obtain the U-Pb ages.</p>
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<p>Concordia and histogram-probability density diagrams of detrital zircon U-Pb data for sandstone samples from the Balikelike and Kalundaer formations, NW Tarim. Of all ages, those with more than 10% discordance degrees were excluded. Errors are shown at 1 sigma level. (<b>a</b>,<b>b</b>) Sample B106-23; (<b>c</b>,<b>d</b>) Sample B301-38; (<b>e</b>,<b>f</b>) Sample B301-71.</p>
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<p>(<b>a</b>) UCC-normalized multi-element diagrams for samples of the Balikelike and Kalundaer formations. Normalized to UCC values from Rudnick (2003) [<a href="#B48-minerals-14-01288" class="html-bibr">48</a>]; (<b>b</b>) chondrite-normalized REE patterns for samples of the Balikelike and Kalundaer formations. Normalized to chondritic values from Taylor (1995) [<a href="#B49-minerals-14-01288" class="html-bibr">49</a>]. The standard composition of average UCC after Rudnick (2003) [<a href="#B48-minerals-14-01288" class="html-bibr">48</a>] is shown for comparison. (for sample records refer to <a href="#app1-minerals-14-01288" class="html-app">Supplementary Table S2</a>).</p>
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<p>Histogram plots of &lt;600 Ma ages for (<b>a</b>–<b>c</b>) detrital zircons in the Keping area (for data see <a href="#app1-minerals-14-01288" class="html-app">Supplementary Tables S1 and S2</a>) and magmatic rocks from (<b>d</b>) the northwest margin of the Tarim Block, (<b>e</b>) the STOB, and (<b>f</b>) the YCTB (data sources: references [<a href="#B17-minerals-14-01288" class="html-bibr">17</a>,<a href="#B66-minerals-14-01288" class="html-bibr">66</a>,<a href="#B67-minerals-14-01288" class="html-bibr">67</a>]).</p>
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<p>Geochemical discriminant diagrams of sedimentary tectonic setting of Early-Guadalupian (squares are from the Balikelike Formation sandstone; round dots are from the Kalundaer Formation sandstone). (<b>a</b>) K<sub>2</sub>O/Na<sub>2</sub>O–SiO<sub>2</sub> diagram (after Roser (1986) [<a href="#B82-minerals-14-01288" class="html-bibr">82</a>]); (<b>b</b>) TiO<sub>2</sub>–TFe<sub>2</sub>O<sub>3</sub>+MgO diagram (after Bhatia (1983) [<a href="#B48-minerals-14-01288" class="html-bibr">48</a>]); (<b>c</b>) <span class="html-italic">F<sub>4</sub></span>–<span class="html-italic">F<sub>3</sub></span> diagram (after Roser (1988) [<a href="#B83-minerals-14-01288" class="html-bibr">83</a>]); (<b>d</b>) La/Th–Hf diagram (after Floyd (1987) [<a href="#B81-minerals-14-01288" class="html-bibr">81</a>]); (<b>e</b>) Th–Sc–Zr/10 diagram (after Bhatia (1986) [<a href="#B80-minerals-14-01288" class="html-bibr">80</a>]); (<b>f</b>) La–Th–Sc diagram (after Bhatia (1986) [<a href="#B80-minerals-14-01288" class="html-bibr">80</a>]). A-Oceanic island arc (OIA); B-continental island arc (CIA); C-active continental margin (ACM); D-passive continental margin (PM).</p>
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<p>Geochemical discriminant diagrams of the sedimentary tectonic setting from the Silurian to Mississippian. (<b>a</b>) K<sub>2</sub>O/Na<sub>2</sub>O–SiO<sub>2</sub> diagram (after Roser (1986) [<a href="#B82-minerals-14-01288" class="html-bibr">82</a>]); (<b>b</b>) <span class="html-italic">F<sub>4</sub></span>–<span class="html-italic">F<sub>3</sub></span> diagram (after Roser (1988) [<a href="#B83-minerals-14-01288" class="html-bibr">83</a>]); (<b>c</b>) La/Th–Hf diagram (after Floyd (1987) [<a href="#B81-minerals-14-01288" class="html-bibr">81</a>]). (Blue round dots are from Silurian samples; brown triangle dots are from Devonian sample; green squares are from Mississippian).</p>
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<p>Tectonic evolution model map of the northwest margin of the Tarim Block from the Early-late Devonian to the Guadalupian. (<b>a</b>) The period of the initial development of the foreland basins (the residual marine basin development stage); (<b>b</b>) The period of early foreland basin development; (<b>c</b>) The period of middle foreland basin development stage; (<b>d</b>) The late-stage foreland basin development; (<b>e</b>) The final stage of foreland basin development. (1. Tarim Block (TB), its pre-Carboniferous strata primarily composed of Silurian and Devonian clastic rocks, Cambrian and Ordovician carbonate rocks, and Precambrian crystalline basement rocks. 2. South Tianshan Block (STB). 3. Foreland basin sediment; 4. Seawater. 5. Direction of crustal movement. I. Wedge top. II. Foredeep. III. Forebulge. IV. Back-bulge. RSB. Remnant sea basin).</p>
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14 pages, 9124 KiB  
Article
Formation of the Liaotianshan Volcano in Southeastern China: Implications for the Evolution and Recharge of Crustal Magma System
by Boyun Shi, Lei Liu and Zengxia Zhao
Minerals 2024, 14(12), 1263; https://doi.org/10.3390/min14121263 - 12 Dec 2024
Viewed by 364
Abstract
Large-volume volcanic activity may offer significant insights into the evolution of silicic magma systems. The Liaotianshan volcano represents one of the earliest and best-preserved examples in SE China, comprising two stages of silicic volcanic rocks followed by extrusive rhyolite porphyries within the conduit. [...] Read more.
Large-volume volcanic activity may offer significant insights into the evolution of silicic magma systems. The Liaotianshan volcano represents one of the earliest and best-preserved examples in SE China, comprising two stages of silicic volcanic rocks followed by extrusive rhyolite porphyries within the conduit. In this study, we present petrological and geochemical analyses, along with zircon dating, of the Liaotianshan volcano. LA–ICP–MS zircon U–Pb dating results revealed that two-stage eruptions occurred between approximately 160 and 157 Ma, and the latest batch of magma was extruded from the conduit around 153 Ma. Volcanic rocks from both stages exhibit similar geochemical compositions, characterized by pronounced depletion in high-field-strength elements and enrichment in large-ion lithophile elements, with the majority of zircon εHf(t) values falling within a narrow range of –9.8 to –5.4. In contrast, the extrusive rhyolite porphyries display distinct geochemical characteristics, demonstrating enrichment in heavy rare earth elements relative to light rare earth elements [(La/Yb)N = 0.14–0.61], obvious negative Eu anomalies (Eu/Eu* = 0.01–0.03), and positive Ce anomalies, alongside markedly depleted zircon Hf isotopic compositions. We propose that the volcanic rocks from the two stages were formed by the reworking of the Paleoproterozoic crustal basement with occasional recharge of parental magma, while the extrusive rhyolite porphyries resulted from the mixing of crustal-derived magma and significantly depleted mantle-derived materials. The Liaotianshan volcano was formed in contradiction to the model of melt extraction and crystal accumulation within a magma chamber, instead reflecting the evolutionary history and replenishment dynamics of the crustal magma system. Full article
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<p>Distribution of Late Mesozoic volcanic–intrusive rocks in SE China (modified after [<a href="#B10-minerals-14-01263" class="html-bibr">10</a>]).</p>
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<p>(<b>a</b>) Geological map of the Liaotianshan volcano and sample locations (modified after [<a href="#B14-minerals-14-01263" class="html-bibr">14</a>]); (<b>b</b>) profile of the section from which the samples were collected. Notes: J<sub>1</sub><sup>Y</sup><span class="html-italic">ξγ</span><sup>C</sup>—early Jurassic biotite syenogranite; C<sub>1</sub><span class="html-italic">l</span>—lower Carboniferous Lindi Formation; P<sub>1</sub><span class="html-italic">c</span>—lower Permian Chuanshan Formation; P<sub>2</sub><span class="html-italic">q</span>—middle Permian Qixia Formation. The letters A, B, and C represent the end positions of the section profile in both (<b>a</b>,<b>b</b>).</p>
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<p>Representative photomicrographs of (<b>a,b</b>) the rhyolite porphyries from the volcanic conduit, (<b>c</b>,<b>d</b>) the second-stage lithic-bearing volcanic rocks, and (<b>e</b>,<b>f</b>) the first-stage crystal-rich volcanic rocks, respectively. Notes: Pl—plagioclase; Kfs—K-feldspar; Qtz—quartz.</p>
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<p>Cathodoluminescence images of representative zircons from the Liaotianshan volcano.</p>
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<p>Zircon U–Pb dating results for (<b>a</b>) extrusive rhyolite porphyry, (<b>b</b>–<b>g</b>) second-stage volcanic rocks, and (<b>h</b>) first-stage volcanic rock, respectively.</p>
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<p>Chondrite-normalized REE patterns for the zircons from (<b>a</b>) extrusive rhyolite porphyry, (<b>b</b>) second-stage volcanic rocks, and (<b>c</b>) first-stage volcanic rock, respectively (normalization values after [<a href="#B21-minerals-14-01263" class="html-bibr">21</a>]). Patterns of the inherited grains are not presented.</p>
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<p>Zircon Hf isotopic compositions of the Liaotianshan volcano and crustal basement materials [<a href="#B22-minerals-14-01263" class="html-bibr">22</a>]. The values of the extrusive rhyolite porphyry and first-stage volcanics are from [<a href="#B14-minerals-14-01263" class="html-bibr">14</a>].</p>
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<p>(<b>a</b>) Total alkali [<a href="#B23-minerals-14-01263" class="html-bibr">23</a>], (<b>b</b>) K<sub>2</sub>O, (<b>c</b>) Al<sub>2</sub>O<sub>3</sub>, and (<b>d</b>) Fe<sub>2</sub>O<sub>3</sub><sup>T</sup> vs. SiO<sub>2</sub> diagrams for rocks of the Liaotianshan volcano.</p>
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<p>(<b>a</b>) Chondrite-normalized REE patterns [<a href="#B21-minerals-14-01263" class="html-bibr">21</a>], and (<b>b</b>) primitive-mantle-normalized trace element variation diagram [<a href="#B24-minerals-14-01263" class="html-bibr">24</a>] for rocks of the Liaotianshan volcano.</p>
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<p>(<b>a</b>) (Sm/La)<sub>N</sub> vs. La, (<b>b</b>) Ti vs. Hf, (<b>c</b>) Th/U vs. Th and (<b>d</b>) Zr/Hf vs. Eu/Eu* variations in zircons of the Liaotianshan volcano.</p>
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<p>(<b>a</b>) Rb vs. Sr and (<b>b</b>) Ba vs. Eu/Eu* variations of extrusive and volcanic rocks from the Liaotianshan volcano, which are inconsistent with the melt extraction and residual cumulates model.</p>
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<p>Fluctuation in the SiO<sub>2</sub> contents of the volcanic rocks from the early to late parts of the volcano.</p>
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24 pages, 19611 KiB  
Article
Caledonian Sn Mineralization in the Yuechengling Granitic Batholith, South China: Geochronology, Geochemistry, Zircon Hf Isotopes, and Tourmaline Chemistry and B Isotopes of the Lijia Sn Deposit and Its Hosting Granites
by Yuhang Liu, Congcong Wang, Meng Feng, Yan Cui, Guicong Fang, Zuohai Feng, Wei Fu, Chuan Zhao and Chunzeng Wang
Minerals 2024, 14(12), 1243; https://doi.org/10.3390/min14121243 - 6 Dec 2024
Viewed by 531
Abstract
The Lijia Sn deposit, located in northeastern Guangxi Zhuang Autonomous Region of south China, occurs on the eastern margin of the Yuechengling granite batholith. The Sn deposit contains quartz vein type and greisen type ores and is spatially associated with the medium-coarse-grained biotite [...] Read more.
The Lijia Sn deposit, located in northeastern Guangxi Zhuang Autonomous Region of south China, occurs on the eastern margin of the Yuechengling granite batholith. The Sn deposit contains quartz vein type and greisen type ores and is spatially associated with the medium-coarse-grained biotite granite and the fine-grained tourmaline-bearing biotite granite. LA-ICP-MS zircon U-Pb dating gave an emplacement age of 431.7 ± 2.5 Ma for the medium-coarse-grained biotite granite and of 430.2 ± 2.4 Ma for the fine-grained tourmaline-bearing biotite granite. LA-ICP-MS cassiterite U-Pb dating yielded Tera-Wasserburg lower intercept ages of 429.1 ± 3.4 Ma and 425.7 ± 3.3 Ma for the quartz vein type and greisen type ores, respectively. The ages demonstrate near coeval Caledonian granitic emplacement and Sn mineralization events that have been considered uncommon in south China. Both granites might be derived from partial melting of the Paleoproterozoic basement, as evidenced from zircon ɛHf(t) values of −3.13 to −10.31 and TDM2 from 1627 Ma to 2134 Ma. Three different types of tourmalines have been identified, including (1) tourmaline in quartz–tourmaline nodules in the fine-grained tourmaline-bearing biotite granite (Tur 1), (2) tourmaline in quartz veins (Tur 2a), and (3) tourmaline in greisen (Tur 2b). Most of the tourmalines belong to the alkali group and the schorl-dravite solid-solution series. The hydrothermal tourmalines of Tur 2a and Tur2b showed similar δ11B values to those of the Tur 1 tourmalines in the fine-grained tourmaline-bearing biotite granite, suggesting ore-forming materials derived from granitic magmas. The hydrothermal tourmalines of Tur 2b had slightly lower δ11B values than Tur 1 and Tur 2a tourmalines as a result of progressive 11B depletion during early tourmaline crystallization. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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<p>(<b>a</b>) Inset showing location of the study area in south China. (<b>b</b>) The Miao’ershan-Yuechengling granitic batholiths and the location of the Lijia Sn deposit in northeastern Guangxi [<a href="#B15-minerals-14-01243" class="html-bibr">15</a>,<a href="#B16-minerals-14-01243" class="html-bibr">16</a>].</p>
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<p>Simplified geological map (<b>a</b>) and cross sections (<b>b</b>) of the Lijia Sn deposit.</p>
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<p>Hand specimen photos (<b>a</b>–<b>d</b>), photomicrographs (<b>e</b>–<b>i</b>; cross-polarizing light), and back-scattered electron images (<b>j</b>–<b>l</b>) show characteristics of different types of granites and Sn ores of the Lijia Sn deposit. (<b>a</b>) The medium-coarse-grained biotite granite; (<b>b</b>) the fine-grained tourmaline-bearing biotite granite with tourmaline–quartz nodule; (<b>c</b>) the quartz vein type ore; (<b>d</b>) the greisen type ore; (<b>e</b>) the medium-coarse-grained biotite granite; (<b>f</b>) the fine-grained tourmaline-bearing biotite granite with euhedral-subhedral short prismatic tourmaline aggregates (Tur 1); (<b>g</b>) euhedral cassiterite co-exiting with needle-like or granular tourmaline (Tur 2a) and quartz in quartz vein type ore; (<b>h</b>) euhedral to subhedral cassiterite co-existing with plagioclase, sericite, and quartz in greisen type ore; (<b>i</b>) tourmaline (Tur 2a) in greisen as prismatic and radial aggregates and coexisting with quartz; (<b>j</b>) tourmaline (Tur 1) in tourmaline–quartz nodules; (<b>k</b>,<b>l</b>) tourmalines (Tur 2a and Tur 2b) in quartz vein and greisen. Pl—plagioclase; Kfs—K-feldspar; Bi-biotite; Tur—tourmaline; Cst—cassiterite; Ser—sericite; Ms—muscovite; Q—quartz.</p>
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<p>TIMA mineral phase maps of tourmaline in granite and Sn ores in the Lijia Sn deposit. (<b>a</b>) Tourmaline in the tourmaline–quartz nodules in the fine-grained tourmaline-bearing biotite granite; (<b>b</b>,<b>c</b>) tourmaline (Tur 1) coexists with quartz, albite, K-feldspar, muscovite, and chlorite; (<b>d</b>) tourmaline (Tur 2a) in the quartz vein coexists with cassiterite, muscovite, and quartz; (<b>e</b>,<b>f</b>) altered tourmaline (Tur 2a) and euhedral cassiterite in quartz vein, with secondary muscovite superimposing on tourmaline; (<b>g</b>) tourmaline (Tur 2b) in greisen coexists with scheelite, muscovite, and quartz; (<b>h</b>,<b>i</b>) scheelite and tourmaline (Tur 2b) in greisen.</p>
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<p>Molar A/NK vs. molar A/CNK diagram of granite in the Lijia Sn deposit. Red dots show the medium-coarse-grained biotite granite; blue dots show the fine-grained tourmaline-bearing biotite granite.</p>
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<p>Harker diagrams for the granites in the Lijia Sn deposit. The whole-rock major elemental compositions have been recalculated to 100% on a volatile-free basis.</p>
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<p>Primitive mantle-normalized trace element spidergram (<b>a</b>) and chondrite-normalized REE patterns (<b>b</b>) of the medium-coarse-grained biotite granite and the fine-grained tourmaline-bearing biotite granite. The normalization values for primitive mantle and chondrite are from [<a href="#B48-minerals-14-01243" class="html-bibr">48</a>].</p>
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<p>CL images and U-Pb concordia plots of zircon crystals from the medium-coarse-grained biotite granite (<b>a</b>,<b>b</b>) and the fine-grained tourmaline-bearing biotite granite (<b>c</b>,<b>d</b>).</p>
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<p>Cassiterite CL images (<b>a</b>,<b>b</b>), U-Pb isochron diagrams (<b>c</b>,<b>e</b>), and concordia diagrams (Ter-Wasserburg) (<b>d</b>,<b>f</b>) (samples YCL1908 and YCL1909).</p>
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<p>Histograms of zircon εHf(t) values and TDM<sub>2</sub> (Ga) for the medium-coarse-grained biotite granite (<b>a</b>,<b>b</b>) and the fine-grained tourmaline-bearing biotite granite (<b>c</b>,<b>d</b>).</p>
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<p>(<b>a</b>) Classification of Lijia tourmalines based on X-site occupancy after [<a href="#B49-minerals-14-01243" class="html-bibr">49</a>]; (<b>b</b>) Al-Fe-Mg ternary diagram showing compositional variations of tourmaline from the Lijia granites and ores. 1. Li-rich granitoids and associated pegmatites and aplites; 2. Li-poor granitoids and associated pegmatites and aplites; 3, Fe<sup>3+</sup>-rich quartz-tourmaline rocks (hydrothermally altered granites); 4. Metapelites and meta-psammites coexisting with an Al-saturated phase; 5. Metapelites and meta-psammites not coexisting with an Al-saturated phase; 6. Fe<sup>3+</sup>-rich quartz-tourmaline rocks, calc-silicate rocks, and metapelites; 7. Low Ca meta-ultramafics and Cr- and V-rich metasediments; 8. Meta-carbonates and meta-pyroxenites [<a href="#B50-minerals-14-01243" class="html-bibr">50</a>].</p>
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<p>(<b>a</b>) Fe/(Fe+Mg) vs. Na/(Na+Ca) diagram for classification of tourmaline; (<b>b</b>) plot of Mg vs. Fe of cation occupancies in tourmalines. Same symbols as in <a href="#minerals-14-01243-f011" class="html-fig">Figure 11</a>.</p>
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<p>Percentile box−and−whisker plots showing comparisons of trace elements in tourmalines from the Lijia granite and Sn ores.</p>
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<p>Boron isotopic compositions of tourmaline measured using in situ LA−MC−ICP−MS.</p>
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<p>Plot of ages vs. ɛHf(t) of the Yuechengling granites. The field for Paleoproterozoic basement in Cathaysia block is from [<a href="#B62-minerals-14-01243" class="html-bibr">62</a>,<a href="#B63-minerals-14-01243" class="html-bibr">63</a>,<a href="#B64-minerals-14-01243" class="html-bibr">64</a>].</p>
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<p>(<b>a</b>) Al<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> vs. CaO/Na<sub>2</sub>O diagram and (<b>b</b>) Rb/Sr vs. Rb/Ba diagram for the Yuechengling granites. The mixing curve between the basalt- and pelite-derived melts in (<b>a</b>,<b>b</b>) is from [<a href="#B65-minerals-14-01243" class="html-bibr">65</a>]. The outlined field of partial melts is from [<a href="#B66-minerals-14-01243" class="html-bibr">66</a>] and references therein.</p>
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<p>Measured boron isotope composition as function of host rock type and inferred B sources (modified after [<a href="#B88-minerals-14-01243" class="html-bibr">88</a>]).</p>
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<p>(<b>a</b>) Sn vs. Zn/Nb diagram and (<b>b</b>) Sn vs. Co/Nb diagram for tourmaline from the Lijia Sn deposit (base map after [<a href="#B19-minerals-14-01243" class="html-bibr">19</a>]).</p>
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20 pages, 21100 KiB  
Article
Petrogenesis and Metallogenic Significance of the Demingding Mo-Cu Porphyry Deposit in the Gangdese Belt, Xizang: Insights from U-Pb and Re-Os Geochronology and Geochemistry
by Sudong Shi, Shuyuan Chen, Sangjiancuo Luo, Huan Ren and Xiaojia Jiang
Minerals 2024, 14(12), 1232; https://doi.org/10.3390/min14121232 - 3 Dec 2024
Viewed by 545
Abstract
The 1500 km-long Gangdese magmatic belt is a crucial region for copper polymetallic mineralization, offering valuable insights into collisional porphyry copper systems. This study focuses on the Demingding deposit, a newly identified occurrence of molybdenum–copper (Mo-Cu) mineralization within the eastern segment of the [...] Read more.
The 1500 km-long Gangdese magmatic belt is a crucial region for copper polymetallic mineralization, offering valuable insights into collisional porphyry copper systems. This study focuses on the Demingding deposit, a newly identified occurrence of molybdenum–copper (Mo-Cu) mineralization within the eastern segment of the belt. While the mineralization age, magmatic characteristics, and tectonic context are still under investigation, we examine the deposit’s petrology, zircon U-Pb geochronology, whole-rock chemistry, and Re-Os isotopic data. The Demingding deposit exhibits a typical alteration zoning, transitioning from an inner potassic zone to an outer propylitic zone, which is significantly overprinted by phyllic alteration closely associated with Mo and Cu mineralization. Zircon U-Pb dating of the ore-forming monzogranite porphyries reveals crystallization ages ranging from 21 to 19 Ma, which is indistinguishable within error from the mean Re-Os age of 21.3 ± 0.4 Ma for Mo veins and veinlets hosted by these porphyries. This alignment suggests a late Miocene magmatic event characterized by Mo-dominated mineralization, coinciding with the continuous thickening of the continental crust during the collision of the Indian and Asian continents. The ore-forming porphyries range in composition from granodiorite to monzogranite and are classified as high-K calc-alkaline with adakite-like features, primarily resulting from the partial melting of subduction-modified thickened mafic lower crust. Notably, the ore-forming porphyries exhibit higher fO2 and H2O levels than barren porphyries in this area during crustal thickening, highlighting the significant contributions of hydrous and oxidized fluids from their source to the Mo-Cu mineralization process. Regional data indicate that the Gangdese porphyry metallogenic belt experienced concentrated Cu-Mo mineralization between 17 and 13 Ma. The formation of Mo-dominated deposits such as Demingding and Tangbula in the eastern segment of the belt, with slightly older ages around 20 Ma, underscores the presence of a significant porphyry Mo metallogenic event during this critical post-collision mineralization period. Full article
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<p>Simplified geologic map of Xizang (<b>a</b>) and map showing the simplified tectonic and regional geologic setting of the Gangdese magmatic belt (<b>b</b>) (modified after Lin et al., 2024 [<a href="#B21-minerals-14-01232" class="html-bibr">21</a>]).</p>
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<p>Simplified geological map (<b>a</b>) and cross-section (<b>b</b>,<b>c</b>) of the Demingding Mo-Cu deposit (modified after Ren et al., 2024 [<a href="#B37-minerals-14-01232" class="html-bibr">37</a>]).</p>
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<p>Hand-specimen photographs of the porphyries and Mo-Cu mineralization from the Demingding Mo-Cu deposit. (<b>a</b>) The exposed location of the ore body shows the rock with red alteration. (<b>b</b>,<b>c</b>) Monzogranite porphyry; (<b>d</b>) Widely developed quartz veins in the granite porphyry; (<b>e</b>–<b>h</b>) Monzogranite porphyry with chalcopyrite and molybdenite mineralization.</p>
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<p>Photomicrographs of ore-forming porphyries with mineral assemblages of quartz, biotite, plagioclase, and K-feldspar. (<b>a</b>) Euhedral to subhedral quartz occurs as phenocrysts in the ore-bearing porphyry; (<b>b</b>,<b>c</b>) The phenocrysts in the ore-bearing porphyry are mainly composed of euhedral to subhedral quartz, plagioclase, biotite, and K-feldspar; (<b>d</b>) A small amount of feldspar has been altered to epidote. Abbreviations: Qz-Quartz; Kfs-K-feldspar; Pl-plagioclase; Bi-biotite.</p>
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<p>Representative photomicrographs of mineralization and alteration from the Demingding Mo-Cu deposit. (<b>a</b>–<b>c</b>) Magnetite and biotite from the potassic alteration stage; (<b>d</b>,<b>e</b>) Quartz + biotite + Cu-Fe sulfides vein in the potassic alteration stage; (<b>f</b>) Sericite intergrow with Cu-Fe sulfides in the phyllic alteration; (<b>g</b>) Chlorite-calcite veins occurred during the propylitic zone; (<b>h</b>,<b>i</b>) Chalcopyrite-quartz vein in the ore-forming porphyries; (<b>j</b>–<b>l</b>) Disseminated chalcopyrite and molybdenite in the ore-forming porphyries. The dashed lines represent the boundaries of the vein in the figure.</p>
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<p>Cathodoluminescence images for representative zircon grains from (<b>a</b>) the 25,053 sample, (<b>b</b>) the 25,028 sample, (<b>c</b>) the ZK005-596.35 sample, and (<b>d</b>) the DMD17 sample in the Demingding rhyolite porphyries and monzogranite porphyries.</p>
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<p>Zircon U-Pb concordia diagrams and mean age for the Demingding rhyolite porphyries and monzogranite porphyries.</p>
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<p>(Ce/Nd)/Y vs. 10,000*(Eu/Eu*)/Y (<b>a</b>) and (Ce/Nd)/Y vs. Eu/Eu* (<b>b</b>) diagrams for the Demingding rhyolite porphyries and monzogranite porphyries (modified after Lu et al., 2016 [<a href="#B48-minerals-14-01232" class="html-bibr">48</a>]).</p>
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<p>Temperatures (<b>a</b>), ∆FMQ (<b>b</b>), and H<sub>2</sub>O contents (<b>c</b>) of Demingding rhyolite porphyries and monzogranite porphyries.</p>
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<p>(<b>a</b>) (K<sub>2</sub>O + Na<sub>2</sub>O) vs. SiO<sub>2</sub> diagram (Middlemost, 1994) [<a href="#B49-minerals-14-01232" class="html-bibr">49</a>]; (<b>b</b>) SiO<sub>2</sub> vs. K<sub>2</sub>O diagram (Roberts and Clemens, 1993) [<a href="#B50-minerals-14-01232" class="html-bibr">50</a>]; (<b>c</b>) Sr/Y vs. Y diagram; (<b>d</b>) (La/Yb)<sub>N</sub> vs. (Yb)<sub>N</sub> diagram.</p>
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<p>Chondrite-normalized REE pattern (<b>a</b>) and primitive mantle-normalized spidergram (<b>b</b>) for the rhyolite porphyries and monzogranite porphyries. Data are normalized by values of chondrite and primitive mantle (Sun and McDonough 1989) [<a href="#B51-minerals-14-01232" class="html-bibr">51</a>].</p>
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<p>Molybdenite Re–Os isochron and weighted mean model age plots of the Mo veins and veinlets hosted in these porphyries.</p>
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<p>Dy/Yb vs. SiO<sub>2</sub> diagram of Demingding rhyolite porphyries and monzogranite porphyries.</p>
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<p>Image illustrating the genetic and geodynamic model for the monzogranite porphyries in the Demingding porphyry Mo -Cu deposit.</p>
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17 pages, 7567 KiB  
Article
Temperature Controls Initial REE Enrichment in Peraluminous Granites: Implication from the Parent Granites in the Shangyou Ion-Adsorption Type REE Deposit
by Jiaohua Zou, Chongwen Xu, Qinghe Yan and Jiang Zhu
Minerals 2024, 14(12), 1222; https://doi.org/10.3390/min14121222 - 29 Nov 2024
Viewed by 568
Abstract
The initial enrichment of rare earth elements (REE) in granites plays an important role for the generation of ion-adsorption type REE deposits. It has been summarized that the mineralization-related granitoids are mostly peraluminous, but the enrichment mechanism of REE in this peraluminous granite [...] Read more.
The initial enrichment of rare earth elements (REE) in granites plays an important role for the generation of ion-adsorption type REE deposits. It has been summarized that the mineralization-related granitoids are mostly peraluminous, but the enrichment mechanism of REE in this peraluminous granite is currently not well understood. In this study, we conducted geochronology, petrological, and geochemical investigations on the biotite granite and muscovite granite from the Shangyou complex in Ganzhou, Jiangxi Province. Zircon U-Pb dating indicates that both the biotite granite and muscovite granite generated in the Early Silurian (ca. 433–434 Ma). The high aluminum saturation index and occurrence of muscovite and old zircon cores indicate that they belong to the S-type granite and are derived from the melting of metagreywacke. The relatively higher FeOT contents, Mg# values, and zirconium saturation temperatures (760–873 °C) for the biotite granite resulted from hydrous melting with the involvement of mantle material. In contrast, the muscovite granite with low FeOT contents, Mg# values, Nb/Ta ratios, and zirconium saturation temperatures (748–761 °C) indicates a purely crust-derived melt formed by muscovite dehydration melting. There is a positive correlation of REE contents with the formation temperature and Th contents in both the Shangyou granites and the data collected from global peraluminous granites. This indicates that temperature plays a key role in the REE enrichment in peraluminous granites, as the high-temperature condition could promote the melting of REE-rich and Th-rich accessory minerals of allanite and REE-phosphate and result in the increases in both REE contents and Th contents in the melts. Given the fact that the parent granites for ion-adsorbing REE deposits are mostly peraluminous and generated in the extensional setting in South China, we concluded that peraluminous granite formed under high-temperature extensional tectonic settings favors initial REE enrichment, which further contributes to the formation of ion-adsorbing REE deposits in South China. Full article
(This article belongs to the Section Mineral Deposits)
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<p>(<b>a</b>) The distributions of granitoids and ion-adsorbing REE deposits in South China [<a href="#B3-minerals-14-01222" class="html-bibr">3</a>,<a href="#B30-minerals-14-01222" class="html-bibr">30</a>]; (<b>b</b>) Simplified geological map of the Shangyou pluton.</p>
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<p>Photomicrographs of the granites from Shangyou pluton. (<b>a</b>): biotite granite; (<b>b</b>): schlieren in the biotite granite; (<b>c</b>): muscovite monzogranite; (<b>d</b>): muscovite enclosed by albite. Q: quartz; Kf: K-feldspar; Pl: plagioclase; Bi: biotite; Ap: apatite; Mus: muscovite.</p>
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<p>U-Pb dating for the (<b>a</b>,<b>b</b>) Shangyou biotite granite and (<b>b</b>–<b>d</b>) muscovite granite.</p>
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<p>(<b>a</b>) TAS [<a href="#B36-minerals-14-01222" class="html-bibr">36</a>] and (<b>b</b>) A/CNK vs. A/NK [<a href="#B37-minerals-14-01222" class="html-bibr">37</a>] diagrams for the Shangyou biotite granite and muscovite monzogranite.</p>
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<p>Harker diagrams for the Shangyou biotite granite and muscovite monzogranite.</p>
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<p>Chondrite-normalized REE patterns (<b>a</b>) and primitive mantle-normalized trace element patterns (<b>b</b>) for the Shangyou biotite granite and muscovite monzogranite. Chondrite and primitive mantle data from Sun et al. (1989) [<a href="#B38-minerals-14-01222" class="html-bibr">38</a>].</p>
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<p>Zr + Nb + Ce + Y vs. K<sub>2</sub>O + Na<sub>2</sub>O)/CaO [<a href="#B40-minerals-14-01222" class="html-bibr">40</a>] (<b>a</b>) and ACF classification [<a href="#B40-minerals-14-01222" class="html-bibr">40</a>] (<b>b</b>) diagrams of the Shangyou biotite granite and muscovite monzogranite.</p>
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<p>Discrimination diagrams of source region of (<b>a</b>) Al<sub>2</sub>O<sub>3</sub> + MgO + TiO<sub>2</sub> + FeO<sup>T</sup> vs. Al<sub>2</sub>O<sub>3</sub>/(MgO + TiO<sub>2</sub> + FeO<sup>T</sup>), and (<b>b</b>) CaO + MgO + TiO<sub>2</sub> + FeO<sup>T</sup> vs. CaO/(MgO + TiO<sub>2</sub> + FeO<sup>T</sup>) for Shangyou biotite granite and muscovite monzogranite (after Douce, 1999 [<a href="#B49-minerals-14-01222" class="html-bibr">49</a>]).</p>
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<p>(<b>a</b>) Na<sub>2</sub>O/K<sub>2</sub>O vs. FeO<sup>T</sup> [<a href="#B61-minerals-14-01222" class="html-bibr">61</a>] and (<b>b</b>) SiO<sub>2</sub> vs. Mg# [<a href="#B62-minerals-14-01222" class="html-bibr">62</a>] diagrams for Shangyou biotite granite and muscovite monzogranite.</p>
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<p>TZr (<b>a</b>), Al<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> (<b>b</b>), and Th (<b>c</b>) vs. REE plots of the Shangyou biotite granite and muscovite monzogranite and peraluminous granitoids from worldwide. The data for global peraluminous granitoids are from Georoc: “<a href="http://georoc.mpch-mainz.gwdg.de/georoc" target="_blank">http://georoc.mpch-mainz.gwdg.de/georoc</a> (accessed on 12 June 2024)”.</p>
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17 pages, 13556 KiB  
Article
Structural Characteristics of E–W-Trending Shear Belts in the Northeastern Dabie Orogen, China: Evidence for Exhumation of High–Ultrahigh-Pressure Rocks
by Yongsheng Wang, Xu Zhang and Qiao Bai
Minerals 2024, 14(12), 1205; https://doi.org/10.3390/min14121205 - 26 Nov 2024
Viewed by 399
Abstract
The Dabie–Sulu Orogen hosts the largest area of ultrahigh-pressure (UHP) rocks in the world. There is still significant divergence regarding the exhumation process and mechanism of UHP rocks in the Dabie Orogen, which mainly resulted from the erosion of large volumes of rocks [...] Read more.
The Dabie–Sulu Orogen hosts the largest area of ultrahigh-pressure (UHP) rocks in the world. There is still significant divergence regarding the exhumation process and mechanism of UHP rocks in the Dabie Orogen, which mainly resulted from the erosion of large volumes of rocks in the Orogen during the post-collisional stage. Based on detailed field investigations, this study discovered the occurrence of E–W-trending sinistral shear belts that developed on the northeastern Dabie Orogen. These shear belts formed under greenschist facies conditions and are characterized by steep foliation and gentle mineral lineation. E–W-trending shear belts developed in HP rocks with metamorphic ages ranging from 227 to 219 Ma and were cut by the older phase of ductile shear belts of the Tan-Lu Fault Zone, indicating that they were formed around 219–197 Ma. Based on a comprehensive analysis of existing data, it can be concluded that E–W-trending shear belts were formed during the exhumation process of HP–UHP rocks. When HP rocks returned to the shallow crust and the lower UHP rocks continued to move, stress concentration occurred in the HP rocks and further resulted in the formation of E–W-trending shear belts. The development of E–W-trending shear belts indicates that HP–UHP rocks had essentially returned to the shallow crust by the Late Triassic, marking the near completion of the exhumation process. Full article
(This article belongs to the Special Issue Geochemistry and Geochronology of High-Grade Metamorphic Rocks)
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<p>Geological sketch of the northeastern Dabie Orogen. (<b>a</b>) The location of the Central China Orogenic Belt. (<b>b</b>) A simplified tectonic framework of the Dabie Orogen (modified after Xu et al. [<a href="#B25-minerals-14-01205" class="html-bibr">25</a>]). (<b>c</b>) Detailed structural map of the Tongcheng massif. (<b>d</b>) Lower-hemisphere, equal-area stereograms of poles to the mylonitic foliation and plunges of mineral elongation lineation of the E–W-trending and NE–SW-trending shear belts in the northeastern Dabie Orogen. (<b>e</b>) Cross-sections showing tectonic framework of the Dabie Orogen (Section line in (<b>b</b>)). TLF: Tan-Lu Fault Zone; SMF: Shangcheng–Macheng Fault; XMSZ: Xiaotian–Mozitan shear zone; WSF: Wuhe–Shuihou Fault; HMF: Hualiangting–Mituo Fault; TMF: Taihu–Mamiao Fault; XSF: Xishui Fault; XGF: Xiangfan–Guangji Fault.</p>
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<p>Field photos of gneisses and mylonites in the northeastern Dabie Orogen. (<b>a</b>) Development of brittle NE–SW-trending faults in gneisses with flat-lying foliation; (<b>b</b>) steeply chlorite-bearing ultramylonite and (<b>c</b>) granitic mylonite; (<b>d</b>) S-C structures in marble mylonite indicates sinistral shear; (<b>e</b>,<b>f</b>) development of E–W-trending shear zone in gneisses with flat-lying foliation.</p>
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<p>Micrographs of mylonites from the E–W-trending shear belts in the northeastern Dabie Orogen. (<b>a</b>) Broken feldspar and recrystallized quartz; (<b>b</b>) fine-grain recrystallized quartz with a few larger quartz grains; (<b>c</b>) crossed polarizers and (<b>d</b>) single polarizers micrographs of ultramylonite, with banded chlorite, sericite and a few epidotes, with sinistral shear; (<b>e</b>) σ-type feldspar porphyroclasts in the ultramylonite indicating sinistral shear; (<b>f</b>) e-twin of calcite in the marble mylonite. Quartz within rectangular frame for EBSD testing. Qz: quartz; Fsp: feldspar; Pl: plagioclase; Ep: epidote.</p>
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<p>Quartz CPO pattern of mylonites from E–W-trending shear belts in the northeastern Dabie Orogen. Lower-hemisphere, equal-area projection. <span class="html-italic">n</span>: measured grain numbers. <span class="html-italic">X</span> and <span class="html-italic">Z</span> are principal axes of finite strain. Thin sections are parallel with <span class="html-italic">XZ</span> plane.</p>
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<p>Cathodoluminescence images of a selection of the dated zircons from mylonites in the eastern Dabie Orogen. Red circles indicate analytical sites.</p>
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<p>Concordia diagrams and weighted mean ages of zircons from mylonites in the E–W-trending shear belts in the northeastern Dabie Orogen.</p>
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<p>Schematic diagram of tectonic evolution during syn-collisional exhumation and post-collisional uplift. (<b>a</b>) During the Late Triassic to the Early Jurassic, the subducted SCB was exhumed to the shallow crust and resulted in the formation of a fold-and-thrust belt in the northern Yangtze Block and the Hefei foreland basin in the southern NCB. (<b>b</b>) Post-collisional uplift caused rocks overlying the ND unit to be eroded and rebuilt the tectonic framework of the Dabie Orogen. The diamond represents the outcrop location of HP–UHP rocks, and the numbers in parentheses are the ages when these HP–UHP rocks returned to the shallow crust. The dashed lines show the eroded part of units in the Dabie Orogen. Age data are from Liu et al. [<a href="#B10-minerals-14-01205" class="html-bibr">10</a>], Leech et al. [<a href="#B11-minerals-14-01205" class="html-bibr">11</a>], Ayers et al. [<a href="#B31-minerals-14-01205" class="html-bibr">31</a>], and the references therein. Please refer to the manuscript for abbreviated names.</p>
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<p>Schematic model of the formation of E–W-trending shear belts in the northeastern Dabie Orogen during the Late Triassic. To highlight the relationship between the formation of E–W-trending shear belts and the exhumation process of HP–UHP rocks, we neglected other units within the orogen in this figure. Please refer to the manuscript for abbreviated names.</p>
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24 pages, 10810 KiB  
Article
Petrogenesis of the Shibaogou Mo-W-Associated Porphyritic Granite, West Henan, China: Constrains from Geochemistry, Zircon U-Pb Chronology, and Sr-Nd-Pb Isotopes
by Zhiwei Qiu, Zhenju Zhou, Nan Qi, Pocheng Huang, Junming Yao, Yantao Feng and Yanjing Chen
Minerals 2024, 14(11), 1173; https://doi.org/10.3390/min14111173 - 19 Nov 2024
Viewed by 516
Abstract
The Shibaogou pluton, located in the Luanchuan orefield of western Henan Province in China, is a typical porphyritic granite within the Yanshanian “Dabie-type” Mo metallogenic system. It is mainly composed of porphyritic monzogranite and porphyritic syenogranite. Zircon U-Pb dating results indicate emplacement ages [...] Read more.
The Shibaogou pluton, located in the Luanchuan orefield of western Henan Province in China, is a typical porphyritic granite within the Yanshanian “Dabie-type” Mo metallogenic system. It is mainly composed of porphyritic monzogranite and porphyritic syenogranite. Zircon U-Pb dating results indicate emplacement ages of 150.1 ± 1.3 Ma and 151.0 ± 1.1 Ma for the monzogranite and 148.1 ± 1.0 Ma and 148.5 ± 1.3 Ma for the syenogranite. The pluton is characterized by geochemical features of high silicon, metaluminous, and high-K calc-alkaline compositions, enriched in Rb, U, Th, and Pb, and exhibits high Sr/Y (18.53–58.82), high (La/Yb)N (9.01–35.51), and weak Eu anomalies. These features indicate a source region from a thickened lower crust with garnet and rutile as residual phases at depths of approximately 40–60 km. Sr-Nd-Pb isotopic analyses suggest that the magmatic source is mainly derived from the Taihua and Xiong’er Groups of the Huaxiong Block, mixed with juvenile crustal rocks from the Kuanping and Erlangping Groups of the North Qinling Accretion Belt. Combined with geological and isotopic characteristics, it is concluded that the Shibaogou pluton formed during the compression–extension transition period associated with the collision between the Yangtze Block and the North China Craton, reflecting the complex partial melting processes in the thickened lower crust. The present study reveals that the magmatic–hydrothermal activity at Shibaogou lasted approximately 5 Ma, showing multi-phase characteristics, further demonstrating the close relationship between the pluton and the Mo-W mineralization. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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Figure 1
<p>(<b>a</b>) Tectonic subdivision map of China, showing the location of the Qinling Orogen (modified after [<a href="#B24-minerals-14-01173" class="html-bibr">24</a>]); (<b>b</b>) tectonic subdivision map of the Qinling Orogen, showing the location of the Luanchuan orefield (modified after [<a href="#B24-minerals-14-01173" class="html-bibr">24</a>]); (<b>c</b>) geological map of Luanchuan orefield, showing the granitoid and deposits distribution (modified after [<a href="#B25-minerals-14-01173" class="html-bibr">25</a>]).</p>
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<p>Geological map of Shibaogou deposit (modified after [<a href="#B34-minerals-14-01173" class="html-bibr">34</a>]). The number of drill holes: 1. ZK6002; 2. ZK6204; 3. ZK6402; 4. ZK6602.</p>
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<p>Geological profiles for prospecting lines L64 (<b>a</b>) and L03 (<b>b</b>) of the Shibaogou deposit [<a href="#B34-minerals-14-01173" class="html-bibr">34</a>].</p>
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<p>Photographs showing petrography of the Shibaogou granite. (<b>a</b>) Hand specimen of monzogranite; (<b>b</b>) monzogranite under plane-polarized light (PPL), with euhedral-tabular plagioclase phenocrysts and anhedral microcline and quartz; (<b>c</b>) monzogranite under crossed-nicols light (CN); (<b>d</b>) sericitized monzogranite (PPL), with chloritized biotite and sericitized–kaolinized orthoclase; (<b>e</b>) hand specimen of K-feldspar-altered monzogranite; (<b>f</b>) K-feldspar alteration in monzogranite (PPL), with plagioclase phenocrysts altered to orthoclase, while orthoclase phenocrysts remain unaltered; (<b>g</b>) hand specimen of syenogranite; (<b>h</b>) microphotograph of syenogranite (PPL), with anhedral quartz and orthoclase phenocrysts as the main components; (<b>i</b>) microphotograph of syenogranite (CN). Mineral abbreviations: Bi. biotite; Mc. microcline; Or. orthoclase; Pl. plagioclase; Qz. quartz; Ttn. titanite.</p>
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<p>Cathodoluminescence (CL) images of zircons from the Shibaogou granite. The red circles indicate the locations of U-Pb dating analyses.</p>
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<p>Zircon U-Pb Concordia diagram of samples from the Shibaogou granite. Monzogranite samples: (<b>a</b>) 6602-11, (<b>b</b>) 6204-60. Syenogranite samples: (<b>c</b>) 6402-36, (<b>d</b>) 6002-1.</p>
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<p>Major elements variation diagrams for the Shibaogou granite: (<b>a</b>) SiO<sub>2</sub> vs. K<sub>2</sub>O plots (base map after [<a href="#B47-minerals-14-01173" class="html-bibr">47</a>]); (<b>b</b>) A/NK vs. A/CNK discriminant diagram (base map after [<a href="#B47-minerals-14-01173" class="html-bibr">47</a>]).</p>
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<p>Chondrite-normalized REE patterns ((<b>a</b>,<b>c</b>), normalized values are from [<a href="#B49-minerals-14-01173" class="html-bibr">49</a>]) and primitive mantle-normalized trace element patterns ((<b>b</b>,<b>d</b>), normalized values are from [<a href="#B50-minerals-14-01173" class="html-bibr">50</a>]) for the Shibaogou granite.</p>
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<p>Whole-rock lead isotopic composition diagram of Shibaogou granite. (<b>a</b>) <sup>208</sup>Pb/<sup>204</sup>Pb vs. <sup>206</sup>Pb/<sup>204</sup>Pb diagram; (<b>b</b>) <sup>207</sup>Pb/<sup>204</sup>Pb vs. <sup>206</sup>Pb/<sup>204</sup>Pb diagram. The Pb isotope of strata has been recalculated to 150 Ma, and the initial data are from Taihua and Xiong’er Group [<a href="#B55-minerals-14-01173" class="html-bibr">55</a>,<a href="#B56-minerals-14-01173" class="html-bibr">56</a>,<a href="#B57-minerals-14-01173" class="html-bibr">57</a>,<a href="#B58-minerals-14-01173" class="html-bibr">58</a>], Luanchuan and Guandaokou Group [<a href="#B59-minerals-14-01173" class="html-bibr">59</a>], and Kuanping and Erlangping Group [<a href="#B60-minerals-14-01173" class="html-bibr">60</a>]. The trends for U (upper crust), O (orogenic belt), M (mantle), and L (lower crust) are from [<a href="#B54-minerals-14-01173" class="html-bibr">54</a>].</p>
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<p>Discriminant diagrams for tectonic environment of Shibaogou granite. (<b>a</b>) Granite (Y + Nb)-Rb tectonic diagram (base map from [<a href="#B63-minerals-14-01173" class="html-bibr">63</a>]). (<b>b</b>) Granite Hf-Rb/30-Ta × 3 tectonic diagram (base map from [<a href="#B64-minerals-14-01173" class="html-bibr">64</a>]).</p>
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<p>(<b>a</b>) La/Sm vs. La plot shows a batch partial melting trend [<a href="#B70-minerals-14-01173" class="html-bibr">70</a>]; (<b>b</b>) Ba vs. Sr plot shows the trend of mineral fractionation phase (arrow direction are after Rollinson [<a href="#B71-minerals-14-01173" class="html-bibr">71</a>]), ruling out the influence from the fractionation of plagioclase and hornblende. Bi = biotite, Hb = hornblende, Kf = K-feldspar, Ms = muscovite, Pl = plagioclase.</p>
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<p>The <span class="html-italic">I</span><sub>Sr</sub>-<span class="html-italic">ε</span><sub>Nd</sub>(<span class="html-italic">t</span>) diagram of Shibaogou granite (t = 150 Ma). The Sr-Nd isotope of strata has been recalculated to 150 Ma, and the initial data are from the Taihua Supergroup [<a href="#B57-minerals-14-01173" class="html-bibr">57</a>,<a href="#B86-minerals-14-01173" class="html-bibr">86</a>,<a href="#B87-minerals-14-01173" class="html-bibr">87</a>], Xiong’er Group [<a href="#B58-minerals-14-01173" class="html-bibr">58</a>,<a href="#B88-minerals-14-01173" class="html-bibr">88</a>,<a href="#B89-minerals-14-01173" class="html-bibr">89</a>], Qinling Group [<a href="#B90-minerals-14-01173" class="html-bibr">90</a>], Kuanping Group and Erlangping Group [<a href="#B60-minerals-14-01173" class="html-bibr">60</a>], Yudongzi Group, and Kongling Group [<a href="#B84-minerals-14-01173" class="html-bibr">84</a>,<a href="#B91-minerals-14-01173" class="html-bibr">91</a>].</p>
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<p>Zircon Hf isotopic diagram of Shibaogou granite (t = 150 Ma). Data on Shibaogou granite are from <a href="#app1-minerals-14-01173" class="html-app">Table S6</a>. Data of strata are from the Guandaokou Group [<a href="#B92-minerals-14-01173" class="html-bibr">92</a>], Kuanping and Erlangping Group (the crustal material of North Qinling) [<a href="#B92-minerals-14-01173" class="html-bibr">92</a>,<a href="#B93-minerals-14-01173" class="html-bibr">93</a>], Qinling Group [<a href="#B93-minerals-14-01173" class="html-bibr">93</a>], Xiong’er Group [<a href="#B89-minerals-14-01173" class="html-bibr">89</a>,<a href="#B94-minerals-14-01173" class="html-bibr">94</a>], and Taihua Supergroup [<a href="#B26-minerals-14-01173" class="html-bibr">26</a>,<a href="#B95-minerals-14-01173" class="html-bibr">95</a>,<a href="#B96-minerals-14-01173" class="html-bibr">96</a>,<a href="#B97-minerals-14-01173" class="html-bibr">97</a>].</p>
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<p>Yanshanian tectonic model of Qinling orogen and genesis model of the Shibaogou pluton (modified after [<a href="#B9-minerals-14-01173" class="html-bibr">9</a>]).</p>
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17 pages, 6334 KiB  
Article
Petrogenesis and Geochronology of Late Devonian Intrusive Rocks in Eastern Tianshan, Xinjiang, China: Subduction Constraints of the North Tianshan Ocean
by Yong Meng, Xin Zhang, Kai Wang, Haibo Zhao, Yuan Han, Yaogang Qi and Zuochen Li
Minerals 2024, 14(11), 1144; https://doi.org/10.3390/min14111144 - 11 Nov 2024
Viewed by 628
Abstract
We conducted a study on the petrology, geochemistry, and zircon U–Pb dating of Late Devonian intrusive rocks in the Tulargen area of the Eastern Tianshan Orogenic Belt, Xinjiang, China. These intrusive rocks primarily consist of gabbro (382 ± 5 Ma), tonalite (370.9 ± [...] Read more.
We conducted a study on the petrology, geochemistry, and zircon U–Pb dating of Late Devonian intrusive rocks in the Tulargen area of the Eastern Tianshan Orogenic Belt, Xinjiang, China. These intrusive rocks primarily consist of gabbro (382 ± 5 Ma), tonalite (370.9 ± 2.7 Ma), and biotite monzogranite (362.8 ± 4.4 Ma). Gabbro belongs to the low-K calc-alkaline series of quasi-aluminous rocks, with a high Al2O3 content (16.46–20.34 wt.%) and Mg# value (64.55–67.73). Tonalite and biotite monzogranite, which belong to the high-K calc-alkaline series, are metaluminous or weakly peraluminous and also exhibit high Al2O3 contents (14.6–15.87 wt.%) and Mg# values (40.12–62.47). These rocks are enriched in light rare-earth and large-ion lithophile elements (Rb, Ba, and K) and depleted in heavy rare-earth and high-field-strength elements (e.g., Ta, Nb, and Ti), characteristics typical of island-arc magmatic rocks. Gabbro melts are primarily derived from the mantle and result from the partial melting of a depleted mantle that has undergone fluid metasomatism due to subducted plates. Tonalite exhibits high 176Hf/177Hf and εHf(t) values, with a younger two-stage model age (tDM2) derived from partial juvenile crust melting. The source magma of the biotite monzogranite originated from partial metabasalt melting at a medium crustal depth combined with a new lower crustal material. We concluded that the Late Devonian intrusive rocks in this area formed within the island-arc tectonic setting are associated with the subduction of the North Tianshan Ocean. Full article
(This article belongs to the Special Issue Metallogenesis of the Central Asian Orogenic Belt)
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Figure 1
<p>Simplified tectonic map showing the Central Asia Orogenic Belt [<a href="#B6-minerals-14-01144" class="html-bibr">6</a>] (<b>a</b>); schematic map of the Eastern Tianshan [<a href="#B37-minerals-14-01144" class="html-bibr">37</a>] (<b>b</b>); simplified geological map of Tulargen regions [<a href="#B37-minerals-14-01144" class="html-bibr">37</a>] (<b>c</b>).</p>
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<p>Field photographs and photomicrographs of the Tulargen intrusions in the Eastern Tianshan: (<b>a</b>) hand specimen of gabbro; (<b>b</b>) field photograph showing tonalite; (<b>c</b>) field photograph showing biotite monzogranite; (<b>d</b>) gabbro, consisting of Pl and Pxz; (<b>e</b>) tonalite, consisting of Pl, Q, Bt, Ms and Chl; (<b>f</b>) biotite monzogranite, consisting of Pl, Kfs, Q, Bt, and Mc. Bt = Biotite; Chl = Chlorite; Ep = Epidote; Kfs = Potash feldspar; Mc = Microcline; Ms = Muscovite; Pl = Plagioclase; Px = Pyroxene; Q = Quartz.</p>
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<p>Zircon U–Pb concordia and <sup>206</sup>Pb/<sup>238</sup>U weighted-average diagrams of the studied intrusive rocks: (<b>a</b>) gabbro; (<b>b</b>) tonalite; (<b>c</b>) biotite monzogranite.</p>
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<p>Major-element classification of Devonian magmatic rocks: (<b>a</b>) SiO<sub>2</sub>– K<sub>2</sub>O diagram [<a href="#B50-minerals-14-01144" class="html-bibr">50</a>]; (<b>b</b>) A/CNK–A/NK diagram [<a href="#B51-minerals-14-01144" class="html-bibr">51</a>].</p>
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<p>Chondrite-normalized rare-earth element (REE) patterns (<b>a</b>) and primitive mantle-normalized trace-element patterns (<b>b</b>) for gabbro, tonalite, and biotite monzogranite [<a href="#B52-minerals-14-01144" class="html-bibr">52</a>].</p>
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<p>Harker diagrams for the major selected elements from the studied intrusive rocks.</p>
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<p>Tectonic setting discrimination diagrams for the studied intrusive rocks: (<b>a</b>) Nb–Y and (<b>b</b>) Rb–(Y + Nb) [<a href="#B59-minerals-14-01144" class="html-bibr">59</a>].</p>
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<p>Rock-type discrimination for Late Devonian granite: (<b>a</b>) (K<sub>2</sub>O + Na<sub>2</sub>O)/CaO vs. (Zr + Nb + Ce + Y) diagram; (<b>b</b>) FeO<sup>T</sup>/MgO vs. (Zr + Nb + Ce + Y) diagram [<a href="#B69-minerals-14-01144" class="html-bibr">69</a>].</p>
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<p>Th/Yb vs. Ta/Yb diagrams [<a href="#B73-minerals-14-01144" class="html-bibr">73</a>].</p>
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<p>Compositional fields of experimental melts derived from dehydration melting of various bulk compositions [<a href="#B82-minerals-14-01144" class="html-bibr">82</a>,<a href="#B83-minerals-14-01144" class="html-bibr">83</a>,<a href="#B84-minerals-14-01144" class="html-bibr">84</a>,<a href="#B85-minerals-14-01144" class="html-bibr">85</a>,<a href="#B86-minerals-14-01144" class="html-bibr">86</a>,<a href="#B87-minerals-14-01144" class="html-bibr">87</a>,<a href="#B88-minerals-14-01144" class="html-bibr">88</a>,<a href="#B89-minerals-14-01144" class="html-bibr">89</a>,<a href="#B90-minerals-14-01144" class="html-bibr">90</a>].</p>
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<p>Tectonic setting discrimination diagrams from Jingerquan gabbro: (<b>a</b>) Hf/3-Th-Ta [<a href="#B96-minerals-14-01144" class="html-bibr">96</a>] and (<b>b</b>) Th/Yb-Nb/Yb [<a href="#B97-minerals-14-01144" class="html-bibr">97</a>]. IAT, island arc tholeiitic basalt; CAB, continental-arc basalt; WPAB, within-plate alkaline basalt; WPT, within-plate basalt; N-MORB, normal mid-ridge basalt; E-MORB, enriched mid-ridge basalt; OIB, oceanic island basalt.</p>
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<p>Tectonic model for the intrusive rocks in Eastern Tianshan.</p>
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22 pages, 12521 KiB  
Article
Mineral Chemistry and In Situ LA-ICP-MS Titanite U-Pb Geochronology of the Changba-Lijiagou Giant Pb-Zn Deposit, Western Qinling Orogen: Implications for a Distal Skarn Ore Formation
by Ran Wei, Yitian Wang, Qiaoqing Hu, Xielu Liu, Huijin Guo and Wenrong Hu
Minerals 2024, 14(11), 1123; https://doi.org/10.3390/min14111123 - 6 Nov 2024
Viewed by 496
Abstract
The giant Changba-Lijiagou (Ch-L) Pb-Zn deposit is in the northeast part of the Xicheng ore cluster, Western Qinling Orogen. The ore genesis remains controversial; it could be either a sedimentary exhalative genetic type or an epigenetic hydrothermal genetic type. Here, in situ titanite [...] Read more.
The giant Changba-Lijiagou (Ch-L) Pb-Zn deposit is in the northeast part of the Xicheng ore cluster, Western Qinling Orogen. The ore genesis remains controversial; it could be either a sedimentary exhalative genetic type or an epigenetic hydrothermal genetic type. Here, in situ titanite U-Pb dating for the two kinds of titanite is presented, yielding ages of 212.8 ± 3.0 Ma in the mineralized skarn ore and 214.6 ± 5.1 Ma in the host rock. These ages conform to the previously reported magmatic zircon age (229–211 Ma) based on the in situ zircon U-Pb dating of plutons in this district and the time of large-scale magmatic–hydrothermal activities in Western Qinling Orogen (229–209 Ma). Titanites occurring in mineralized skarn and those that are calcite-hosted are similar to hydrothermal-origin titanites in major element characteristics. The Eu anomalies in the two types of titanite record oxidizing conditions during the mineralization process. A mineral assemblage of garnet, pyroxene, riebeckite, biotite, and potash feldspar, replacing the albite, is well-developed in the deposit. The mineralogical and geochronological characteristics indicate that the Ch-L Pb-Zn deposit is a distal skarn deposit and the result of intensive tectonomagmatic processes in the Xicheng ore cluster during the process of the Late Triassic orogeny. Full article
(This article belongs to the Section Mineral Deposits)
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<p>Geological map of the Xicheng ore cluster, South Qinling belt [<a href="#B8-minerals-14-01123" class="html-bibr">8</a>].</p>
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<p>Geological map of the Ch-L Pb-Zn deposit [<a href="#B8-minerals-14-01123" class="html-bibr">8</a>].</p>
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<p>Stratigraphic column of the Ch-L deposit [<a href="#B13-minerals-14-01123" class="html-bibr">13</a>].</p>
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<p>Cross-section of the Ch-L Pb-Zn deposit [<a href="#B13-minerals-14-01123" class="html-bibr">13</a>].</p>
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<p>Ore types of the Ch-L Pb-Zn deposit: (<b>a</b>) banded ore of brown sphalerite hosted in marble (gray-white layers); (<b>b</b>) medium-grained, euhedral sphalerite (brown) in banded ore, made up of interlayered calcite host and sulfide rock; (<b>c</b>) banded ore of brown sphalerite hosted in schist; (<b>d</b>) breccia ore and quartz breccia cemented by medium-grained sphalerite; (<b>e</b>) quartz–sulfide vein in the banded ore; (<b>f</b>) and the banded ore conformable to contacting the massive ore hosted in the marble, with underground exposure at the Changba mine section. Abbreviations: Sp—sphalerite; Py—pyrite; Gn—galena; Cal—calcite; Qtz—quartz; Mb—marble; Sch—schist.</p>
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<p>Paragenesis of the mineral assemblages displaying the mineralized sequence of the Ch-L Pb-Zn deposit.</p>
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<p>Photos of hand specimens and a photomicrograph from the Ch-L Pb-Zn deposit: (<b>a</b>) banded ore conformable to contacting the massive ore hosted in the marble: Sp-I is coarse-grained, low-Fe sphalerite; Sp-II is fine-grained, high-Fe sphalerite. (<b>b</b>) Photomicrograph of two stages of sphalerite. The features are listed below. (<b>c</b>) Coarse-grained Sp-1 hosted in the barite-bearing marble; (<b>d</b>) titanite hosted in quart-carbonate with Py-1 and Sp-1. (<b>e</b>) Py-1 coexisting with tremolite in marble; (<b>f</b>) coarse-grained Sp-1 with barite in silicified limestone; (<b>g</b>) coarse-grained Sp-1 overgrowth with fine-grained Sp-2 (1–10 μm); the Sp-2 is saccharoidal; (<b>h</b>) coarse-grained Sp-1 with barite in quartz breccia-bearing limestone; (<b>i</b>) fine-grained Sp-2 intergrowth with galena and Py-2 in massive ore; (<b>j</b>) fine-grained Sp-2 intergrowth with pyrrhotite in quart-carbonate; (<b>k</b>) albite replaced by K-feldspar intergrowth with Sp-3 in marble; (<b>l</b>) galena with arsenopyrite in a quartz vein; (<b>m</b>) pyrite growth zoning; (<b>n</b>) chalcopyrite intergrowth with pyrrhotite and K-feldspar in a quartz vein; and (<b>o</b>) chalcopyrite and pyrrhotite developed in the quartz cleavage crack in limestone. Abbreviations: Sp—sphalerite; Py—pyrite; Cpy—chalcopyrite; Gn—galena; Po—pyrrhotite; Apy—arsenopyrite; Q—quartz; Kfs—K—feldspar; Brt—barite; Cal—calcite; Bt—biotite; Ab—albite.</p>
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<p>Photographs, photomicrographs, and BSE images of skarn from the Ch-L Pb-Zn deposit: (<b>a</b>,<b>b</b>) titanite in mineralized and barren hand specimens; (<b>c</b>) marcasite replaced pyrite; (<b>d</b>) garnet in the biotite–quartz schist; (<b>e</b>–<b>h</b>) photomicrographs of titanite in mineralized hand specimens; and (<b>i</b>) photomicrographs of titanite in BSE images of titanite. Abbreviations: Grt—garnet; Bt—biotite; Qtz—quartz; Py—pyrite; Ttn—titanite; Cal—calcite; Kfs—potash feldspar; Sp—sphalerite; Gl—galena; Tr—tremolite.</p>
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<p>The clear negative/positive relationships between TiO<sub>2</sub> (<b>a</b>) or F (<b>b</b>) versus Al<sub>2</sub>O<sub>3</sub> + FeO<sub>T</sub> in titanites from the Ch-L Pb-Zn deposit when comparing magmatic and hydrothermal titanite [<a href="#B17-minerals-14-01123" class="html-bibr">17</a>,<a href="#B18-minerals-14-01123" class="html-bibr">18</a>,<a href="#B19-minerals-14-01123" class="html-bibr">19</a>,<a href="#B20-minerals-14-01123" class="html-bibr">20</a>,<a href="#B21-minerals-14-01123" class="html-bibr">21</a>,<a href="#B22-minerals-14-01123" class="html-bibr">22</a>,<a href="#B23-minerals-14-01123" class="html-bibr">23</a>].</p>
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<p>Chondrite-normalized REE patterns of titanite grains from mineralized skarn (<b>a</b>) and calcite (<b>b</b>) [<a href="#B24-minerals-14-01123" class="html-bibr">24</a>].</p>
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<p>Tera–Wasserburg and weighted average plots of age data for the titanite U-Pb dating of the Ch-L Pb-Zn deposit: (<b>a</b>,<b>b</b>) titanites from the orebodies; (<b>c</b>,<b>d</b>) titanites from the host rock.</p>
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34 pages, 11964 KiB  
Article
Formation and Tectonic Evolution of Ophiolites in the Sabah Area (Borneo, SE Asia)
by Zhiwen Tian, Youfeng Gao, Pujun Wang and Huafeng Tang
Minerals 2024, 14(11), 1078; https://doi.org/10.3390/min14111078 - 25 Oct 2024
Viewed by 1273
Abstract
Zircon U-Pb dating, rock geochemistry, Sr-Nd-Pb, and zircon Hf isotope analyses were conducted on the ultrabasic and basic rocks of ophiolites in the Sabah area (Borneo, SE Asia). The zircon U-Pb ages of ultrabasic and basic rocks range from 248 to 244 Ma, [...] Read more.
Zircon U-Pb dating, rock geochemistry, Sr-Nd-Pb, and zircon Hf isotope analyses were conducted on the ultrabasic and basic rocks of ophiolites in the Sabah area (Borneo, SE Asia). The zircon U-Pb ages of ultrabasic and basic rocks range from 248 to 244 Ma, indicating that the ophiolites already existed in the early Triassic. The rare earth elements of basic rocks in Central Sabah show N-MORB-type characteristics and E-MORB-type characteristics in the northwest and southeast. The εNd(t) values of basic rocks range from 3.66 to 8.73, and the εHf(t) values of zircon in ultrabasic rocks are between −10.2 and −6.1. Trace element analysis shows that the magmatic source was influenced by melts and fluids from the subducting plate of the Paleo-Tethys Ocean. The tectonic evolution of the Sabah area can be traced back to the Early Triassic. At that time, the fast subduction of the Paleo-Tethys Ocean plate and the retreating of the Paleo-Pacific plate resulted in the upwelling of mantle material in relatively small extensional settings, leading to the formation of the ophiolites. From the Jurassic to the Early Cretaceous, the Paleo-Pacific plate was intensely subducted, and the ophiolite intrusion in the Sabah area moved to the continental crust of South China or the Sundaland margin as fore-arc ophiolites. From the Late Cretaceous to the Miocene, with the expansion of the Proto-South China Sea and South China Sea oceanic crust, the ophiolites in the Sabah area drifted southward with microplate fragments and sutured with East Borneo. Full article
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Figure 1
<p>Tectonic sketch map of Southeast Asia [<a href="#B8-minerals-14-01078" class="html-bibr">8</a>,<a href="#B13-minerals-14-01078" class="html-bibr">13</a>,<a href="#B32-minerals-14-01078" class="html-bibr">32</a>]. Yellow square is represented Figure 2a. D, Devonian; P, Permian; P<sub>2</sub>, Late Permian; T, Triassic; J, Jurassic; K, Cretaceous; K<sub>1</sub>, Early Cretaceous; K<sub>2</sub>, Late Cretaceous; E, Paleogene; E<sub>1</sub>, Paleocene; E<sub>2</sub>, Eocene; E<sub>3</sub>, Oligocene; N, Neogene.</p>
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<p>Geological map of the Sabah area and the sample locations ((<b>a</b>), location shown in <a href="#minerals-14-01078-f001" class="html-fig">Figure 1</a>), and related cross section (<b>b</b>), location shown in <a href="#minerals-14-01078-f001" class="html-fig">Figure 1</a>, reference from Hall (2013) [<a href="#B56-minerals-14-01078" class="html-bibr">56</a>].</p>
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<p>Meso- and microphotographs of the Sabah area. (<b>a</b>,<b>b</b>) Sp, Bouma sequence, sandstones, shale, and mudstones; (<b>c</b>,<b>d</b>) radiolarites of Cs; (<b>e</b>,<b>f</b>) pillow lava and basalts of Cs; (<b>g</b>,<b>h</b>) KET, gabbro, and basalt; (<b>i</b>,<b>j</b>) KET, serpentine peridotite; and (<b>k</b>,<b>l</b>) Cb, cataclastic granite. Aug, Augite; Ol, olivine; Pl, Plagioclase; Q, Quartz; Ser, serpentine.</p>
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<p>CL images of zircons from the Sabah area samples.</p>
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<p>LA-ICP-MS U-Pb concordia diagram, weighted mean age diagram, histogram, and probability density distribution diagram. (<b>a</b>) Serpentinite peridotite, KET; (<b>b</b>) gabbro, KET; (<b>c</b>–<b>d</b>) basalt, KET; and (<b>e</b>–<b>f</b>) sandstone from Sp.</p>
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<p>Chondrite-normalized rare earth element abundances (<b>a</b>,<b>c</b>,<b>e</b>) and primitive mantle-normalized trace element abundances (<b>b</b>,<b>d</b>,<b>f</b>) for the igneous rocks of KET and Cs in the Sabah area. The normalizing values are from Sun and McDonough (1989) [<a href="#B66-minerals-14-01078" class="html-bibr">66</a>].</p>
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<p>Discrimination diagrams for the tectonic setting of the host rocks of zircon (<b>a</b>–<b>d</b>), after Schulz et al. (2006) [<a href="#B91-minerals-14-01078" class="html-bibr">91</a>]), zircon Hf versus U/Yb and Y versus U/Yb diagrams (<b>e</b>,<b>f</b>), after Grimes et al. (2007, 2015) [<a href="#B92-minerals-14-01078" class="html-bibr">92</a>,<a href="#B93-minerals-14-01078" class="html-bibr">93</a>]). Sabah ophiolites and non-ophiolite basement data from Wang et al. (2023) [<a href="#B14-minerals-14-01078" class="html-bibr">14</a>]. KDS-Cs-a and BLR-Cs-a data from Tian et al. (2021) [<a href="#B94-minerals-14-01078" class="html-bibr">94</a>].</p>
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<p>Plots of Zr/Nb versus La/Yb ((<b>a</b>), after Göncüoglu et al. (2010) [<a href="#B103-minerals-14-01078" class="html-bibr">103</a>]), La/Sm versus Sm/Yb ((<b>b</b>), after Pearce et al. (2008) [<a href="#B104-minerals-14-01078" class="html-bibr">104</a>]), Nb/Yb versus Th/Yb (<b>c</b>), after Pearce et al. (2008) [<a href="#B104-minerals-14-01078" class="html-bibr">104</a>]), Nb/Yb versus TiO<sub>2</sub>/Yb (<b>d</b>), after Pearce et al. (2008) [<a href="#B104-minerals-14-01078" class="html-bibr">104</a>]), Ti/1000 versus V (<b>e</b>), after Shervais (1982) [<a href="#B105-minerals-14-01078" class="html-bibr">105</a>]), and 2Nb versus Zr/4 versus Y (<b>f</b>), after Meschede (1986) [<a href="#B106-minerals-14-01078" class="html-bibr">106</a>]) for the mafic rocks from the Sabah ophiolites. Sabah ophiolite data from Wang et al. (2023) [<a href="#B14-minerals-14-01078" class="html-bibr">14</a>]. Palawan ophiolite data from Gibaga et al. (2020) and Dycoco et al. (2021) [<a href="#B46-minerals-14-01078" class="html-bibr">46</a>,<a href="#B47-minerals-14-01078" class="html-bibr">47</a>]. Kuching mafic rock data from Wang et al. (2021) [<a href="#B51-minerals-14-01078" class="html-bibr">51</a>]. Meratus complex data from Wang et al. (2022) [<a href="#B16-minerals-14-01078" class="html-bibr">16</a>]. Philippine ophiolite data from Yumul et al. (2013), Deng et al. (2015), and Guotana et al. (2017) [<a href="#B107-minerals-14-01078" class="html-bibr">107</a>,<a href="#B108-minerals-14-01078" class="html-bibr">108</a>,<a href="#B109-minerals-14-01078" class="html-bibr">109</a>]. South Schwaner Mountains and South China Sea mafic–intermediate rock data from Wang et al. (2022) [<a href="#B52-minerals-14-01078" class="html-bibr">52</a>]. Hainan Island mafic rock data from Tang et al. (2010), Chen et al. (2014), Zhou et al. (2015), Shen et al. (2018), and Liu et al. (2022) [<a href="#B101-minerals-14-01078" class="html-bibr">101</a>,<a href="#B102-minerals-14-01078" class="html-bibr">102</a>,<a href="#B110-minerals-14-01078" class="html-bibr">110</a>,<a href="#B111-minerals-14-01078" class="html-bibr">111</a>,<a href="#B112-minerals-14-01078" class="html-bibr">112</a>].</p>
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<p>Plots of Th/La versus Nb/La ((<b>a</b>), after [<a href="#B14-minerals-14-01078" class="html-bibr">14</a>]), Th/Zr versus Nb/Zr ((<b>b</b>), after [<a href="#B14-minerals-14-01078" class="html-bibr">14</a>]), La/Sm versus Sr/Th ((<b>c</b>), after [<a href="#B14-minerals-14-01078" class="html-bibr">14</a>]), Th/Nb versus Ba/Th (<b>d</b>), after [<a href="#B114-minerals-14-01078" class="html-bibr">114</a>]), Th/Nb versus Ba/La ((<b>e</b>), after [<a href="#B114-minerals-14-01078" class="html-bibr">114</a>]), and Th/Zr versus U/Th ((<b>f</b>), after [<a href="#B115-minerals-14-01078" class="html-bibr">115</a>]) for the basalt from the Sabah ophiolites.</p>
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<p>Initial <sup>87</sup>Sr/<sup>86</sup>Sr versus ε<sub>Nd</sub>(t) (<b>a</b>), <sup>206</sup>Pb/<sup>204</sup>Pb versus <sup>208</sup>Pb/<sup>204</sup>Pb and <sup>207</sup>Pb/<sup>204</sup>Pb (<b>b</b>–<b>c</b>), and Δβ versus Δγ (<b>d</b>). NHRL, with a northern hemisphere reference line. Data are from Zindler and Hart (1986), Burton-Johnson et al. (2020), and Wang et al. (2018, 2020, 2021, 2022, 2023) [<a href="#B14-minerals-14-01078" class="html-bibr">14</a>,<a href="#B16-minerals-14-01078" class="html-bibr">16</a>,<a href="#B19-minerals-14-01078" class="html-bibr">19</a>,<a href="#B25-minerals-14-01078" class="html-bibr">25</a>,<a href="#B41-minerals-14-01078" class="html-bibr">41</a>,<a href="#B53-minerals-14-01078" class="html-bibr">53</a>,<a href="#B54-minerals-14-01078" class="html-bibr">54</a>,<a href="#B100-minerals-14-01078" class="html-bibr">100</a>,<a href="#B116-minerals-14-01078" class="html-bibr">116</a>,<a href="#B117-minerals-14-01078" class="html-bibr">117</a>,<a href="#B118-minerals-14-01078" class="html-bibr">118</a>,<a href="#B119-minerals-14-01078" class="html-bibr">119</a>,<a href="#B120-minerals-14-01078" class="html-bibr">120</a>].</p>
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<p>Hf isotopic composition versus age of the zircons from sample KDS-KET-a: (<b>a</b>) εHf(<span class="html-italic">t</span>)-<span class="html-italic">t</span> diagram and (<b>b</b>) <sup>176</sup>Hf/<sup>177</sup>Hf-<span class="html-italic">t</span> diagram. The chondrite and depleted mantle lines are from Blichert-Toft and Albarède (1997) and Griffin et al. (2000) [<a href="#B61-minerals-14-01078" class="html-bibr">61</a>,<a href="#B62-minerals-14-01078" class="html-bibr">62</a>].</p>
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<p>Tectonic settings and processes of continental margin (<b>a</b>), supra-subduction zone (<b>b</b>), and volcanic (<b>c</b>) ophiolite types, with columnar sections depicting the simplified structural architecture of the ophiolite type [<a href="#B121-minerals-14-01078" class="html-bibr">121</a>]. Emplacement pattern of ophiolites (<b>d</b>) [<a href="#B2-minerals-14-01078" class="html-bibr">2</a>].</p>
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<p>Tectonic cartoons showing the evolution of the Sabah ophiolite. (<b>a</b>) In the Triassic or older Sabah ophiolite formed. (<b>b</b>) The Jurassic -Early Cretaceous, Sabah ophiolite emplaced on the continental crust basement. (<b>c</b>) The late Late Cretaceous, Sabah and Palawan ophiolites split and drifted southward from the margin of the Dangerous Grounds or Sundaland. (<b>d</b>) The Oligocene, the suturing of the Sabah and Palawan ophiolites with East Borneo. (<b>e</b>) The Miocene, the Sabah orogeny leading to ophiolite exposure. DGS, Dangerous Grounds; EB, East Borneo; PSCS, Proto-South China Sea; SCB, South China Block; SCS, South China Sea; SD, Sundaland.</p>
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<p>Detrital zircon discrimination diagram (Cawood et al., 2012) [<a href="#B133-minerals-14-01078" class="html-bibr">133</a>]. A, convergent settings; B, collisional settings; C, extensional settings. CA, crystallization age; DA, deposition age. The KDS-Cs-a and BLR-Cs-a detrital zircon age data from Tian et al. (2021) [<a href="#B94-minerals-14-01078" class="html-bibr">94</a>].</p>
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39 pages, 18863 KiB  
Article
Provenance of the He 8 Member of the Upper Paleozoic Shihezi Formation, Ordos Basin, China: Insights from Heavy Minerals, Paleocurrents, Detrital Zircon Chronology, and Hf Isotopes
by Wenqi Pan, Ziwen Jiang, Liyong Fan, Zhengtao Zhang, Zhichao Li, Shangwei Ma, Zhendong Wang, Xiangjun Li and Weiran Zhao
Minerals 2024, 14(11), 1076; https://doi.org/10.3390/min14111076 - 25 Oct 2024
Viewed by 597
Abstract
The Ordos Basin is located in the western part of the North China Craton. The Upper Paleozoic Shihezi Formation, particularly the He 8 Member, is one of the main gas-bearing strata. However, the source areas for the north and south sections have not [...] Read more.
The Ordos Basin is located in the western part of the North China Craton. The Upper Paleozoic Shihezi Formation, particularly the He 8 Member, is one of the main gas-bearing strata. However, the source areas for the north and south sections have not been clearly distinguished, which has constrained oil and gas exploration to some extent. Therefore, understanding the source rock evolution of He 8 Member in both the south and north basins will provide a favorable theoretical basis for oil and gas exploration. The provenance of the He 8 Member of the Shihezi Formation in the Ordos Basin has not been well defined until now. Seven wellbore sandstone samples and three field outcrop sandstone samples from the He 8 Member in the Ordos Basin were analyzed. Based on zircon U–Pb dating and Lu–Hf isotope analyses, zircon assemblages of 520–386 Ma and 350–268 Ma in the southern Ordos Basin might have originated from the North Qinling Orogenic Belt (NQinOB) and the North Qilian Orogenic Belt (NQiOB); the 350–268 Ma age group of zircons from the NQinOB, and a large number of ~320–260 Ma detrital zircons supplied to the southern Ordos Basin by the NQinOB suggest that NQinOB magmatic and/or metamorphic events may have occurred in the NQinOB during the ~320–260 Ma period. From ~320–260 Ma, the NQinOB might have experienced significant tectonic activity that has not been fully revealed thus far. The zircons from 2600–2300 Ma, 2000–1600 Ma, and 450–300 Ma in the northern Ordos Basin might have been derived from the Trans-North China Orogenic Belt (TNCO), the Khondalite Belt, the Yinshan Belt, and the Alxa Belt. The paleocurrent and heavy mineral analyses determined that there are certain differences between the northern Ordos Basin and southern Ordos Basin, with unstable minerals such as barite and pyrite, as well as moderately stable minerals such as garnet, showing an increasing trend from south to north. There are also differences in the dominant paleocurrent directions between the south and north parts of the basin, and the Hf isotope data in the Ordos Basin show two-stage Hf model ages (TDM2) ranging from 918 Ma to 3574 Ma. As a result, the He 8 Member deposits in the southern Ordos Basin and northern Ordos Basin had different sources. The southern Ordos Basin might have derived from the NQinOB, the NQiOB, and the TNCO, and the northern Ordos Basin might have derived from the TNCO, the Khondalite Belt, the Yinshan Belt, and the Alxa Belt. Full article
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Figure 1
<p>Schematic geological map showing the tectonic subdivision of the Ordos Basin ((<b>a</b>) modified from [<a href="#B34-minerals-14-01076" class="html-bibr">34</a>]) and TNCO ((<b>b</b>) modified from [<a href="#B35-minerals-14-01076" class="html-bibr">35</a>]) and the Ordos Basin with the Upper Paleozoic formation systems (modified from [<a href="#B13-minerals-14-01076" class="html-bibr">13</a>]).</p>
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<p>Microphotos of the sandstone samples N1 (<b>a</b>) and N2 (<b>b</b>) from the northern Ordos Basin. All are shown under cross-polarized light. Q: quartz, Pl: plagioclase, Bi: biotite, LF: lithic fragment.</p>
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<p>Heavy minerals sample distribution, paleocurrent direction, and distribution characteristics of heavy minerals of the He 8 Member in the Ordos Basin (base map modified from [<a href="#B34-minerals-14-01076" class="html-bibr">34</a>], paleocurrent direction according to [<a href="#B4-minerals-14-01076" class="html-bibr">4</a>,<a href="#B8-minerals-14-01076" class="html-bibr">8</a>,<a href="#B9-minerals-14-01076" class="html-bibr">9</a>,<a href="#B15-minerals-14-01076" class="html-bibr">15</a>,<a href="#B16-minerals-14-01076" class="html-bibr">16</a>,<a href="#B20-minerals-14-01076" class="html-bibr">20</a>,<a href="#B35-minerals-14-01076" class="html-bibr">35</a>,<a href="#B39-minerals-14-01076" class="html-bibr">39</a>]).</p>
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<p>Heavy mineral assemblages (<b>a</b>) and heavy mineral indices (<b>b</b>) of the He 8 Member in the Ordos Basin.</p>
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<p>U–Pb harmonic diagrams of detrital zircons. Errors are quoted at 1σ level.</p>
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<p>Representative cathodoluminescence (CL) images of the zircons from samples.</p>
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<p>U–Pb age vs. Th/U ratio diagram. The shaded area denotes values for typical metamorphic zircons with Th/U &lt; 0.1.</p>
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<p>Zircon U–Pb age histograms. The ages with less than 10% discordance are used only. The yellow, pink, blue, gray, and green bars show the age groups of 350–268 Ma, 520–386 Ma, 2000–1600 Ma, 2300–2000 Ma, and 2600–2300 Ma, respectively. Data sources: the magmatic ages and metamorphic ages data of the Trans-North China Orogen (TNCO) are from [<a href="#B50-minerals-14-01076" class="html-bibr">50</a>,<a href="#B51-minerals-14-01076" class="html-bibr">51</a>,<a href="#B52-minerals-14-01076" class="html-bibr">52</a>,<a href="#B53-minerals-14-01076" class="html-bibr">53</a>,<a href="#B54-minerals-14-01076" class="html-bibr">54</a>,<a href="#B55-minerals-14-01076" class="html-bibr">55</a>,<a href="#B56-minerals-14-01076" class="html-bibr">56</a>,<a href="#B57-minerals-14-01076" class="html-bibr">57</a>,<a href="#B58-minerals-14-01076" class="html-bibr">58</a>,<a href="#B59-minerals-14-01076" class="html-bibr">59</a>,<a href="#B60-minerals-14-01076" class="html-bibr">60</a>,<a href="#B61-minerals-14-01076" class="html-bibr">61</a>,<a href="#B62-minerals-14-01076" class="html-bibr">62</a>,<a href="#B63-minerals-14-01076" class="html-bibr">63</a>,<a href="#B64-minerals-14-01076" class="html-bibr">64</a>,<a href="#B65-minerals-14-01076" class="html-bibr">65</a>,<a href="#B66-minerals-14-01076" class="html-bibr">66</a>,<a href="#B67-minerals-14-01076" class="html-bibr">67</a>,<a href="#B68-minerals-14-01076" class="html-bibr">68</a>,<a href="#B69-minerals-14-01076" class="html-bibr">69</a>,<a href="#B70-minerals-14-01076" class="html-bibr">70</a>,<a href="#B71-minerals-14-01076" class="html-bibr">71</a>,<a href="#B72-minerals-14-01076" class="html-bibr">72</a>,<a href="#B73-minerals-14-01076" class="html-bibr">73</a>], the magmatic ages data of the North Qinling Orogenic Belt (NQinOB) from [<a href="#B74-minerals-14-01076" class="html-bibr">74</a>,<a href="#B75-minerals-14-01076" class="html-bibr">75</a>,<a href="#B76-minerals-14-01076" class="html-bibr">76</a>,<a href="#B77-minerals-14-01076" class="html-bibr">77</a>,<a href="#B78-minerals-14-01076" class="html-bibr">78</a>,<a href="#B79-minerals-14-01076" class="html-bibr">79</a>,<a href="#B80-minerals-14-01076" class="html-bibr">80</a>,<a href="#B81-minerals-14-01076" class="html-bibr">81</a>,<a href="#B82-minerals-14-01076" class="html-bibr">82</a>,<a href="#B83-minerals-14-01076" class="html-bibr">83</a>,<a href="#B84-minerals-14-01076" class="html-bibr">84</a>,<a href="#B85-minerals-14-01076" class="html-bibr">85</a>,<a href="#B86-minerals-14-01076" class="html-bibr">86</a>,<a href="#B87-minerals-14-01076" class="html-bibr">87</a>,<a href="#B88-minerals-14-01076" class="html-bibr">88</a>], the metamorphic ages data of the NQinOB from [<a href="#B74-minerals-14-01076" class="html-bibr">74</a>,<a href="#B80-minerals-14-01076" class="html-bibr">80</a>,<a href="#B85-minerals-14-01076" class="html-bibr">85</a>,<a href="#B89-minerals-14-01076" class="html-bibr">89</a>,<a href="#B90-minerals-14-01076" class="html-bibr">90</a>,<a href="#B91-minerals-14-01076" class="html-bibr">91</a>,<a href="#B92-minerals-14-01076" class="html-bibr">92</a>,<a href="#B93-minerals-14-01076" class="html-bibr">93</a>,<a href="#B94-minerals-14-01076" class="html-bibr">94</a>,<a href="#B95-minerals-14-01076" class="html-bibr">95</a>,<a href="#B96-minerals-14-01076" class="html-bibr">96</a>,<a href="#B97-minerals-14-01076" class="html-bibr">97</a>,<a href="#B98-minerals-14-01076" class="html-bibr">98</a>,<a href="#B99-minerals-14-01076" class="html-bibr">99</a>,<a href="#B100-minerals-14-01076" class="html-bibr">100</a>,<a href="#B101-minerals-14-01076" class="html-bibr">101</a>,<a href="#B102-minerals-14-01076" class="html-bibr">102</a>,<a href="#B103-minerals-14-01076" class="html-bibr">103</a>,<a href="#B104-minerals-14-01076" class="html-bibr">104</a>,<a href="#B105-minerals-14-01076" class="html-bibr">105</a>,<a href="#B106-minerals-14-01076" class="html-bibr">106</a>,<a href="#B107-minerals-14-01076" class="html-bibr">107</a>,<a href="#B108-minerals-14-01076" class="html-bibr">108</a>,<a href="#B109-minerals-14-01076" class="html-bibr">109</a>,<a href="#B110-minerals-14-01076" class="html-bibr">110</a>,<a href="#B111-minerals-14-01076" class="html-bibr">111</a>,<a href="#B112-minerals-14-01076" class="html-bibr">112</a>], the magmatic ages data of the North Qilian Orogenic Belt (NQiOB) from [<a href="#B74-minerals-14-01076" class="html-bibr">74</a>,<a href="#B78-minerals-14-01076" class="html-bibr">78</a>,<a href="#B113-minerals-14-01076" class="html-bibr">113</a>,<a href="#B114-minerals-14-01076" class="html-bibr">114</a>,<a href="#B115-minerals-14-01076" class="html-bibr">115</a>,<a href="#B116-minerals-14-01076" class="html-bibr">116</a>,<a href="#B117-minerals-14-01076" class="html-bibr">117</a>,<a href="#B118-minerals-14-01076" class="html-bibr">118</a>,<a href="#B119-minerals-14-01076" class="html-bibr">119</a>,<a href="#B120-minerals-14-01076" class="html-bibr">120</a>,<a href="#B121-minerals-14-01076" class="html-bibr">121</a>,<a href="#B122-minerals-14-01076" class="html-bibr">122</a>,<a href="#B123-minerals-14-01076" class="html-bibr">123</a>,<a href="#B124-minerals-14-01076" class="html-bibr">124</a>,<a href="#B125-minerals-14-01076" class="html-bibr">125</a>,<a href="#B126-minerals-14-01076" class="html-bibr">126</a>,<a href="#B127-minerals-14-01076" class="html-bibr">127</a>,<a href="#B128-minerals-14-01076" class="html-bibr">128</a>,<a href="#B129-minerals-14-01076" class="html-bibr">129</a>,<a href="#B130-minerals-14-01076" class="html-bibr">130</a>,<a href="#B131-minerals-14-01076" class="html-bibr">131</a>,<a href="#B132-minerals-14-01076" class="html-bibr">132</a>,<a href="#B133-minerals-14-01076" class="html-bibr">133</a>,<a href="#B134-minerals-14-01076" class="html-bibr">134</a>,<a href="#B135-minerals-14-01076" class="html-bibr">135</a>], the metamorphic ages data of the NQiOB from [<a href="#B96-minerals-14-01076" class="html-bibr">96</a>,<a href="#B114-minerals-14-01076" class="html-bibr">114</a>,<a href="#B131-minerals-14-01076" class="html-bibr">131</a>,<a href="#B132-minerals-14-01076" class="html-bibr">132</a>,<a href="#B133-minerals-14-01076" class="html-bibr">133</a>,<a href="#B136-minerals-14-01076" class="html-bibr">136</a>,<a href="#B137-minerals-14-01076" class="html-bibr">137</a>,<a href="#B138-minerals-14-01076" class="html-bibr">138</a>], the magmatic ages data of the Khondalite Belt (KB) from [<a href="#B139-minerals-14-01076" class="html-bibr">139</a>,<a href="#B140-minerals-14-01076" class="html-bibr">140</a>,<a href="#B141-minerals-14-01076" class="html-bibr">141</a>,<a href="#B142-minerals-14-01076" class="html-bibr">142</a>,<a href="#B143-minerals-14-01076" class="html-bibr">143</a>,<a href="#B144-minerals-14-01076" class="html-bibr">144</a>,<a href="#B145-minerals-14-01076" class="html-bibr">145</a>,<a href="#B146-minerals-14-01076" class="html-bibr">146</a>,<a href="#B147-minerals-14-01076" class="html-bibr">147</a>,<a href="#B148-minerals-14-01076" class="html-bibr">148</a>,<a href="#B149-minerals-14-01076" class="html-bibr">149</a>,<a href="#B150-minerals-14-01076" class="html-bibr">150</a>], the metamorphic ages data of the KB from [<a href="#B68-minerals-14-01076" class="html-bibr">68</a>,<a href="#B142-minerals-14-01076" class="html-bibr">142</a>,<a href="#B143-minerals-14-01076" class="html-bibr">143</a>,<a href="#B144-minerals-14-01076" class="html-bibr">144</a>,<a href="#B145-minerals-14-01076" class="html-bibr">145</a>,<a href="#B147-minerals-14-01076" class="html-bibr">147</a>,<a href="#B151-minerals-14-01076" class="html-bibr">151</a>,<a href="#B152-minerals-14-01076" class="html-bibr">152</a>,<a href="#B153-minerals-14-01076" class="html-bibr">153</a>,<a href="#B154-minerals-14-01076" class="html-bibr">154</a>,<a href="#B155-minerals-14-01076" class="html-bibr">155</a>,<a href="#B156-minerals-14-01076" class="html-bibr">156</a>,<a href="#B157-minerals-14-01076" class="html-bibr">157</a>,<a href="#B158-minerals-14-01076" class="html-bibr">158</a>,<a href="#B159-minerals-14-01076" class="html-bibr">159</a>,<a href="#B160-minerals-14-01076" class="html-bibr">160</a>,<a href="#B161-minerals-14-01076" class="html-bibr">161</a>,<a href="#B162-minerals-14-01076" class="html-bibr">162</a>,<a href="#B163-minerals-14-01076" class="html-bibr">163</a>,<a href="#B164-minerals-14-01076" class="html-bibr">164</a>], the magmatic ages data of the Yinshan Block (YB) from [<a href="#B165-minerals-14-01076" class="html-bibr">165</a>,<a href="#B166-minerals-14-01076" class="html-bibr">166</a>,<a href="#B167-minerals-14-01076" class="html-bibr">167</a>,<a href="#B168-minerals-14-01076" class="html-bibr">168</a>,<a href="#B169-minerals-14-01076" class="html-bibr">169</a>,<a href="#B170-minerals-14-01076" class="html-bibr">170</a>,<a href="#B171-minerals-14-01076" class="html-bibr">171</a>,<a href="#B172-minerals-14-01076" class="html-bibr">172</a>,<a href="#B173-minerals-14-01076" class="html-bibr">173</a>,<a href="#B174-minerals-14-01076" class="html-bibr">174</a>,<a href="#B175-minerals-14-01076" class="html-bibr">175</a>,<a href="#B176-minerals-14-01076" class="html-bibr">176</a>,<a href="#B177-minerals-14-01076" class="html-bibr">177</a>,<a href="#B178-minerals-14-01076" class="html-bibr">178</a>,<a href="#B179-minerals-14-01076" class="html-bibr">179</a>,<a href="#B180-minerals-14-01076" class="html-bibr">180</a>,<a href="#B181-minerals-14-01076" class="html-bibr">181</a>,<a href="#B182-minerals-14-01076" class="html-bibr">182</a>,<a href="#B183-minerals-14-01076" class="html-bibr">183</a>,<a href="#B184-minerals-14-01076" class="html-bibr">184</a>,<a href="#B185-minerals-14-01076" class="html-bibr">185</a>,<a href="#B186-minerals-14-01076" class="html-bibr">186</a>,<a href="#B187-minerals-14-01076" class="html-bibr">187</a>,<a href="#B188-minerals-14-01076" class="html-bibr">188</a>,<a href="#B189-minerals-14-01076" class="html-bibr">189</a>,<a href="#B190-minerals-14-01076" class="html-bibr">190</a>,<a href="#B191-minerals-14-01076" class="html-bibr">191</a>,<a href="#B192-minerals-14-01076" class="html-bibr">192</a>], the metamorphic ages data of the YB from [<a href="#B169-minerals-14-01076" class="html-bibr">169</a>,<a href="#B170-minerals-14-01076" class="html-bibr">170</a>,<a href="#B176-minerals-14-01076" class="html-bibr">176</a>,<a href="#B177-minerals-14-01076" class="html-bibr">177</a>,<a href="#B179-minerals-14-01076" class="html-bibr">179</a>,<a href="#B192-minerals-14-01076" class="html-bibr">192</a>,<a href="#B193-minerals-14-01076" class="html-bibr">193</a>,<a href="#B194-minerals-14-01076" class="html-bibr">194</a>], the detrital zircon ages data of the northern Ordos Basin from [<a href="#B195-minerals-14-01076" class="html-bibr">195</a>], the detrital zircon ages data of the QinOB from [<a href="#B196-minerals-14-01076" class="html-bibr">196</a>,<a href="#B197-minerals-14-01076" class="html-bibr">197</a>,<a href="#B198-minerals-14-01076" class="html-bibr">198</a>,<a href="#B199-minerals-14-01076" class="html-bibr">199</a>] (the QinOB data include the Permian in Zhen’an Basin data in the South Qinling Orogenic Belt, the Liuye River Basin data in the NQinOB, and the Lintan area data in Western Qinling Orogenic Belt), the magmatic ages data of the AB from [<a href="#B165-minerals-14-01076" class="html-bibr">165</a>,<a href="#B179-minerals-14-01076" class="html-bibr">179</a>,<a href="#B200-minerals-14-01076" class="html-bibr">200</a>,<a href="#B201-minerals-14-01076" class="html-bibr">201</a>,<a href="#B202-minerals-14-01076" class="html-bibr">202</a>,<a href="#B203-minerals-14-01076" class="html-bibr">203</a>,<a href="#B204-minerals-14-01076" class="html-bibr">204</a>,<a href="#B205-minerals-14-01076" class="html-bibr">205</a>,<a href="#B206-minerals-14-01076" class="html-bibr">206</a>,<a href="#B207-minerals-14-01076" class="html-bibr">207</a>,<a href="#B208-minerals-14-01076" class="html-bibr">208</a>,<a href="#B209-minerals-14-01076" class="html-bibr">209</a>,<a href="#B210-minerals-14-01076" class="html-bibr">210</a>,<a href="#B211-minerals-14-01076" class="html-bibr">211</a>,<a href="#B212-minerals-14-01076" class="html-bibr">212</a>,<a href="#B213-minerals-14-01076" class="html-bibr">213</a>,<a href="#B214-minerals-14-01076" class="html-bibr">214</a>,<a href="#B215-minerals-14-01076" class="html-bibr">215</a>,<a href="#B216-minerals-14-01076" class="html-bibr">216</a>,<a href="#B217-minerals-14-01076" class="html-bibr">217</a>,<a href="#B218-minerals-14-01076" class="html-bibr">218</a>,<a href="#B219-minerals-14-01076" class="html-bibr">219</a>,<a href="#B220-minerals-14-01076" class="html-bibr">220</a>,<a href="#B221-minerals-14-01076" class="html-bibr">221</a>,<a href="#B222-minerals-14-01076" class="html-bibr">222</a>,<a href="#B223-minerals-14-01076" class="html-bibr">223</a>,<a href="#B224-minerals-14-01076" class="html-bibr">224</a>,<a href="#B225-minerals-14-01076" class="html-bibr">225</a>,<a href="#B226-minerals-14-01076" class="html-bibr">226</a>,<a href="#B227-minerals-14-01076" class="html-bibr">227</a>,<a href="#B228-minerals-14-01076" class="html-bibr">228</a>,<a href="#B229-minerals-14-01076" class="html-bibr">229</a>,<a href="#B230-minerals-14-01076" class="html-bibr">230</a>,<a href="#B231-minerals-14-01076" class="html-bibr">231</a>,<a href="#B232-minerals-14-01076" class="html-bibr">232</a>,<a href="#B233-minerals-14-01076" class="html-bibr">233</a>,<a href="#B234-minerals-14-01076" class="html-bibr">234</a>,<a href="#B235-minerals-14-01076" class="html-bibr">235</a>,<a href="#B236-minerals-14-01076" class="html-bibr">236</a>,<a href="#B237-minerals-14-01076" class="html-bibr">237</a>,<a href="#B238-minerals-14-01076" class="html-bibr">238</a>,<a href="#B239-minerals-14-01076" class="html-bibr">239</a>,<a href="#B240-minerals-14-01076" class="html-bibr">240</a>,<a href="#B241-minerals-14-01076" class="html-bibr">241</a>,<a href="#B242-minerals-14-01076" class="html-bibr">242</a>,<a href="#B243-minerals-14-01076" class="html-bibr">243</a>,<a href="#B244-minerals-14-01076" class="html-bibr">244</a>,<a href="#B245-minerals-14-01076" class="html-bibr">245</a>,<a href="#B246-minerals-14-01076" class="html-bibr">246</a>,<a href="#B247-minerals-14-01076" class="html-bibr">247</a>,<a href="#B248-minerals-14-01076" class="html-bibr">248</a>,<a href="#B249-minerals-14-01076" class="html-bibr">249</a>,<a href="#B250-minerals-14-01076" class="html-bibr">250</a>,<a href="#B251-minerals-14-01076" class="html-bibr">251</a>,<a href="#B252-minerals-14-01076" class="html-bibr">252</a>,<a href="#B253-minerals-14-01076" class="html-bibr">253</a>,<a href="#B254-minerals-14-01076" class="html-bibr">254</a>,<a href="#B255-minerals-14-01076" class="html-bibr">255</a>,<a href="#B256-minerals-14-01076" class="html-bibr">256</a>,<a href="#B257-minerals-14-01076" class="html-bibr">257</a>,<a href="#B258-minerals-14-01076" class="html-bibr">258</a>,<a href="#B259-minerals-14-01076" class="html-bibr">259</a>,<a href="#B260-minerals-14-01076" class="html-bibr">260</a>,<a href="#B261-minerals-14-01076" class="html-bibr">261</a>,<a href="#B262-minerals-14-01076" class="html-bibr">262</a>,<a href="#B263-minerals-14-01076" class="html-bibr">263</a>,<a href="#B264-minerals-14-01076" class="html-bibr">264</a>,<a href="#B265-minerals-14-01076" class="html-bibr">265</a>,<a href="#B266-minerals-14-01076" class="html-bibr">266</a>,<a href="#B267-minerals-14-01076" class="html-bibr">267</a>,<a href="#B268-minerals-14-01076" class="html-bibr">268</a>,<a href="#B269-minerals-14-01076" class="html-bibr">269</a>,<a href="#B270-minerals-14-01076" class="html-bibr">270</a>,<a href="#B271-minerals-14-01076" class="html-bibr">271</a>,<a href="#B272-minerals-14-01076" class="html-bibr">272</a>,<a href="#B273-minerals-14-01076" class="html-bibr">273</a>,<a href="#B274-minerals-14-01076" class="html-bibr">274</a>,<a href="#B275-minerals-14-01076" class="html-bibr">275</a>,<a href="#B276-minerals-14-01076" class="html-bibr">276</a>,<a href="#B277-minerals-14-01076" class="html-bibr">277</a>,<a href="#B278-minerals-14-01076" class="html-bibr">278</a>,<a href="#B279-minerals-14-01076" class="html-bibr">279</a>,<a href="#B280-minerals-14-01076" class="html-bibr">280</a>,<a href="#B281-minerals-14-01076" class="html-bibr">281</a>,<a href="#B282-minerals-14-01076" class="html-bibr">282</a>,<a href="#B283-minerals-14-01076" class="html-bibr">283</a>,<a href="#B284-minerals-14-01076" class="html-bibr">284</a>,<a href="#B285-minerals-14-01076" class="html-bibr">285</a>,<a href="#B286-minerals-14-01076" class="html-bibr">286</a>,<a href="#B287-minerals-14-01076" class="html-bibr">287</a>,<a href="#B288-minerals-14-01076" class="html-bibr">288</a>,<a href="#B289-minerals-14-01076" class="html-bibr">289</a>,<a href="#B290-minerals-14-01076" class="html-bibr">290</a>,<a href="#B291-minerals-14-01076" class="html-bibr">291</a>,<a href="#B292-minerals-14-01076" class="html-bibr">292</a>,<a href="#B293-minerals-14-01076" class="html-bibr">293</a>], the metamorphic ages data of the AB from [<a href="#B201-minerals-14-01076" class="html-bibr">201</a>,<a href="#B202-minerals-14-01076" class="html-bibr">202</a>,<a href="#B203-minerals-14-01076" class="html-bibr">203</a>,<a href="#B204-minerals-14-01076" class="html-bibr">204</a>,<a href="#B205-minerals-14-01076" class="html-bibr">205</a>,<a href="#B206-minerals-14-01076" class="html-bibr">206</a>,<a href="#B207-minerals-14-01076" class="html-bibr">207</a>,<a href="#B212-minerals-14-01076" class="html-bibr">212</a>,<a href="#B214-minerals-14-01076" class="html-bibr">214</a>,<a href="#B216-minerals-14-01076" class="html-bibr">216</a>,<a href="#B232-minerals-14-01076" class="html-bibr">232</a>,<a href="#B243-minerals-14-01076" class="html-bibr">243</a>,<a href="#B250-minerals-14-01076" class="html-bibr">250</a>,<a href="#B268-minerals-14-01076" class="html-bibr">268</a>,<a href="#B273-minerals-14-01076" class="html-bibr">273</a>,<a href="#B281-minerals-14-01076" class="html-bibr">281</a>,<a href="#B293-minerals-14-01076" class="html-bibr">293</a>,<a href="#B294-minerals-14-01076" class="html-bibr">294</a>,<a href="#B295-minerals-14-01076" class="html-bibr">295</a>,<a href="#B296-minerals-14-01076" class="html-bibr">296</a>,<a href="#B297-minerals-14-01076" class="html-bibr">297</a>,<a href="#B298-minerals-14-01076" class="html-bibr">298</a>,<a href="#B299-minerals-14-01076" class="html-bibr">299</a>,<a href="#B300-minerals-14-01076" class="html-bibr">300</a>,<a href="#B301-minerals-14-01076" class="html-bibr">301</a>,<a href="#B302-minerals-14-01076" class="html-bibr">302</a>,<a href="#B303-minerals-14-01076" class="html-bibr">303</a>,<a href="#B304-minerals-14-01076" class="html-bibr">304</a>], and the detrital zircon ages data of (<b>a</b>–<b>h</b>) from this study and the Research Institute of Petroleum Exploration and Development, PetroChina Changqing Oilfield Company. The relative probability curves were drawn with the DensityPlotter program (version 8.5) by using the model of kernel density estimation (KED). The width of one column in (<b>m</b>–<b>o</b>) is 25 Ma.</p>
Full article ">Figure 9
<p>ε<sub>Hf</sub>(t) values vs. U–Pb ages (<b>a</b>) and T<sub>DM2</sub> vs. U–Pb ages (<b>b</b>). The yellow, orange, blue, gray, and green bars show the age groups of 350–268 Ma, 520–386 Ma, 2000–1600 Ma, 2300–2000 Ma, and 2600–2300 Ma, respectively. The Hf isotope evolution line for depleted mantle follows [<a href="#B305-minerals-14-01076" class="html-bibr">305</a>]. The Lu–Hf isotopic compositions of the TNCO are from [<a href="#B50-minerals-14-01076" class="html-bibr">50</a>,<a href="#B51-minerals-14-01076" class="html-bibr">51</a>,<a href="#B52-minerals-14-01076" class="html-bibr">52</a>,<a href="#B53-minerals-14-01076" class="html-bibr">53</a>,<a href="#B54-minerals-14-01076" class="html-bibr">54</a>,<a href="#B55-minerals-14-01076" class="html-bibr">55</a>,<a href="#B56-minerals-14-01076" class="html-bibr">56</a>,<a href="#B57-minerals-14-01076" class="html-bibr">57</a>,<a href="#B58-minerals-14-01076" class="html-bibr">58</a>,<a href="#B59-minerals-14-01076" class="html-bibr">59</a>], the NQiOB from [<a href="#B114-minerals-14-01076" class="html-bibr">114</a>,<a href="#B132-minerals-14-01076" class="html-bibr">132</a>,<a href="#B133-minerals-14-01076" class="html-bibr">133</a>,<a href="#B306-minerals-14-01076" class="html-bibr">306</a>], the NQinOB from [<a href="#B75-minerals-14-01076" class="html-bibr">75</a>,<a href="#B78-minerals-14-01076" class="html-bibr">78</a>,<a href="#B80-minerals-14-01076" class="html-bibr">80</a>,<a href="#B82-minerals-14-01076" class="html-bibr">82</a>,<a href="#B85-minerals-14-01076" class="html-bibr">85</a>,<a href="#B86-minerals-14-01076" class="html-bibr">86</a>], the KB from the references [<a href="#B139-minerals-14-01076" class="html-bibr">139</a>,<a href="#B140-minerals-14-01076" class="html-bibr">140</a>,<a href="#B141-minerals-14-01076" class="html-bibr">141</a>,<a href="#B142-minerals-14-01076" class="html-bibr">142</a>,<a href="#B143-minerals-14-01076" class="html-bibr">143</a>,<a href="#B144-minerals-14-01076" class="html-bibr">144</a>,<a href="#B145-minerals-14-01076" class="html-bibr">145</a>,<a href="#B146-minerals-14-01076" class="html-bibr">146</a>,<a href="#B147-minerals-14-01076" class="html-bibr">147</a>,<a href="#B148-minerals-14-01076" class="html-bibr">148</a>,<a href="#B149-minerals-14-01076" class="html-bibr">149</a>,<a href="#B150-minerals-14-01076" class="html-bibr">150</a>], the YB from [<a href="#B149-minerals-14-01076" class="html-bibr">149</a>,<a href="#B168-minerals-14-01076" class="html-bibr">168</a>,<a href="#B173-minerals-14-01076" class="html-bibr">173</a>,<a href="#B175-minerals-14-01076" class="html-bibr">175</a>,<a href="#B176-minerals-14-01076" class="html-bibr">176</a>,<a href="#B178-minerals-14-01076" class="html-bibr">178</a>,<a href="#B179-minerals-14-01076" class="html-bibr">179</a>,<a href="#B181-minerals-14-01076" class="html-bibr">181</a>,<a href="#B184-minerals-14-01076" class="html-bibr">184</a>,<a href="#B185-minerals-14-01076" class="html-bibr">185</a>,<a href="#B186-minerals-14-01076" class="html-bibr">186</a>,<a href="#B189-minerals-14-01076" class="html-bibr">189</a>], the AB from [<a href="#B149-minerals-14-01076" class="html-bibr">149</a>,<a href="#B168-minerals-14-01076" class="html-bibr">168</a>,<a href="#B173-minerals-14-01076" class="html-bibr">173</a>,<a href="#B175-minerals-14-01076" class="html-bibr">175</a>,<a href="#B176-minerals-14-01076" class="html-bibr">176</a>,<a href="#B178-minerals-14-01076" class="html-bibr">178</a>,<a href="#B179-minerals-14-01076" class="html-bibr">179</a>,<a href="#B181-minerals-14-01076" class="html-bibr">181</a>,<a href="#B182-minerals-14-01076" class="html-bibr">182</a>,<a href="#B184-minerals-14-01076" class="html-bibr">184</a>,<a href="#B186-minerals-14-01076" class="html-bibr">186</a>,<a href="#B200-minerals-14-01076" class="html-bibr">200</a>,<a href="#B203-minerals-14-01076" class="html-bibr">203</a>,<a href="#B260-minerals-14-01076" class="html-bibr">260</a>,<a href="#B291-minerals-14-01076" class="html-bibr">291</a>,<a href="#B307-minerals-14-01076" class="html-bibr">307</a>,<a href="#B308-minerals-14-01076" class="html-bibr">308</a>,<a href="#B309-minerals-14-01076" class="html-bibr">309</a>,<a href="#B310-minerals-14-01076" class="html-bibr">310</a>], the Permian in Zhen’an Basin (ZAB Permian) in South Qinling Orogenic Belt (SQinOB) from [<a href="#B199-minerals-14-01076" class="html-bibr">199</a>], and the southern Ordos Basin and northern Ordos Basin from this study.</p>
Full article ">Figure 10
<p>Cumulative probability curves of measured crystallization ages for detrital zircon grains relative to the depositional age of zircon samples from the Ordos Basin (basic map according to reference [<a href="#B331-minerals-14-01076" class="html-bibr">331</a>]). (A): Convergent setting; (B): Collisional setting; (C): Extensional setting.</p>
Full article ">Figure 11
<p>Zircon U–Pb age (200–550 Ma) distribution diagram (<b>a</b>–<b>n</b>). The ages with less than 10% discordance are used only. The yellow, orange, blue, gray, and green bars show the age groups of 285–260 Ma, 320–285 Ma, 350–320 Ma, 400–370 Ma, and 520–400 Ma, respectively. Data sources: the magmatic ages data of the NQinOB are from [<a href="#B74-minerals-14-01076" class="html-bibr">74</a>,<a href="#B75-minerals-14-01076" class="html-bibr">75</a>,<a href="#B78-minerals-14-01076" class="html-bibr">78</a>,<a href="#B80-minerals-14-01076" class="html-bibr">80</a>,<a href="#B87-minerals-14-01076" class="html-bibr">87</a>,<a href="#B88-minerals-14-01076" class="html-bibr">88</a>,<a href="#B89-minerals-14-01076" class="html-bibr">89</a>], the metamorphic ages data of the NQinOB from [<a href="#B74-minerals-14-01076" class="html-bibr">74</a>,<a href="#B81-minerals-14-01076" class="html-bibr">81</a>,<a href="#B86-minerals-14-01076" class="html-bibr">86</a>,<a href="#B90-minerals-14-01076" class="html-bibr">90</a>,<a href="#B91-minerals-14-01076" class="html-bibr">91</a>,<a href="#B92-minerals-14-01076" class="html-bibr">92</a>,<a href="#B93-minerals-14-01076" class="html-bibr">93</a>,<a href="#B94-minerals-14-01076" class="html-bibr">94</a>,<a href="#B95-minerals-14-01076" class="html-bibr">95</a>,<a href="#B96-minerals-14-01076" class="html-bibr">96</a>,<a href="#B97-minerals-14-01076" class="html-bibr">97</a>,<a href="#B98-minerals-14-01076" class="html-bibr">98</a>,<a href="#B99-minerals-14-01076" class="html-bibr">99</a>,<a href="#B100-minerals-14-01076" class="html-bibr">100</a>,<a href="#B101-minerals-14-01076" class="html-bibr">101</a>,<a href="#B102-minerals-14-01076" class="html-bibr">102</a>,<a href="#B103-minerals-14-01076" class="html-bibr">103</a>,<a href="#B104-minerals-14-01076" class="html-bibr">104</a>,<a href="#B105-minerals-14-01076" class="html-bibr">105</a>,<a href="#B106-minerals-14-01076" class="html-bibr">106</a>,<a href="#B107-minerals-14-01076" class="html-bibr">107</a>,<a href="#B108-minerals-14-01076" class="html-bibr">108</a>,<a href="#B110-minerals-14-01076" class="html-bibr">110</a>,<a href="#B112-minerals-14-01076" class="html-bibr">112</a>,<a href="#B333-minerals-14-01076" class="html-bibr">333</a>], the magmatic ages data of the NQiOB from [<a href="#B114-minerals-14-01076" class="html-bibr">114</a>,<a href="#B115-minerals-14-01076" class="html-bibr">115</a>,<a href="#B116-minerals-14-01076" class="html-bibr">116</a>,<a href="#B117-minerals-14-01076" class="html-bibr">117</a>,<a href="#B118-minerals-14-01076" class="html-bibr">118</a>,<a href="#B119-minerals-14-01076" class="html-bibr">119</a>,<a href="#B120-minerals-14-01076" class="html-bibr">120</a>,<a href="#B121-minerals-14-01076" class="html-bibr">121</a>,<a href="#B123-minerals-14-01076" class="html-bibr">123</a>,<a href="#B126-minerals-14-01076" class="html-bibr">126</a>,<a href="#B128-minerals-14-01076" class="html-bibr">128</a>,<a href="#B129-minerals-14-01076" class="html-bibr">129</a>,<a href="#B130-minerals-14-01076" class="html-bibr">130</a>,<a href="#B131-minerals-14-01076" class="html-bibr">131</a>,<a href="#B132-minerals-14-01076" class="html-bibr">132</a>,<a href="#B133-minerals-14-01076" class="html-bibr">133</a>,<a href="#B134-minerals-14-01076" class="html-bibr">134</a>,<a href="#B135-minerals-14-01076" class="html-bibr">135</a>], the metamorphic ages data of the NQiOB from [<a href="#B131-minerals-14-01076" class="html-bibr">131</a>,<a href="#B132-minerals-14-01076" class="html-bibr">132</a>,<a href="#B133-minerals-14-01076" class="html-bibr">133</a>,<a href="#B136-minerals-14-01076" class="html-bibr">136</a>,<a href="#B137-minerals-14-01076" class="html-bibr">137</a>,<a href="#B138-minerals-14-01076" class="html-bibr">138</a>], the magmatic ages data of the YB from [<a href="#B165-minerals-14-01076" class="html-bibr">165</a>,<a href="#B166-minerals-14-01076" class="html-bibr">166</a>,<a href="#B172-minerals-14-01076" class="html-bibr">172</a>,<a href="#B173-minerals-14-01076" class="html-bibr">173</a>,<a href="#B174-minerals-14-01076" class="html-bibr">174</a>,<a href="#B175-minerals-14-01076" class="html-bibr">175</a>,<a href="#B179-minerals-14-01076" class="html-bibr">179</a>,<a href="#B180-minerals-14-01076" class="html-bibr">180</a>,<a href="#B181-minerals-14-01076" class="html-bibr">181</a>,<a href="#B182-minerals-14-01076" class="html-bibr">182</a>,<a href="#B184-minerals-14-01076" class="html-bibr">184</a>,<a href="#B185-minerals-14-01076" class="html-bibr">185</a>,<a href="#B186-minerals-14-01076" class="html-bibr">186</a>,<a href="#B187-minerals-14-01076" class="html-bibr">187</a>,<a href="#B189-minerals-14-01076" class="html-bibr">189</a>,<a href="#B190-minerals-14-01076" class="html-bibr">190</a>,<a href="#B192-minerals-14-01076" class="html-bibr">192</a>,<a href="#B334-minerals-14-01076" class="html-bibr">334</a>], the metamorphic zircon ages data of the AB from [<a href="#B180-minerals-14-01076" class="html-bibr">180</a>,<a href="#B232-minerals-14-01076" class="html-bibr">232</a>,<a href="#B273-minerals-14-01076" class="html-bibr">273</a>,<a href="#B281-minerals-14-01076" class="html-bibr">281</a>,<a href="#B294-minerals-14-01076" class="html-bibr">294</a>,<a href="#B299-minerals-14-01076" class="html-bibr">299</a>], the magmatic zircon ages data of AB from [<a href="#B173-minerals-14-01076" class="html-bibr">173</a>,<a href="#B174-minerals-14-01076" class="html-bibr">174</a>,<a href="#B175-minerals-14-01076" class="html-bibr">175</a>,<a href="#B176-minerals-14-01076" class="html-bibr">176</a>,<a href="#B177-minerals-14-01076" class="html-bibr">177</a>,<a href="#B178-minerals-14-01076" class="html-bibr">178</a>,<a href="#B179-minerals-14-01076" class="html-bibr">179</a>,<a href="#B180-minerals-14-01076" class="html-bibr">180</a>,<a href="#B181-minerals-14-01076" class="html-bibr">181</a>,<a href="#B182-minerals-14-01076" class="html-bibr">182</a>,<a href="#B183-minerals-14-01076" class="html-bibr">183</a>,<a href="#B184-minerals-14-01076" class="html-bibr">184</a>,<a href="#B185-minerals-14-01076" class="html-bibr">185</a>,<a href="#B186-minerals-14-01076" class="html-bibr">186</a>,<a href="#B187-minerals-14-01076" class="html-bibr">187</a>,<a href="#B188-minerals-14-01076" class="html-bibr">188</a>,<a href="#B189-minerals-14-01076" class="html-bibr">189</a>,<a href="#B190-minerals-14-01076" class="html-bibr">190</a>,<a href="#B191-minerals-14-01076" class="html-bibr">191</a>,<a href="#B192-minerals-14-01076" class="html-bibr">192</a>,<a href="#B193-minerals-14-01076" class="html-bibr">193</a>,<a href="#B194-minerals-14-01076" class="html-bibr">194</a>,<a href="#B195-minerals-14-01076" class="html-bibr">195</a>,<a href="#B196-minerals-14-01076" class="html-bibr">196</a>,<a href="#B197-minerals-14-01076" class="html-bibr">197</a>,<a href="#B198-minerals-14-01076" class="html-bibr">198</a>,<a href="#B199-minerals-14-01076" class="html-bibr">199</a>,<a href="#B200-minerals-14-01076" class="html-bibr">200</a>,<a href="#B201-minerals-14-01076" class="html-bibr">201</a>,<a href="#B202-minerals-14-01076" class="html-bibr">202</a>,<a href="#B203-minerals-14-01076" class="html-bibr">203</a>,<a href="#B204-minerals-14-01076" class="html-bibr">204</a>,<a href="#B205-minerals-14-01076" class="html-bibr">205</a>,<a href="#B206-minerals-14-01076" class="html-bibr">206</a>,<a href="#B207-minerals-14-01076" class="html-bibr">207</a>,<a href="#B208-minerals-14-01076" class="html-bibr">208</a>,<a href="#B209-minerals-14-01076" class="html-bibr">209</a>,<a href="#B210-minerals-14-01076" class="html-bibr">210</a>,<a href="#B211-minerals-14-01076" class="html-bibr">211</a>,<a href="#B212-minerals-14-01076" class="html-bibr">212</a>,<a href="#B213-minerals-14-01076" class="html-bibr">213</a>,<a href="#B214-minerals-14-01076" class="html-bibr">214</a>,<a href="#B215-minerals-14-01076" class="html-bibr">215</a>,<a href="#B216-minerals-14-01076" class="html-bibr">216</a>,<a href="#B217-minerals-14-01076" class="html-bibr">217</a>,<a href="#B218-minerals-14-01076" class="html-bibr">218</a>,<a href="#B219-minerals-14-01076" class="html-bibr">219</a>,<a href="#B220-minerals-14-01076" class="html-bibr">220</a>,<a href="#B222-minerals-14-01076" class="html-bibr">222</a>,<a href="#B224-minerals-14-01076" class="html-bibr">224</a>,<a href="#B235-minerals-14-01076" class="html-bibr">235</a>,<a href="#B256-minerals-14-01076" class="html-bibr">256</a>,<a href="#B258-minerals-14-01076" class="html-bibr">258</a>,<a href="#B260-minerals-14-01076" class="html-bibr">260</a>,<a href="#B265-minerals-14-01076" class="html-bibr">265</a>,<a href="#B268-minerals-14-01076" class="html-bibr">268</a>,<a href="#B280-minerals-14-01076" class="html-bibr">280</a>,<a href="#B291-minerals-14-01076" class="html-bibr">291</a>], the detrital zircon ages data of the South Qinling Orogenic Belt (SQinOB, the Permian in Zhen’an Basin) from [<a href="#B196-minerals-14-01076" class="html-bibr">196</a>,<a href="#B200-minerals-14-01076" class="html-bibr">200</a>], the Western Qinling Orogenic Belt (WQinOB, the Permian in Lintan area) from [<a href="#B197-minerals-14-01076" class="html-bibr">197</a>], the detrital zircon ages data of the <a href="#minerals-14-01076-f008" class="html-fig">Figure 8</a>a–h from this study and the Research Institute of Petroleum Exploration and Development, PetroChina Changqing Oilfield Company.</p>
Full article ">Figure 12
<p>ε<sub>Hf</sub>(t) values vs. U–Pb ages (200–520 Ma (<b>a</b>)) and T<sub>DM2</sub> values vs. U–Pb ages (200–520 Ma (<b>b</b>)). The yellow, pink, blue, gray, and green bars show the age groups of 285–260 Ma, 320–285 Ma, 350–320 Ma, 400–370 Ma, and 520–400 Ma, respectively. The Hf–isotope evolution line for depleted mantle follows from [<a href="#B305-minerals-14-01076" class="html-bibr">305</a>]. The Lu–Hf isotopic compositions of the NQinOB are from [<a href="#B75-minerals-14-01076" class="html-bibr">75</a>,<a href="#B78-minerals-14-01076" class="html-bibr">78</a>,<a href="#B80-minerals-14-01076" class="html-bibr">80</a>,<a href="#B82-minerals-14-01076" class="html-bibr">82</a>,<a href="#B85-minerals-14-01076" class="html-bibr">85</a>,<a href="#B86-minerals-14-01076" class="html-bibr">86</a>], the NQiOB from [<a href="#B114-minerals-14-01076" class="html-bibr">114</a>,<a href="#B132-minerals-14-01076" class="html-bibr">132</a>,<a href="#B133-minerals-14-01076" class="html-bibr">133</a>,<a href="#B306-minerals-14-01076" class="html-bibr">306</a>], the YB from [<a href="#B173-minerals-14-01076" class="html-bibr">173</a>,<a href="#B175-minerals-14-01076" class="html-bibr">175</a>,<a href="#B179-minerals-14-01076" class="html-bibr">179</a>,<a href="#B181-minerals-14-01076" class="html-bibr">181</a>,<a href="#B182-minerals-14-01076" class="html-bibr">182</a>,<a href="#B184-minerals-14-01076" class="html-bibr">184</a>,<a href="#B185-minerals-14-01076" class="html-bibr">185</a>,<a href="#B186-minerals-14-01076" class="html-bibr">186</a>,<a href="#B189-minerals-14-01076" class="html-bibr">189</a>], the AB from [<a href="#B333-minerals-14-01076" class="html-bibr">333</a>] the Permian in Zhen’an Basin (ZAB Permian) in the South Qinling Orogenic Belt (SQinOB) from [<a href="#B199-minerals-14-01076" class="html-bibr">199</a>] and the southern Ordos Basin and northern Ordos Basin from this study.</p>
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