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Search Results (938)

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Keywords = polypropylene fiber

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24 pages, 9880 KiB  
Article
Effect of Fiber Types and Dosages on the Properties of Modified Aluminum Dross–Coal Gangue-Based Foam Filling Materials
by Keyuan Yin, Kai Wang, Xiaoqiang Zhang, Yulong Jiang and Shiyu Zhang
Minerals 2025, 15(2), 106; https://doi.org/10.3390/min15020106 (registering DOI) - 22 Jan 2025
Abstract
Fiber reinforcement offers a promising solution to improve the mechanical performance and durability of cement-based foam backfill (CFB), addressing critical issues such as brittleness and poor crack resistance under high-stress conditions. This study investigates the effects of polypropylene and polyacrylonitrile fibers, at varying [...] Read more.
Fiber reinforcement offers a promising solution to improve the mechanical performance and durability of cement-based foam backfill (CFB), addressing critical issues such as brittleness and poor crack resistance under high-stress conditions. This study investigates the effects of polypropylene and polyacrylonitrile fibers, at varying contents and lengths, on the mechanical and flow properties of CFB. A series of experiments, including slump tests, rheology analysis, uniaxial compressive strength (UCS) tests, pore structure analysis, and scanning electron microscopy (SEM), were conducted to comprehensively evaluate fiber reinforcement mechanisms. The results show that increasing fiber content and length reduced fluidity due to fiber entanglement, while significantly enhancing mechanical properties through anchoring effects and network formation. After 28 days of curing, UCS increased by 208.2% with 2 wt% polypropylene fibers and 215.3% with 1 wt% polyacrylonitrile fibers (both at 6 mm length). Fiber-reinforced CFB demonstrated improved structural integrity and crack resistance, with failure modes transitioning from brittle to ductile. These findings highlight the potential of fiber-reinforced CFB to deliver durable, crack-resistant, and efficient mine backfill solutions, contributing to enhanced safety and sustainability in underground mining operations. Full article
(This article belongs to the Special Issue Metallurgy Waste Used for Backfilling Materials)
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<p>Polypropylene fiber and polyacrylonitrile fiber: (<b>a</b>) PP3; (<b>b</b>) PP6; (<b>c</b>) PP12; (<b>d</b>) PAN6; (<b>e</b>) PAN12.</p>
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<p>(<b>a</b>) XRD patterns of raw aluminum dross and (<b>b</b>) aluminum dross after calcination at 950 °C. Yobs represents the observed diffraction intensity as a function of the scattering angle (2θ). Ycal refers to the calculated diffraction intensity obtained through the Rietveld refinement process. Yobs-Ycal denotes the difference between the observed and calculated intensities, providing a visual representation of the fitting accuracy. Rwp (Weighted Profile R-factor) quantifies the goodness-of-fit in the Rietveld refinement. Calcium carbonate—CaCO<sub>3</sub>; calcium oxide—CaO; magnesium oxide—MgO; rhönite—Al<sub>4</sub>Ca<sub>2</sub>Mg<sub>4</sub>O<sub>20</sub>Si<sub>20</sub>Ti<sub>2</sub>; titanium oxide—TiO<sub>2</sub>; silica—Si; sodium chloride—NaCl; aluminum nitride—AlN; aluminum—Al; corundum—Al<sub>2</sub>O<sub>3</sub>; spinel—MgAl<sub>2</sub>O<sub>4</sub>; silicon—SiO<sub>2</sub>; gehlenite—Ca<sub>2</sub>AlSi<sub>2</sub>O<sub>7</sub>; calcium tetra aluminum oxide—CaAl<sub>4</sub>O<sub>7</sub>; calcium aluminum oxide—Ca<sub>12</sub>Al<sub>14</sub>O<sub>33</sub>.</p>
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<p>Fresh CFB samples: (<b>a</b>) N; (<b>b</b>) PP3-1.0; (<b>c</b>) PP6-0.5; (<b>d</b>) PP6-1.0; (<b>e</b>) PP6-2.0; (<b>f</b>) PP12-1.0; (<b>g</b>) PAN6-0.5; (<b>h</b>) PAN6-1.0; (<b>i</b>) PAN6-2.0; (<b>j</b>) PAN12-1.0.</p>
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<p>Relationship between the spread diameter of CFB slurry and fiber content.</p>
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<p>Relationship between shear stress and shear rate: (<b>a</b>) different fiber contents; (<b>b</b>) different fiber lengths.</p>
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<p>Relationship between apparent viscosity of CFB and shear rate. (<b>a</b>) Different fiber contents; (<b>b</b>) different fiber lengths.</p>
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<p>Force–displacement curves of FCFB samples at 3 d, 7 d, and 28 d hydration.</p>
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<p>Force–displacement curves of FCFB samples at 3 d, 7 d, and 28 d hydration.</p>
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<p>The relationship between the strength characteristics of CFB and the curing age and fiber. (<b>a</b>) Different fiber contents; (<b>b</b>) different fiber types.</p>
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<p>SEM micrographs illustrating the microscopic effects of fiber types on CFB samples: (<b>a</b>) polypropylene fibers with lengths of 3 mm, 6 mm, and 12 mm; (<b>b</b>) polyacrylonitrile fibers with lengths of 6 mm and 12 mm.</p>
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<p>SEM micrographs showing the microscopic effects of fiber content on CFB samples: (<b>a</b>) fiber contents of 0.5 wt%, 1.0 wt%, and 2.0 wt% for polypropylene fibers; (<b>b</b>) fiber contents of 0.5 wt%, 1.0 wt%, and 2.0 wt% for polyacrylonitrile fibers.</p>
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<p>CFB surface hydration products.</p>
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<p>Map of elements of hydration products.</p>
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<p>Failure modes of 10 sample groups after 28-day compressive strength testing: (<b>a</b>) N; (<b>b</b>) PP3-1.0; (<b>c</b>) PP6-0.5; (<b>d</b>) PP6-1.0; (<b>e</b>) PP6-2.0; (<b>f</b>) PP12-1.0; (<b>g</b>) PAN6-0.5; (<b>h</b>) PAN6-1.0; (<b>i</b>) PAN6-2.0; (<b>j</b>) PAN12-1.0.</p>
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<p>Pore throat size distribution of CFB: (<b>a</b>) different fiber contents; (<b>b</b>) different fiber types.</p>
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18 pages, 5889 KiB  
Article
Glass Fiber-Reinforced Polypropylene Composites with High Solar Reflectance for Thermal Insulation Applications
by Csenge Vámos and Tamás Bárány
Polymers 2025, 17(3), 274; https://doi.org/10.3390/polym17030274 - 22 Jan 2025
Viewed by 52
Abstract
Reflective thermal insulation layers can offer an energy-efficient strategy for preventing temperature rises by reflecting sunlight on surfaces. Our previous study presented a novel solvent-based method to prepare porous polypropylene (PP) with high solar reflectivity. However, the stiffness and strength of the neat [...] Read more.
Reflective thermal insulation layers can offer an energy-efficient strategy for preventing temperature rises by reflecting sunlight on surfaces. Our previous study presented a novel solvent-based method to prepare porous polypropylene (PP) with high solar reflectivity. However, the stiffness and strength of the neat porous PP were insufficient for thermal insulation applications, as mechanical loads from installation and environmental factors limit the applicability of such products. This paper addresses this gap by applying our solvent-based surface modification technology to glass fiber (GF)-reinforced PP composite sheets, creating a previously unexplored system. While the enhanced modulus and strength aligned with expectations, the micro- and nano-structured porous outer layers situated below the skin layer of the sheets, the refractive index mismatch between the PP matrix and the GF, and the size of the GF delivered a notable advancement in reflective thermal insulation performance. The combined effect of 30 wt% GF, nucleating agents, and surface modification resulted in a highly porous surface layer featuring spherulite sizes of 0.5–2.0 μm. With these combined effects, we achieved a modulus value of ~4 GPa, a tensile strength of 60 MPa, and an average solar reflectance of up to 94%. Thermal insulation performance measurements demonstrated that the registered inner temperature was lower by 24.1 °C compared to neat PP sheets. These combined effects demonstrate the potential of our solvent-based surface modification technology to develop cost-effective, porous PP composite sheets for efficient reflective thermal insulation. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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<p>Schematic diagram of the apparatus for testing the reflective thermal insulation performance.</p>
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<p>SEM images showing the cross-section of an extruded GFPP 30 sheet at (<b>a</b>) 100× magnification and at (<b>b</b>) 500× magnification. The (<b>c</b>) GFPP 20, (<b>d</b>) GFPP 30, and (<b>e</b>) GFPP 40 sheets after solvent treatment at 125 °C for 60 s at 200× magnification.</p>
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<p>SEM images showing the cross-section of an extruded GFPP 30 sheet at (<b>a</b>) 100× magnification and at (<b>b</b>) 500× magnification. The (<b>c</b>) GFPP 20, (<b>d</b>) GFPP 30, and (<b>e</b>) GFPP 40 sheets after solvent treatment at 125 °C for 60 s at 200× magnification.</p>
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<p>The thickness of the porous layers of the solvent-treated neat PP, GFPP, and NA GFPP 30 samples as a function of the solvent penetration depth. The samples were solvent-treated at 125 °C for (<b>a</b>) 60 s, (<b>b</b>) 120 s, and (<b>c</b>) 180 s.</p>
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<p>TSR of the solvent-treated samples as a function of porous layer thickness. The samples were solvent-treated at 125 °C for (<b>a</b>) 60 s, (<b>b</b>) 120 s and (<b>c</b>) 180 s.</p>
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<p>(<b>a</b>) Temperature tracking during the laboratory-based sun test and (<b>b</b>) final temperatures inside the boxes.</p>
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<p>The recorded temperature of NA GFPP 30_60 s, ambient air, and neat PP.</p>
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<p>Typical stress–strain curves of solvent-treated (<b>a</b>) PP and (<b>b</b>) GFPP samples.</p>
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<p>The effects of fiber content and immersion time on (<b>a</b>) the stiffness and (<b>b</b>) the tensile strength of the solvent-treated samples.</p>
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<p>The effects of fiber content, NA, and immersion time on (<b>a</b>) the stiffness and (<b>b</b>) the tensile strength of solvent-treated samples.</p>
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<p>Perforation energy of the solvent-treated composite samples.</p>
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21 pages, 6058 KiB  
Article
Determination of Compressive Stress Limits for Tightened Plastic Components up to 3 mm in Bolted Joints Applicable in the Automotive Industry
by Zuzana Murčinková, Rudolf Holíček, Petr Baron and Martin Onufer
Polymers 2025, 17(3), 268; https://doi.org/10.3390/polym17030268 - 21 Jan 2025
Viewed by 185
Abstract
This paper addresses the analysis of compressive stress limit values of plastic components with a thickness of no more than 3 mm used in bolted joints, especially in the automotive industry. The results of the compression tests show that the compressive stress limit [...] Read more.
This paper addresses the analysis of compressive stress limit values of plastic components with a thickness of no more than 3 mm used in bolted joints, especially in the automotive industry. The results of the compression tests show that the compressive stress limit values often exceed the tensile stress limit values specified in the material data sheets, which has a significant impact on the way in which reliable bolted joints are designed without the risk of plastic deformation. In addition to compression tests, stress tests involving axial force and torque (combined load typical for bolted joints) were also performed. Th results of both types of tests were compared in the final table, involving a comparison of yield strength under compression and yield strength under a combined load with yield strength and/or stress at break from material data sheets, estimated using tensile stress tests. Various plastic materials were tested, including Acrylonitrile Butadiene Styrene (ABS), Polyamide (PA), Polyoxymethylene (POM), Polypropylen (PP) and the glass fiber-reinforced materials. The tests showed that it is possible to exceed the tensile stress limit in material data sheets by 5 to 10% without plastic deformation and by approximately 50%, in some cases by 280%, when loading by pure compression. Considering the combined load, the compressive stress limit values are within the range of 95 to 224% of tensile stress limits. The results of the study contribute to the optimization of the plastic tightened components design and reduce the need for excessive testing in automotive production. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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<p>Test sample of Hostaform<sup>®</sup> C9021 XAP<sup>®</sup>2.</p>
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<p>Shaft for axial force transmission during compressive stress test.</p>
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<p>The plastic sample compressive stress test.</p>
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<p>Graphical representation of the course of testing the sample no. 1—ABS material.</p>
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<p>Graphical representation of the course of testing the sample no. 1—PP01 COBA A184.</p>
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<p>Graphical representation of the course of testing the sample no. 1—Tecnoprene<sup>®</sup> VK6LE NERO900.</p>
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<p>Diagram of the testing under implementation of axial force and torque.</p>
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<p>The stress test involving axial force and torque.</p>
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<p>Detail of the sample before the test and damage to the sample.</p>
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<p>Graphical representation of testing the sample no. 1 of ABS material—compressive stress and torsion test (combined load).</p>
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<p>Graphical representation of testing the sample no. 1 of the PP01 COBA A184—stress and torsion test (combined load).</p>
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<p>Graphical representation of testing the sample no. 1 of Tecnoprene<sup>®</sup> VK6LE NERO900—stress test involving axial force and torque.</p>
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12 pages, 1379 KiB  
Article
Fabrication of High-Strength Waste-Wind-Turbine-Blade-Powder-Reinforced Polypropylene Composite via Solid-State Stretching
by Bo Tan, Xiaotong Wang, Zhilong Pu, Shuangqiao Yang and Min Nie
Sustainability 2025, 17(3), 840; https://doi.org/10.3390/su17030840 - 21 Jan 2025
Viewed by 289
Abstract
In recent years, wind energy has emerged as one of the fastest-growing green technologies globally, with projections indicating that decommissioned wind turbine blades (WTBs) will accumulate to millions of tons by the 2030s. Due to their thermosetting nature and high glass/carbon fiber content, [...] Read more.
In recent years, wind energy has emerged as one of the fastest-growing green technologies globally, with projections indicating that decommissioned wind turbine blades (WTBs) will accumulate to millions of tons by the 2030s. Due to their thermosetting nature and high glass/carbon fiber content, the efficient recycling of WTBs remains a challenge. In this study, we utilized solid-state shear milling (S3M) to produce a fine WTB powder, which then underwent surface modification with a silane coupling agent (KH550), and we subsequently fabricated WTB-reinforced polypropylene (PP) composites with enhanced mechanical performance through solid-state stretching. The stretching-process-induced orientation of the PP molecular chains and glass fibers led to orientation-induced crystallization of PP and significant improvements in the mechanical properties of the PP/WTB@550 composites. With 30 wt. % WTB content, the PP/WTB@550 composite achieved a tensile strength of 142.61 MPa and a Young’s modulus of 3991.19 MPa at a solid-state stretching temperature of 110 °C and a stretching ratio of 3, representing increases of 268% and 471%, respectively, compared to the unstretched sample. This work offers both theoretical insights and experimental evidence supporting the high-value recycling and reuse of WTBs through a cost-effective, environmentally friendly, and scalable approach. Due to the enhanced mechanical properties of the PP/WTB composite and the intrinsic waterproofing and corrosion resistance of PP, it is hoped that such a composite would be used in road engineering and building materials, such as geogrids, wall panels, floor boards, and floor tiles. Full article
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<p>Schematic fabrication of PP/WTB@550 samples.</p>
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<p>(<b>a</b>) Size distribution and (<b>b</b>) SEM image of S3M-treated WTB powder.</p>
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<p>The tensile properties of the composite after solid-phase stretching and the fracture after solid-phase stretching.</p>
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<p>The tensile properties of PP/WTB composites at different draw rates.</p>
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<p>SEM of the cross-section of the composites along the tensile direction at 110 °C (<b>a</b>,<b>d</b>), 130 °C (<b>b</b>,<b>e</b>) (The red circle indicated the non-oriented structure caused by the intensified thermal motion of the molecular chain, which led to the deorientation of some oriented structures), and 150 °C (<b>c</b>,<b>f</b>).</p>
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<p>Corresponding SAXS patterns of PP/WTB@550-30 at 110 °C (<b>a</b>), 130 °C (<b>b</b>), and 150 °C (<b>c</b>).</p>
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<p>(<b>a</b>) Tensile properties, (<b>b</b>) DSC curves, and (<b>c</b>,<b>d</b>) dynamic mechanical spectra of composites at different solid-state stretching temperatures.</p>
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<p>(<b>a</b>) Tensile properties and (<b>b</b>,<b>c</b>) dynamic mechanical spectra of composites with different draw ratios.</p>
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31 pages, 9721 KiB  
Article
Investigation of the Mechanical Properties and Durability of Fiber-Reinforced Geopolymer Mortars Containing Metakaolin and Glass Powder
by Mir Alimohammad Mirgozar Langaroudi, Mohammad Mohtasham Moein, Ashkan Saradar and Moses Karakouzian
Infrastructures 2025, 10(2), 25; https://doi.org/10.3390/infrastructures10020025 - 21 Jan 2025
Viewed by 408
Abstract
The increasing global emphasis on sustainable construction practices has spurred significant international research into developing durable and eco-friendly concrete materials. This study investigates the potential of metakaolin and glass powder as supplementary aluminosilicate materials in slag- based geopolymer mortars, aiming to enhance their [...] Read more.
The increasing global emphasis on sustainable construction practices has spurred significant international research into developing durable and eco-friendly concrete materials. This study investigates the potential of metakaolin and glass powder as supplementary aluminosilicate materials in slag- based geopolymer mortars, aiming to enhance their mechanical properties and durability. To further improve the performance, polypropylene fibers were incorporated at various dosages. Therefore, 13 mixtures of geopolymer mortar based on blast furnace slag have been developed. The control mix does not contain fibers or slag replacement materials, whereas in the other formulations, glass powder and metakaolin have been employed as substitutes for slag at weight percentages (relative to the weight of slag) of 5% and 10%, separately and in combination. Additionally, the fiber-containing samples are divided into two groups based on the volume percentage of polypropylene fibers, comprising 0.2% and 0.4%. The results of the investigation show that the use of glass powder, particularly at a replacement percentage of 10%, leads to an improvement in the 28-day compressive strength. Furthermore, the mixes containing glass powder demonstrated higher flexural strength compared to those containing metakaolin, irrespective of the volume percentage of fibers. The best performance in the rapid chloride permeability test is associated with the mix containing a combination of glass powder and metakaolin at a replacement percentage of 10%. Satisfactory results have been obtained when using fibers at volume percentages of 0.2% and 0.4%. Additionally, this study utilized a fuzzy inference system to predict compressive strength. The results indicate that, by considering uncertainties, the compressive strength of the mortar can be predicted with an error of less than 1% without the need for complex mathematical calculations. Full article
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<p>Geopolymer Mortar/Concrete: (<b>a</b>) Process of creation; (<b>b</b>) Conceptual model of geopolymerization; (<b>c</b>) Comparison with conventional concrete/mortar; (<b>d</b>) Efflorescence in geopolymer materials.</p>
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<p>Methodology.</p>
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<p>Granulation curve of used sand.</p>
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<p>The experimental setup for measuring electrical resistivity.</p>
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<p>Rapid Chloride Migration Test (RCMT).</p>
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<p>Inputs and outputs in the FL model.</p>
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<p>Compressive strength results: (<b>a</b>) 7 days; (<b>b</b>) 28 days.</p>
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<p>Changes in compressive strength at 7 and 28 days.</p>
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<p>(<b>a</b>) Flexural strength results. (<b>b</b>) Flexural strength changes.</p>
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<p>(<b>a</b>) Electrical resistivity results. (<b>b</b>) Electrical resistivity changes.</p>
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<p>(<b>a</b>) Final water absorption results, (<b>b</b>) Final water absorption changes.</p>
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<p>(<b>a</b>) RCMT results. (<b>b</b>) Variation in RCMT results.</p>
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<p>Regression results for different tests. (<b>a</b>) Compressive and flexural strength. (<b>b</b>) Electrical resistivity and final water absorption. (<b>c</b>) Electrical resistivity and RCMT.</p>
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<p>Experimental results and compressive strength predictions using the FL model: (<b>a</b>) 7 days, (<b>b</b>) 28 days.</p>
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<p>Measurement error using the FL model.</p>
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<p>The correlation of the measured and predicted compressive strengths: (<b>a</b>) 7 days, (<b>b</b>) 28 days.</p>
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18 pages, 3492 KiB  
Article
Physical Foam Injection Molding of Cellulose Fiber Reinforced Polypropylene by Using CO2: Parameter Variation and Comparison to Chemical Foam Injection Molding
by Claudia Pretschuh, Matthias Mihalic, Christian Sponner, Thomas Lummerstorfer, Andreas Steurer and Christoph Unterweger
J. Compos. Sci. 2025, 9(1), 50; https://doi.org/10.3390/jcs9010050 - 20 Jan 2025
Viewed by 433
Abstract
The use of cellulose fiber-filled polypropylene (PP) composites in combination with foam injection molding has enabled the lightweight design of injection-molded parts. The study provides achievements for the physical foam injection molding (MuCell®) process of PP–cellulose fiber compounds by using CO [...] Read more.
The use of cellulose fiber-filled polypropylene (PP) composites in combination with foam injection molding has enabled the lightweight design of injection-molded parts. The study provides achievements for the physical foam injection molding (MuCell®) process of PP–cellulose fiber compounds by using CO2 as the direct foaming agent, including a comparison of MuCell® foaming with N2 and a comparison to a chemical foaming process. Weight and density reductions, foam structure and specific mechanical properties are highly dependent on the applied processing parameters. The maximum weight reduction reached values of up to 16%, and density reduction even reached 33% in relation to the compact plates. The extent of weight and density reduction could be adjusted, among other factors, by a reduction in the shot volume. Setting the density reduction to 22% allowed for simultaneously decreasing weight while sustaining the specific flexural properties and limiting the loss of specific impact strength. By using optimized FIM parameters, the mechanical performance could be improved, with specific modulus values even outperforming the compact reference sample. This presents a significant benefit for the preparation of lightweight products and sets the basis for further optimization and modeling studies. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2024)
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<p>Research design and aim of the present study.</p>
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<p>Reduction in weight of several PP–cellulose plates prepared with MuCell<sup>®</sup> FIM with CO<sub>2</sub> and N<sub>2</sub>, and with chemical FIM for the complete plates (y-axis) and for the middle part of the plate (x-axis). The line represents equal values for weight reduction in the middle and complete plates.</p>
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<p>Flexural modulus (<b>a</b>) and flexural strength (<b>b</b>) of the PP–cellulose plates prepared using FIM.</p>
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<p>Specific flexural modulus (<b>a</b>) and specific flexural strength (<b>b</b>) of the PP–cellulose plates, prepared using FIM in relation to a compact reference. Error bars represent the 95% confidence interval.</p>
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<p>Charpy impact strength, notched (<b>a</b>) and unnotched (<b>b</b>) of PP–cellulose plates, prepared using FIM.</p>
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<p>Charpy impact strength, specific, notched (<b>a</b>) and unnotched (<b>b</b>), of PP–cellulose plates, prepared using FIM in relation to a compact reference. Error bars represent a 95% confidence interval.</p>
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<p>Microscopy images of foamed PP–cellulose. MuCell<sup>®</sup> with CO<sub>2</sub>: Sample 1 (<b>a</b>), Sample 5 (<b>b</b>), Sample 6 (<b>c</b>) and Sample 7 (<b>d</b>); MuCell<sup>®</sup> with N<sub>2</sub>: Sample 10 (<b>e</b>) and Sample 16, derived using chemical FIM (<b>f</b>).</p>
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19 pages, 8711 KiB  
Article
Production and Characterization of H. perforatum Oil-Loaded, Semi-Resorbable, Tri-Layered Hernia Mesh
by Özlem Eğri, Feyza Güneş and Sinan Eğri
Polymers 2025, 17(2), 240; https://doi.org/10.3390/polym17020240 - 19 Jan 2025
Viewed by 383
Abstract
Hernia repair is the most common surgical operation applied worldwide. Mesh prostheses are used to support weakened or damaged tissue to decrease the risk of hernia recurrence. However, the patches currently used in clinic applications have significant short-term and long-term risks. This study [...] Read more.
Hernia repair is the most common surgical operation applied worldwide. Mesh prostheses are used to support weakened or damaged tissue to decrease the risk of hernia recurrence. However, the patches currently used in clinic applications have significant short-term and long-term risks. This study aimed to design, produce, and characterize a three-layered semi-resorbable composite hernia mesh using the electrospinning technique, where the upper layer (parietal side) was made of non-resorbable polypropylene (PP-Cl) fibers, the partially resorbable middle layer was made of PP-Cl and polycaprolactone (PCL) fibers, and the fully resorbable lower layer (visceral side) was made of H. perforatum oil-loaded polyethylene glycol (PEG) fibers. The extracellular matrix-like fibrous structure of the patches provided low density and high porosity, minimizing the risk of long-term foreign body reactions, and the hydrophilic/hydrophobic character of the surfaces and the detected swelling rates supported biocompatibility. The patches exhibited mechanical properties comparable to commercially available products. Controlled release of therapeutic oil could be achieved from the oil-integrated patches due to the dissolution of PEG in the acute process. In vitro cell culture studies with the L929 mouse fibroblast cell line revealed that the meshes do not have a cytotoxic nor a biomaterial-induced necrotic effect that will induce apoptosis of the cells. The visceral side of the meshes exhibited non-adherence of cell-like structures to the surface due to the dissolution of PEG. The composite hernia patches were concluded to reduce the risk of adhering to internal organs in the hernia area, have the potential to be used in in vivo biomedical applications, and will support the search for an ideal hernia mesh that can be used in the treatment of abdominal hernias. Full article
(This article belongs to the Topic Advanced Biomaterials: Processing and Applications)
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<p>Schematic representation of tri-layered hernia mesh production.</p>
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<p>ATR-FTIR spectra of patches (0 and 1), polymers used in the production of patches (PP−Cl, PCL, PEG), and <span class="html-italic">H. perforatum</span> oil.</p>
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<p>SEM images of patch 0. (<b>A</b>) and (<b>B</b>) are upper (parietal) layer 5000× and 500× magnifications; (<b>C</b>) and (<b>D</b>) are lower (visceral) layer 10,000× and 500× magnifications.</p>
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<p>SEM images of patch 1. (<b>A</b>) and (<b>B</b>) are upper (parietal) layer 5000× and 500× magnifications; (<b>C</b>) and (<b>D</b>) are lower (visceral) layer 10,000× and 500× magnifications.</p>
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<p>Swelling ratios of patches (0 and 1) over time.</p>
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<p>Mass loss of the patches (0 and 1) over time.</p>
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<p>Calibration curve at 225 nm (<b>left</b>); release profile from patch 1 for <span class="html-italic">H. perforatum</span> (<b>right</b>).</p>
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<p>Cytotoxic, apoptotic, and necrotic effects on L929 mouse fibroblast cells.</p>
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<p>SEM images at different magnifications of patches (patches 0 and 1) cultivated with L929 mouse fibroblast cells: (<b>A</b>) patch 0 220×; (<b>B</b>) patch 0 400×; (<b>C</b>) patch 1 200×; (<b>D</b>) patch 1 450×.</p>
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14 pages, 2307 KiB  
Article
Quantitative Analysis of Yield Stress and Its Evolution in Fiber-Reinforced Cemented Paste Backfill
by Shili Hu, Jingping Qiu, Qingsong Zhang, Zhenbang Guo and Chen Liu
Minerals 2025, 15(1), 81; https://doi.org/10.3390/min15010081 - 16 Jan 2025
Viewed by 278
Abstract
Fiber-reinforced cemented paste backfill (FR-CPB) has attracted considerable attention in modern mining applications due to its superior mechanical properties and adaptability. Despite its potential, understanding its rheological behavior remains limited, largely because of the absence of quantitative methods for assessing fiber packing behavior [...] Read more.
Fiber-reinforced cemented paste backfill (FR-CPB) has attracted considerable attention in modern mining applications due to its superior mechanical properties and adaptability. Despite its potential, understanding its rheological behavior remains limited, largely because of the absence of quantitative methods for assessing fiber packing behavior within CPB. This study develops a rheology-based approach to determine the maximum packing fraction of polypropylene fibers in fresh CPB, revealing that shorter fibers (3 mm) achieve a maximum packing fraction of 0.661, significantly higher than longer fibers (12 mm) with 0.534. Building on these findings, a quantitative model for the static yield stress of FR-CPB was developed, showing that under a high fiber content (0.9%) and with longer fibers (12 mm), the yield stress reached 274.34 kPa, a 40% increase compared to shorter fibers. Additionally, the study modeled the time-dependent evolution of yield stress, achieving a prediction accuracy with a correlation coefficient of 0.92. These advancements enable the optimization of FR-CPB composition, which can reduce material usage, enhance pipeline transport efficiency, and improve backfill stability in underground voids. By minimizing the risk of structural failure and optimizing resource allocation, this research provides a theoretical foundation for safer and more cost-effective mining operations. Full article
(This article belongs to the Special Issue Advances in Mine Backfilling Technology and Materials)
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<p>(<b>a</b>) Evolution of floc morphology with shear stress (adapted from [<a href="#B36-minerals-15-00081" class="html-bibr">36</a>]). (<b>b</b>) Evolution of <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>ϕ</mi> </mrow> <mrow> <mi>f</mi> <mi>m</mi> <mi>e</mi> <mi>f</mi> <mi>f</mi> </mrow> </msub> <mfenced separators="|"> <mrow> <mi>τ</mi> </mrow> </mfenced> </mrow> </semantics></math> with shear stress (adapted from [<a href="#B29-minerals-15-00081" class="html-bibr">29</a>]).</p>
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<p>(<b>a</b>) Flow curves of FR-CPB varying in fiber dosages (<math display="inline"><semantics> <mrow> <msub> <mrow> <mi>ϕ</mi> </mrow> <mrow> <mi>f</mi> <mn>1</mn> </mrow> </msub> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>ϕ</mi> </mrow> <mrow> <mi>f</mi> <mn>2</mn> </mrow> </msub> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>ϕ</mi> </mrow> <mrow> <mi>f</mi> <mn>3</mn> </mrow> </msub> </mrow> </semantics></math>) under stress ramp-up tests [<a href="#B29-minerals-15-00081" class="html-bibr">29</a>]; (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>ϕ</mi> </mrow> <mrow> <mi>f</mi> <mi>m</mi> <mi>e</mi> <mi>f</mi> <mi>f</mi> </mrow> </msub> <mfenced separators="|"> <mrow> <msub> <mrow> <mi>τ</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msub> </mrow> </mfenced> </mrow> </semantics></math> corresponding to the fiber configuration under <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>τ</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msub> </mrow> </semantics></math> [<a href="#B29-minerals-15-00081" class="html-bibr">29</a>]; (<b>c</b>) determination of <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>ϕ</mi> </mrow> <mrow> <mi>f</mi> <mi>m</mi> </mrow> </msub> </mrow> </semantics></math> [<a href="#B29-minerals-15-00081" class="html-bibr">29</a>].</p>
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<p>(<b>a</b>) XRD results of the gold tailings used. (<b>b</b>) Particle size distribution of the tailings and cement used.</p>
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<p>Acquisition of rheological data for FR-CPB: (<b>a</b>) yield stress; (<b>b</b>) yield stress evolution rate.</p>
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<p>(<b>a</b>) Evolution of <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>ϕ</mi> </mrow> <mrow> <mi>f</mi> <mi>m</mi> <mi>e</mi> <mi>f</mi> <mi>f</mi> </mrow> </msub> <mfenced separators="|"> <mrow> <mi>τ</mi> </mrow> </mfenced> </mrow> </semantics></math> of different fibers with shear stress. (<b>b</b>) Relationship between fiber aspect ratio and maximum packing fraction.</p>
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<p>(<b>a</b>) Effect of fiber length and content on the yield stress of CPB. (<b>b</b>) Comparison between Sultangaliyeva model predictions and actual yield stress values. (<b>c</b>) Comparison of calculated yield stress and experimental yield stress.</p>
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<p>(<b>a</b>) Maximum packing fraction of combined fibers. (<b>b</b>) Comparison of calculated yield stress and experimental yield stress.</p>
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<p>(<b>a</b>) Effect of fiber length and content on yield stress evolution rate of FR-CPB within 2 h. (<b>b</b>) Variation in relative yield stress and relative yield stress evolution rate with relative fiber volume fraction. (<b>c</b>) Comparison of calculated yield stress evolution rates and experimental yield stress evolution rates.</p>
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17 pages, 5096 KiB  
Article
Effect of Polypropylene and Straw Fiber Materials on the Unconfined Compressive Strength of Tailings and Wasted Stone Mixed Backfill
by Xiuzhi Shi, Yuan Shi, Xin Chen and Wenyang Wang
Materials 2025, 18(2), 392; https://doi.org/10.3390/ma18020392 - 16 Jan 2025
Viewed by 267
Abstract
Ensuring the mechanical performance of backfill materials while reducing cementation costs is a key challenge in mine backfill research. To address this, fiber materials such as polypropylene (PP) fiber and rice straw (RS) fiber have been incorporated into cement-based mixtures for mine backfilling. [...] Read more.
Ensuring the mechanical performance of backfill materials while reducing cementation costs is a key challenge in mine backfill research. To address this, fiber materials such as polypropylene (PP) fiber and rice straw (RS) fiber have been incorporated into cement-based mixtures for mine backfilling. This study investigates the effects of PP and RS fibers on the mechanical properties, flow characteristics, and microstructure of Tailings and Wasted Stone Mixed Backfill (TWSMB). A series of orthogonal experiments were designed to evaluate the influence of variables, including the cement–sand ratio, solid mass concentration, wasted stone mass concentration, fiber content, and fiber length on the TWSMB properties. The results indicate that the influence of cement–sand ratio and solid mass concentration have a more significant impact on strength than fibers, though the fibers show a stronger effect than the wasted stone mass concentration. Both fiber types enhanced the strength of the specimens, with PP fiber exhibiting a stronger reinforcing effect than RS fiber. Furthermore, the effect of PP fiber content was more pronounced than that of fiber length, whereas the opposite trend was observed for RS fiber. The optimum fiber parameter levels were determined for each type: PP fiber performed best at a mass concentration of 1.5% and a length of 6 mm, while RS fiber showed optimal performance at a mass concentration of 1.0% and a length of 5–10 mm. Macroscopic damage analysis indicated that the structural integrity and residual compressive strength of the TWSMB specimens were preserved even after surpassing the ultimate compressive strength, due to the crack-bridging effect of the fibers. Microstructural analysis showed that PP fiber-reinforced specimens exhibited a dense structure formed through reactions with other hydration products. In contrast, the surface of RS fibers was nearly fully encapsulated by hydration products, resulting in the formation of a physical skeleton structure. This study provides new insights into minimizing cement consumption and reducing backfilling costs in mining operations. Full article
(This article belongs to the Special Issue Research on Alkali-Activated Materials (Second Edition))
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<p>Rod-mill tailings preparation process.</p>
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<p>Cumulative particle size distribution of graded tailings and rod-mill tailings.</p>
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<p>PP fiber and RS fiber: (<b>a</b>) PP fiber, (<b>b</b>) RS fiber.</p>
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<p>Specimens preparation process.</p>
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<p>The diffusivity of slurry: (<b>a</b>) unreinforced, (<b>b</b>) PP fiber-reinforced, (<b>c</b>) RS fiber-reinforced.</p>
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<p>The UCS of specimens: (<b>a</b>) Unreinforced specimens, (<b>b</b>) PP fiber-reinforced specimens, (<b>c</b>) RS fiber-reinforced specimens.</p>
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<p>Macroscopic failure of different specimens at different curing times; figure (<b>a</b>–<b>c</b>) show the stress–strain curves of different specimens at 3 d, 7 d, and 28 d, respectively.</p>
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<p>A, B, and E factors influence the results of orthogonal test of unreinforced, PP fiber-reinforced, and RS fiber-reinforced specimens.</p>
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<p>Orthogonal test results of PP fiber-reinforced and RS fiber-reinforced specimens influenced by five factors.</p>
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<p>SEM images of specimens under different magnifications: (<b>a-1</b>, <b>a-2</b> and <b>a-3</b>) are images of unreinforced specimens magnified 3000×, 10,000×, and 20,000×, respectively; (<b>b-1</b>, <b>b-2</b> and <b>b-3</b>) are images of PP fiber-reinforced specimens magnified 3000×, 10,000×, and 20,000×, respectively; (<b>c-1</b>, <b>c-2</b> and <b>c-3</b>) are images of RS fiber-reinforced specimens magnified 1000×, 5000×, and 10,000×, respectively.</p>
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22 pages, 5905 KiB  
Article
Properties of High-Strength Concrete Incorporating Calcined Diatomaceous Earth, Polypropylene, and Glass Fibers
by Muttaqin Hasan, Yulius Rief Alkhaly, Hamzani, Rijalul Fikri and Taufiq Saidi
Buildings 2025, 15(2), 225; https://doi.org/10.3390/buildings15020225 - 14 Jan 2025
Viewed by 383
Abstract
This study was aimed at determining the hardened and fresh properties as well as the high-temperature resistance of high-strength concrete (HSC) produced by incorporating diatomaceous earth, polypropylene, and glass fibers. CDE (calcined diatomaceous earth) was employed as a 10% cement replacement, while polypropylene [...] Read more.
This study was aimed at determining the hardened and fresh properties as well as the high-temperature resistance of high-strength concrete (HSC) produced by incorporating diatomaceous earth, polypropylene, and glass fibers. CDE (calcined diatomaceous earth) was employed as a 10% cement replacement, while polypropylene and glass fibers were added separately to the mixtures at 0.2, 0.4, 0.6, 0.8, and 1.0% volumetric contents. Moreover, the mixtures without using CDE and fibers were used as references. The concrete mixtures were fabricated, followed by the determination of the fresh concrete flow, the absorption capacity, and the flexural, compressive, and splitting tensile strengths of hardened concrete. Furthermore, the specimens fabricated for the hardened concrete were exposed to temperatures of 400 °C, 500 °C, and 600 °C, and the remaining compressive strength was examined. The findings suggested that the incorporation of polypropylene and glass fibers in HSC with CDE enhanced the compressive, flexural, and splitting tensile strengths by 23.4 and 32.6%, 70.0 and 83.5%, and 18.9 and 17.9%, respectively. Moreover, the inclusion of polypropylene and glass fibers reduced the absorption of hardened concrete. Meanwhile, the inclusion of CDE lowered the strengths and increased the absorption. It was further identified that the incorporation of CDE enhanced the resistance of HSC to high temperatures, while polypropylene and glass fibers lowered the resistance. The incorporation of CDE, polypropylene, and glass fibers also lowered the flow of fresh concrete. Full article
(This article belongs to the Special Issue Research on Mechanical Properties of Cement and Concrete)
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<p>Particle size distribution of OPC and CDE.</p>
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<p>XRD pattern of CDE.</p>
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<p>CDE microphotograph.</p>
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<p>Gradation of aggregates.</p>
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<p>Fibers: (<b>a</b>) polypropylene and (<b>b</b>) glass.</p>
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<p>Flow speed of fresh HSC with (<b>a</b>) polypropylene fiber and (<b>b</b>) glass fiber.</p>
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<p>HSC compressive strength with (<b>a</b>) polypropylene and (<b>b</b>) glass fibers.</p>
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<p>Flexural strength of HSC with (<b>a</b>) polypropylene and (<b>b</b>) glass fibers.</p>
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<p>Splitting tensile strength of HSC with (<b>a</b>) polypropylene and (<b>b</b>) glass fibers.</p>
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<p>Modulus of elasticity of HSC with (<b>a</b>) polypropylene and (<b>b</b>) glass fibers.</p>
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<p>Absorption of HSC with (<b>a</b>) polypropylene and (<b>b</b>) glass fibers.</p>
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<p>Compressive strength after exposure to high temperatures of HSC containing polypropylene fiber (<b>a</b>) without and (<b>b</b>) with CDE.</p>
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<p>Compressive strength after exposure to high temperatures of HSC containing glass fiber (<b>a</b>) without and (<b>b</b>) with CDE.</p>
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<p>Remaining compressive strength after exposure to high temperatures of HSC containing polypropylene fiber (<b>a</b>) without and (<b>b</b>) with CDE.</p>
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<p>Remaining compressive strength after exposure to high temperatures of HSC containing glass fiber (<b>a</b>) without and (<b>b</b>) with CDE.</p>
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31 pages, 4220 KiB  
Article
Improving the Long-Term Mechanical Properties of Thermoplastic Short Natural Fiber Compounds by Using Alternative Matrices
by Renato Lemos Cosse, Tobias van der Most, Vincent S. D. Voet, Rudy Folkersma and Katja Loos
Biomimetics 2025, 10(1), 46; https://doi.org/10.3390/biomimetics10010046 - 13 Jan 2025
Viewed by 509
Abstract
Wood plastic composites (WPCs) offer a means to reduce the carbon footprint by incorporating natural fibers to enhance the mechanical properties. However, there is limited information on the mechanical properties of these materials under hostile conditions. This study evaluated composites of polypropylene (PP), [...] Read more.
Wood plastic composites (WPCs) offer a means to reduce the carbon footprint by incorporating natural fibers to enhance the mechanical properties. However, there is limited information on the mechanical properties of these materials under hostile conditions. This study evaluated composites of polypropylene (PP), polystyrene (PS), and polylactic acid (PLA) processed via extrusion and injection molding. Tests were conducted on tensile and flexural strength and modulus, heat deflection temperature (HDT), and creep analysis under varying relative humidity conditions (10% and 90%) and water immersion, followed by freeze—thaw cycles. The addition of fibers generally improved the mechanical properties but increased water absorption. HDT and creep were dependent on the crystallinity of the composites. PLA and PS demonstrated a superior overall performance, except for their impact properties, where PP was slightly better than PLA. Full article
(This article belongs to the Special Issue Advances in Biomaterials, Biocomposites and Biopolymers 2024)
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<p>Differences in preparation between (<b>A</b>) PLA1+F35, (<b>B</b>) PLA1+MA+DCP+F35, and (<b>C</b>) PLA1+G-MA+F35. MA and DCP are amplified 10×.</p>
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<p>Macro-scale wetting of wood fibers by the polymer matrix. (<b>A</b>) PLA1+F17.5; (<b>B</b>) PLA1+F35; (<b>C</b>) PLA1+C35; (<b>D</b>) PLA2+F35; (<b>E</b>) PLA1+MA+DCP+F35; (<b>F</b>) PLA1+G-MA+F35.</p>
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<p>Side-by-side images of all the injection-molded samples.</p>
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<p>Water absorption behavior of submerged tensile bars fabricated from neat polymers and compatibilized polymer composites.</p>
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<p>Water absorption of submersed PLA1, PLA2, and their respective composite tensile bars for 28 days. The composites that underwent the test were PLA2+F35, PLA1+G-MA+F35, PLA1+MA+DCP+F35, PLA1+F35, PLA1+C35, and PLA1+F35.</p>
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<p>Tensile modulus of pure polymers and compatibilized compounds under various moisture.</p>
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<p>Tensile strength of pure polymers and compatibilized compounds under various moisture conditions.</p>
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<p>Tensile modulus of pure PLA and PLA compounds under various moisture conditions.</p>
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<p>Tensile strength of pure PLA and PLA compounds under various moisture conditions.</p>
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<p>Flexural creep of pure polymers and their compatibilized compounds.</p>
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<p>Flexural creep of PLA and PLA-based composites.</p>
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<p>Flexural creep of crystallized PLA and PLA compounds compared to that of the PP composite.</p>
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17 pages, 4894 KiB  
Article
Study on the Improvement Effect of Polypropylene Fiber on the Mechanical Properties and Freeze–Thaw Degradation Performance of High Fly Ash Content Alkali-Activated Fly Ash Slag Concrete
by Zhu Yuan, Yanmin Jia and Junming Xu
Polymers 2025, 17(2), 175; https://doi.org/10.3390/polym17020175 - 13 Jan 2025
Viewed by 421
Abstract
This article systematically investigated the improvement effect of polypropylene fiber (PPF) on the mechanical and freeze–thaw properties of alkali-activated fly ash slag concrete (AAFSC) with high fly ash content and cured at room temperature. Fly ash and slag were used as precursors, with [...] Read more.
This article systematically investigated the improvement effect of polypropylene fiber (PPF) on the mechanical and freeze–thaw properties of alkali-activated fly ash slag concrete (AAFSC) with high fly ash content and cured at room temperature. Fly ash and slag were used as precursors, with fly ash accounting for 80% of the total mass. A mixed solution of sodium hydroxide and sodium silicate was used as alkali activator, and short-cut PPF was added to improve the performance of AAFSC. Firstly, the strength characteristics of AAFSC at different curing ages were studied. Then, key indicators such as morphology, residual compressive strength, weight loss, relative dynamic modulus of elasticity (RDME), and pore characteristics of AAFSC after different freeze–thaw cycles were tested and analyzed. The strength performance analysis showed that the optimal dosage of PPF was 0.90%. When the alkali equivalent of the alkali activator was increased from 4% to 6%, the frost resistance of AAFSC could be improved. Furthermore, adding 0.90% PPF could increase the freeze–thaw cycle number of AAFSC by about 50 times (measured by RDME). With the increase in freeze–thaw cycles, the porosity of AAFSC increased, the fractal dimension decreased, and the proportion of harmless and less harmful pores decreased, while the proportion of harmful and multiple harmful pores increased. The relationship model between the porosity and compressive strength of AAFSC after freeze–thaw cycles was established. Full article
(This article belongs to the Special Issue Polymers in Civil Engineering)
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<p>Concrete specimens cured at room temperature. (<b>a</b>) Cube specimens with dimensions of 100 mm × 100 mm × 100 mm. (<b>b</b>) Prism specimens with dimensions of 100 mm × 100 mm × 400 mm.</p>
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<p>Rapid freeze–thaw test equipment for concrete.</p>
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<p>RDME tester for concrete.</p>
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<p>Compressive strength of AAFSC without fiber addition.</p>
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<p>Compressive strength of AAFSC mixed with PPF.</p>
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<p>Flexural strength of AAFSC without fiber addition.</p>
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<p>Flexural strength of AAFSC mixed with PPF.</p>
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<p>Morphology of freeze–thaw failure of A4M1.</p>
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<p>Morphology of freeze–thaw failure of A6M1.</p>
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<p>Morphology of freeze–thaw failure of A6M1PPF0.90.</p>
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<p>Compressive strength of AAFSC after freeze–thaw cycles.</p>
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<p>Weight loss of AAFSC during freeze–thaw cycles.</p>
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<p>RDME ratio of AAFSC after freeze–thaw cycles.</p>
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<p>Relationship between freeze–thaw times of AAFSC and porosity and fractal dimension.</p>
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<p>Compressive strength and porosity of AAFSC after freeze–thaw cycles.</p>
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<p>Distribution of pore size of AAFSC after freeze–thaw cycles.</p>
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18 pages, 4050 KiB  
Article
Influence of the Thermoplastic Fiber Ratio on the Mechanical Properties of Recycled Carbon Fibers During the Carding Process
by Jean Ivars, Ahmad Rashed Labanieh and Damien Soulat
Materials 2025, 18(2), 302; https://doi.org/10.3390/ma18020302 - 10 Jan 2025
Viewed by 423
Abstract
This study investigates the impact of carding and blending recycled carbon fibers (rCF) with crimped thermoplastic polypropylene (PP) fibers on the mechanical properties of rCF, using a Weibull statistical approach. Tensile properties of rCF were evaluated before and after carding with varying rCF/PP [...] Read more.
This study investigates the impact of carding and blending recycled carbon fibers (rCF) with crimped thermoplastic polypropylene (PP) fibers on the mechanical properties of rCF, using a Weibull statistical approach. Tensile properties of rCF were evaluated before and after carding with varying rCF/PP blend ratios (100/0%, 85/15%, 70/30%, and 50/50%). A comparison between the two-parameter and three-parameter Weibull models showed that the two-parameter model provided a better fit for rCF properties before carding. The results show that adding crimped PP fibers during carding helps to decrease the stress-at-break disparity and move their distribution to higher values. Furthermore, a slight increase in tensile modulus was observed in carded rCF, with higher PP ratios associated with smaller scatter modulus distributions. Elongation at break remained consistent, with the Weibull modulus increasing slightly with carding and the inclusion of PP fibers, indicating improved consistency. Overall, carding rCF with PP fibers helped in the mechanical property uniformity of the resulting carded webs without compromising tensile performance. This work shows the potential of the carding process with or without thermoplastic fibers to efficiently realign and give continuity to discontinuous recycled carbon fibers. Full article
(This article belongs to the Topic Advanced Composites Manufacturing and Plastics Processing)
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<p>Carding machine schema.</p>
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<p>Carded web with a mix of PP and rCF.</p>
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<p>Cross-section of rCF before carding (<b>left</b>), diameter measurement of rCF before tensile testing (<b>right</b>).</p>
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<p>Weibull model evaluation for rCF before carding.</p>
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<p>Stress-at-break boxplots for different blending ratios.</p>
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<p>Weibull two-parameter probability plot—stress at break.</p>
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<p>Weibull two-parameter probability plot—tensile modulus.</p>
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<p>Heatmap for Weibull modulus on the tensile modulus.</p>
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<p>Fiber pull-out from tuft during carding.</p>
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<p>Weibull two-parameter probability plot—elongation at break.</p>
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21 pages, 4146 KiB  
Article
How Reducing Fossil-Based Plastic Use Can Help the Overall Sustainability of Oyster Farming: The Case of the Gulf of La Spezia
by Daniela Summa, Elena Tamisari, Mattia Lanzoni, Giuseppe Castaldelli and Elena Tamburini
Resources 2025, 14(1), 10; https://doi.org/10.3390/resources14010010 - 8 Jan 2025
Viewed by 440
Abstract
Oyster farming plays a crucial role in sustainable food production due to its high nutritional value and relatively low environmental impact. However, in a scenario of increasing production, it is necessary to consider the issue of plastic use as a limitation to be [...] Read more.
Oyster farming plays a crucial role in sustainable food production due to its high nutritional value and relatively low environmental impact. However, in a scenario of increasing production, it is necessary to consider the issue of plastic use as a limitation to be addressed. A life cycle assessment (LCA) was conducted on oyster farming in La Spezia (Italy) as a case study, utilizing 1 kg of packaged oysters as the functional unit. Fossil-based plastics and wooden packaging were identified as the primary environmental concerns. To analyze potential strategies for reducing the environmental impact of oyster farming, alternative scenarios were considered wherein fossil-based materials were replaced with bio-based materials. Specifically, this study examined the substitution of the current packaging, consisting of a wooden box and a polypropylene (PP) film, with a fully recyclable PP net. Additionally, polylactic acid (PLA), polyhydroxyalkanoates (PHAs), and bio-based polyethylene terephthalate (Bio-PET) were proposed as alternatives to virgin high-density polyethylene (HDPE) and PP for buoys, oyster bags, and boxes. Among the scenarios analyzed, the sole effective strategy to reduce the impact of plastics on the process is to replace them with PHA. In the other cases, the high energy consumption of their non-optimized production renders them disadvantageous options. However, the assessment must include the effects of degradation that traditional plastics can have in the marine environment, an aspect that potentially renders natural fibers more advantageous. The use of PP net packaging has demonstrated high efficacy in reducing impacts and provides a foundation for considering the need to combine sustainability and marketing with current legislation regarding food packaging. Full article
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<p>Oyster farming area in (scale 143 m/cm). (<b>a</b>) Northwest Italy and (<b>b</b>) the gulf of La Spezia, (scale 1:600) [modified from Google Earth, 2024].</p>
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<p>Scheme (plan view) of a single module in the longline plant.</p>
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<p>Contribution (%) of farming phases (<b>a</b>) and processes (<b>b</b>) involved in S0, considering 1 kg of oysters as the functional unit.</p>
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<p>Contribution (%) of farming phases (<b>a</b>) and processes (<b>b</b>) involved in S0, considering 1 kg of oysters as the functional unit.</p>
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<p>Impact variation (%) in scenarios S1, S2, S3, and S4 in relation to scenario S0 (the asterisk indicates a value more than 100%).</p>
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<p>Impact variation (%) in scenarios S5 and S6 in relation to scenario S0 (the asterisks indicate a value more than 100%).</p>
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<p>Impact variation (%) in scenario S7 in relation to scenario S0.</p>
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17 pages, 6537 KiB  
Article
Development of Acoustic Insulating Carpets from Milkweed Fibers Using Air-Laid Spike Process
by Deborah Lupescu, Mathieu Robert and Said Elkoun
Fibers 2025, 13(1), 4; https://doi.org/10.3390/fib13010004 - 7 Jan 2025
Viewed by 413
Abstract
Fibers from milkweed, which grows in Quebec (Canada), offer a distinct and outstanding advantage compared to other natural fibers: their ultra-lightweight hollow structure provides excellent acoustic and thermal insulation properties for the automobile industry. To highlight the properties of milkweed fibers and reduce [...] Read more.
Fibers from milkweed, which grows in Quebec (Canada), offer a distinct and outstanding advantage compared to other natural fibers: their ultra-lightweight hollow structure provides excellent acoustic and thermal insulation properties for the automobile industry. To highlight the properties of milkweed fibers and reduce the use of synthetic materials in vehicles, nonwoven carpeting made from a blend of milkweed fibers and polylactic acid (PLA) fibers was produced using the air-laid process. Some of the nonwovens were compressed to investigate the effects of increased mass per unit area on their thermal, acoustic, and mechanical properties. The nonwovens’ mass per unit area, thermal insulation, sound absorption coefficient, airflow resistivity, compression, and resistance to moisture were evaluated and compared to other carpets made of natural and synthetic fibers. The findings indicate that milkweed and PLA carpets have lower thermal conductivity values of 37.45 (mW/m·K), (mW/m·K) less than carpets made from cotton and polypropylene. At low frequencies, none of the carpets absorbed sound. At high frequencies, milkweed and PLA carpets showed sound absorption values of at least 0.6, which provide better acoustic insulation than nonwoven materials made from jute and polyethylene (PE) fibers. Milkweed and PLA carpets exhibited better compression values than polypropylene (PP) carpets. Full article
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<p>Milkweed fiber.</p>
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<p>The manufacturing process of nonwoven mats and carpets using the air-laid process.</p>
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<p>Carpets.</p>
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<p>Steps to calculate the compression resistance and recovery (ASTM D6571-22).</p>
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<p>SEM images of milkweed fibers from (<b>a</b>) UC nonwoven, (<b>b</b>) C1, (<b>c</b>) C2, (<b>d</b>) C3, (<b>e</b>) C4, and (<b>f</b>) C5.</p>
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<p>The sound absorption coefficient versus the frequency for the nonwoven and the carpets.</p>
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<p>Sound absorption coefficient values versus the frequency for the nonwoven and the carpets with and without a 30 mm deep cavity, (<b>a</b>) the UC nonwoven, (<b>b</b>) C1, (<b>c</b>) C2, (<b>d</b>) C3, (<b>e</b>) C4, (<b>f</b>) C5.</p>
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<p>Sound absorption coefficient values versus the frequency for carpets with the same thickness of 8.65 mm.</p>
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<p>Airflow resistivity values versus (<b>a</b>) density and (<b>b</b>) porosity.</p>
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